High-Performance Solid Composite Polymer Electrolyte for all Solid-State Lithium Battery Through Facile Microstructure Regulation

Solid composite polymer electrolytes are the optimal candidate for all solid-state lithium batteries, because of their enhanced ionic conductivities, long-life cycle ability and compatibility to lithium anode. Herein, we reported a kind of solid composite polymer electrolyte comprised of poly(ethylene oxide), graphitic-like carbon nitride and lithium perchlorate, which was prepared by a facile solution blending method. Microstructure of the solid composite polymer electrolyte was regulated by thermal annealing and interaction among components and was characterized by XRD, DSC, FTIR-ATR, and ROM. The obtained solid composite polymer electrolyte achieved an ionic conductivity as high as 1.76 × 10−5 S cm−1 at 25°C. And the electrochemical stable window and the lithium ion transference number, t+, were also obviously enhanced. LiFePO4/Li solid-state batteries with the annealed PEO-LiClO4-g-C3N4 solid polymer electrolyte presented a high initial discharge capacity of 161.2 mAh g−1 and superior cycle stability with a capacity retention ratio of 81% after 200 cycles at 1C at 80°C. The above results indicates that the thermal annealing treatment and g-C3N4 as a novel structure modifier is crucial for obtaining the high-performance solid composite polymer electrolytes used in the all solid-state lithium battery.


INTRODUCTION
During recent years, high-energy-density storage batteries are urgently needed to satisfy the increasing demand in electric vehicles, consumer electronics and grid energy storage (Manthiram et al., 2017;Fan et al., 2018). Lithium metal secondary batteries have been considered as the potential candidate for high-energy-density storage batteries, since lithium metal anode possessed the highest theoretical specific capacity (3,862 mAh g −1 ) and the lowest reduction potential (−3.04V VS. standard hydrogen electrode) (Shen et al., 2018;Wu et al., 2018). Moreover, lithium metal used as the anode can even act as the lithium source in the battery with non-lithiated materials such as sulfur or oxygen as the cathode to achieve higher storage capacity compared to the current commercial lithium-ion batteries (Pan et al., 2019). However, practical and large-scale development of lithium metal batteries with liquid electrolytes is limited by safety concerns and the rapid capacity attenuation and short cycling capability . During the charge-discharge process of lithium metal secondary batteries with organic liquid electrolytes, the propensity of faster lithium dendrites formation was resulted from the plating and stripping of Li ions on the anode, which would result in the capacity attenuation and poor cycling capability and short-circuit of cells.
In order to further develop the practical use of lithium metal as anode, scientists made great efforts to solve the lithium dendrites problems and achieved much progress on suppressing dendrite formation and growth Nie et al., 2018;Shen et al., 2018;Wu et al., 2018;Pan et al., 2019). Strategies such as electrolyte modification, multifunctional barriers, composite metallic lithium electrode, and 3D current collectors were proposed to suppress the formation of Lithium dendrites Xiao et al., 2018). Replacement of current organic liquid electrolytes with the solid-state electrolytes is considered as the most promising way to realize excellent performance of lithium metal secondary batteries (Goodenough, 2018;Nie et al., 2018). Because the organic liquid electrolyte is flammable, toxic and environmental contamination, solidstate electrolytes are therefore of crucial importance because of their excellent safety and mechanical ability for dendritic growth inhibition (Ban et al., 2018). And all solid-state lithium metal batteries are widely regarded as promising candidates for next generation of energy storage devices with improved energy density and superior safety performances.
Solid-state electrolytes are generally divided into inorganic superionic conductors (or the solid ceramic electrolytes) and solid polymer electrolytes. Compared with the inorganic superionic conductors, solid polymer electrolytes, benefiting from shape versatility, flexibility, light weight and low processing costs, are being investigated as promising candidates to replace currently available organic liquid electrolytes in lithium metal batteries (Bae et al., 2018b), . However, due to the inherent low ionic conductivity at RT and poor mechanical property of solid polymer electrolytes, polymer-based solid composite electrolytes taking advantage of the merits of both inorganic and polymeric materials have been attracting more and more attention in all solid-state lithium metal battery applications (Tan et al., 2018). And Poly(ethylene oxide) (PEO) based solid composite electrolytes were widely considered as promising candidates solid electrolytes for high energy density lithium metal batteries (Xue et al., 2015;Tan et al., 2018). Numerous fillers were added into the PEO-based composite solid electrolyte to improve the ionic conductivity and the interfacial properties in contact with the electrodes (Tan et al., 2018). And it was the simplest method to achieve the composite polymer electrolyte, whose physical properties can be easily controlled by compositional change (Tan et al., 2018;Xiao et al., 2018;). However, the particle agglomeration especially at high concentration of fillers would inhibit the further improvement of properties of the solid polymer electrolyte. New kind of effective filler or percolated nanofiller structure needs to be developed by researchers.
