Organic geochemistry of Ordovician ultra-deep natural gas in the north Shuntuoguole area, Tarim Basin, NW China: Insights into genetic types, maturity, and sources

As a gas-rich region in the Tarim Basin, the northern Shuntuoguole area (also known as the Shunbei area) is an attractive prospect. Non-etheless, the debate about the origins of these natural gas continues. The analysis on the geological context, natural gas components, and the carbon and hydrogen isotope ratios prove that methane is the predominate component of alkane gases. Alkane gases’ carbon isotope fractionation (δ13C2 < −28‰ and δ13C3 < −25‰) shows that they are oil-associated gas, and their parent material type is I kerogen. Natural gas can be broken down further into three subgroups—Type I1, Type I2, and Type I3. Based on the link between the carbon number 1/n and δ13Cn of the gas. Modified plots of lnC1/C2 vs. lnC2/C3 reveal that kerogen cracking is the primary source of natural gas in the Shunbei area, and that this gas is combined with the contribution of oil cracking gas. Petroleum exploration and development in the Shunbei area can be justified on the basis that natural gas in the area originate primarily from Ordovician source rocks, as shown by carbon isotopic compositions.

At present, a large number of practices and researches have been carried out on the exploration of oil and gas in deep and ultra-deep basins in the world, and a series of major breakthroughs have been made. Especially, the three deepest wells in the world, namely Odoptu OP-11 Well in Sakhalin, Russia (12,345 m, in 2011), Ashosin Well in Qatar (12289 m in 2008 and SG-3 Well in kola peninsula (12,262 m in 1989) (Wu et al., 2006;Zhai et al., 2012), have obtained important information on deep oil and gas generation and reservoir properties. At present, the deepest drilling well in China is Luntan 1Well (8882 m, in 2019) in Tarim Basin, which can obtain high-yield industrial oil and gas flow in Cambrian below 8,200 m. Some industrial oil and gas reservoirs have also been found in Sichuan Basin and Tarim Basin in China in the depth range of 6,500-8,000 m (Pang et al., 2015), which shows that the ultra-deep still has good oil and gas exploration potential.
Natural gas, crude oil, and hydrocarbon source rocks in the Lower Paleozoic Ordovician and Cambrian reservoirs have been the subject of intense study since the discovery of the Shunbei Oilfield in China (Wang et al., 2003;He et al., 2008;Dai et al., 2014;Chen et al., 2015;Jiao, 2018;Zheng, 2018;Deng et al., 2019;Ma et al., 2020;Ma et al., 2021). However, the origin of these materials has been strongly contested (Zhu et al., 2015;Zhu et al., 2018;Qi, 2021). Palaeohigh in the Tarim Basin has been the target of petroleum exploration efforts in recent years. Insight into the strike-slip fault zone's tectonic history, structural features, active fault evolution process, and petroleum geological conditions has led to the growing understanding that it plays a crucial role in the formation of Tarim Basin's carbonate reservoirs and hydrocarbon accumulation (Zhang et al., 2021. A significant advancement in recent years has been the discovery of the Shunbei Oilfield (Zhao et al., 2018;Ma et al., 2019). This discovery has furthered the argument that intracratonic strike-slip faults with small displacements are crucial for reservoir development and hydrocarbon accumulation in the Ordovician carbonates (Qi, 2021). Deep oil and gas resources in China have great potential, and the exploration degree of oil and gas is low (13% and 10%, respectively). Deep and ultra-deep are the realistic fields for oil and gas exploration and development in the future (Jia et al., 2015;Pan et al., 2022). The research on the accumulation conditions and accumulation rules of the ultra-deep ancient strata has become a hot topic, and a number of high quality results have been obtained (Zhai and He, 2004;Bai et al., 2014;Ren et al., 2020;Li et al., 2021). It is of great significance to study the controlling effect of deep and ultra-deep natural gas geochemical characteristics on hydrocarbon accumulation and enrichment in order to guide the deep oil and gas exploration and development and meet the important national demand. In this study, we conducted a thorough investigation into the carbon and hydrogen isotopic compositions of the Ordovician natural gas in the Shunbei, and their geochemical properties.

