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<front>
<journal-meta>
<journal-id journal-id-type="publisher-id">Front. Energy Res.</journal-id>
<journal-title>Frontiers in Energy Research</journal-title>
<abbrev-journal-title abbrev-type="pubmed">Front. Energy Res.</abbrev-journal-title>
<issn pub-type="epub">2296-598X</issn>
<publisher>
<publisher-name>Frontiers Media S.A.</publisher-name>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="publisher-id">702456</article-id>
<article-id pub-id-type="doi">10.3389/fenrg.2021.702456</article-id>
<article-categories>
<subj-group subj-group-type="heading">
<subject>Energy Research</subject>
<subj-group>
<subject>Original Research</subject>
</subj-group>
</subj-group>
</article-categories>
<title-group>
<article-title>Production Performance Analysis of Class II Hydrate-Bearing Layers Based on an Analytic Aquifer Model</article-title>
<alt-title alt-title-type="left-running-head">Yu et&#x20;al.</alt-title>
<alt-title alt-title-type="right-running-head">Simulation of Class II HBLs</alt-title>
</title-group>
<contrib-group>
<contrib contrib-type="author" corresp="yes">
<name>
<surname>Yu</surname>
<given-names>Jing</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
<xref ref-type="corresp" rid="c001">&#x2a;</xref>
</contrib>
<contrib contrib-type="author">
<name>
<surname>Zhuo</surname>
<given-names>Lubin</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author">
<name>
<surname>Chen</surname>
<given-names>Yang</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author">
<name>
<surname>Sun</surname>
<given-names>Wenchao</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
<uri xlink:href="https://loop.frontiersin.org/people/802233/overview"/>
</contrib>
<contrib contrib-type="author">
<name>
<surname>Liu</surname>
<given-names>Yongge</given-names>
</name>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
<uri xlink:href="https://loop.frontiersin.org/people/1080239/overview"/>
</contrib>
</contrib-group>
<aff id="aff1">
<label>
<sup>1</sup>
</label>CNPC Engineering Technology R&#x26;D Company Limited, <addr-line>Beijing</addr-line>, <country>China</country>
</aff>
<aff id="aff2">
<label>
<sup>2</sup>
</label>China Petroleum Technology Development Company Limited, Middle East Branch, <addr-line>Beijing</addr-line>, <country>China</country>
</aff>
<aff id="aff3">
<label>
<sup>3</sup>
</label>School of Petroleum Engineering in China University of Petroleum (East China), <addr-line>Qingdao</addr-line>, <country>China</country>
</aff>
<author-notes>
<fn fn-type="edited-by">
<p>
<bold>Edited by:</bold> <ext-link ext-link-type="uri" xlink:href="https://loop.frontiersin.org/people/1026972/overview">Chungang Xu</ext-link>, Guangzhou Institute of Energy Conversion (CAS), China</p>
</fn>
<fn fn-type="edited-by">
<p>
<bold>Reviewed by:</bold> <ext-link ext-link-type="uri" xlink:href="https://loop.frontiersin.org/people/1334534/overview">Yi Wang</ext-link>, Guangzhou Institute of Energy Conversion (CAS), China</p>
<p>
<ext-link ext-link-type="uri" xlink:href="https://loop.frontiersin.org/people/1332757/overview">Bai Jing</ext-link>, Zhengzhou University, China</p>
<p>
<ext-link ext-link-type="uri" xlink:href="https://loop.frontiersin.org/people/1357427/overview">Yanghui Li</ext-link>, Dalian University of Technology, China</p>
<p>
<ext-link ext-link-type="uri" xlink:href="https://loop.frontiersin.org/people/1357446/overview">Liu Jianwu</ext-link>, Guangzhou Institute of Energy Conversion (CAS), China</p>
</fn>
<corresp id="c001">&#x2a;Correspondence: Jing Yu, <email>yujingdri@126.com</email>
</corresp>
<fn fn-type="other">
<p>This article was submitted to Carbon Capture, Storage, and Utilization, a section of the journal Frontiers in Energy Research</p>
</fn>
</author-notes>
<pub-date pub-type="epub">
<day>04</day>
<month>08</month>
<year>2021</year>
</pub-date>
<pub-date pub-type="collection">
<year>2021</year>
</pub-date>
<volume>9</volume>
<elocation-id>702456</elocation-id>
<history>
<date date-type="received">
<day>29</day>
<month>04</month>
<year>2021</year>
</date>
<date date-type="accepted">
<day>01</day>
<month>07</month>
<year>2021</year>
</date>
</history>
<permissions>
<copyright-statement>Copyright &#xa9; 2021 Yu, Zhuo, Chen, Sun and Liu.</copyright-statement>
<copyright-year>2021</copyright-year>
<copyright-holder>Yu, Zhuo, Chen, Sun and Liu</copyright-holder>
<license xlink:href="http://creativecommons.org/licenses/by/4.0/">
<p>This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these&#x20;terms.</p>
</license>
</permissions>
<abstract>
<p>In the current numerical simulation studies, bottom water in Class II hydrate-bearing layers is represented by grids with high water saturation that significantly extends the calculation time if the volume of the bottom water is large or grid size is small. Moreover, the influence of the bottom water volume on the depressurization performance of Class II hydrate-bearing layers has not been fully investigated. In this study, the Fetkovich analytic aquifer model was coupled with a simulation model of a hydrate reservoir to accelerate the simulation of Class II hydrate-bearing layers. Then the simulation results and calculation time were compared between the coupled model and the model in which the bottom water layer is only represented by grids. Finally, the influence of the bottom water volume on the productivity of gas and water in the depressurization method was investigated and the variation of pressure, temperature, and hydrate saturation during the production process was analyzed. The results show that the coupled model can significantly reduce the simulation time of Class II hydrate-bearing layer while ensuring calculation accuracy. When the pore volume of the aquifer increases to 20&#x20;times that of the bottom water layer, the computation time of a single model in which the bottom water layer is represented by grids is 18.7&#x20;times that of the coupled model. Bottom water invasion slows down the depressurization, and therefore, the larger the aquifer, the lower the peak value of gas production, and the later it appears. However, the invading bottom water can provide heat for hydrate dissociation; therefore, the gas production rate of the hydrate-bearing layer with bottom water is higher than that of the hydrate-bearing layer without bottom water in the late development stage. Generally, the presence of bottom water reduces the cumulative gas production and increases the cumulative water production; therefore, the larger the aquifer, the more unfavorable the depressurization development of the hydrate-bearing&#x20;layer.</p>
</abstract>
<kwd-group>
<kwd>natural gas hydrate</kwd>
<kwd>depressurization</kwd>
<kwd>bottom aquifer</kwd>
<kwd>numerical simulation</kwd>
<kwd>analytic aquifer model</kwd>
</kwd-group>
</article-meta>
</front>
<body>
<sec id="s1">
<title>Introduction</title>
<p>Natural gas hydrates (NGHs) are ice-like substances formed by gas and water that remain stable under low-temperature and high-pressure conditions (<xref ref-type="bibr" rid="B4">Chong et&#x20;al., 2016</xref>; <xref ref-type="bibr" rid="B1">Aydin et&#x20;al., 2016</xref>; <xref ref-type="bibr" rid="B33">Yang et&#x20;al., 2019</xref>). They are mainly deposited in deep-water sediments and permafrost and have huge global reserves. NGHs have been regarded as one of the most important future alternative energy sources and pilot production tests have been conducted in several countries including the US, Canada, China, and Japan (<xref ref-type="bibr" rid="B6">Collett et&#x20;al., 2011</xref>; <xref ref-type="bibr" rid="B27">Song et&#x20;al., 2014</xref>; <xref ref-type="bibr" rid="B12">Li et&#x20;al., 2018</xref>; <xref ref-type="bibr" rid="B34">Ye et&#x20;al., 2020</xref>). The main method for developing hydrate-bearing layers (HBL) is to break the phase equilibrium condition of NGHs, which leads to the dissociation of NGHs into gas and water (<xref ref-type="bibr" rid="B3">Boswell et&#x20;al., 2019</xref>; <xref ref-type="bibr" rid="B26">Ruan et&#x20;al., 2021</xref>). According to these mechanisms, the main development methods can be divided into depressurization, thermal stimulation, inhibitor injection, and CO<sub>2</sub> replacement, among which the depressurization method is currently the most economical method (<xref ref-type="bibr" rid="B32">Wei et&#x20;al., 2018</xref>).</p>
