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<front>
<journal-meta>
<journal-id journal-id-type="publisher-id">Front. Earth Sci.</journal-id>
<journal-title>Frontiers in Earth Science</journal-title>
<abbrev-journal-title abbrev-type="pubmed">Front. Earth Sci.</abbrev-journal-title>
<issn pub-type="epub">2296-6463</issn>
<publisher>
<publisher-name>Frontiers Media S.A.</publisher-name>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="publisher-id">764319</article-id>
<article-id pub-id-type="doi">10.3389/feart.2021.764319</article-id>
<article-categories>
<subj-group subj-group-type="heading">
<subject>Earth Science</subject>
<subj-group>
<subject>Original Research</subject>
</subj-group>
</subj-group>
</article-categories>
<title-group>
<article-title>Thrust Faults Promoted Hydrocarbon Leakage at the Compressional Zone of Fine-Grained Mass-Transport Deposits</article-title>
<alt-title alt-title-type="left-running-head">Sun et&#x20;al.</alt-title>
<alt-title alt-title-type="right-running-head">Thrust Faults Promoted Hydrocarbon Leakage</alt-title>
</title-group>
<contrib-group>
<contrib contrib-type="author" corresp="yes">
<name>
<surname>Sun</surname>
<given-names>Qiliang</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
<xref ref-type="corresp" rid="c001">&#x2a;</xref>
<uri xlink:href="https://loop.frontiersin.org/people/1453939/overview"/>
</contrib>
<contrib contrib-type="author">
<name>
<surname>Xie</surname>
<given-names>Xinong</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author">
<name>
<surname>Wu</surname>
<given-names>Shiguo</given-names>
</name>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
<uri xlink:href="https://loop.frontiersin.org/people/1225244/overview"/>
</contrib>
<contrib contrib-type="author">
<name>
<surname>Yin</surname>
<given-names>Guorui</given-names>
</name>
<xref ref-type="aff" rid="aff4">
<sup>4</sup>
</xref>
</contrib>
</contrib-group>
<aff id="aff1">
<label>
<sup>1</sup>
</label>Hubei Key Laboratory of Marine Geological Resources, China University of Geosciences, <addr-line>Wuhan</addr-line>, <country>China</country>
</aff>
<aff id="aff2">
<label>
<sup>2</sup>
</label>Laboratory for Marine Mineral Resources, Qingdao National Laboratory for Marine Science and Technology, <addr-line>Qingdao</addr-line>, <country>China</country>
</aff>
<aff id="aff3">
<label>
<sup>3</sup>
</label>Laboratory of Marine Geophysics and Georesource, Institute of Deep-sea Science and Engineering, Chinese Academy of Sciences, <addr-line>Sanya</addr-line>, <country>China</country>
</aff>
<aff id="aff4">
<label>
<sup>4</sup>
</label>PetroChina Changqing Oil Field Company, <addr-line>Xian</addr-line>, <country>China</country>
</aff>
<author-notes>
<fn fn-type="edited-by">
<p>
<bold>Edited by:</bold> <ext-link ext-link-type="uri" xlink:href="https://loop.frontiersin.org/people/1152972/overview">Adam McArthur</ext-link>, University of Leeds, United&#x20;Kingdom</p>
</fn>
<fn fn-type="edited-by">
<p>
<bold>Reviewed by:</bold> <ext-link ext-link-type="uri" xlink:href="https://loop.frontiersin.org/people/1462774/overview">Xishuang Li</ext-link>, Ministry of Natural Resources, China</p>
<p>
<ext-link ext-link-type="uri" xlink:href="https://loop.frontiersin.org/people/1464248/overview">Nan Wu</ext-link>, Tongji University, China</p>
</fn>
<corresp id="c001">&#x2a;Correspondence: Qiliang Sun, <email>sunqiliang@cug.edu.cn</email>
</corresp>
<fn fn-type="other">
<p>This article was submitted to Sedimentology, Stratigraphy and Diagenesis, a section of the journal Frontiers in Earth Science</p>
</fn>
</author-notes>
<pub-date pub-type="epub">
<day>17</day>
<month>11</month>
<year>2021</year>
</pub-date>
<pub-date pub-type="collection">
<year>2021</year>
</pub-date>
<volume>9</volume>
<elocation-id>764319</elocation-id>
<history>
<date date-type="received">
<day>25</day>
<month>08</month>
<year>2021</year>
</date>
<date date-type="accepted">
<day>15</day>
<month>10</month>
<year>2021</year>
</date>
</history>
<permissions>
<copyright-statement>Copyright &#xa9; 2021 Sun, Xie, Wu and Yin.</copyright-statement>
<copyright-year>2021</copyright-year>
<copyright-holder>Sun, Xie, Wu and Yin</copyright-holder>
<license xlink:href="http://creativecommons.org/licenses/by/4.0/">
<p>This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these&#x20;terms.</p>
</license>
</permissions>
<abstract>