Graphitic-like carbon nitride (g-C 3 N 4 ) is a stacked 2D structure, which was mainly composed of carbon, nitrogen and a few residual -NH 2 or -NH groups, and was metal-free and lightweight (Wang et al., 2012;Shi et al., 2014). And its intrinsic polarity and semiconductor property may be helpful to modulate the spatial and interface distribution of ionic charge carriers (Hu et al., 2017). These properties make g-C 3 N 4 a potential candidate as polymer electrolyte filler for all-in-solid lithium batteries. Shi et al. proved that the introduction of 6.0 wt% g-C 3 N 4 nanosheets in the sodium alginate (SA) nanocomposite films could greatly enhance the thermal stability and mechanical properties of SA biopolymer electrolyte nanocomposite films (Shi et al., 2014). Hu et al. reported about a kind of composite electrolyte with bis(triffuoromethanesulfonimide) lithium salt (LiTFSI), di(ethylene glycol) dimethyl ether (DGM) and g-C 3 N 4 , which was used to suppress lithium dendrite growth during cycling and improve the long-term cycling property of the composite electrolyte (Hu et al., 2017). But quantitative and even qualitative descriptions of the interactions between separate components of the state electrolyte system are still lacking. Understanding of the different interactions in the system and its influence on the microstructure and final electrochemical properties of the solid composite polymer electrolyte is crucial for achieving high performance solid polymer electrolyte.
In this article, we present for the very first time, to the best of our knowledge, the addition of g-C 3 N 4 as fillers in PEO and its influence on the lithium ionic dissociation in lithium perchlorate (LiClO 4 ) and transport and the crystallization of PEO in solid composite polymer electrolytes. Thermal annealing treatment and the interactions regulation among components by addition of g-C 3 N 4 were introduced to tailor the microstructure of the solid composite polymer electrolyte. And through controlling the microstructure of solid composite polymer electrolytes, excellent improvement of the desired physical and chemical properties and electrochemical properties was achieved. When the weight percent of g-C 3 N 4 was 10%, the annealed solid composite polymer electrolyte gave the best performance in the all solidstate lithium battery with lithium metal as the anode and LiFePO 4 as the cathode.
Preparation of g-C 3 N 4 The g-C 3 N 4 filler was synthesized by thermal polymerization as we reported in the previous article . Twenty gram of urea was put into a crucible with a cover in the muffle furnace. And then the crucible was heated to 580 • C to stay for 4 h, with a heating rate of 3 • C/min. And the powder product was in light yellow color. The detailed characterization of pure g-C 3 N 4 was displayed in Figures S1, S3.

Solid Composite Polymer Electrolyte Films Preparation
Firstly, the prepared g-C 3 N 4 filler was ultrasonic dispersed in ACN. Then PEO and LiClO 4 (molar ratio of ethylene oxide (EO) to LiClO 4 is 15:1) were added into the solution under stirring, in order to obtain uniform mixture solution. The weight percentage of g-C 3 N 4 compared to PEO was controlled as 0, 5, 10, 15, and 20%, respectively. The mixture solution was casted into a homemade Teflon mold and dried in the vacuum oven at 40 • C for 48 h. And the above mentioned state polymer electrolytes films were firstly annealed at 120 • C for 2 h and then quenched to RT before use. In contrast, the state polymer electrolyte films were also prepared without thermal annealing process. The thickness of obtained solid state polymer electrolyte films was regulated to about 100 µm. And the state polymer electrolytes films were cut into rounds with diameter of 19 mm before loaded into the glovebox.