<p>Moridis et&#x20;al. investigated HBLs and divided them into three classes (<xref ref-type="bibr" rid="B20">Moridis et&#x20;al., 2011a</xref>). Class I HBLs comprise an overlying hydrate layer and an underlying free gas layer. Class II HBLs contain a hydrate layer and a bottom water layer, whereas Class III HBLs only have a single hydrate layer (<xref ref-type="bibr" rid="B22">Moridis and Reagan, 2011</xref>). For Class II HBLs, the bottom water significantly affects the gas production because the invasion of bottom water from the underlying layer to the hydrate layer supplements the pressure drawdown caused by gas production, and therefore, the depressurization speed decreases (<xref ref-type="bibr" rid="B16">Liu et&#x20;al., 2018a</xref>; <xref ref-type="bibr" rid="B7">Esmaeilzadeh et&#x20;al., 2020</xref>; <xref ref-type="bibr" rid="B24">Pang et&#x20;al., 2021</xref>). Over the past few years, many researchers have investigated the performance of Class II HBLs using the experimental and simulation methods. Based on the geological parameters of HBLs in Malik, Canada, <xref ref-type="bibr" rid="B20">Moridis et&#x20;al. (2011a</xref>; <xref ref-type="bibr" rid="B23">2011b</xref>) carried out numerical simulation studies and compared the performance of the depressurization method under different perforation schemes. The results show that the method involves a gas production interval within the water layer, and heating of the outer surface of the wellbore gives the best performance. <xref ref-type="bibr" rid="B25">Reagan et&#x20;al. (2008)</xref> studied the influence of permeability, porosity, and heterogeneity on the development of class II HBLs using the Tough &#x2b; Hydrate simulator. The results show that the gas production is dependent strongly on the formation porosity and less on the anisotropy: The smaller the well spacing, the greater the gas production over short-time periods. <xref ref-type="bibr" rid="B18">Liu et&#x20;al. (2018b)</xref> coupled the particle swarm optimization algorithm and HydrateResSim (open-source edition of Tough &#x2b; Hydrate) and key parameters such as the conversion time of depressurization to hot water injection, injected water temperature, and injection&#x2013;production ratio were optimized. <xref ref-type="bibr" rid="B29">Uddin et&#x20;al. (2014)</xref> investigated the performance of a Class II HBL in the Mallik area using a numerical simulation method and found that owing to the low pressure and temperature, the production from the middle hydrate layer yields better performance than that from&#x20;the upper layer. <xref ref-type="bibr" rid="B13">Li et&#x20;al. (2021)</xref> analyzed the performance of Class II HBLs using the CMG-STARS module. The simulation results show that if the bottom water layer is perforated, water production significantly increases, and the bottom water layer should not be perforated if permeability is greater than 1,000&#xa0;mD. <xref ref-type="bibr" rid="B2">Bhade and Phirani (2015)</xref> investigated the influence of heterogeneity on the depressurization performance of Class II HBLs. The results show that the characterization of the aquifer is important for the depressurization performance of Class II HBLs. Along with an increase in the permeability of the aquifer, gas production decreases, and water production increases.</p>
<p>From the above discussion, it is clear that the mechanisms and depressurization performance of Class II HBLs have been&#x20;comprehensively investigated. However, in these simulations,&#x20;the aquifer is represented by grids that are saturated with water and the calculation time is significantly extended if the bottom water layer is thick or if the grid size is small. Moreover, the influence of aquifer volume on the depressurization performance has not been&#x20;fully studied. Given this, the Fetkovich analytic aquifer model, which has been widely used in commercial software of the petroleum industry, is coupled with an HBL simulator. Then, the simulation results are validated, and the calculation time is compared between the coupled model and&#x20;the model in which the bottom water layer is only represented by grids. Finally, a model was built based on the geological parameters of an HBL in the Shenhu area of the South China Sea, and the influence of bottom water volume on the depressurization performance of Class II HBLs was analyzed.</p>
</sec>
<sec id="s2">
<title>Coupling of Aquifer Model and Hydrate-Bearing Layers Model</title>
<sec id="s2-1">
<title>Fetkovich Analytic Aquifer Model</title>
<p>The Fetkovich analytic aquifer model is based on the principle of material balance; that is, the volume of water at the initial time under the current pressure should be equal to the sum of the pore volume under the current pressure and the volume of water invading the adjacent reservoir (<xref ref-type="bibr" rid="B8">Fetkovich, 1971</xref>). When the source and sink are not considered in the aquifer, they can be expressed as<disp-formula id="e1">
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<label>(1)</label>
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<xref ref-type="disp-formula" rid="e1">Equation 1</xref> can be transformed to:<disp-formula id="e2">
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<label>(5)</label>
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</p>
</sec>
<sec id="s2-2">
<title>Hydrate-Bearing Layers Numerical Simulation Model</title>
<p>At present, the commonly used numerical simulation tools for HBL development include the STOMP-HYD simulator of the Pacific Northwest National Laboratory in the United&#x20;States, the MH21-HYDRES simulator of Japan, and the TOUGH &#x2b; HYDRATE and HydrateResSim simulators of the Berkeley National Laboratory in the United&#x20;States. (<xref ref-type="bibr" rid="B14">Li et&#x20;al., 2016</xref>; <xref ref-type="bibr" rid="B19">Luo et&#x20;al., 2020</xref>). Among these simulators, the phase equilibrium and kinetic models are the most widely used models (<xref ref-type="bibr" rid="B21">Moridis, 2003</xref>; <xref ref-type="bibr" rid="B30">Wan et&#x20;al., 2020</xref>). The equilibrium model considers the hydrate formation and dissociation to occur at chemical equilibrium, and the system is always assumed to be equilibrium. For laboratory scale models, the timestep is quite small (seconds or minutes) and the assumption of equilibrium is hard to be satisfied. Therefore, the kinetic model should be selected under such circumstances. However, the timestep of field scale model is days or even months. The assumption of equilibrium is easily satisfied, and therefore, the equilibrium and kinetic model obtain quite similar results (<xref ref-type="bibr" rid="B10">Kowalsky and Moridis, 2007</xref>). The calculation process of the kinetic model is more complex, so the convergence is relatively poor, and the calculation time is longer. Therefore, a phase equilibrium model was used in this study considering that the field scale model is used. The components used only include methane and water, and the mass conservation equation for each component can be expressed as follows:<disp-formula id="e6">
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</disp-formula>The energy conservation equation is as follows:<disp-formula id="e7">
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</disp-formula>Hydrate formation and dissociation is based on the phase equilibrium condition. The phase equilibrium curve used in this study is the regression form proposed by <xref ref-type="bibr" rid="B23">Moridis et&#x20;al. (2011b)</xref> as follows:<disp-formula id="e8">
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</p>
</sec>
<sec id="s2-3">
<title>Coupling of the Fetkovich and Hydrate-Bearing Layers Models</title>
<p>
<xref ref-type="fig" rid="F1">Figure&#x20;1</xref> shows a diagram of the coupling process of the Fetkovich aquifer model and the HBL model. As shown in this figure, the widely used two-way coupling method was used to couple the two models. First, the HBL and aquifer models were initialized, and the temperature of the aquifer was set to be the same as the initial temperature of the adjacent HBL grid. When the simulation began, the pressure, temperature, and hydrate saturation of the HBL were obtained according to the numerical simulation model of the HBL. When&#x20;the pressure of the grids adjacent to the aquifer is lower than the initial pressure of the aquifer, the total water invasion rate from the aquifer to the HBL in the next time step is calculated&#x20;using <xref ref-type="disp-formula" rid="e5">Eq. 5</xref>, and the aquifer pressure is updated according to <xref ref-type="disp-formula" rid="e2">Eq. 2</xref>. According to the principles of the numerical simulation, the mass flow rate of water from the aquifer to the grids adjacent to the aquifer can be calculated according to the following equation:<disp-formula id="e9">