<p>Fine-grained mass-transport deposits (MTDs), especially their compressional toe zones, are traditionally considered as effective seal in constraining the vertical fluid migration underneath. However, this study documents thrust faults at the compressional toe zone of fine-grained MTDs that could disaggregate the seal competence and promote vertical fluid flow. The investigated MTD referred to as MTD-a lies directly over a large hydrocarbon reservoir that is located within the Central Canyon of northern South China Sea, which is examined by using high-resolution 3D seismic and borehole data. Thrust faults and irregular blocks composed of coarse-grained sandstones are observed in the compressional zone of the MTD-a&#x2019;s toe. More importantly, seismic evidence (e.g., enhanced seismic reflections) suggests that a large amount of hydrocarbons from the underlying reservoir penetrated through the MTD-a along these thrust faults and charged into the coarse-grained sandstone blocks. This clear evidence of thrust faults compromising the MTD&#x2019;s seal effectiveness and thus facilitating the vertical fluid flow through the non-permeable strata demonstrate the importance of reassessing the seal capacity of&#x20;MTD.</p>
</abstract>
<kwd-group>
<kwd>mass-transport deposits</kwd>
<kwd>thrust fault</kwd>
<kwd>hydrocarbon leakage</kwd>
<kwd>block</kwd>
<kwd>South China Sea</kwd>
</kwd-group>
<contract-num rid="cn001">2018YFC0310000</contract-num>
<contract-sponsor id="cn001">National Key Research and Development Program of China<named-content content-type="fundref-id">10.13039/501100012166</named-content>
</contract-sponsor>
<contract-sponsor id="cn002">National Natural Science Foundation of China<named-content content-type="fundref-id">10.13039/501100001809</named-content>
</contract-sponsor>
</article-meta>
</front>
<body>
<sec id="s1">
<title>Introduction</title>
<p>Mass-transport deposits (MTDs) widely occur at the continental margins and island flanks. They are usually composed of the headwall domain, translational domain, and toe domain (<xref ref-type="bibr" rid="B27">Martinsen, 1994</xref>; <xref ref-type="bibr" rid="B20">Lastras et&#x20;al., 2002</xref>) and, accordingly, a systematic distribution of strain transferred from extensional structures in the headwall zone to compressional structures in the toe zone (<xref ref-type="bibr" rid="B39">Trincardi and Argnani, 1990</xref>; <xref ref-type="bibr" rid="B5">Canals et&#x20;al., 2004</xref>; <xref ref-type="bibr" rid="B12">Frey Martinez et&#x20;al., 2005</xref>). Thrust faults are an important component of MTDs at their compressional toe zones (<xref ref-type="bibr" rid="B4">Bull et&#x20;al., 2009</xref>; <xref ref-type="bibr" rid="B30">Ogata et&#x20;al., 2014</xref>; <xref ref-type="bibr" rid="B1">Alsop et&#x20;al., 2017</xref>). They are usually caused by the translating material buttressing against a seabed obstacle (<xref ref-type="bibr" rid="B21">Lewis, 1971</xref>; <xref ref-type="bibr" rid="B29">Moscardelli et&#x20;al., 2006</xref>) and typically affect the entire thickness of the MTD (<xref ref-type="bibr" rid="B12">Frey Martinez et&#x20;al., 2005</xref>; <xref ref-type="bibr" rid="B4">Bull et&#x20;al., 2009</xref>).</p>
<p>Thrust faults are mainly imaged by geophysical data (e.g., seismic reflection data) and shown as imbricated structures (<xref ref-type="bibr" rid="B19">Lamarche et&#x20;al., 2008</xref>; <xref ref-type="bibr" rid="B17">Lackey et&#x20;al., 2018</xref>). Because of the shear compaction and dewatering during the mass movement (e.g., decreases of porosities and permeability), MTDs, especially those mainly composed of unlithified fine-grained sediments, are proposed as seal/barrier for the vertical fluid flow (<xref ref-type="bibr" rid="B10">Dugan, 2012</xref>; <xref ref-type="bibr" rid="B2">Alves et&#x20;al., 2014</xref>; <xref ref-type="bibr" rid="B38">Sun and Alves, 2020</xref>). Furthermore, failed sediments are inclined to accumulate and thus thicken at the compressional toe zones (<xref ref-type="bibr" rid="B29">Moscardelli et&#x20;al., 2006</xref>; <xref ref-type="bibr" rid="B19">Lamarche et&#x20;al., 2008</xref>). Furthermore, the long-distance transportation of failed sediments at the toe zone is typically highly deformed and thus their fabrics are greatly damaged. These make the seal capacity of compressional toe zones of MTDs more effective. Although remnant blocks within MTDs are proposed to provide conduits for the vertical fluid flows (<xref ref-type="bibr" rid="B2">Alves et&#x20;al., 2014</xref>; <xref ref-type="bibr" rid="B13">Gamboa and Alves, 2015</xref>; <xref ref-type="bibr" rid="B9">Cox et&#x20;al., 2020</xref>), no vertical flow pathways have been identified at the compressional toe zone until&#x20;now.</p>
<p>In this study, the investigated MTD, here referred to as MTD-a, is immediately lying on a large hydrocarbon reservoir in the Qiongdongnan Basin (QDNB) of the northern South China Sea, based on high-resolution 3D seismic and borehole data. The aims of this study are 1) to characterize the MTD-a, including the internal structures, blocks, and free gas within the MTD-a; 2) to assess the seal completeness of the compressional zone of MTD-a; and 3) to explore the vertical fluid migration system in the study area. This study demonstrates that free gas has leaked from the underlying hydrocarbon reservoir and migrated into the blocks through thrust faults. Therefore, it provides clear evidence for the thrust faults at the compressional zone of MTDs serving as fluid pathways for the first time, which suggests that the seal completeness of MTDs should be reassessed where the thrust faults develop.</p>