Characterization
Bruker Vertex 70 FTIR spectrometer with Access ATR TM attachment was used to characterize the composition of samples. The melting temperature of PEO in samples was collected by a differential scanning calorimeter (DSC, Mettler DSC823e) under nitrogen atmosphere. Samples with a mass of 5∼10 mg were sealed into aluminum crucible, and then heated at a rate of 10 • C/min. X-ray powder diffraction (XRD) patterns were collected by a XRD-6000 (Shimazu, Japan) X-Ray diffractometer equipped with Cu K α radiation in the range of 5∼50 • at a scanning rate of 4 • /min. The reflection optical microscopy (ROM) observations were performed with a Leica DM2500P optical microscope equipped with a C-5050ZOOM camera. The ionic conductivity of SPEs was measured by electrochemical impedance spectroscopy (EIS) by using a Princeton PARSTAT 4000A (AMETEK) electrochemical workstation over frequency range from 1 to 10 5 Hz with an applied voltage of 10 mV. The measured SPEs were sandwiched between two stainless steel electrodes, which were assembled into CR2025 coin cells. And the temperature was controlled by an oven in the range of 25∼120 • C. The electrochemical stability window was determined by linear sweep voltammetry (LSV) by a Princeton PARSTAT 4000A (AMETEK) electrochemical workstation. The cell was assembled by sandwiching SPEs between a stainless steel and lithium metal (SS/SPE/Li) as the counter and reference electrode, respectively. And the measurement was cycled from 2.0 to 6.0 V (VS. Li/Li + ) at a scan rate of 10 mV/S. The lithium transference number (t + ) was tested in a symmetric cell (Li/SPE/Li) by chronoamperometry combined with electrochemical impedance spectroscopy according to the method provided by Bruce et al. (Evans et al., 1987). In order to characterize the battery performances, the prepared state polymer electrolytes were fabricated as CR2025 coin-type cells with lithium metal anode and LiFePO 4 cathode. And LiFePO 4 was blended with carbon black (Super-P) and poly(vinylidene fluoride) at a weight ratio of 8:1:1 with NMP as the solvent. The weight of cathode used in the test was controlled to about 2.40 mg. As a result, the weight of active material was about 1.92 mg. The battery performances of coin cells were examined at 80 • C using a Battery Testing System (NEWARE CT-4008, Shenzhen, China), including cycle property and C-rate capability (0.1, 0.2, 0.5, 1, 2, and 5C). The cut-off voltages were chosen as 4.2 V (charge) and 2.5 V (discharge) during the charge-discharge cycle performance.

Microstructure Regulation by Thermal Annealing and Interaction Among Components in Solid Composite Polymer Electrolytes
In order to avoid the effect of thermal history on the crystallization of PEO during the solid composite polymer electrolyte preparation process to an extreme, 120 • C annealing and then quenching method was introduced, as shown in Figure 1. And we have reported on this preparation method in detail in a previous work . During the solid polymer electrolyte preparation process, samples were firstly dried at 40 • C for 48 h, which would provide an isothermal crystallization condition for PEO. As a result, the crystallinity of PEO in the samples was high. However, when the sample was quenching from the amorphous state, the non-isothermal crystallization might happened, which gave a lower crystallinity of PEO in the sample. And this deduction was further proved by the following XRD and DSC results.
In order to clarify the influence of thermal annealing and the interaction among components of the solid composite polymer electrolyte on the microstructure of solid composite polymer electrolytes, XRD was used to characterize the crystallization of samples as shown in Figure 2. As shown in Figure 2Aa, pure g-C 3 N 4 gave a typical diffraction peak at 27.5 • , which was the typical peak of (002) crystal plane of g-C 3 N 4 . Moreover, the interlamellar spacing of g-C  (120) and (132)/(032)/(212)/(112) crystal planes of PEO, respectively . It was obvious that the intensity of typical diffraction peak of PEO at Furthermore, the diffraction peaks of crystalline phase and amorphous phase in XRD patterns were fitted by the Jade 6.0 software. And the crystallization degree of PEO in samples was calculated by divided the summation of peak areas of crystallization phase and amorphous phase by the summation of peak areas of crystalline phase. Therefore, the crystallization degree of PEO was decreased from about 15.49% to about 8%, when the solid composite polymer electrolyte was thermal treated. This result demonstrated that the thermal annealing process could greatly suppress the crystallization of PEO.