Geological background
China's largest inland oil-gas yielding basin is located in the Tarim Basin, which is a large-scale superimposition basin. It is situated in Xinjiang, Northwest China, and has a size of around 560,000 square kilometers. Seven primary structural units plus a few subsidiary structural units make up the Tarim basin. Northern depression area is home to Shuntuoguole, which sits on secondary structural units. Accordingly, Shuntuoguole is subdivided into four tertiary structural units: the Shunbei gentle slope, the Shundong gentle slope, the Shuntuo low uplift, and the Shunnan gentle slope (Qi, 2021). The Shunbei Oilfield is located in the northern portion of the Shuntuoguole low uplift, and its near neighbors are the Shaya uplift to the north, the Kathak uplift to the south, the Awati depression to the west, and the Mangar depression to the east (Figure 1). From the perspective of tectonic evolution, the Tarim Basin has an ancient evolutionary history, which has undergone several subsidence and uplift movements on the plane. It is composed of seven tectonic evolution stages, and the evolution process is very complex (Jia, 1997). Substantial sedimentary layers, some of which are over ten thousand meters thick, and about 800 million years of geological history offer the material basis and objective conditions for the formation of oil and gas resources. Of these, 21 maritime oil and gas fields date back to the Paleozoic era, which is currently the focus of exploration and development (Jia, 1997;Zheng, 2018). To date, 18 main strike-slip faults have been found in the Tarim Basin, providing crucial information regarding the pattern of fault distribution. Overall structural characteristics of the Tarim Basin are governed by three fault types that can be categorized as NWW, NEE, or NNE (Jia, 1997;Deng et al., 2019). An important step forward was achieved in 2016 at the Shunbei Oilfield. Tarim basin has been a hotspot for petroleum exploration due to estimates that 18 strike-slip fault zones spanning 3,400 km 2 contain oil and gas with a total production of 1.7 billion tons, 70% of which is oil reserves, and natural gas reserves exceeding 5,000 cubic meters (Yang et al., 2017).

Materials and methods
The natural gas and crude oils samples were collected from the Ordovician Fault No. 7 (F7),Fault No. 5 (F5),Fault No.1 (F1) and Fault No.4 (F4) in the Shunbei area. The sample component is determined by HP5980 gas chromatograph. Chromatographic conditions were as follows: MS molecular sieve with column length of 2.4 mm; GDX-502 column of 4 m. The chromatographic temperature rise program is the initial temperature of 30°C, kept for 10 min, and then the temperature rise rate is 10°C/min to 180°C. The carbon isotope value of main alkane in natural gas is determined by Optima isotope mass spectrometer. Natural gas samples are separated into single components in HP5890 gas chromatograph by chromatographic column (HP-PLOTQ column). The natural gas sample was separated into a single component by a HP-PLOTQ column (30 m×0.32 mm×20 µm) in the HP5980 gas chromatograph. The single component hydrocarbons were converted into CO 2 by high temperature, and then directly entered the isotope mass spectrometer to determine the carbon isotope composition. The initial furnace temperature of the Frontiers in Earth Science frontiersin.org 02 chromatograph is 35°C, and the temperature rise rate is 8°C/min to 80°C, and the temperature rise rate is 5°C/min to 260°C, and the temperature rise is maintained for 10 min. The CO 2 experiment utilized a PorparKQ column (2 m×3 mm) with Helium as the carrier gas. The temperature of the GC column was raised from 40 to 100°C in one-minute increments. It took a TDX column (2 m×3 mm) heated at a rate of 20°C per minute from 32°C to 120°C to separate the remaining gases that are not hydrocarbons. By comparing the results to the PDB carbon isotope, the precision of the analysis was found to be ±0.5‰. All the above tests were completed in Sinopec Key Laboratory of Petroleum Accumulation (Wuxi). Using the relationship between Ro and δ 13 C1, δ 13 C1=21.88logRo−45.6, the corresponding Ro value is obtained. Frontiers in Earth Science frontiersin.org 03