</sec>
<sec id="s2">
<title>Geological Setting</title>
<p>The QDNB, one of the Cenozoic basins in the northern South China Sea located to the southeast of Hainan Island (<xref ref-type="fig" rid="F1">Figure&#x20;1</xref>), covers an area of &#x223c;45,000&#xa0;km<sup>2</sup> (<xref ref-type="bibr" rid="B46">Xie et&#x20;al., 2008</xref>; <xref ref-type="bibr" rid="B35">Su et&#x20;al., 2014</xref>). It comprises a few uplifts (massifs) and depressions (sags) (<xref ref-type="fig" rid="F1">Figure&#x20;1B</xref>). The QDNB formed through two-stage tectonic evolutions, the Eocene-Oligocene rifting stage and the Miocene-to-Present post-rifting stage (<xref ref-type="fig" rid="F2">Figure&#x20;2</xref>) (<xref ref-type="bibr" rid="B14">Gong and Li, 1997</xref>; <xref ref-type="bibr" rid="B44">Wu et&#x20;al., 2008</xref>). During the rifting stage, deposits from the marsh-to-coastal plain Yacheng Formation and the littoral Lingshui Formation formed the main source rocks in the QDNB (<xref ref-type="bibr" rid="B47">Zhu et&#x20;al., 2009</xref>). The post-rifting strata are composed of the littoral to neritic Sanya and Meishan formations, as well as the bathyal to abyssal Huangliu, Yinggehai, and Ledong formations (<xref ref-type="fig" rid="F2">Figure&#x20;2</xref>) (<xref ref-type="bibr" rid="B14">Gong and Li, 1997</xref>; <xref ref-type="bibr" rid="B47">Zhu et&#x20;al., 2009</xref>).</p>
<fig id="F1" position="float">
<label>FIGURE 1</label>
<caption>
<p>
<bold>(A)</bold> Geological setting of the Qiongdongnan Basin in the northern South China Sea (modified from <xref ref-type="bibr" rid="B26">Mao et&#x20;al., 2015</xref>; <xref ref-type="bibr" rid="B24">Liang et&#x20;al., 2020</xref>). The Central Canyon is marked with yellow color; <bold>(B)</bold> the subdivisions (depressions and uplifts) of Qiongdongnan Basin (Modified from <xref ref-type="bibr" rid="B35">Su et&#x20;al., 2014</xref>; <xref ref-type="bibr" rid="B24">Liang et&#x20;al., 2020</xref>). The study area is mainly located in the Songnan Low Uplift. Well Cc1 and locations of <xref ref-type="fig" rid="F3">Figures 3</xref>, <xref ref-type="fig" rid="F4">4</xref> are labeled.</p>
</caption>
<graphic xlink:href="feart-09-764319-g001.tif"/>
</fig>
<fig id="F2" position="float">
<label>FIGURE 2</label>
<caption>
<p>Geological column of structural evolution stages, depositional environments, and relative sea-level changes in the Qiongdongnan Basin (modified from <xref ref-type="bibr" rid="B35">Su et&#x20;al., 2014</xref>; <xref ref-type="bibr" rid="B45">Wu et&#x20;al., 2018</xref>). The focused interval of this study is between T29 (4.2&#xa0;Ma) and T28 (3.7&#xa0;Ma).</p>
</caption>
<graphic xlink:href="feart-09-764319-g002.tif"/>
</fig>
<p>The QDNB is petroliferous, especially along the axis of the Central Canyon where numerous hydrocarbon fields have been found (<xref ref-type="bibr" rid="B47">Zhu et&#x20;al., 2009</xref>; <xref ref-type="bibr" rid="B43">Wang Z. et&#x20;al., 2015</xref>; <xref ref-type="bibr" rid="B6">Chen et&#x20;al., 2015</xref>). The Central Canyon is &#x3e; 425&#xa0;km long and 3&#x2013;16&#xa0;km wide (<xref ref-type="bibr" rid="B35">Su et&#x20;al., 2014</xref>). Its deep incision into the strata as old as 8.2&#xa0;Ma was fully filled at &#x223c;4.2&#xa0;Ma (<xref ref-type="bibr" rid="B24">Liang et&#x20;al., 2020</xref>). Moreover, the Central Canyon is mainly filled by the fine-grained mudstone and layered coarse-grained sandstone that acts as hydrocarbon reservoir (<xref ref-type="bibr" rid="B43">Wang Z. et&#x20;al., 2015</xref>). After &#x223c;4.2&#xa0;Ma, multiple MTDs are draped on the Central Canyon strata and formed the seal for the hydrocarbon reservoir (<xref ref-type="bibr" rid="B24">Liang et&#x20;al., 2020</xref>).</p>
<p>MTDs widely developed in the QDNB and those in the southern QDNB (Huaguang Sag) are well studied (<xref ref-type="bibr" rid="B36">Sun et&#x20;al., 2011</xref>; <xref ref-type="bibr" rid="B40">Wang et&#x20;al., 2013</xref>; <xref ref-type="bibr" rid="B41">Wang D. et&#x20;al., 2015</xref>). Those MTDs are cyclic with turbidities, such as triple packs of turbidities and MTDs, which are probably related to the sea-level changes (<xref ref-type="bibr" rid="B36">Sun et&#x20;al., 2011</xref>). Moreover, the reactivation of major faults and associated volcanism in the late Miocene were proposed as the dominant trigger mechanisms for those MTDs (<xref ref-type="bibr" rid="B40">Wang et&#x20;al., 2013</xref>). MTDs also frequently occurred in the central QDNB, as mentioned above (<xref ref-type="bibr" rid="B24">Liang et&#x20;al., 2020</xref>). They may source from the northern slope area, western slope area, or Guangle Massif (<xref ref-type="bibr" rid="B7">Cheng et&#x20;al., 2021</xref>) and mainly formed after &#x223c;4.2&#xa0;Ma (<xref ref-type="bibr" rid="B24">Liang et&#x20;al., 2020</xref>). Moreover, the slope overstepping resulting from high sediment supply likely triggered the slope instability (<xref ref-type="bibr" rid="B32">Qin et&#x20;al., 2015</xref>; <xref ref-type="bibr" rid="B24">Liang et&#x20;al., 2020</xref>). The occurrence of MTDs greatly changed the sediment dispersal pattern in the Central Canyon and thus influenced the hydrocarbon systems (reservoirs and seals) in the study area (<xref ref-type="bibr" rid="B22">Li et&#x20;al., 2015</xref>; <xref ref-type="bibr" rid="B24">Liang et&#x20;al., 2020</xref>).</p>