As shown in Figure 2B, the intensity of diffraction peak observed at 27.5 • increased with the content of g-C 3 N 4 increasing. Figures 2Ba-e showed that intensity of typical peaks of PEO crystals was firstly decreased and then increased due to the addition of g-C 3 N 4 , with a minimum value appeared in the solid composite polymer electrolyte with 10% g-C 3 N 4 . Moreover, when the content of g-C 3 N 4 was chosen as 0, 5, 10, 15, and 20%, the crystallization degree of PEO was calculated as about 28,25,8,19, and 20%, respectively. It was obvious that the introduction of g-C 3 N 4 could significantly decrease the crystallinity of PEO. But the crystallization degree of PEO was firstly decreased and then increased as the content of g-C 3 N 4 increased, with a minimum value in the solid composite polymer electrolyte with 10% g-C 3 N 4 . In the state polymer electrolyte, the porous microstructure of g-C 3 N 4 sheets (as shown in Figure S1) might serve as the hard limitation and inhibit the ordered chain arrangement of PEO, while on the other hand also serve as the nucleation sites for PEO chains. As a result, the heterogeneous nucleation could be enhanced, when the content of g-C 3 N 4 sheets was over 10%, which would improve the crystallization of PEO. Furthermore, the g-C 3 N 4 nanosheets might change the priority growth of PEO crystal planes, as shown by the relative intensity of fitting peaks at 19.3 • and 23.4 • in Figures 2Ba,e. It implied that the interaction between g-C 3 N 4 and PEO could greatly influence the crystallization preference of crystal planes in PEO.
The effect of thermal annealing and the interaction among components of the solid composite polymer electrolyte on the crystallization of PEO was further proved by DSC. As shown in Figures 3Aa,b the melting temperature of PEO was decreased from 52.4 to 48.7 • C, when the state polymer electrolyte was annealed at 120 • C and then quenched to RT. Also shoulder peak appeared at 46.0 • C in Figure 3Aa. It meant that PEO crystals in the sample undergone thermal annealing formed lamellae with thinner thickness and the thickness of lamellae gave a wider distribution. It implied that the thermal annealing process could regulate the crystallization of PEO.
Furthermore, the melting behavior of PEO in PEO homopolymer, PEO-LiClO 4 electrolyte and the solid composite polymer electrolytes with different content of g-C 3 N 4 (5, 10, 15, and 20%), which were treated by the thermal annealing process, was displayed in Figure 3B. Due to the interaction between PEO chains and LiClO 4 , the melting temperature of PEO crystals decreased from 66.7 to 53.3 • C, as shown in Figures 3Ba,b. Moreover, the addition of g-C 3 N 4 further restrained the crystallization of PEO, as shown in Figures 3Bc-f. The melting temperature of PEO crystals in the solid composite polymer electrolyte was 51.5, 48.7, 52.3, and 53.1 • C, respectively, with the content of g-C 3 N 4 increasing from 5 to 20%. The melting temperature of PEO firstly decreased and then increased, with a minimum value of 48.7 • C in the sample with 10% g-C 3 N 4 . Also the crystallinity of PEO was calculated by dividing the melting enthalpy obtained from DSC curves in Figure 3B by the equilibrium enthalpy of PEO fusion (197 J/g). And the crystallinity of PEO in different samples shown in Figure 3B was about 54, 25, 22, 7, 18, and 20%, respectively. With the addition of LiClO 4 , the coordination effect of EO unit and Li + would decrease the crystallization of PEO. Moreover, the introduction of g-C 3 N 4 further decreased the crystallization of PEO. The residual -NH 2 or -NH groups presenting in g-C 3 N 4 can act as active sites for hydrogen bonding with ether oxygen in PEO.  And the hydrogen bonds formation restrained the chain folding of PEO, and then reduced the crystallinity of PEO in the solid composite polymer electrolytes. On the other hand, the existence of g-C 3 N 4 also served as the heterogeneous nucleation sites for PEO crystallization. As a result, the crystallinity degree of PEO firstly decreased and then increased slightly in the solid composite electrolytes, with 10% as the optimum content. This result was in good accordance with the foregoing XRD results.