Molecular composition of natural gas
Natural gas's constituents are a crucial indicator of the genetic types of natural gas that are present. Given that hydrocarbons, which make up more than 70% of the total gas and dominate the molecular composition of the natural gas in the study area, the natural gas are likely mostly derived from organic sources, according to this theory. Methane is the main hydrocarbon gas in natural gas, and the methane content ranges from 12.57% to 87.90% (Table 1), with an average of 67.3%, the main peak  between 70% and 90%. The minor ethane content varies between 1.91% and 25.50%, with an average of 9.64%; the trace propane content varies between 0.41% and 21.56%, with an average of 5.18%; and Well No.13 has the highest concentration, at 87.90%. Well No.5 has the lowest concentration, at 12.57%. Natural gas's dryness indices (C 1 /C 1-5 ) range from 0.19% on the low end to 0.97% on the high end, with an average of 0.8% (which is typical for wet gas) across faults (Table 1). Nitrogen (N 2 ), carbon dioxide (CO 2 ), and hydrogen (H 2 ) are the most common nonhydrocarbon gases in Shunbei's natural gas, albeit at low amounts. The CO 2 content ranges from 1.65% to 68.21% (11.77% on average), with the majority of the CO 2 content being less than 10% (Table 1). The N 2 content ranges from 0.37% to 11.34% (2.92% on average) (Table 1), with the majority of the N 2 content being around 2%; and the H 2 content ranges from 0.01% to 1.58% (0.19% on average) (Table 1).

Genetic types and origins of natural gas
Oil and gas' geochemical properties are mostly determined by their parent material, degree of maturation, and other processes. Natural gas formation theories center mostly on the peculiarities of light hydrocarbons and various isotopes of carbon and hydrogen. 12 C is typically enriched in the low molecular hydrocarbon as a result of organic matter breaking, whereas 13 C is significantly enriched in the large molecular hydrocarbon, such that the carbon isotope ratios of natural gas components are ordered from small to large (δ 13 C 1 < δ 13 C 2 < δ 13 C 3 < δ 13 C 4 ). The difference in carbon isotope content between neighboring components correlates with the age of the parent rock. When the maturity is low, the difference of carbon isotope is obvious. Differences tend to decrease and sometimes reverse as maturity increases (δ 13 C 1 >δ 13 C 2 >δ 13 C 3 >δ 13 C 4 ) (Schoell 1980;Whiticar et al., 1986;Whiticar 1999;Dai et al., 2016;Xie et al., 2017;Ni et al., 2019). Therefore, the carbon isotope ratio index can be adopted to determine the origin and genetic makeup of various parent natural gases at various times in their development. Carbon isotope characteristics of ethane and propane, as well as the geological history of the study area, suggest that the natural gas in the Shunbei area are likely thermogenic gases (Figure 2). Methane's hydrogen isotopic composition varies with its sedimentary context, and this variation can be used as a valuable indication of that environment. For methane, the concentration of hydrogen isotopes is highest in marine environments rich in salt, followed by those rich in brackish water and finally those rich in fresh water. The value of methane hydrogen isotope is bounded by −180‰, when the value more than −180‰, indicating marine source rocks; otherwise, indicating continental source rocks . The average δD−CH 4 values of the naturally occurring gases in Fault 7, 5, 1, and 4 are −208‰, −190‰, and −168.5‰, and −148.5‰, respectively (Table 1). The carbon and hydrogen

FIGURE 3
Generalized summary plots of δD −CH 4 vs. δ 13 C −CH 4 for the natural gases from Shunbei area (Modified from Wang et al., 2015).

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frontiersin.org 06 isotope properties of methane are used to identify the origin of natural gas, and these measurements showed that the gases in the research area were consistent with a sapropelic-kerogen source ( Figure 3). To more accurately determine the genetic types of natural gases based on their isotopic makeup, scientists have discovered that carbon isotopes may be utilized to distinguish

FIGURE 4
Genetic identification of alkane gases showing that the natural gases from the Shunbei area along the exhibits the characteristics of oil-associated gas (Modified from Dai et al., 1992).