</sec>
<sec id="s3">
<title>Data and Methods</title>
<p>The time-migrated 3D seismic reflection data used in this study cover an area of &#x223c;1,050&#xa0;km<sup>2</sup> and were provided by the China National Offshore Oil Corporation (CNOOC). It was acquired in 2010 with 3,000-m-long streamers consisting of 240 channels at a spacing of 12.5&#xa0;m and a sample rate of 4&#xa0;ms. The bin spacing of the 3D seismic data is 25&#xa0;m in the crossline and 12.5&#xa0;m in the inline. The dominant frequency of the focused strata is &#x223c;35&#xa0;Hz, and thus, a vertical resolution of &#x223c;20&#xa0;m is calculated, based on the strata velocity of 2,800&#xa0;m/s from the Well Cc1 (<xref ref-type="fig" rid="F1">Figure&#x20;1B</xref>). The 3D seismic reflection data are zero-phase processed and displayed with the Society of Exploration Geophysicists (SEG) normal polarity, whereby a downward increase in acoustic impedance corresponds to a positive reflection event (red on seismic profiles) (<xref ref-type="bibr" rid="B3">Brown, 2004</xref>). Exploration well Cc1 is used for the lithology and strata velocity correlation. This well was located at the flank of the Central Canyon and drilled through several gas-charged sandstone layers (<xref ref-type="fig" rid="F3">Figure&#x20;3</xref>). To better image the blocks, a variance attribute is used in this study (<xref ref-type="fig" rid="F4">Figure&#x20;4</xref>). The variance attribute measures the variability in shape between seismic traces (<xref ref-type="bibr" rid="B3">Brown, 2004</xref>). It is directly derived from the processed data and thus is free of interpreter bias. The variance attribute is typically used to map structural and stratigraphic discontinuities (e.g., blocks, faults, and channels).</p>
<fig id="F3" position="float">
<label>FIGURE 3</label>
<caption>
<p>
<bold>(A)</bold> A 3D seismic profile crossing through the Well Cc1, mass transport deposit a (MTD-a), and Central Canyon. The location of Well Cc1 is marked with a black thick line, and loggings of gamma ray (GR, blue curve) and density (RHOB, red curve) are also labeled. Gas-charged blocks (enhanced negative seismic reflections) within MTD-a and several gas-charged reservoirs within the Central Canyon are also clearly observed; <bold>(B)</bold> detailed characteristics of the GR and RHOB curves. The gas-charged layers are marked with cyan squares, and they show sharp decreases of the GR and RHOB; <bold>(C)</bold> interpretation of the seismic profile <bold>(A)</bold>. Green colors above the Central Canyon representing gas occurrences within the coarse-grained siltstone/sandstone.</p>
</caption>
<graphic xlink:href="feart-09-764319-g003.tif"/>
</fig>
<fig id="F4" position="float">
<label>FIGURE 4</label>
<caption>
<p>Variance slices above 100&#xa0;ms twt <bold>(A)</bold> and 30&#xa0;ms twt <bold>(B)</bold> of MTD-a&#x2019;s base. The northern highly deformed zone (without blocks), blocked zone (with blocks and thrust faults), and southern highly deformed zone (with suspected blocks) are subdivided. The blocks within the blocked zone are gas-charged. Boundary of MTD-a, boundary of gas-charged blocks, and locations of <xref ref-type="fig" rid="F5">Figures 5</xref>, <xref ref-type="fig" rid="F6">6A</xref>,<xref ref-type="fig" rid="F6">B</xref> are marked.</p>
</caption>
<graphic xlink:href="feart-09-764319-g004.tif"/>
</fig>
</sec>
<sec sec-type="results" id="s4">
<title>Results</title>
<sec id="s4-1">
<title>General Characteristics</title>
<p>The most prominent structure in the study area is the &#x201c;V&#x201d;-shaped Central Canyon. It quickly widens upward, and the fill sediments onlap onto its walls (<xref ref-type="fig" rid="F3">Figures 3A,C</xref>, <xref ref-type="fig" rid="F6">6</xref>). The strata are mainly parallel/subparallel along the axis of the Central Canyon (<xref ref-type="fig" rid="F5">Figure&#x20;5</xref>), and tapering/onlapping seismic reflections are only occasionally observed along the axis (<xref ref-type="fig" rid="F5">Figure&#x20;5</xref>). Many boreholes have targeted the hydrocarbon-rich Central Canyon and show that the strata mainly comprise fine-grained mudstone (<xref ref-type="bibr" rid="B35">Su et&#x20;al., 2014</xref>; <xref ref-type="bibr" rid="B24">Liang et&#x20;al., 2020</xref>). Coarse-grained siltstone and sandstone are also observed within the Central Canyon (<xref ref-type="fig" rid="F3">Figure&#x20;3C</xref>), which is the main hydrocarbon reservoir (<xref ref-type="bibr" rid="B43">Wang Z. et&#x20;al., 2015</xref>).</p>