The influence of thermal annealing and the interaction among components of the solid composite polymer electrolyte on the microstructure morphology of solid composite polymer electrolyte was observed by ROM. Perfect spherulites with diameter of about 100 µm were formed in the solid PEO-LiClO 4 polymer electrolyte, as observed in Figure 4a. Figures 4b-e showed that the morphology perfection and the crystal's size and number of PEO obviously changed with the content of g-C 3 N 4 . PEO spherulites were firstly disappeared and then re-formed with the weight percent of g-C 3 N 4 increasing, with 10% as a critical content. It was ascribed to the hydrogen bonding interaction between g-C 3 N 4 and PEO that could inhibit the crystallization of PEO, while g-C 3 N 4 could also serve as the heterogeneous nucleation sites for PEO. Therefore, when the content of g-C 3 N 4 was over 10%, more and more spherulites were formed in the sample. It implied that the interaction between PEO and g-C 3 N 4 could greatly affect the morphology of the solid composite polymer electrolyte.
Moreover, compared Figure 4c with Figure 4f, the thermal annealing treatment might greatly change the morphology of PEO crystals from spherulites to lamellae stack. It demonstrated that the thermal treatment also influenced the morphology of the solid composite polymer electrolyte. The morphology of the solid composite polymer electrolyte was tailored by the thermal treatment and the interactions among components in the sample. And the morphology would play an important role in the compatibility between solid electrolytes and electrodes. Uniformly distributed PEO crystals might control the nucleation of lithium, which would help to inhibit the lithium dendrite formation.

Effects of Interaction Among Components in Solid Composite Polymer Electrolytes on the Lithium Salt Dissociation
FTIR spectra of PEO, pure g-C 3 N 4 , the PEO-LiClO 4 solid polymer electrolyte and the PEO-LiClO 4 -g-C 3 N 4 solid composite polymer electrolyte were shown in Figure S4. And the typical band of LiClO 4 was identified at 624 cm −1 . In order to study the effect of g-C 3 N 4 on the dissociation of LiClO 4 in the solid composite polymer electrolytes, FTIR-ATR spectra in the range of 610-650 cm −1 were carefully analyzed. It was reported that the peaks at ∼624 and ∼635 cm −1 were assigned to the dissociated free anion and the bonded ion pair in LiClO 4 , respectively, Lin et al. (2016). As shown in Figure 5, the absorbance peak of dissociated free anion shifted from 624 to 623 cm −1 , as the weight percent of g-C 3 N 4 increased to 15%. It demonstrated that the vibration energy level transition of free ClO − 4 was easier, due to the interaction of g-C 3 N 4 and LiClO 4 . It is because the residual -NH 2 and -NH could coordinate with the lithium ion, which would accelerate the dissociation of LiClO 4 . Moreover, the relative absorbance of peaks at ∼624 and ∼635 cm −1 (labeled as A 624 /A 635 ) was obtained from curves in Figure 5. And A 624 /A 635 was 2. 24, 3.01, 4.79, 4.34, and 4.41, respectively, with the weight percent of g-C 3 N 4 increasing from 0 to 20%. It demonstrated that the introduction of g-C 3 N 4 could enhance the dissociation of LiClO 4 , with 10% as the optimum content. Also the residual -NH 2 and -NH groups in g-C 3 N 4 could form hydrogen bonds with PEO, which would limit the ordered folding of PEO chains and helped to enhance the chain segment motion. As a result, the dissociation of LiClO 4 was accelerated, due to the coordination between Li + and the ether oxygen. The above factors contributed to the separation of Li + and ClO − 4 in the solid composite polymer electrolyte. And the dissociation of LiClO 4 in the solid composite polymer electrolyte is critical for the good ionic conductivity.

