TY - JOUR AU - Zhao, Yangzhi AU - Fang, Chen AU - Zhang, Guangzhao AU - Hubble, Dion AU - Nallapaneni, Asritha AU - Zhu, Chenhui AU - Zhao, Zhuowen AU - Liu, Zhimeng AU - Lau, Jonathan AU - Fu, Yanbao AU - Liu, Gao PY - 2020 M3 - Original Research TI - A Micelle Electrolyte Enabled by Fluorinated Ether Additives for Polysulfide Suppression and Li Metal Stabilization in Li-S Battery JO - Frontiers in Chemistry UR - https://www.frontiersin.org/articles/10.3389/fchem.2020.00484 VL - 8 SN - 2296-2646 N2 - The Li-S battery is a promising next-generation technology due to its high theoretical energy density (2600 Wh kg−1) and low active material cost. However, poor cycling stability and coulombic efficiency caused by polysulfide dissolution have proven to be major obstacles for a practical Li-S battery implementation. In this work, we develop a novel strategy to suppress polysulfide dissolution using hydrofluoroethers (HFEs) with bi-functional, amphiphlic surfactant-like design: a polar lithiophilic “head” attached to a fluorinated lithiophobic “tail.” A unique solvation mechanism is proposed for these solvents whereby dissociated lithium ions are readily coordinated with lithiophilic “head” to induce self-assembly into micelle-like complex structures. Complex formation is verified experimentally by changing the additive structure and concentration using small angle X-ray scattering (SAXS). These HFE-based electrolytes are found to prevent polysulfide dissolution and to have excellent chemical compatibility with lithium metal: Li||Cu stripping/plating tests reveal high coulombic efficiency (>99.5%), modest polarization, and smooth surface morphology of the uniformly deposited lithium. Li-S cells are demonstrated with 1395 mAh g−1 initial capacity and 71.9% retention over 100 cycles at >99.5% efficiency—evidence that the micelle structure of the amphiphilic additives in HFEs can prohibit polysulfide dissolution while enabling facile Li+ transport and anode passivation. ER -