<fig id="F5" position="float">
<label>FIGURE 5</label>
<caption>
<p>A 3D seismic profile perpendicular to the extension of MTD-a shows its lateral boundaries. Gas-charged blocks are clearly observed within MTD-a. Central Canyon is mainly unfilled by layered sediments. Top and base of MTD-a are marked with cyan and blue dashed lines. See location in <xref ref-type="fig" rid="F4">Figure&#x20;4</xref>.</p>
</caption>
<graphic xlink:href="feart-09-764319-g005.tif"/>
</fig>
<p>Multiple MTDs characterized by chaotic/blanking seismic reflections are observed above the Central Canyon, separated by continuous seismic surfaces (<xref ref-type="fig" rid="F3">Figures 3A, 5, 6</xref>). This study is focused on the lowermost MTD, here named as MTD-a, which is directly draped on the Central Canyon (<xref ref-type="fig" rid="F3">Figure&#x20;3A</xref>).</p>
<p>Many irregular blocks, characterized by short enhanced-amplitude, negative-polarity seismic reflections are identified inside the MTD-a (<xref ref-type="fig" rid="F3">Figures 3A, 5&#x2013;7</xref>). Although there is no well directly through these blocks, referencing the Well Cc1&#x2019;s layered structure leads to a reasonable assumption that the blocks are mainly composed of sandstones (<xref ref-type="fig" rid="F3">Figure&#x20;3</xref>). The blocks are surrounded by fine-grained mudstone (chaotic seismic reflections). The head zone of MTD-a has not been imaged, because of the limitation of 3D seismic coverage (<xref ref-type="fig" rid="F4">Figure&#x20;4</xref>). It may have originated from the slope of QDNB to the north (<xref ref-type="fig" rid="F1">Figure&#x20;1</xref>) and flowed toward the southeast part, judging from the extension of MTD-a (e.g., the direction of the lateral margins) (<xref ref-type="fig" rid="F4">Figure&#x20;4</xref>). In the 3D seismic coverage, MTD-a could be divided into three subzones, such as a northern highly deformed zone, a blocked zone, and a southern highly deformed zone (<xref ref-type="fig" rid="F4">Figure&#x20;4</xref>). No macroscopic blocks could be observed within the northern highly deformed zone, and it is mainly composed of chaotic seismic reflections (<xref ref-type="fig" rid="F6">Figure&#x20;6</xref>). In the blocked zone, blocks float within the fine-grained strata (mudstone) and they are separated by high-angle thrust faults (<xref ref-type="fig" rid="F5">Figure&#x20;5</xref>). There are suspected blocks observed on the variance slices in the highly deformed zone to the south (<xref ref-type="fig" rid="F4">Figure&#x20;4</xref>). However, the seismic identification of these structures is not definitive (<xref ref-type="fig" rid="F3">Figures 3A</xref>,&#x20;<xref ref-type="fig" rid="F6">6</xref>).</p>
<fig id="F6" position="float">
<label>FIGURE 6</label>
<caption>
<p>3D seismic profiles nearly parallel to the extension of MTD-a. MTD-a directly overlies the Central Canyon. Several gas-charged layers (enhanced negative seismic reflections), especially the uppermost layers, occurred within the Central Canyon. Gas-charged blocks within the MTD-a are surrounded by chaotic seismic reflections, interpreted as mudstone. Normal faults developed below the Central Canyon, and they provide the main pathways for the deep-seated hydrocarbon migration. Locations of <xref ref-type="fig" rid="F7">Figures 7A,B</xref> are marked with black squares.</p>
</caption>
<graphic xlink:href="feart-09-764319-g006.tif"/>
</fig>
</sec>
<sec id="s4-2">
<title>Blocks</title>
<p>A total of 306&#x20;seismic-scale irregular blocks were recorded in the study area, characterized by enhanced seismic reflections as mentioned above, and are observed in the toe zone of MTD-a, especially those close to the southeastern boundary (blocked zone; green dashed zones in <xref ref-type="fig" rid="F4">Figure&#x20;4A</xref>). However, the blocks are rarely observed at the distal termination part of MTD-a (southern highly deformed zone; <xref ref-type="fig" rid="F4">Figure&#x20;4A</xref>). They are mainly bounded by thrust faults to their northwestern and southeastern sides and surrounded by chaotic seismic reflections (<xref ref-type="fig" rid="F6">Figures 6</xref>, <xref ref-type="fig" rid="F7">7</xref>). In other words, they &#x201c;float&#x201d; within the chaotic seismic reflections. Although they are bounded by the thrust faults, the blocks are close to each other and some of them are even directly connected (<xref ref-type="fig" rid="F7">Figure&#x20;7</xref>).</p>
<fig id="F7" position="float">
<label>FIGURE 7</label>
<caption>
<p>Enlargements of seismic profiles <bold>(A,C)</bold> and their interpretation <bold>(B,D)</bold> showing the details of blocks and thrust faults within MTD-a. MTD-a directly lies on the hydrocarbon reservoir. Thrust faults link the underlying hydrocarbon reservoir and MTD-a&#x2019; blocks and provide pathways for the gas leaking upward.</p>