Ionic Conductivity and the Electrochemical Properties of the Solid Composite Polymer Electrolytes
In order to confirm our hypothesis of the increasing conductivity by thermal annealing treatment and the addition of g-C 3 N 4 , the ionic conductivity and electrochemistry properties of the solid composite polymer electrolytes were further studied. The ionic conductivity of the solid composite polymer electrolytes with different content of g-C 3 N 4 was investigated by EIS. The Arrhenius plot of ionic conductivity with temperature from 25 to 120 • C was displayed in Figure 6. Compared with that of PEO-LiClO 4 polymer electrolyte (Figure 6e), significant improvement of ionic conductivity was observed in the annealed solid composite polymer electrolyte. Moreover, the ionic conductivity was firstly increased and then decreased at each temperature with the content of g-C 3 N 4 increasing from 5 to 20%, as shown in Figures 6a-d. The solid composite polymer electrolyte with 10% g-C 3 N 4 exhibited the maximum ionic conductivity (1.76 × 10 −5 S cm −1 ) at 25 • C, and the conductivity reached to about 1.08 × 10 −3 S cm −1 at 100 • C. And this ionic conductivity at room temperature was much higher than that of the recently reported PEO/g-C 3 N 4 /LiTFSI solid electrolytes (2.3 × 10 −6 S cm −1 , at 30 • C) (Sun et al., 2019). Also this ionic conductivity is nearly close to that (2.2 × 10 −5 S cm −1 at 28 • C) of the PEO based solid composite electrolyte, which needed LiTFSI as the lithium salt and 2D MXene as the filler (Pan et al., 2019). DSC and XRD results demonstrated that the crystallinity of PEO in the solid composite polymer electrolytes was greatly affected by the content of g-C 3 N 4 . And when the content of g-C 3 N 4 was 10%, PEO gave the minimum crystallinity degree, which was preferred for the high ionic conductivity. Besides effects on the crystallinity of PEO, the residual -NH 2 or -NH groups exited on the 2D structure of g-C 3 N 4 could coordinate with Li + . Also the porous structure might provide a potential transport path for Li + . When the content of g-C 3 N 4 was 10%, continuous percolating pathways for Li + diffusion might be formed. Nonetheless, when the content of g-C 3 N 4 was over 10%, the redundant inactive fillers would hinder lithium ionic conduction according to effective medium theory (EMT) . Moreover, the modification of PEO-LiClO 4 using inorganic nanoparticles fillers were always enslaved to the aggregation of particles, which was also harmful for the ionic conducting (Bae et al., 2018a), Evans et al. (1987). As a result, it demonstrated that the thermal annealed PEO-LiClO 4 -g-C 3 N 4 solid composite polymer electrolyte using 10% g-C 3 N 4 would give an easy way to achieve excellent ionic conductivity in the solid polymer electrolyte.  Since the PEO-LiClO 4 -10% g-C 3 N 4 gave the best ionic conductivity, it was chosen for the following electrochemical studies. The lithium ion transportation in the solid composite polymer electrolytes was studied as well. And the lithium ion transference number, t + , was analyzed according to the method provided by Bruce and coworkers (Evans et al., 1987). Figure 7 showed the relation between time and current crossing a symmetric Li/PEO-LiClO 4 /Li battery (A) and Li/PEO-LiClO 4 -10% g-C 3 N 4 /Li (B) battery polarized by a small voltage of 10 mV at 80 • C. The inset was the AC impedance spectra of the same battery before and after the polarization. And the t + can be calculated by the equation: t + = I s ( V−I 0 R 0 ) I 0 ( V−I s R s ) , where the I 0 and I s are the initial current and the steady-state current, respectively; V is the potential applied across the cell, and R 0 and R s are the initial and steady-state interfacial resistances, respectively. Therefore, the t + of the PEO-LiClO 4 electrolyte was 0.241, while the t + of the annealed PEO-LiClO 4 -g-C 3 N 4 electrolyte was 0.37. It indicated that the thermal annealing treatment coupled with the addition of g-C 3 N 4 would greatly enhance the mobility of Li + . And this result was in good accordance with the FTIR-ATR results. Effects of g-C 3 N 4 on the electrochemical stability of the solid composite polymer electrolytes were characterized by the electrochemical window analysis. The electrochemical stability window of PEO-LiClO 4 electrolyte and annealed PEO-LiClO 4 -g-C 3 N 4 electrolyte at 80 • C were measured by LSV, as shown in Figure 8. Detected current of PEO-LiClO 4 electrolyte increased sharply as the applying voltage exceeded 3.5 V, as seen from Figure 8a. But Figure 8b showed that the detected current of PEO-LiClO 4 -g-C 3 N 4 electrolyte was more stable and displayed a decomposition voltage at about 4.8 V. It implied that the annealed solid composite polymer electrolyte might guarantee a higher working voltage of electrode. And due to the interaction between g-C 3 N 4 and PEO, the stability of the solid polymer electrolyte was greatly enhanced. It was reasonable to modify the properties of PEO electrolyte through physically thermal annealing treatment and using g-C 3 N 4 as the filler.