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</disp-formula>The heat of the invading water was obtained according to the water temperature and the calculated invasion rate. Then, the mass flow rate and heat of the invasion water are considered the source and sink terms of mass and energy, respectively, in <xref ref-type="disp-formula" rid="e6">Eq. 6</xref> and <xref ref-type="disp-formula" rid="e7">Eq. 7</xref> to calculate the pressure, temperature, and fluid saturation of the HBL in the next step. The above steps are repeated until the predetermined simulation time <italic>T</italic>
<sub>
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</sub> is reached.</p>
<fig id="F1" position="float">
<label>FIGURE 1</label>
<caption>
<p>Coupling process of the Fetkovich and HBL models.</p>
</caption>
<graphic xlink:href="fenrg-09-702456-g001.tif"/>
</fig>
</sec>
<sec id="s2-4">
<title>Validation and Computational Efficiency Analysis of the Coupled Model</title>
<p>No similar coupling model has been reported in the literature; therefore, no simulation results can be directly used to validate the coupled model proposed in this article. However, in the two-way coupling process, only related data are transferred, and the procedure used to compute outputs from the two models is not changed (<xref ref-type="bibr" rid="B28">Tran et&#x20;al., 2005</xref>). Therefore, if the water invasion rate is computed correctly, the results can be considered reliable. Many commercial software packages of the petroleum industry have incorporated the Fetkovich model. In this study, the commercial software CMG-STARS module was used to validate the calculation results of the coupled model. To make the simulation results comparable, a single water phase that can be simulated by both the STARS module and the coupled model is used. The coupled model built is shown in <xref ref-type="fig" rid="F2">Figure&#x20;2A</xref> and its basic parameters are listed in <xref ref-type="table" rid="T1">Table&#x20;1</xref>. As shown in <xref ref-type="fig" rid="F2">Figure&#x20;2A</xref>, the model uses radial coordinates and is divided into 28 vertical grids, of which the top three grids represent the overburden with a total thickness of 10&#xa0;m, and the remaining 25 grids represent a water layer with a total thickness of 25&#xa0;m. According to the basic parameters in <xref ref-type="table" rid="T1">Table&#x20;1</xref>, the pore volume of the water layer is 9.42 &#xd7; 105&#xa0;m<sup>3</sup>. The analytical aquifer is connected to the bottom of the water layer, and the outer boundaries are all no-flux boundaries except the bottom (water in the aquifer will flow from the aquifer to the water layer through the bottom). The initial pressures of the water layer and the analytical aquifer were both 13&#xa0;MPa. A vertical well is located in the center and produces water at a fixed pressure of 4&#xa0;MPa, which means that the inner boundary (wellbore boundary) is the Dirichlet boundary.</p>
<fig id="F2" position="float">
<label>FIGURE 2</label>
<caption>
<p>The coupled model built and results used for validation. <bold>(A)</bold> Coupled model built. <bold>(B)</bold> Water production&#x20;rate.</p>
</caption>
<graphic xlink:href="fenrg-09-702456-g002.tif"/>
</fig>
<table-wrap id="T1" position="float">
<label>TABLE 1</label>
<caption>
<p>Basic parameters of the coupled&#x20;model.</p>
</caption>
<table>
<thead valign="top">
<tr>
<th align="left">Parameter</th>
<th align="center">Value</th>
<th align="center">Parameter</th>
<th align="center">Value</th>
</tr>
</thead>
<tbody valign="top">
<tr>
<td align="left">Grid number (<italic>r</italic>&#xd7;<italic>z</italic>)</td>
<td align="center">36 &#xd7; 28</td>
<td align="center">Radius of reservoir</td>
<td align="center">200&#xa0;m</td>
</tr>
<tr>
<td align="left">Overburden thickness</td>
<td align="center">10&#xa0;m</td>
<td align="center">Thickness of water layer</td>
<td align="center">25&#xa0;m</td>
</tr>
<tr>
<td align="left">Plane permeability of water layer</td>
<td align="center">0.1&#xa0;&#x3bc;m<sup>2</sup>
</td>
<td align="center">Vertical permeability of water layer</td>
<td align="center">0.02&#xa0;&#x3bc;m<sup>2</sup>
</td>
</tr>
<tr>
<td align="left">Plane permeability of overburden</td>
<td align="center">1 &#xd7; 10<sup>&#x2013;5</sup>&#xa0;<italic>&#x3bc;</italic>m<sup>2</sup>
</td>
<td align="center">Vertical permeability of overburden</td>
<td align="center">1 &#xd7; 10<sup>&#x2013;5</sup>&#xa0;<italic>&#x3bc;</italic>m<sup>2</sup>
</td>
</tr>
<tr>
<td align="left">Porosity of water layer</td>
<td align="center">0.3</td>
<td align="center">Porosity of overburden</td>
<td align="center">0.01</td>
</tr>
</tbody>
</table>
</table-wrap>
<p>Three cases were compared in which the pore volumes of the aquifer were 4, 20, and 100&#x20;times that of the bottom water layer. <xref ref-type="fig" rid="F2">Figure&#x20;2B</xref> shows a comparison of the water production rates obtained by the STARS module and the coupled model. It can be seen that the initial water production rate is almost the same for the three cases, which indicates that the elastic energy of the water layer is sufficient at the beginning. However, with an increase in time, the difference in water production rates among the different cases gradually increases. An aquifer with a larger pore volume can provide more water flow from the aquifer to the adjacent layer, and therefore, the larger the pore volume of the aquifer, the slower the deceleration of the water production rate. From the comparison, it can be seen that the water production rates of the coupled model established in this study are consistent with those calculated by the STARS module, and the coupled model is reliable.</p>
<p>The advantage of the coupled model is that it uses an analytical aquifer model to characterize the bottom water layer, while the single HBL model can only increase the pore volume of the bottom water layer by increasing the number of grids. Therefore, the calculation time of the single model increased significantly when the aquifer was large. <xref ref-type="fig" rid="F3">Figure&#x20;3</xref> shows a comparison of the calculation results and calculation time of the coupling model and the single model. Because the case in which the pore volume of the aquifer is 100&#x20;times that of the bottom water layer requires too many grids for the single model and the simulation time is too long, only the other two cases are compared. As shown in <xref ref-type="fig" rid="F3">Figure&#x20;3A</xref>, the water production rates simulated by the coupled and single models are almost the same, which indicates that the analytical aquifer model can accurately simulate the water invasion, and the calculation results of the coupled model are reliable. As shown in <xref ref-type="fig" rid="F3">Figure&#x20;3B</xref>, when the pore volume of the aquifer is four times that of the bottom water layer, the calculation time of the coupled model is approximately 2&#xa0;min (CPU: Intel Core i7 7,700; Memory: 8&#xa0;GB), while the calculation time of the single model is approximately 7&#xa0;min. When the pore volume of the aquifer increases to 20&#x20;times that of the bottom water layer, the calculation time of the coupled model is approximately 3&#xa0;min, which is not a significant increase. However, the calculation time of the single model was increased to 56&#xa0;min owing to the increase in the grid number. The computation time of the single model is 18.7&#x20;times that of the coupled model. The above results show that the coupled model can ensure calculation accuracy and significantly reduce the calculation&#x20;time.</p>
<fig id="F3" position="float">
<label>FIGURE 3</label>
<caption>
<p>Simulation results and calculation time comparison of the coupled model and single model. <bold>(A)</bold> Water production rate. <bold>(B)</bold> Calculation&#x20;time.</p>
</caption>
<graphic xlink:href="fenrg-09-702456-g003.tif"/>
</fig>
</sec>
</sec>
<sec id="s3">
<title>Case Study</title>
<sec id="s3-1">
<title>Numerical Simulation Model</title>