FIGURE 5
Relationship between carbon number 1/n and δ 13 Cn of natural gases in Shunbei (A) Classification of natural gas types in Shunbei and (B) Type I 1 natural gases and (C) Type I 2 natural gases and (D) Type I 3 natural gases (Modified from Chung et al., 1988;Dai et al., 2003).

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frontiersin.org 07 between gas originating from coal and gas related with oil. Researchers in Shunbei could tell that the gas was predominantly from zone II and that it was an oil-associated gas by analyzing its carbon isotope composition (Figure 4).
Natural gas genetic kinds can be determined using carbon isotopes contained in gas components as trustworthy indicators. In order to gauge the precision of the method, the reciprocal value of the carbon number associated with methane and pentanes is used (Chung et al., 1988;Dai et al., 2016). In the case when δ 13 Cn is proportional to 1/n, it can be inferred that the carbon isotopic composition of the ancestor is also homologous. However, if this is not the case, it suggests that the genetic source has a complex carbon isotope makeup (Prinzhofer et al., 1995;Zhang et al., 2005;Zou et al., 2007). In the Shunbei, there is a positive trend in the carbon isotopic compositions of alkanes, suggesting that these gases are produced by the cracking of organic materials. This is denoted by the notation δ 13 C 1 < δ 13 C 2 < δ 13 C 3. According to the information presented in Table 1, δ 13 C 1 and δ 13 C 2 values of natural gases display quite wide ranges of variation, with values ranging from −51.7‰ to −44.2‰ (average −47‰) and −39.3‰ to −28.6‰ (average −34‰), respectively. Natural gases are oil-associated gas and its parent material type is I kerogen in Shunbei, which can be further divided three subcategories. Type I 1 , Type I 2 and Type I 3 ( Figure 5A). Type I 1 shows a positive trend, δ 13 C 1 values range from −47.5‰ to −44.2‰ (average −45.85‰), δ 13 C 2 values range from −28.6‰ to −29.9‰ (average −29.3‰) (Table 1; Figure 5B), the representative wells are No. 26 and No. 13, and C 1 /ƩC 1-5 values range from 0.97 to 0.95, respectively, indicating dry gas and oilassociated gas of high maturity. Type I 2 shows a positive trend, δ 13 C 1 values of the Type I 2 range from −51.7‰ to −44.7‰ (average −47.2‰), δ 13 C 2 values of the Type I 2 range from −34.8‰ to −32.1‰ (average −33.7‰) (Table 1; Figure 5C). C 1 /ƩC 1-5 values of Type I 2 range from 0.81 to 0.97 (average 0.87), the Type I 2 gas is wet gas. The δ 13 C 1 values of the Type I 3 range from −49.2‰ to −46.4‰ (average −48.51‰), δ 13 C 2 values of the Type I 3 range from −39.3‰ to −37.7‰ (average −38.6‰) (Table 1; Figure 5D). C 1 /ƩC 1-5 values of Type I 3 range from 0.19 to 0.72 (average 0.56), the Type I 3 gas is wet gas. Type I 2 and Type I 3 gases are distinguished from Type I1 gases by having δ 13 C 3 values typically lower than −28.0‰. In addition, Type I 1 gas exhibits heavier δ 13 C 3 values than Type I 2 and Type I 3 gas, indicating a greater degree of thermal maturity.