</caption>
<graphic xlink:href="feart-09-764319-g007.tif"/>
</fig>
<p>The irregular blocks are distributed in a linear fashion in plain view with orientations of E&#x2013;W at the northwestern corner of the blocked zone and NE&#x2013;SW at the left blocked zone (<xref ref-type="fig" rid="F4">Figure&#x20;4</xref>). The dips of blocks are perpendicular to their strike extensions, and a few blocks are nearly horizontal elongation without any dips (<xref ref-type="fig" rid="F5">Figure&#x20;5</xref>). The lengths of blocks range from &#x223c;0.20 to &#x223c;6.34&#xa0;km with an average of &#x223c;1.48&#xa0;km, while the blocks&#x2019; widths are between &#x223c;0.10 and &#x223c;2.05&#xa0;km, with an average of &#x223c;0.27&#xa0;km. There is no apparent relationship between the lengths and widths of blocks (R<sup>2</sup> &#x3d; 0.03; <xref ref-type="fig" rid="F8">Figure&#x20;8A</xref>). The blocks cover an average area of &#x223c;0.44&#xa0;km<sup>2</sup> ranging from &#x223c;0.02 to &#x223c;4.24&#xa0;km<sup>2</sup>. The areas of blocks are moderately related to their lengths (R<sup>2</sup> &#x3d; 0.54; <xref ref-type="fig" rid="F8">Figure&#x20;8B</xref>) and widths (R<sup>2</sup> &#x3d; 0.50; <xref ref-type="fig" rid="F8">Figure&#x20;8C</xref>). The average height of blocks is &#x223c;42.4&#xa0;m (&#x223c;30.3&#xa0;ms twt), and thus the total volume of blocks (total area &#xd7; average height) is &#x223c;5.68&#xa0;km<sup>3</sup>.</p>
<fig id="F8" position="float">
<label>FIGURE 8</label>
<caption>
<p>Parameters of blocks (number &#x3d; 306) and thrust faults (number &#x3d; 350) within MTD-a. <bold>(A)</bold> Block length vs. block width; <bold>(B)</bold> block length vs. block area; <bold>(C)</bold> block width vs. block area; <bold>(D)</bold> strike of thrust fault vs. length of thrust fault; <bold>(E)</bold> inclination of thrust fault vs. length of thrust fault; and <bold>(F)</bold> dip of thrust fault vs. length of thrust&#x20;fault.</p>
</caption>
<graphic xlink:href="feart-09-764319-g008.tif"/>
</fig>
</sec>
<sec id="s4-3">
<title>Thrust Faults</title>
<p>A total of 350&#x20;seismic-scale thrust faults are identified in the blocked zone, which separate the blocks apart (<xref ref-type="fig" rid="F5">Figures 5</xref>, <xref ref-type="fig" rid="F7">7</xref>). Most of the thrust faults penetrate the whole MTD-a and terminate at the upper surface of the underlying Central Canyon strata (<xref ref-type="fig" rid="F6">Figure&#x20;6</xref>). However, some small-scale thrust faults are mainly located in the upper part (above the blocks) of MTD-a (<xref ref-type="fig" rid="F7">Figure&#x20;7B</xref>). The lengths of thrust faults range between &#x223c;0.27 and &#x223c;4.92&#xa0;km with an average of &#x223c;1.4&#xa0;km (<xref ref-type="fig" rid="F8">Figure&#x20;8D</xref>). The strikes of thrust faults mainly extend between 40&#xb0; and 70&#xb0; (&#x223c;84% of the total thrust faults) (<xref ref-type="fig" rid="F8">Figure&#x20;8D</xref>). Less thrust faults strike 90&#xb0;&#x2013;147&#xb0;, and they usually have short vertical extensions (&#x3c;1.0&#xa0;km; <xref ref-type="fig" rid="F8">Figure&#x20;8D</xref>). Accordingly, the thrust faults mainly incline 130&#xb0;&#x2013;160&#xb0; (37% of the total thrust faults) and 320&#xb0;&#x2013;340&#xb0; (45% of the total thrust faults; <xref ref-type="fig" rid="F8">Figure&#x20;8E</xref>). The dips of thrust faults range from &#x223c;25&#xb0; to &#x223c;87&#xb0;, and most of them (90%) are between &#x223c;30&#xb0; and &#x223c;70&#xb0; (<xref ref-type="fig" rid="F8">Figure&#x20;8F</xref>).</p>
</sec>
<sec id="s4-4">
<title>Free Gas</title>
<p>Enhanced seismic anomalies characterized by negative reflections are observed in the Central Canyon and MTD-a&#x2019;s blocks (<xref ref-type="fig" rid="F3">Figures 3A, 5&#x2013;7</xref>), which is similar to the typical seismic characteristics of free gas (e.g., <xref ref-type="bibr" rid="B16">Judd and Hovland, 2007</xref>; <xref ref-type="bibr" rid="B25">L&#xf8;seth et&#x20;al., 2009</xref>; <xref ref-type="bibr" rid="B37">Sun et&#x20;al., 2017</xref>). In fact, the exploration well Cc1 drilled through these enhanced seismic anomalies and confirmed that they are gas-charged sandstones (<xref ref-type="fig" rid="F3">Figures 3A,C</xref>). Furthermore, these gas-charged sandstones characterized by sharp decreases of gamma ray (GR) and density (RHOB) are surrounded by fine-grained mudstones (<xref ref-type="fig" rid="F3">Figure&#x20;3B</xref>). Accordingly, the irregular blocks within MTD-a could be interpreted as the counterparts of sandstones (<xref ref-type="fig" rid="F3">Figure&#x20;3C</xref>). Moreover, the enhanced negative seismic reflections of blocks (<xref ref-type="fig" rid="F3">Figures 3A, 5&#x2013;7</xref>) indicate that free gas also charged into them. The average porosity of sandstone from well Cc1 is &#x223c;29.6%, and that of gas saturation is &#x223c;71.2%; hence, the volume of free gas stored within the MTD-a&#x2019; blocks can be as high as &#x223c;1.2 &#xd7; 109&#xa0;m<sup>3</sup>.</p>