<p>The numerical simulation model was demonstrated using the basic parameters of the HBL at station SH7 in the Shenhu area of the South China Sea, and the initial temperature and pressure of the model were 14.15&#xb0;C and 13&#xa0;MPa, respectively (<xref ref-type="bibr" rid="B15">Liu et&#x20;al., 2012</xref>; <xref ref-type="bibr" rid="B11">Li et&#x20;al., 2011</xref>). According to <xref ref-type="disp-formula" rid="e8">Eq. 8</xref>, the equilibrium pressure corresponding to 14.15&#xb0;C is 11.53&#xa0;MPa, and therefore, the hydrate is stable under the initial conditions. The model can&#x20;be divided into overburden, hydrate, and bottom water layers as shown in <xref ref-type="fig" rid="F4">Figure&#x20;4</xref>. The thickness of the overburden layer is 10&#xa0;m and that of the hydrate layer is 20&#xa0;m. It is recommended that aquifers be modeled at least partially using water-filled grid blocks because if flow reversal occurs, the model with no water-filled grid blocks will encounter convergence problems [CMG (Computer Modelling Group), 2020]. The aquifer used in this study is composed of two parts. One part is the bottom water layer with 10&#xa0;m thickness and the other part is an analytical aquifer represented by the Fetkovich model. A vertical well was located at the center of the formation. Similar to the model built in <italic>Validation and Computational Efficiency Analysis of the Coupled Model</italic> Section, the outer boundaries are all no-flux boundaries except the bottom, and the inner boundary is the Dirichlet boundary. The vertical well maintained a constant bottomhole pressure of 4&#xa0;MPa during the entire depressurization process, and the perforated section of the vertical well ran through the entire hydrate layer. In the model, the hydrate phase cannot flow, and its relative permeability is 0. The modified STONE model is used for the gas-water relative permeability, which is expressed as follows (<xref ref-type="bibr" rid="B21">Moridis, 2003</xref>; <xref ref-type="bibr" rid="B17">Liu et&#x20;al., 2020</xref>):<disp-formula id="e11">
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</disp-formula>The specific parameters of the model are listed in <xref ref-type="table" rid="T2">Table&#x20;2</xref>. Three cases were simulated with the analytical aquifer model, and the total pore volumes of the aquifer (the sum of the pore volumes of the water layer and the aquifer model) were 4 (case 2), 20 (case 3), and 100 (case 4) times that of the hydrate layer. A class III HBL model (case 1) which only has overburden, underburden, and hydrate layers was also simulated for comparison. This case does not have a water layer or an analytic aquifer model; therefore, the pore volumes of the water layer and aquifer model are 0. The simulation time for all the four cases was 10&#xa0;years.</p>
<fig id="F4" position="float">
<label>FIGURE 4</label>
<caption>
<p>Layers of the model.</p>
</caption>
<graphic xlink:href="fenrg-09-702456-g004.tif"/>
</fig>
<table-wrap id="T2" position="float">
<label>TABLE 2</label>
<caption>
<p>Main parameters of the&#x20;model.</p>
</caption>
<table>
<thead valign="top">
<tr>
<th align="left">Parameter</th>
<th align="center">Value</th>
<th align="center">Parameter</th>
<th align="center">Value</th>
</tr>
</thead>
<tbody valign="top">
<tr>
<td align="left">Grid number (<italic>r</italic>&#x20;&#xd7; <italic>z</italic>)</td>
<td align="center">36 &#xd7; 26</td>
<td align="center">Radius of reservoir</td>
<td align="center">200&#xa0;m</td>
</tr>
<tr>
<td align="left">Thickness of overburden</td>
<td align="center">10&#xa0;m</td>
<td align="center">Thickness of HBL</td>
<td align="center">20&#xa0;m</td>
</tr>
<tr>
<td align="left">Thickness of water layer</td>
<td align="center">10&#xa0;m</td>
<td align="center">Porosity of HBL</td>
<td align="center">0.41</td>
</tr>
<tr>
<td align="left">Plane permeability</td>
<td align="center">0.075&#xa0;&#x3bc;m<sup>2</sup>
</td>
<td align="center">Vertical permeability</td>
<td align="center">0.015&#xa0;&#x3bc;m<sup>2</sup>
</td>
</tr>
<tr>
<td align="left">Initial pressure</td>
<td align="center">13&#xa0;MPa</td>
<td align="center">Initial temperature</td>
<td align="center">14.15&#xb0;C</td>
</tr>
<tr>
<td align="left">Initial hydrate saturation</td>
<td align="center">0.44</td>
<td align="center">
<italic>S</italic>
<sub>
<italic>irw</italic>
</sub>
</td>
<td align="center">0.33</td>
</tr>
<tr>
<td align="left">
<italic>S</italic>
<sub>
<italic>irg</italic>
</sub>
</td>
<td align="center">0.02</td>
<td align="center">
<italic>n</italic>
<sub>
<italic>w</italic>
</sub>
</td>
<td align="center">2.2</td>
</tr>
<tr>
<td align="left">
<italic>n</italic>
<sub>
<italic>g</italic>
</sub>
</td>
<td align="center">2.5</td>
<td align="center">Thermal conductivity of hydrate</td>
<td align="center">0.47&#xa0;W/m/C</td>
</tr>
<tr>
<td align="left">Thermal conductivity of rock</td>
<td align="center">2.9&#xa0;W/m/C</td>
<td align="center">Rock density</td>
<td align="center">2,650&#xa0;kg/m<sup>3</sup>
</td>
</tr>
<tr>
<td align="left">Hydrate density</td>
<td align="center">920&#xa0;kg/m<sup>3</sup>
</td>
<td align="center">Rock compressibility</td>
<td align="center">1.5 &#xd7; 10<sup>&#x2013;8</sup>&#xa0;1/Pa</td>
</tr>
</tbody>
</table>
</table-wrap>
</sec>
<sec id="s3-2">
<title>Influence of Aquifer on Gas and Water Production</title>
<p>The gas production rate and cumulative gas production for each case are shown in <xref ref-type="fig" rid="F5">Figure&#x20;5</xref>. It can be seen that the pore volume of the aquifer has a significant impact on the depressurization performance. The peak daily gas production rates for cases 1 to 4 are 4.24 &#xd7; 10<sup>4</sup>, 3.33 &#xd7; 10<sup>4</sup>, 2.61 &#xd7; 10<sup>4</sup>, and 1.20 &#xd7; 104&#xa0;m<sup>3</sup>/d, respectively, and the peak gas production times are 250, 310, 550, and 1,270&#xa0;days, respectively, indicating that the higher the pore volume of the aquifer, the lower the gas production peak, and the later the gas production peak appears. This is mainly because when the aquifer is large, the amount of water that can flow into the HBL from the aquifer is also large, and the depressurization rate of the HBL is accordingly low. The hydrate dissociation rate is positively correlated with the amplitude of depressurization; therefore, the larger the aquifer, the lower the dissociation and gas production rates. In the later stage of depressurization development, the gas production rate shows the opposite trend; that is, the larger the aquifer, the higher the gas production rate. This is mainly because hydrate dissociation is an endothermic reaction. When there is no aquifer, hydrate dissociation in the early stage of depressurization causes the reservoir temperature to rapidly decrease and move closer to the phase equilibrium temperature of the hydrate; thus, the dissociation rate decreases significantly, and the gas production decreases accordingly. When the bottom water layer exists, the heat energy contained in the invasion water can promote hydrate dissociation, and therefore, the gas production for case 4 with the largest aquifer is also the highest in the later stages of depressurization. However, it can be seen from <xref ref-type="fig" rid="F5">Figure&#x20;5B</xref> that case 1 without an aquifer can achieve the highest cumulative gas production in 10&#xa0;years of depressurization development, followed by cases 2, 3, and 4 in order, where the largest aquifer achieves the lowest cumulative gas production.</p>
<fig id="F5" position="float">
<label>FIGURE 5</label>
<caption>
<p>Influence of aquifer on gas production. <bold>(A)</bold> Gas production rate. <bold>(B)</bold> Cumulative gas production.</p>
</caption>
<graphic xlink:href="fenrg-09-702456-g005.tif"/>
</fig>
<p>A comparison of the water production rate and cumulative water production for each case is shown in <xref ref-type="fig" rid="F6">Figure&#x20;6</xref>. It can be seen that in the early stage of depressurization, the water production rates for all the four cases were high. However, when there is no bottom water (case 1), the water production rate decreases rapidly with a decrease in the dissociation rate of the hydrate, while in the cases with bottom water, the decrease in the water production rate is slower. In the late stage of depressurization, the water production rates for cases 2 and 3 are close to those for case 1 owing to the limited pore volume of the aquifer. However, because of the large pore volume of the aquifer and sufficient water supply, the water production rate for case 4 is still significantly higher than those for the other cases after 10&#xa0;years of depressurization development.</p>
<fig id="F6" position="float">
<label>FIGURE 6</label>
<caption>
<p>Influence of aquifer on water production. <bold>(A)</bold> Water production rate. <bold>(B)</bold> Cumulative water production.</p>
</caption>
<graphic xlink:href="fenrg-09-702456-g006.tif"/>
</fig>
</sec>
<sec id="s3-3">
<title>Influence of the Aquifer on the Pressure of the Hydrate-Bearing Layers</title>
<p>