Carbon dioxide
Although CO 2 is widely distributed in nature, its concentration is generally low. If located near to oil fields, large reserves of CO 2 have the potential to be used to enhance oil recovery. Natural gas typically contains a number of components, carbon dioxide being one of the most frequent that is not a hydrocarbon. Most natural gases contain a certain CO 2 content. The CO 2 content is an effective indicator for geologists to understand geochemical processes in natural gases. The starting point for evaluating the regularity of CO 2 enrichment is the source of the gas. Many studies have been conducted to determine where CO 2 first appeared in the atmosphere (Gould et al., 1981;Shang et al., 1990;Tassi et al., 2012;Dai et al., 2016;Mikov et al., 2018). Dai et al. (1996) divided carbon dioxide gas reservoirs into four categories according to the content of CO 2 in gas reservoirs, and believed that the content of CO 2 in gas reservoirs is more than 60%, CO 2 is of inorganic origin, and the content of CO 2 is 15%-60% Mainly of inorganic origin. There is little difference about CO 2 content in Shunbei area. Most of wells have been acidified fracturing in Shunbei, CO 2 content will be increase during the process of acidizing fracturing. The CO 2 produced by the dissolution of acid in the formation water of carbonate rocks is generally low in formation rate and gas production intensity, because the acid in the formation water is generally low in content and concentration. However, the high concentration and quantity of strong acid injected during artificial acid fracturing can quickly react with the carbonate formation to produce a large amount of CO 2 in a short period of time, resulting in high CO 2 content in gas samples collected during this period (Zhang et al., 2010). Therefore, the CO 2 content were related to acidified fracturing in Shunbei. Carbon dioxide origin can be determined by measuring its δ 13 C isotope signature, which has been shown to be greater than −8% for inorganic carbon dioxide and less than −10% for organic carbon dioxide (Dai et al., 1996). Figure 6 shows that the majority of the CO 2 in natural gases in the Shunbei region comes from inorganic sources and exists in a coexisting zone.

Identification of kerogen cracking gas and oil cracking gas
For a complete picture of the natural gas cycle and its origin, it is also important to distinguish between oil-associated gas and coal-type gas, as well as kerogen cracking gas and oil cracking gas (Tissot et al., 1984;Lan et al., 2009;Cheng et al., 2013). If the natural gas is oil cracking gas, then the oil and gas that the source rock produces during the peak phase of oil generation are in the large cracking gas stage when they are trapped to form paleoreservoirs. Since the oil reservoir created in the early stage of the source rock would have been destroyed, the availability of Plot of δ 13 C CO2 vs. CO 2 content of natural gases from the Shunbei area (Modified from Dai et al., 1996).

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frontiersin.org 08 natural gas would be drastically impacted if it were determined to be kerogen cracking gas (Stahl et al., 1975;Berner et al., 1996;. Zhao et al. (2001) proved that there are two kinds of cracking gas in the Tarim Basin, namely, the natural gas in the eastern Tabei Uplift is mainly kerogen cracking gas, and the natural gas in the Hetianhe gas field is mainly crude oil cracking gas; Zhang et al. (2011) proposed that the natural gas in the east Lungu area was mainly crude oil cracking gas.
The natural logarithmic relationship of methane, ethane, and propane ratios shows a positive trend for this ln (C 1 /C 2 ) and ln (C 2 /C 3 ) (Figure 7) . The results show that the values of ln(C 1 /C 2 ) of natural gas in Shunbei area range from 0.20 to 3.81, and the values of ln(C 2 /C 3 ) vary from 0.26 to 1.78, which mainly fall on the evolution curve of kerogen cracking gas, most of which are below 1.5%. Some natural gas is located between the curves of kerogen cracking gas and oil cracking gas, which indicates the contribution of natural gas mixed with oil cracking gas. However, the ln(C 1 /C 2 ) values of natural gas in Shunnan, Gulong and Gucheng areas are mostly greater than 4, and the ln(C 2 /C 3 ) values vary greatly, ranging from 0.5 to 3.04, which falls on the evolution curve of crude oil cracking gas. The maturity of natural gas is mostly between 1.5% and 2.5% (Ma et al., 2021).
From Shunbei to Shuntuo to Shunnan area, the content of methyl adamantane in crude oil shows an increasing trend, which indicates that the cracking degree of crude oil has increased, which provides geochemical evidence that the natural gas is crude oil cracking gas in Shuntuo and Shunnan areas (Ma et al., 2021). The oil cracking degree of Well Shuntuo 1 and Well Shunnan 1 are 96%, 98%, respectively (Ma et al., 2021). The coke bitumen developed in the Ordovician Yingshan Formation reservoir in Shunnan, Gulong and Gucheng area provides petrological evidence for the formation of natural gas as crude oil cracking gas in this area. The high vitrinite reflectance of pyrobitumen indicates a high degree of cracking of the paleo-oil reservoir Zhou et al., 2019).

