%A Yoshizawa,Akina %A Feula,Antonio %A Leach,Andrew G. %A Male,Louise %A Fossey,John S. %D 2018 %J Frontiers in Chemistry %C %F %G English %K Azetidine,Ligand,Platinum,Palladium,complex,pyrrolidine %Q %R 10.3389/fchem.2018.00211 %W %L %M %P %7 %8 2018-June-21 %9 Original Research %# %! Azetidine complexes %* %< %T Palladium and Platinum 2,4-cis-amino Azetidine and Related Complexes %U https://www.frontiersin.org/articles/10.3389/fchem.2018.00211 %V 6 %0 JOURNAL ARTICLE %@ 2296-2646 %X Seven N,N'-palladium(II) chloride complexes, one N,N'-palladium(II) acetate complex of 2,4-cis-azetidines where prepared and analyzed by single crystal XRD. Two platinum(II) chloride N,N'-complexes of 2,4-cis-azetidines where prepared and analyzed by single crystal XRD. Computational analysis and determination of the %Vbur was examined conducted. A CNN' metallocyclic complex was prepared by oxidative addition of palladium(0) to an ortho bromo 2,4-cis-disubstituted azetidine and its crystal structure displays a slightly pyramidalized metal-ligand orientation.