</sec>
</sec>
<sec sec-type="discussion" id="s5">
<title>Discussion</title>
<sec id="s5-1">
<title>Seal Disintegration and Vertical Hydrocarbon Migration</title>
<p>Fine-grained MTDs usually have decreased porosities and permeability, because of shear compaction and dewatering during their emplacement (<xref ref-type="bibr" rid="B31">Piper et&#x20;al., 1997</xref>; <xref ref-type="bibr" rid="B34">Shipp et&#x20;al., 2004</xref>; <xref ref-type="bibr" rid="B33">Sawyer et&#x20;al., 2007</xref>; <xref ref-type="bibr" rid="B10">Dugan, 2012</xref>; <xref ref-type="bibr" rid="B38">Sun and Alves, 2020</xref>). Therefore, they usually act as effective seal to hinder the vertical migration of fluids (<xref ref-type="bibr" rid="B2">Alves et&#x20;al., 2014</xref>; <xref ref-type="bibr" rid="B38">Sun and Alves, 2020</xref>). Remnant blocks that break through the MTDs could occasionally support the vertical fluid migration (<xref ref-type="bibr" rid="B13">Gamboa and Alves, 2015</xref>; <xref ref-type="bibr" rid="B9">Cox et&#x20;al., 2020</xref>). However, there are no reports about vertical fluid flow in the compressional toe zone of MTDs as yet, where the compressional stress in the toe zone is proposed to strengthen the seal capacity of sediments.</p>
<p>Gas-charged blocks within MTD-a indicate that significant amounts of hydrocarbon have leaked from the gas field underlying the MTD-a (<xref ref-type="fig" rid="F5">Figures 5</xref>&#x2013;<xref ref-type="fig" rid="F7">7</xref>). Because the blocks are surrounded by fine-grained sediments and are not directly connected with the underlying gas reservoir, the thrust faults are believed to act as the primary pathways for vertical fluid migration. Normally, the thrust faults in the compressional environment would be tight/closed to barrier fluids (<xref ref-type="bibr" rid="B11">Elmore et&#x20;al., 2003</xref>; <xref ref-type="bibr" rid="B28">Micklethwaite, 2008</xref>). However, the thrust faults, likely with fractured medias, are mechanically weak zones (e.g., <xref ref-type="bibr" rid="B18">Lacroix et&#x20;al., 2014</xref>; <xref ref-type="bibr" rid="B8">Cook et&#x20;al., 2020</xref>), and they would likely reactivate under overpressure due to the underlying accumulation of hydrocarbons. Moreover, the blocked zone has weaker deformation compared to the northern and southern highly deformed zones where the failed sediments are probably fully mixed (<xref ref-type="fig" rid="F4">Figure&#x20;4</xref>). The less mixture of sediments in the blocked zone would partly keep the fabrics of the strata, which is also in favor of reactivation of the thrust faults. This study documents the thrust faults at the compressional zone of MTDs to serve as fluid pathways for the first time. It also indicates that the fabric heterogeneity plays an important role on the seal completeness, and certain factors (e.g., overpressure) may trigger the disintegration of seal, even for the fine-grained sediment-dominated compressional zones of&#x20;MTDs.</p>
</sec>
<sec id="s5-2">
<title>Hydrocarbon Migration and Accumulation System</title>
<p>The hydrocarbon migration and accumulation system in the study area can be updated through this study together with previous studies (<xref ref-type="bibr" rid="B47">Zhu et&#x20;al., 2009</xref>; <xref ref-type="bibr" rid="B23">Li et&#x20;al., 2017</xref>). The deeply buried coal-bearing strata of the lower Oligocene Yacheng Formation serve as the main source rock in the QDNB (<xref ref-type="bibr" rid="B15">Huang et&#x20;al., 2003</xref>). The source rock entered the peak gas-generation window during the late Miocene and Pliocene (<xref ref-type="bibr" rid="B47">Zhu et&#x20;al., 2009</xref>). Hydrocarbon (gas) from the source rock migrated upward mainly along tectonic faults (<xref ref-type="fig" rid="F6">Figure&#x20;6A</xref>) and charged into the reservoir of the Central Canyon from the Pliocene to the present (<xref ref-type="bibr" rid="B42">Wang et&#x20;al., 2014</xref>). Within the Central Canyon, the interconnected coarse-grained siltstone/sandstones provided the lateral and vertical hydrocarbon migration pathways (<xref ref-type="fig" rid="F9">Figure&#x20;9</xref>). Finally, the hydrocarbon accumulated at the topmost part of the Central Canyon where the reservoir is directly capped by the compressional zone of the fine-grained MTD-a (<xref ref-type="fig" rid="F6">Figures 6</xref>, <xref ref-type="fig" rid="F9">9</xref>). The compressional zone of MTD-a is composed of a series of thrust faults and coarse-grained blocks, as mentioned above (<xref ref-type="fig" rid="F3">Figure&#x20;3</xref>). Accompanying the gradual accumulation of hydrocarbon, overpressure would increase and finally exceed the yield strength of thrust faults. Therefore, the thrust faults would reactivate and arrow hydrocarbons would migrate upward along these faults and charge the blocks, as observed in this study (<xref ref-type="fig" rid="F7">Figures 7</xref>, <xref ref-type="fig" rid="F9">9</xref>). This study indicates that a large amount of hydrocarbons (&#x223c;1.2 &#xd7; 109&#xa0;m<sup>3</sup>) has probably leaked from the main reservoir of the gas field. Furthermore, the hydrocarbon system including the hydrocarbon migration, accumulation, and leakage in the study area is probably still dynamic, and special attention should be paid to the seal completeness where thrust faults occur within the&#x20;MTDs.</p>