Thermal maturity of natural gas
Since the thermal maturity of natural gas cannot be directly obtained, it is necessary to use its carbon isotope to judge. Methane carbon isotopes in natural gas are closely related to maturity. Important theoretical support for tracing the gas's origins and establishing a gas-source correlation comes from a set of empirical carbon isotope-maturity relationships given for evaluating the maturity of gases and estimated Ro value (Dai, 1989;Huang et al., 1996). There are some discrepancies between the calculated conclusions of the δ 13 C-maturity models in the Shunbei, however, because of the region's varied geological settings and/or accumulation history. Because of this, Huang (1979) advocated using the δ 13 C-maturity model, with the equation δ 13 C 1 = 21.88logRo−45.6 (Huang et al., 1996). The δ 13 C 1 -Ro model was used to calculate the Ro values ( Table 1). The carbon isotope of methane and Ro values are displayed in Table 1 in accordance with the dryness coefficient, demonstrating that the maturity of natural gases in the Shunbei area steadily increases from west to east. The southern part of Fault 5 has a higher maturity level than the center and northern parts. The northern portion of Fault 1 is more mature than the southern portion. Natural gas maturity can be determined using a variety of markers, the most popular and reliable of which is the light hydrocarbon component. The light hydrocarbon component's n-and iso-heptane may efficiently discriminate between various maturity stages (Thompson, 1979). Figure 8 shows that the natural gas in Shunbei area is in the mature to high mature stage.

FIGURE 8
The relationship between the heptane index and the iso-heptane index of natural gases in Shunbei area (Modified from Thompson 1979).
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Source of natural gas
It is common knowledge that the Cambrian, Lower-Middle Ordovician, and Upper Ordovician were the most productive times for production of the marine source rocks that make up the Tarim Basin (Zhang et al., 2000b). While both the Xishanbulake-Xidashan and Yuertusi Formations contributed to the formation of Cambrian source rocks, the Yuertusi Formation was far more instrumental. Well XH1 uncovered the Cambrian Yuertusi Formation, which has a total thickness of about 40 m and a total organic carbon (TOC) concentration of 1.0%-9.43% (7 samples averaged out to 5.5%) Jin et al., 2017). Type I-II organic compounds make up the bulk of all organic materials (Xiao et al., 2000). There is now a stage of extreme maturity in the Cambrian source rocks (Zhan, 2016).
The Heituao and Saergan Formations have the highest concentration of middle and lower Ordovician source rocks (Chen et al., 2014). The presence of kerogen type II in algae and acritarchs causes a wide range of total organic carbon (TOC) values in Middle-Lower Ordovician source rocks (average 1.77%; 7 samples) (Zhao et al., 2012;Zhao et al., 2014). There is a total organic carbon concentration of 0.47-0.56% in the Upper Ordovician source rocks of the North Uplift of the Tarim Basin, and a TOC concentration of 0.5% or higher in rocks with a thickness of 6-28 m. Natural gas in the Shunbei area was determined to be oil-associated gas based on its geochemical features and those of the source rocks. The Ordovician age is largely responsible for the generation of the gas found in oil reservoirs. The evidence is broken down and addressed in detail below.
①The δ 13 C properties of the natural gas in the Shunbei exploratory wells show that the oil-associated gas originates from the Ordovician source rocks. Gaseous alkanes from the Middle-Upper Ordovician and Cambrian have been dated using their carbon isotope distribution curves, which have been published by Wang et al. (2014). It is discovered that the wet gases show steep C 1 -C 3 alkane carbon isotope distribution curves with negative δ 13 C 1 values (<− 42.5‰), which are assumed to have originated from Middle-Upper Ordovician source rocks. In contrast, Cambrian natural gas had δ 13 C values that were considerably high (>−42.5‰), along with flat distribution curves for carbon isotopes C 1 -C 3 . Therefore, using the carbon isotopes of gaseous alkanes permits one to determine the origin of gases and establish relationships between gases. The wet gas from the Shunbei correlates well with gases from the Middle-Upper Ordovician, with δ 13 C values that range from 44‰ to 52‰ (or <− 42.5‰) and a steep distribution curve of C 1 -C 3 alkanes carbon isotopes (Table 1; Figure 9).
②In accordance with the inheritance of isotopes, dispersion of isotopes, and variation of isotopes during the formation and evolution of hydrocarbons, the carbon isotopes can be utilized to correlate oil sources. The majority of Cambrian source rock samples exhibit stable carbon isotopes heavier than −30‰, with the greatest values seen in Well H4 at −25.8‰. The isotopic curve distribution of Cambrian and Ordovician crude oils is shown in Figure 10 and Table 2. Obviously, Cambrian crude oils are consistent with Cambrian source rocks. On the other hand, the isotopes of Ordovician crude oil are obviously lighter and are distributed in −32‰~−36‰ (Song et al., 2016), so it is obviously impossible for them to be derived from Cambrian source rocks.