The battery performance of all-solid-state lithium battery (LiFePO 4 /Li) based on the solid polymer electrolyte was also performed. Figure 9 showed the long-term cycling performance and coulombic efficiencies of LiFePO 4 /Li batteries assembled using the annealed state polymer electrolyte with 10% g-C 3 N 4 and PEO/LiClO 4 with a current density of 1 C at 80 • C. As shown in Figure 9A, the cell based on PEO-LiClO 4 electrolyte gave an initial discharge capacity of only 133.3 mAh g −1 , and displayed a capacity retention ratio of 80% after 115 cycles. On the other hand, Figure 9B demonstrated that the cell based on the solid composite polymer electrolyte with a capacity retention ratio FIGURE 9 | The cycling performance and coulombic efficiencies of LiFePO 4 /Li batteries assembled using PEO/LiClO 4 electrolyte (A) and using the annealed state polymer electrolyte with 10% g-C 3 N 4 (B) at 80 • C with a current density of 1 C. And the insert in (A) and (B) are typical potential VS. specific capacity profiles of the corresponding sample during the cycling performance. of 80% after 200 cycles possessed an initial discharge capacity of 161.2 mAh g −1 , which was very close to the theoretical capacity of LiFePO 4 (170 mAh g −1 ). Moreover, this cycling performance was better than the reported LiFePO 4 /Li solid-state batteries based on PEO-LiTFSI-g-C 3 N 4 polymer electrolytes, which gave an initial discharge specific capacity of 161.3 mAh g −1 but cycled for 120 cycles at 60 • C (Sun et al., 2019). The coulombic efficiency of batteries based on the solid composite polymer electrolyte during charge-discharge cycling test was as high as 99.7% in Figure 9B, which was higher than that of the battery based on the PEO-LiClO 4 electrolyte shown in Figure 9A. Moreover, the prevailing experiments using LiFePO 4 cathode in SPE based solid state lithium batteries were cycled within 3.8 V, in order to guarantee the cycle stability (Nie et al., 2018). In this article, the LiFePO 4 /Li solid battery could operate in the range of 4.2∼2.5 V and gave excellent cycle stability. Furthermore, the charge-discharge voltage profiles of the corresponding LiFePO 4 /Li solid battery during the cycling FIGURE 10 | The C-rate performance of LiFePO 4 /Li coin cells at 80 • C assembled using PEO/LiClO 4 electrolyte (A) and using annealed state polymer electrolyte with 10% g-C 3 N 4 (B). And every different C-rate was performed for 5 cycles with a charge current density of 0.1 C.
performance were displayed as the insert in Figures 9A,B. The voltage plateau at around 3.48 V was steady in Figure 9B, while a sloping voltage plateau was observed in Figure 9A. And the attenuation of specific capacity during charge-discharge cycling process was more clearly in the LiFePO 4 /Li batteries with PEO/LiClO 4 electrolyte shown in Figure 9A, compared with that in the LiFePO 4 /Li batteries with annealed PEO-LiClO 4 -g-C 3 N 4 electrolyte shown in Figure 9B. It implied that the addition of g-C 3 N 4 enhanced the electrochemical stability of PEO-based solid polymer electrolytes.