<xref ref-type="fig" rid="F7">Figure&#x20;7</xref> shows changes in the average pressure, and <xref ref-type="fig" rid="F8">Figure&#x20;8</xref> shows the pressure distribution of each case after 10&#xa0;years of depressurization. It can be observed that the average pressure in all cases decreases with time. However, the larger the aquifer volume, the slower the pressure drop. After years of depressurization, the pressure of the entire HBL dropped to approximately 4MPa when there was no bottom water, as shown in <xref ref-type="fig" rid="F8">Figure&#x20;8A</xref>. The pressure distributions for case 2 (<xref ref-type="fig" rid="F8">Figure&#x20;8B</xref>) and case 3 (<xref ref-type="fig" rid="F8">Figure&#x20;8C</xref>) are similar to those for case 1 owing to the smaller pore volume of the aquifer. However, when the pore volume of the aquifer was large (<xref ref-type="fig" rid="F8">Figure&#x20;8D</xref>), only the reservoir pressure near the well was close to the bottom hole pressure, while the reservoir pressure far away from the well was still high, which indicates that the HBL can achieve effective depressurization when the aquifer is small, but it is difficult to achieve rapid depressurization when the bottom water is sufficient.</p>
<fig id="F7" position="float">
<label>FIGURE 7</label>
<caption>
<p>Changes of average pressure.</p>
</caption>
<graphic xlink:href="fenrg-09-702456-g007.tif"/>
</fig>
<fig id="F8" position="float">
<label>FIGURE 8</label>
<caption>
<p>Pressure distribution of each case. <bold>(A)</bold> Case 1. <bold>(B)</bold> Case 2. <bold>(C)</bold> Case 3. <bold>(D)</bold> Case 4.</p>
</caption>
<graphic xlink:href="fenrg-09-702456-g008.tif"/>
</fig>
</sec>
<sec id="s3-4">
<title>Influence of the Aquifer on the Temperature of the Hydrate-Bearing Layers</title>
<p>
<xref ref-type="fig" rid="F9">Figure&#x20;9</xref> shows the changes in average temperature, and <xref ref-type="fig" rid="F10">Figure&#x20;10</xref> shows the temperature distribution for each case after 10&#xa0;years of depressurization. It can be seen that the temperatures for all the cases decreased owing to the dissociation of the hydrate. The temperature of the whole HBL dropped to approximately 4.2&#xb0;C, which corresponds to the phase equilibrium temperature of the bottom hole pressure of 4&#xa0;MPa at the end of depressurization development because there is no external energy supplement for case 1 (<xref ref-type="fig" rid="F10">Figure&#x20;10A</xref>). For cases 2 and 3 (<xref ref-type="fig" rid="F10">Figures 10B,C</xref>), the temperature of the area far away from the vertical well also dropped to near the phase equilibrium temperature, but there was an evident cone-shaped high-temperature area at the bottom of the well. This is mainly because bottom water coning on the vertical well can supplement the heat energy consumed by hydrate dissociation near the bottom of the well. For case 4, the temperature of the HBL was significantly higher than the phase equilibrium temperature. This is mainly because it is difficult for the HBL to achieve rapid depressurization when the aquifer is large (<xref ref-type="fig" rid="F10">Figure&#x20;10D</xref>); thus, the hydrate dissociation rate is lowered, and the thermal energy of the HBL is not fully utilized. Similar to cases 2 and 3, the temperature of the bottom water coning area in <xref ref-type="fig" rid="F10">Figure&#x20;10D</xref> is also significantly higher than that of the non-coning area because of the energy supplement of the bottom&#x20;water.</p>
<fig id="F9" position="float">
<label>FIGURE 9</label>
<caption>
<p>Changes of average temperature.</p>
</caption>
<graphic xlink:href="fenrg-09-702456-g009.tif"/>
</fig>
<fig id="F10" position="float">
<label>FIGURE 10</label>
<caption>
<p>Temperature distribution of each case. <bold>(A)</bold> Case 1. <bold>(B)</bold> Case 2. <bold>(C)</bold> Case 3. (D) Case 4.</p>
</caption>
<graphic xlink:href="fenrg-09-702456-g010.tif"/>
</fig>
</sec>
<sec id="s3-5">
<title>Influence of the Aquifer on the Hydrate Saturation of the Hydrate Bearing Layers</title>
<p>
<xref ref-type="fig" rid="F11">Figure&#x20;11</xref> shows the changes in average hydrate saturation of the hydrate layer and <xref ref-type="fig" rid="F12">Figure&#x20;12</xref> shows the hydrate saturation distribution for each case after 10&#xa0;years of depressurization. When depressurization begins, the hydrate near the well quickly dissociates because the near-well zone has the lowest pressure and the average hydrate saturation decreases. At the end of the depressurization development, the hydrate in the near-well zone was completely dissociated in all cases. However, the shapes of the hydrate dissociation region of the four cases were different. For case 1, the distribution of the hydrate saturation is approximately symmetrical in the vertical direction, while for other cases with bottom water, there is a cone-shaped dissociation zone near the bottom water; in addition, the larger the pore volume of the aquifer, the larger the area of the cone-shaped dissociation zone. This is mainly because the heat carried by the bottom water can effectively promote hydrate dissociation in the water invasion area. At the end of depressurization, there is still a large quantity of un-dissociated hydrate in each case, and the larger the aquifer, the greater the saturation of the remaining hydrate.</p>
<fig id="F11" position="float">
<label>FIGURE 11</label>
<caption>
<p>Changes of average hydrate saturation of the hydrate&#x20;layer.</p>
</caption>
<graphic xlink:href="fenrg-09-702456-g011.tif"/>
</fig>
<fig id="F12" position="float">
<label>FIGURE 12</label>
<caption>
<p>Hydrate saturation distribution of each case. <bold>(A)</bold> Case 1. <bold>(B)</bold> Case 2. <bold>(C)</bold> Case 3. <bold>(D)</bold> Case 4.</p>
</caption>
<graphic xlink:href="fenrg-09-702456-g012.tif"/>
</fig>
<p>From the above analysis, it can be seen that bottom water can have a significant impact on the performance of the HBL. The larger the aquifer, the slower the depressurization rate, and the lower the corresponding gas production. Therefore, the invasion of bottom water is not conducive to the depressurization development of Class II&#x20;HBLs.</p>
</sec>
</sec>
<sec sec-type="discussion" id="s4">
<title>Discussion</title>
<p>Although the coupled model built in this study shows good performance and the calculated water invasion rates are consistent with those obtained by the commercial software CMG, the reliability of the simulation results should be validated by physical experiments. However, at present, it is quite difficult to construct a physical model in which the upper layer is a hydrate layer and the lower layer is a water layer. Moreover, if the aquifer volume is large, the large size of the model will cause considerable difficulties in the implementation of the experiment. Therefore, new experimental setups and procedures should be investigated in the future.</p>
<p>Furthermore, field tests and studies have shown that many HBLs are poorly cemented, and therefore, sediment deformation should be evaluated, and the influence of sediment deformation on depressurization should be considered for this type of HBLs (<xref ref-type="bibr" rid="B31">Wan et&#x20;al., 2018</xref>). This study emphasizes the coupling of the HBL and aquifer models to reduce the simulation time of Class II HBLs, and sediment deformation is neglected. An integrated model that includes the HBL, geomechanical, and analytical aquifer models should be developed in the future to investigate the performance of Class II&#x20;HBLs.</p>
</sec>
<sec sec-type="conclusion" id="s5">
<title>Conclusion</title>
<p>A coupled numerical simulation model of the analytical aquifer model and the HBL model was proposed and validated. Using the model, the influence of bottom water on the gas depressurization performance was analyzed. The main conclusions are as follows:<list list-type="simple">
<list-item>
<p>1) By coupling the HBL and analytic aquifer numerical simulation models, the simulation time of a Class II hydrate reservoir with a large aquifer volume can be significantly reduced while ensuring calculation accuracy. For the bottom water layer investigated in this study, for which the pore volume of the aquifer is 20&#x20;times that of the bottom water layer, the computation time of the single model is 18.7&#x20;times that of the coupled&#x20;model.</p>
</list-item>
<list-item>
<p>2) The larger the aquifer, the lower the peak value of gas production, and the later the peak value appears. When the pore volume of the aquifer is large, the water production remains high in the later stages of depressurization. The invasion of bottom water slows down the depressurization of the HBL, and the hydrate dissociation and gas production rates decrease. Furthermore, the larger the aquifer, the higher the pressure, temperature, and residual hydrate saturation at the end of depressurization.</p>
</list-item>
<list-item>
<p>3) Owing to high levels of hydrate dissociation, the temperature of the HBL decreases rapidly to the equilibrium temperature when there is no bottom water layer. When a bottom water layer is present, the invasion of the bottom water provides heat to the water invasion area, creating a cone-shaped hydrate dissociation area near the&#x20;well.</p>