<fig id="F9" position="float">
<label>FIGURE 9</label>
<caption>
<p>Model for the hydrocarbon migration system in the study area. Fault-controlled hydrocarbon migration (FCHM): deep-seated normal faults provide pathways for the hydrocarbons migrating upward from the source rock; canyon-controlled hydrocarbon migration (CCHM): interconnected coarse-grained siltstone/sandstone provides pathways for the lateral/vertical hydrocarbon migration; thrust fault-controlled hydrocarbon migration (TFCHM): hydrocarbons leaked from the main reservoir in the Central Canyon and charged into blocks within MTD-a through the thrust faults.</p>
</caption>
<graphic xlink:href="feart-09-764319-g009.tif"/>
</fig>
</sec>
</sec>
<sec sec-type="conclusion" id="s6">
<title>Conclusion</title>
<p>This paper is focused on an MTD-a that is directly overlying a large gas field in the Central Canyon of the Qiongdongnan Basin (South China Sea), using high-resolution 3D seismic data and borehole data. The main conclusions are drawn as follows:<list list-type="simple">
<list-item>
<p>1) Well-developed seismic-scale blocks and thrust faults are widespread in the compressional zone of MTD-a.</p>
</list-item>
<list-item>
<p>2) Thrust faults helped to penetrate MTD-a&#x2019;s seal and provided pathways for vertical fluid migration. This is the primary mechanism for as much as 1.2 &#xd7; 109&#xa0;m<sup>3</sup> of hydrocarbon to escape from the reservoir, migrate upward, and eventually accumulate in the sandstone blocks.</p>
</list-item>
</list>
</p>
<p>This study provided clear evidence for the thrust faults promoting fluid flow at the compressional zone of MTDs for the first time, which has important implication on the assessment of MTDs&#x2019; seal competence and underlying reservoir completeness. Moreover, reevaluation of other fine-grained MTDs assumed as seals is advised to reduce uncertainty in the sealing capacity of MTDs, particularly those displaying blocky and faulted textures.</p>
</sec>
</body>
<back>
<sec id="s7">
<title>Data Availability Statement</title>
<p>The original contributions presented in the study are included in the article/Supplementary Material, further inquiries can be directed to the corresponding author.</p>
</sec>
<sec id="s8">
<title>Author Contributions</title>
<p>QS is the principal author and primary seismic interpreter, and also writes and edits the paper. XX and SW contribute on the interpreting the seismic data, and writing/editing the paper. GY contributes on preparing the figures and writing the paper.</p>
</sec>
<sec id="s9">
<title>Funding</title>
<p>This work was supported by the National Key R&#x26;D Program of China (No. 2018YFC0310000), the National Scientific Foundation of China (No. 41676051), and the Fundamental Research Funds for the Central Universities-the China University of Geosciences (Wuhan) (No. CUG2106207).</p>
</sec>
<sec sec-type="COI-statement" id="s10">
<title>Conflict of Interest</title>
<p>GY was employed by the company PetroChina Changqing Oil Field Company.</p>
<p>The remaining authors declare that the research was conducted in the absence of any commercial or financial relationships that could be construed as a potential conflict of interest.</p>
</sec>
<sec sec-type="disclaimer" id="s11">
<title>Publisher&#x2019;s Note</title>
<p>All claims expressed in this article are solely those of the authors and do not necessarily represent those of their affiliated organizations, or those of the publisher, the editors and the reviewers. Any product that may be evaluated in this article, or claim that may be made by its manufacturer, is not guaranteed or endorsed by the publisher.</p>
</sec>
<ack>
<p>The China National Offshore Oil Company (CNOOC) is thanked for permission to release the data. The data that support the findings of this study are available from the CNOOC. Restrictions apply to the availability of these data, which were used under license for this study. Prof. Jingping Xu is thanked for his constructive comments on the original version of this paper. Guest Editor AM, Reviewer NW and an reviewer are thanked for their constructive comments that greatly improved this&#x20;paper.</p>
</ack>
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