Oil and gas accumulation and enrichment patterns
The crude oil in Shunbei area mainly comes from the Lower Cambrian Yuertusi Formation source rocks , the Ordovician reservoir is mainly controlled by the multi-stage structural rupture of the strike-slip fault zone and the dissolution along the fault (Jiang et al., 2005). The characteristics of hydrocarbon reservoirs revealed in shallow and deep parts of the same fault zone are consistent. For example, deep well SHB1-10H and shallow well SHB1-3 of Shunbei No. 1 fault zone have basically the same crude oil density and gas dryness coefficient of the two Wells, which

FIGURE 9
Carbon isotopic series of alkane gas in the Tarim Basin.

FIGURE 10
Carbon isotope curves of non-hydrocarbon from the Tarim Basin.

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frontiersin.org proves that the oil and gas generated by in-situ source rock is mainly formed by vertical transport along the fault in Shunbei area. The movable oil and gas are mainly accumulated since the late Hercynian period, and the fault zone plays an obvious role in controlling reservoir and accumulation. This area is located in the sedimentary area of gentle slope source rocks in the early Cambrian period. In the later period, the pass-source strike-slip fault was developed and the reservoir was dominated by "faultkarst". Therefore, because strike slip faults influence in-reservoir geochemical processes and vertical petroleum migration, strike slip faults play an important role in the ultra-deep fault-karst petroleum systems present in the Shunbei area ( Figure 11) (Qi, 2021).

Conclusion
In the Shunbei area, the natural gas is the origin of oilassociated gas and its parent material type is I kerogen. The relationship between carbon number 1/n and natural gas δ 13 Cn can be further subdivided into I 1 , I 2 and I 3 subclasses. The δ 13 C 1 and δ 13 C 2 values for Type I 1 gases are highly enriched at δ 13 C, ranging from −47.5‰ to −44.2‰ (−45.85‰ on average) and −28.6‰ to −29.9‰ (−29.3‰ on average), respectively. However, Type I 2 and Type I 3 gases have higher δ 13 C depletion levels than Type I 1 gases.
Inevitably, the natural gas in the Shunbei area was dominated by oil-associated gas, as shown by modified lnC 1 /C 2 vs. lnC 2 /C 3 plots, and oil cracking gas is present in the natural gas mixture. Carbon isotope ratios of the source rocks, natural gas, and oil in the Shunbei area suggest that the gases originated in the Ordovician source rocks.
The fault zone in the Shunbei area can be shown to control accumulation within reservoirs. As a new type of reservoir, ultra-deep fault-karst reservoir in the Shunbei area extended the theory of hydrocarbon accumulation in marine carbonates, shows a great exploration potential of ultra-deep marine

FIGURE 11
Oil and gas accumulation and enrichment patterns of different segments of strike slip fault zone in Shunbei Oilfield (Modified from Qi 2021).

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Data availability statement
The datasets presented in this study can be found in online repositories. The names of the repository/repositories and accession number(s) can be found in the article/Supplementary Material.

Author contributions
Conceptualization, DH; methodology, ZJ; software, XZ and JB; review and editing, XM and ZJ.

Funding
The work was supported by project No. 202107ZB0123.