</list-item>
</list>
</p>
</sec>
</body>
<back>
<sec id="s6">
<title>Data Availability Statement</title>
<p>The original contributions presented in the study are included in the article/Supplementary Material, further inquiries can be directed to the corresponding author.</p>
</sec>
<sec id="s7">
<title>Author Contributions</title>
<p>JY: Writing&#x2014;original draft, Methodology, Investigation. LZ: Supervision, Validation. YC: Supervision, Methodology, Data curation. WS: Visualization, review and editing. YL: Writing, simulation.</p>
</sec>
<sec id="s8">
<title>Funding</title>
<p>This work was financially supported by Basic Research and Strategic Reserve Technology Research Fund of CNPC (Grant No. 2017B4906) and Research Project of CNPC Engineering Technology R&#x26;D Company Limited (Grant No. CPETQ202111).</p>
</sec>
<sec sec-type="COI-statement" id="s9">
<title>Conflict of Interest</title>
<p>JY, LZ, and WS were employed by the company CNPC Engineering Technology R&#x26;D Company Limited, and YC was employed by the company China Petroleum Technology Development Company Limited.</p>
<p>The remaining author declares that the research was conducted in the absence of any commercial or financial relationships that could be construed as a potential conflict of interest.</p>
</sec>
<sec id="s10" sec-type="disclaimer">
<title>Publisher&#x2019;s Note</title>
<p>All claims expressed in this article are solely those of the authors and do not necessarily represent those of their affiliated organizations, or those of the publisher, the editors and the reviewers. Any product that may be evaluated in this article, or claim that may be made by its manufacturer, is not guaranteed or endorsed by the publisher.</p>
</sec>
<ref-list>
<title>References</title>
<ref id="B1">
<citation citation-type="journal">
<person-group person-group-type="author">
<name>
<surname>Aydin</surname>
<given-names>G.</given-names>
</name>
<name>
<surname>Jang</surname>
<given-names>H.</given-names>
</name>
<name>
<surname>Topal</surname>
<given-names>E.</given-names>
</name>
</person-group> (<year>2016</year>). <article-title>Energy Consumption Modeling Using Artificial Neural Networks: The Case of the World&#x27;s Highest Consumers</article-title>. <source>Energ. Sourc. B: Econ. Plann. Pol.</source> <volume>11</volume>, <fpage>212</fpage>&#x2013;<lpage>219</lpage>. <pub-id pub-id-type="doi">10.1080/15567249.2015.1075086</pub-id> </citation>
</ref>
<ref id="B2">
<citation citation-type="journal">
<person-group person-group-type="author">
<name>
<surname>Bhade</surname>
<given-names>P.</given-names>
</name>
<name>
<surname>Phirani</surname>
<given-names>J.</given-names>
</name>
</person-group> (<year>2015</year>). <article-title>Effect of Geological Layers on Hydrate Dissociation in Natural Gas Hydrate Reservoirs</article-title>. <source>J.&#x20;Nat. Gas Sci. Eng.</source> <volume>26</volume>, <fpage>1549</fpage>&#x2013;<lpage>1560</lpage>. <pub-id pub-id-type="doi">10.1016/j.jngse.2015.05.016</pub-id> </citation>
</ref>
<ref id="B3">
<citation citation-type="journal">
<person-group person-group-type="author">
<name>
<surname>Boswell</surname>
<given-names>R.</given-names>
</name>
<name>
<surname>Yoneda</surname>
<given-names>J.</given-names>
</name>
<name>
<surname>Waite</surname>
<given-names>W. F.</given-names>
</name>
</person-group> (<year>2019</year>). <article-title>India National Gas Hydrate Program Expedition 02 Summary of Scientific Results: Evaluation of Natural Gas-Hydrate-Bearing Pressure Cores</article-title>. <source>Mar. Pet. Geology.</source> <volume>108</volume>, <fpage>143</fpage>&#x2013;<lpage>153</lpage>. <pub-id pub-id-type="doi">10.1016/j.marpetgeo.2018.10.020</pub-id> </citation>
</ref>
<ref id="B4">
<citation citation-type="journal">
<person-group person-group-type="author">
<name>
<surname>Chong</surname>
<given-names>Z. R.</given-names>
</name>
<name>
<surname>Yang</surname>
<given-names>S. H. B.</given-names>
</name>
<name>
<surname>Babu</surname>
<given-names>P.</given-names>
</name>
<name>
<surname>Linga</surname>
<given-names>P.</given-names>
</name>
<name>
<surname>Li</surname>
<given-names>X.-S.</given-names>
</name>
</person-group> (<year>2016</year>). <article-title>Review of Natural Gas Hydrates as an Energy Resource: Prospects and Challenges</article-title>. <source>Appl. Energ.</source> <volume>162</volume>, <fpage>1633</fpage>&#x2013;<lpage>1652</lpage>. <pub-id pub-id-type="doi">10.1016/j.apenergy.2014.12.061</pub-id> </citation>
</ref>
<ref id="B6">
<citation citation-type="journal">
<person-group person-group-type="author">
<name>
<surname>Collett</surname>
<given-names>T. S.</given-names>
</name>
<name>
<surname>Lee</surname>
<given-names>M. W.</given-names>
</name>
<name>
<surname>Agena</surname>
<given-names>W. F.</given-names>
</name>
<name>
<surname>Miller</surname>
<given-names>J.&#x20;J.</given-names>
</name>
<name>
<surname>Lewis</surname>
<given-names>K. A.</given-names>
</name>
<name>
<surname>Zyrianova</surname>
<given-names>M. V.</given-names>
</name>
<etal/>
</person-group> (<year>2011</year>). <article-title>Permafrost-associated Natural Gas Hydrate Occurrences on the Alaska North Slope</article-title>. <source>Mar. Pet. Geology.</source> <volume>28</volume>, <fpage>279</fpage>&#x2013;<lpage>294</lpage>. <pub-id pub-id-type="doi">10.1016/j.marpetgeo.2009.12.001</pub-id> </citation>
</ref>
<ref id="B7">
<citation citation-type="journal">
<person-group person-group-type="author">
<name>
<surname>Esmaeilzadeh</surname>
<given-names>F.</given-names>
</name>
<name>
<surname>Hamedi</surname>
<given-names>N.</given-names>
</name>
<name>
<surname>Karimipourfard</surname>
<given-names>D.</given-names>
</name>
<name>
<surname>Rasoolzadeh</surname>
<given-names>A.</given-names>
</name>
</person-group> (<year>2020</year>). <article-title>An Insight into the Role of the Association Equations of States in Gas Hydrate Modeling: a Review</article-title>. <source>Pet. Sci.</source> <volume>17</volume>, <fpage>1432</fpage>&#x2013;<lpage>1450</lpage>. <pub-id pub-id-type="doi">10.1007/s12182-020-00471-9</pub-id> </citation>
</ref>
<ref id="B8">
<citation citation-type="journal">
<person-group person-group-type="author">
<name>
<surname>Fetkovich</surname>
<given-names>M. J.</given-names>
</name>
</person-group> (<year>1971</year>). <article-title>A Simplified Approach to Water Influx Calculations-Finite Aquifer Systems</article-title>. <source>J.&#x20;Pet. Technol.</source> <volume>23</volume> (<issue>07</issue>), <fpage>814</fpage>&#x2013;<lpage>828</lpage>. <pub-id pub-id-type="doi">10.2118/2603-pa</pub-id> </citation>
</ref>
<ref id="B9">
<citation citation-type="journal">
<person-group person-group-type="author">
<name>
<surname>Hou</surname>
<given-names>J.</given-names>
</name>
<name>
<surname>Xia</surname>
<given-names>Z.</given-names>
</name>
<name>
<surname>Li</surname>
<given-names>S.</given-names>
</name>
<name>
<surname>Zhou</surname>
<given-names>K.</given-names>
</name>
<name>
<surname>Lu</surname>
<given-names>N.</given-names>
</name>
</person-group> (<year>2016</year>). <article-title>Operation Parameter Optimization of a Gas Hydrate Reservoir Developed by Cyclic Hot Water Stimulation with a Separated-Zone Horizontal Well Based on Particle Swarm Algorithm</article-title>. <source>Energy</source> <volume>96</volume>, <fpage>581</fpage>&#x2013;<lpage>591</lpage>. <pub-id pub-id-type="doi">10.1016/j.energy.2015.12.066</pub-id> </citation>
</ref>
<ref id="B10">
<citation citation-type="journal">
<person-group person-group-type="author">
<name>
<surname>Kowalsky</surname>
<given-names>M. B.</given-names>
</name>
<name>
<surname>Moridis</surname>
<given-names>G. J.</given-names>
</name>
</person-group> (<year>2007</year>). <article-title>Comparison of Kinetic and Equilibrium Reaction Models in Simulating Gas Hydrate Behavior in Porous media</article-title>. <source>Energ. Convers. Manag.</source> <volume>48</volume>, <fpage>1850</fpage>&#x2013;<lpage>1863</lpage>. <pub-id pub-id-type="doi">10.1016/j.enconman.2007.01.017</pub-id> </citation>
</ref>
<ref id="B11">
<citation citation-type="journal">
<person-group person-group-type="author">
<name>
<surname>Li</surname>
<given-names>G.</given-names>
</name>
<name>
<surname>Moridis</surname>
<given-names>G. J.</given-names>
</name>
<name>
<surname>Zhang</surname>
<given-names>K.</given-names>
</name>
<name>
<surname>Li</surname>
<given-names>X.-s.</given-names>
</name>
</person-group> (<year>2011</year>). <article-title>The Use of Huff and Puff Method in a Single Horizontal Well in Gas Production from marine Gas Hydrate Deposits in the Shenhu Area of South China Sea</article-title>. <source>J.&#x20;Pet. Sci. Eng.</source> <volume>77</volume>, <fpage>49</fpage>&#x2013;<lpage>68</lpage>. <pub-id pub-id-type="doi">10.1016/j.petrol.2011.02.009</pub-id> </citation>