Moreover, in order to ascertain the usefulness of the solid composite polymer electrolyte, the C-rate cycling property of PEO-LiClO 4 electrolyte and the annealed PEO-LiClO 4 -g-C 3 N 4 electrolyte at 80 • C were characterized and results were shown in Figure 10. As shown in Figure 10A, the discharge specific capacity of the all solid-state battery based on the PEO-LiClO 4 electrolyte was 148.0, 150.6, 139.5, 123.1, 80.4, and 22.2 mAh g −1 , respectively, with the C-rate increasing from 0.1, 0.2, 0.5C, 1, 2 to 5C. And it was obvious that the discharge specific capacity was gradually decreased at higher C-rates, which was reported as a typical characteristic of LiFePO 4 material (Brutti et al., 2012). The low discharge specific capacity at 5C-rate was attributed to the electrode polarization and solid electrolyte interface caused by the low electronic conductivity, limited diffusion of Li + into the LiFePO 4 structure (Kumar et al., 2014). On the other hand, Figure 10B showed the performance of the battery with PEO-LiClO 4 -g-C 3 N 4 electrolyte. It delivered an initial discharge specific capacity of 161.0 mAh g −1 at 0.1C-rate. And the discharge specific capacity was 159.5, 159.7, 158.8, and 155.6 mAh g −1 , respectively, at 0.2C-rate, 0.5C-rate, 1C-rate, and 2C-rate without any obvious attenuation. The battery was even able to deliver a specific capacity of 59.7 mAh g −1 even at 5C-rate, which was 168% higher than that of the battery based on the PEO-LiClO 4 solid polymer electrolyte. Moreover, when the rate returned to 0.1C, the average discharge capacity of the battery was still as high as 157.2 mAh g −1 . Also the coulombic efficiencies were close to 100%. This result implied that the PEO-LiClO 4 -g-C 3 N 4 solid polymer electrolyte could facilitate the cycling performance of LiFePO 4 cathode, due to its good compatibility with the cathode and good lithium ionic transport capability. Moreover, the solid state battery based on the solid composite polymer electrolyte was able to light up several LED lamps under a normal condition as shown in Figure S5. It demonstrated that the annealed PEO-LiClO 4 -g-C 3 N 4 electrolyte could be an outstanding candidate used in all solid-state lithium batteries.

CONCLUSIONS
To conclude, we reported a novel method to prepare the solid polymer electrolyte with high performance using facile thermal annealing treatment and by addition g-C 3 N 4 as the modification filler. XRD and DSC results demonstrated that the crystallinity degree of PEO was greatly decreased by the thermal annealing treatment and by interaction between PEO chains and the g-C 3 N 4 filler. Moreover, the dissociation of LiClO 4 was obviously enhanced as proved by the FTIR-ATR results. The final morphology of the obtained solid composite polymer electrolyte was even changed with the content of g-C 3 N 4 increasing and changed by the thermal annealing treatment. When the weight percent of g-C 3 N 4 was 10% in the annealed solid composite polymer electrolyte, spherulites morphology of PEO crystals was totally destroyed, which would facilitate the compatibility between the solid electrolyte and electrodes. And the crystallinity of PEO was only about 8%, which was helpful for the lithium ion transport in the solid composite polymer electrolyte.
As a result, the obtained solid composite polymer electrolyte with 10% g-C 3 N 4 achieved an ionic conductivity as high as 1.76 × 10 −5 S cm −1 at 25 • C, due to the above microstructure regulation.
The electrochemical stable window was increased to about 4.8 V. The lithium ion transference number, t + , was changed from 0.24 to 0.37, and increased about 54.8%. Finally, the annealed PEO-LiClO 4 -10% g-C 3 N 4 electrolyte was also assembled into an all solid-state battery using LiFePO 4 as the cathode and lithium metal as the anode. And the battery demonstrated excellent performance, with a high initial discharge capacity of 161.2 mAh·g −1 and superior cycle stability with a capacity retention ratio of 81% after 200 cycles at 1C at 80 • C. Furthermore, the C-rate cycling results also demonstrated that the stability of the assembled solid state battery was markedly improved by using PEO-LiClO 4 -10% g-C 3 N 4 electrolyte. The above results indicates that the thermal annealing treatment and g-C 3 N 4 as a novel structure modifier provide an useful and facile way to prepare the state polymer electrolytes used in the all solid-state lithium battery.

DATA AVAILABILITY
The raw data supporting the conclusions of this manuscript will be made available by the authors, without undue reservation, to any qualified researcher.

AUTHOR CONTRIBUTIONS
LS and JY developed the concept and designed the experiment. They contributed equally to this work. XW and JY conducted the experiments. KX, GZ, and AM co-supervised the experiments. JY and LS wrote the manuscript. KX, CS, and WC helped to revise the work critically. All authors listed have made a substantial, crucial and direct contribution to the work, and approved it for publication.