</ref>
<ref id="B12">
<citation citation-type="journal">
<person-group person-group-type="author">
<name>
<surname>Li</surname>
<given-names>J.-f.</given-names>
</name>
<name>
<surname>Ye</surname>
<given-names>J.</given-names>
</name>
<name>
<surname>Ye</surname>
<given-names>J.-l.</given-names>
</name>
<name>
<surname>Qin</surname>
<given-names>X.-w.</given-names>
</name>
<name>
<surname>Qiu</surname>
<given-names>H.-j.</given-names>
</name>
<name>
<surname>Wu</surname>
<given-names>N.-y.</given-names>
</name>
<etal/>
</person-group> (<year>2018</year>). <article-title>The First Offshore Natural Gas Hydrate Production Test in South China Sea</article-title>. <source>China Geol.</source> <volume>1</volume> (<issue>1</issue>), <fpage>5</fpage>&#x2013;<lpage>16</lpage>. <pub-id pub-id-type="doi">10.31035/cg2018003</pub-id> </citation>
</ref>
<ref id="B13">
<citation citation-type="journal">
<person-group person-group-type="author">
<name>
<surname>Li</surname>
<given-names>S.</given-names>
</name>
<name>
<surname>Li</surname>
<given-names>S.</given-names>
</name>
<name>
<surname>Zheng</surname>
<given-names>R.</given-names>
</name>
<name>
<surname>Li</surname>
<given-names>Q.</given-names>
</name>
<name>
<surname>Pang</surname>
<given-names>W.</given-names>
</name>
</person-group> (<year>2021</year>). <article-title>Strategies for Gas Production from Class 2 Hydrate Accumulations by Depressurization</article-title>. <source>Fuel</source> <volume>286</volume>, <fpage>119380</fpage>. <pub-id pub-id-type="doi">10.1016/j.fuel.2020.119380</pub-id> </citation>
</ref>
<ref id="B14">
<citation citation-type="journal">
<person-group person-group-type="author">
<name>
<surname>Li</surname>
<given-names>X.-S.</given-names>
</name>
<name>
<surname>Xu</surname>
<given-names>C.-G.</given-names>
</name>
<name>
<surname>Zhang</surname>
<given-names>Y.</given-names>
</name>
<name>
<surname>Ruan</surname>
<given-names>X.-K.</given-names>
</name>
<name>
<surname>Li</surname>
<given-names>G.</given-names>
</name>
<name>
<surname>Wang</surname>
<given-names>Y.</given-names>
</name>
</person-group> (<year>2016</year>). <article-title>Investigation into Gas Production from Natural Gas Hydrate: A Review</article-title>. <source>Appl. Energ.</source> <volume>172</volume>, <fpage>286</fpage>&#x2013;<lpage>322</lpage>. <pub-id pub-id-type="doi">10.1016/j.apenergy.2016.03.101</pub-id> </citation>
</ref>
<ref id="B15">
<citation citation-type="journal">
<person-group person-group-type="author">
<name>
<surname>Liu</surname>
<given-names>C.</given-names>
</name>
<name>
<surname>Ye</surname>
<given-names>Y.</given-names>
</name>
<name>
<surname>Meng</surname>
<given-names>Q.</given-names>
</name>
<name>
<surname>He</surname>
<given-names>X.</given-names>
</name>
<name>
<surname>Lu</surname>
<given-names>H.</given-names>
</name>
<name>
<surname>Zhang</surname>
<given-names>J.</given-names>
</name>
<etal/>
</person-group> (<year>2012</year>). <article-title>The Characteristics of Gas Hydrates Recovered from Shenhu Area in the South China Sea</article-title>. <source>Mar. Geology.</source> <volume>307-310</volume>, <fpage>22</fpage>&#x2013;<lpage>27</lpage>. <pub-id pub-id-type="doi">10.1016/j.margeo.2012.03.004</pub-id> </citation>
</ref>
<ref id="B16">
<citation citation-type="journal">
<person-group person-group-type="author">
<name>
<surname>Liu</surname>
<given-names>Y.</given-names>
</name>
<name>
<surname>Bai</surname>
<given-names>Y.</given-names>
</name>
<name>
<surname>Xia</surname>
<given-names>Z.</given-names>
</name>
<name>
<surname>Hou</surname>
<given-names>J.</given-names>
</name>
</person-group> (<year>2018a</year>). <article-title>Parameter Optimization of Depressurization&#x2212;to&#x2212;Hot&#x2212;Water&#x2212;Flooding in Heterogeneous Hydrate Bearing Layers Based on the Particle Swarm Optimization Algorithm</article-title>. <source>J.&#x20;Nat. Gas Sci. Eng.</source> <volume>53</volume>, <fpage>403</fpage>&#x2013;<lpage>415</lpage>. <pub-id pub-id-type="doi">10.1016/j.jngse.2018.03.017</pub-id> </citation>
</ref>
<ref id="B17">
<citation citation-type="journal">
<person-group person-group-type="author">
<name>
<surname>Liu</surname>
<given-names>Y.</given-names>
</name>
<name>
<surname>Hou</surname>
<given-names>J.</given-names>
</name>
<name>
<surname>Chen</surname>
<given-names>Z.</given-names>
</name>
<name>
<surname>Su</surname>
<given-names>H.</given-names>
</name>
<name>
<surname>Zhao</surname>
<given-names>E.</given-names>
</name>
<name>
<surname>Li</surname>
<given-names>G.</given-names>
</name>
</person-group> (<year>2020</year>). <article-title>A Novel Natural Gas Hydrate Recovery Approach by Delivering Geothermal Energy through Dumpflooding</article-title>. <source>Energ. Convers. Manag.</source> <volume>209</volume>, <fpage>112623</fpage>. <pub-id pub-id-type="doi">10.1016/j.enconman.2020.112623</pub-id> </citation>
</ref>
<ref id="B18">
<citation citation-type="journal">
<person-group person-group-type="author">
<name>
<surname>Liu</surname>
<given-names>Y.</given-names>
</name>
<name>
<surname>Hou</surname>
<given-names>J.</given-names>
</name>
<name>
<surname>Zhao</surname>
<given-names>H.</given-names>
</name>
<name>
<surname>Liu</surname>
<given-names>X.</given-names>
</name>
<name>
<surname>Xia</surname>
<given-names>Z.</given-names>
</name>
</person-group> (<year>2018b</year>). <article-title>A Method to Recover Natural Gas Hydrates with Geothermal Energy Conveyed by CO2</article-title>. <source>Energy</source> <volume>144</volume>, <fpage>265</fpage>&#x2013;<lpage>278</lpage>. <pub-id pub-id-type="doi">10.1016/j.energy.2017.12.030</pub-id> </citation>
</ref>
<ref id="B19">
<citation citation-type="journal">
<person-group person-group-type="author">
<name>
<surname>Luo</surname>
<given-names>T.</given-names>
</name>
<name>
<surname>Li</surname>
<given-names>Y.</given-names>
</name>
<name>
<surname>Madhusudhan</surname>
<given-names>B. N.</given-names>
</name>
<name>
<surname>Sun</surname>
<given-names>X.</given-names>
</name>
<name>
<surname>Song</surname>
<given-names>Y.</given-names>
</name>
</person-group> (<year>2020</year>). <article-title>Deformation Behaviors of Hydrate-Bearing Silty Sediment Induced by Depressurization and thermal Recovery</article-title>. <source>Appl. Energ.</source> <volume>276</volume>, <fpage>115468</fpage>. <pub-id pub-id-type="doi">10.1016/j.apenergy.2020.115468</pub-id> </citation>
</ref>
<ref id="B20">
<citation citation-type="journal">
<person-group person-group-type="author">
<name>
<surname>Moridis</surname>
<given-names>G. J.&#x20;J.</given-names>
</name>
<name>
<surname>Collett</surname>
<given-names>T. S. S.</given-names>
</name>
<name>
<surname>Pooladi-Darvish</surname>
<given-names>M.</given-names>
</name>
<name>
<surname>Hancock</surname>
<given-names>S.</given-names>
</name>
<name>
<surname>Santamarina</surname>
<given-names>C.</given-names>
</name>
<name>
<surname>Boswell</surname>
<given-names>R.</given-names>
</name>
<etal/>
</person-group> (<year>2011a</year>). <article-title>Challenges, Uncertainties, and Issues Facing Gas Production from Gas-Hydrate Deposits</article-title>. <source>SPE Reservoir Eval. Eng.</source> <volume>14</volume>, <fpage>76</fpage>&#x2013;<lpage>112</lpage>. <pub-id pub-id-type="doi">10.2118/131792-pa</pub-id> </citation>
</ref>
<ref id="B21">
<citation citation-type="journal">
<person-group person-group-type="author">
<name>
<surname>Moridis</surname>
<given-names>G. J.</given-names>
</name>
</person-group> (<year>2003</year>). <article-title>Numerical Studies of Gas Production from Methane Hydrates</article-title>. <source>SPE J.</source> <volume>8</volume>, <fpage>359</fpage>&#x2013;<lpage>370</lpage>. <pub-id pub-id-type="doi">10.2118/87330-pa</pub-id> </citation>
</ref>
<ref id="B22">
<citation citation-type="journal">
<person-group person-group-type="author">
<name>
<surname>Moridis</surname>
<given-names>G. J.</given-names>
</name>
<name>
<surname>Reagan</surname>
<given-names>M. T.</given-names>
</name>
</person-group> (<year>2011</year>). <article-title>Estimating the Upper Limit of Gas Production from Class 2 Hydrate Accumulations in the Permafrost: 1. Concepts, System Description, and the Production Base Case</article-title>. <source>J.&#x20;Pet. Sci. Eng.</source> <volume>76</volume>, <fpage>194</fpage>&#x2013;<lpage>204</lpage>. <pub-id pub-id-type="doi">10.1016/j.petrol.2010.11.023</pub-id> </citation>
</ref>
<ref id="B23">
<citation citation-type="journal">
<person-group person-group-type="author">
<name>
<surname>Moridis</surname>
<given-names>G. J.</given-names>
</name>
<name>
<surname>Silpngarmlert</surname>
<given-names>S.</given-names>
</name>
<name>
<surname>Reagan</surname>
<given-names>M. T.</given-names>
</name>
<name>
<surname>Collett</surname>
<given-names>T.</given-names>
</name>
<name>
<surname>Zhang</surname>
<given-names>K.</given-names>
</name>
</person-group> (<year>2011b</year>). <article-title>Gas Production from a Cold, Stratigraphically-Bounded Gas Hydrate deposit at the Mount Elbert Gas Hydrate Stratigraphic Test Well, Alaska North Slope: Implications of Uncertainties</article-title>. <source>Mar. Pet. Geology.</source> <volume>28</volume>, <fpage>517</fpage>&#x2013;<lpage>534</lpage>. <pub-id pub-id-type="doi">10.1016/j.marpetgeo.2010.01.005</pub-id> </citation>
</ref>
<ref id="B24">
<citation citation-type="journal">
<person-group person-group-type="author">
<name>
<surname>Pang</surname>
<given-names>X.</given-names>
</name>
<name>
<surname>Chen</surname>
<given-names>Z.</given-names>
</name>
<name>
<surname>Jia</surname>
<given-names>C.</given-names>
</name>
<name>
<surname>Wang</surname>
<given-names>E.</given-names>
</name>
<name>
<surname>Shi</surname>
<given-names>H.</given-names>
</name>
<name>
<surname>Wu</surname>
<given-names>Z. Y.</given-names>
</name>
<etal/>
</person-group> (<year>2021</year>). <article-title>Evaluation and Re-understanding of the Global Natural Gas Hydrate Resources</article-title>. <source>Pet. Sci.</source> <volume>18</volume>, <fpage>1</fpage>&#x2013;<lpage>16</lpage>. <pub-id pub-id-type="doi">10.1007/s12182-021-00568-9</pub-id> </citation>
</ref>
<ref id="B25">
<citation citation-type="confproc">
<person-group person-group-type="author">
<name>
<surname>Reagan</surname>
<given-names>M.</given-names>
</name>
<name>
<surname>Moridis</surname>
<given-names>G.</given-names>
</name>
<name>
<surname>Zhang</surname>
<given-names>K.</given-names>
</name>
</person-group> (<year>2008</year>). &#x201c;<article-title>Sensitivity Analysis of Gas Production from Class 2 and Class 3 Hydrate Deposits</article-title>,&#x201d; in <conf-name>Offshore Technology Conference</conf-name>, <conf-date>May 5-8, 2008</conf-date>, <conf-loc>Texas, USA</conf-loc>. <pub-id pub-id-type="doi">10.4043/19554-ms</pub-id> </citation>
</ref>
<ref id="B26">
<citation citation-type="journal">
<person-group person-group-type="author">
<name>
<surname>Ruan</surname>
<given-names>X.</given-names>
</name>
<name>
<surname>Li</surname>
<given-names>X.-S.</given-names>
</name>
<name>
<surname>Xu</surname>
<given-names>C.-G.</given-names>
</name>
</person-group> (<year>2021</year>). <article-title>A Review of Numerical Research on Gas Production from Natural Gas Hydrates in China</article-title>. <source>J.&#x20;Nat. Gas Sci. Eng.</source> <volume>85</volume>, <fpage>103713</fpage>. <pub-id pub-id-type="doi">10.1016/j.jngse.2020.103713</pub-id> </citation>
</ref>
<ref id="B27">
<citation citation-type="journal">
<person-group person-group-type="author">
<name>
<surname>Song</surname>
<given-names>Y.</given-names>
</name>
<name>
<surname>Yang</surname>
<given-names>L.</given-names>
</name>
<name>
<surname>Zhao</surname>
<given-names>J.</given-names>
</name>
<name>
<surname>Liu</surname>
<given-names>W.</given-names>
</name>
<name>
<surname>Yang</surname>
<given-names>M.</given-names>
</name>
<name>
<surname>Li</surname>
<given-names>Y.</given-names>
</name>
<etal/>
</person-group> (<year>2014</year>). <article-title>The Status of Natural Gas Hydrate Research in China: A Review</article-title>. <source>Renew. Sust. Energ. Rev.</source> <volume>31</volume>, <fpage>778</fpage>&#x2013;<lpage>791</lpage>. <pub-id pub-id-type="doi">10.1016/j.rser.2013.12.025</pub-id> </citation>
</ref>
<ref id="B28">
<citation citation-type="journal">
<person-group person-group-type="author">
<name>
<surname>Tran</surname>
<given-names>D.</given-names>
</name>
<name>
<surname>Nghiem</surname>
<given-names>L.</given-names>
</name>
<name>
<surname>Buchanan</surname>
<given-names>B.</given-names>
</name>
</person-group> (<year>2005</year>). &#x201c;<article-title>An Overview of Iterative Coupling between Geomechanical Deformation and Reservoir Flow</article-title>,&#x201d; in <conf-name>SPE International Thermal Operations and Heavy Oil Symposium</conf-name>, <conf-date>November 1-3, 2005</conf-date>, <conf-loc>Alberta, Canada</conf-loc>. <pub-id pub-id-type="doi">10.2118/97879-ms</pub-id> </citation>
</ref>
<ref id="B29">
<citation citation-type="journal">
<person-group person-group-type="author">
<name>
<surname>Uddin</surname>
<given-names>M.</given-names>
</name>
<name>
<surname>Wright</surname>
<given-names>F.</given-names>
</name>
<name>
<surname>Dallimore</surname>
<given-names>S.</given-names>
</name>
<name>
<surname>Coombe</surname>
<given-names>D.</given-names>
</name>
</person-group> (<year>2014</year>). <article-title>Gas Hydrate Dissociations in Mallik Hydrate Bearing Zones A, B, and C by Depressurization: Effect of Salinity and Hydration Number in Hydrate Dissociation</article-title>. <source>J.&#x20;Nat. Gas Sci. Eng.</source> <volume>21</volume>, <fpage>40</fpage>&#x2013;<lpage>63</lpage>. <pub-id pub-id-type="doi">10.1016/j.jngse.2014.07.027</pub-id> </citation>
</ref>
<ref id="B30">
<citation citation-type="journal">
<person-group person-group-type="author">
<name>
<surname>Wan</surname>
<given-names>Q.-C.</given-names>
</name>
<name>
<surname>Si</surname>
<given-names>H.</given-names>
</name>
<name>
<surname>Li</surname>
<given-names>G.</given-names>
</name>
<name>
<surname>Feng</surname>
<given-names>J.-C.</given-names>
</name>
<name>
<surname>Li</surname>
<given-names>B.</given-names>
</name>
</person-group> (<year>2020</year>). <article-title>Heterogeneity Properties of Methane Hydrate Formation in a Pilot-Scale Hydrate Simulator</article-title>. <source>Appl. Energ.</source> <volume>261</volume>, <fpage>114325</fpage>. <pub-id pub-id-type="doi">10.1016/j.apenergy.2019.114325</pub-id> </citation>
</ref>
<ref id="B31">
<citation citation-type="journal">
<person-group person-group-type="author">
<name>
<surname>Wan</surname>
<given-names>Y.</given-names>
</name>
<name>
<surname>Wu</surname>
<given-names>N.</given-names>
</name>
<name>
<surname>Hu</surname>
<given-names>G.</given-names>
</name>
<name>
<surname>Xin</surname>
<given-names>X.</given-names>
</name>
<name>
<surname>Jin</surname>
<given-names>G.</given-names>
</name>
<name>
<surname>Liu</surname>
<given-names>C.</given-names>
</name>
<etal/>
</person-group> (<year>2018</year>). <article-title>Reservoir Stability in the Process of Natural Gas Hydrate Production by Depressurization in the Shenhu Area of the south China Sea</article-title>. <source>Nat. Gas Industry B</source> <volume>5</volume>, <fpage>631</fpage>&#x2013;<lpage>643</lpage>. <pub-id pub-id-type="doi">10.1016/j.ngib.2018.11.012</pub-id> </citation>
</ref>
<ref id="B32">
<citation citation-type="journal">
<person-group person-group-type="author">
<name>
<surname>Wei</surname>
<given-names>J.</given-names>
</name>
<name>
<surname>Fang</surname>
<given-names>Y.</given-names>
</name>
<name>
<surname>Lu</surname>
<given-names>H.</given-names>
</name>
<name>
<surname>Lu</surname>
<given-names>H.</given-names>
</name>
<name>
<surname>Lu</surname>
<given-names>J.</given-names>
</name>
<name>
<surname>Liang</surname>
<given-names>J.</given-names>
</name>
<etal/>
</person-group> (<year>2018</year>). <article-title>Distribution and Characteristics of Natural Gas Hydrates in the Shenhu Sea Area, South China Sea</article-title>. <source>Mar. Pet. Geology.</source> <volume>98</volume>, <fpage>622</fpage>&#x2013;<lpage>628</lpage>. <pub-id pub-id-type="doi">10.1016/j.marpetgeo.2018.07.028</pub-id> </citation>
</ref>
<ref id="B33">
<citation citation-type="journal">
<person-group person-group-type="author">
<name>
<surname>Yang</surname>
<given-names>M.</given-names>
</name>
<name>
<surname>Zhao</surname>
<given-names>J.</given-names>
</name>
<name>
<surname>Zheng</surname>
<given-names>J.-n.</given-names>
</name>
<name>
<surname>Song</surname>
<given-names>Y.</given-names>
</name>
</person-group> (<year>2019</year>). <article-title>Hydrate Reformation Characteristics in Natural Gas Hydrate Dissociation Process: A Review</article-title>. <source>Appl. Energ.</source> <volume>256</volume>, <fpage>113878</fpage>. <pub-id pub-id-type="doi">10.1016/j.apenergy.2019.113878</pub-id> </citation>
</ref>
<ref id="B34">
<citation citation-type="journal">
<person-group person-group-type="author">
<name>
<surname>Ye</surname>
<given-names>J.</given-names>
</name>
<name>
<surname>Qin</surname>
<given-names>X.</given-names>
</name>
<name>
<surname>Xie</surname>
<given-names>W.</given-names>
</name>
<name>
<surname>Lu</surname>
<given-names>H.</given-names>
</name>
<name>
<surname>Ma</surname>
<given-names>B.</given-names>
</name>
<name>
<surname>Qiu</surname>
<given-names>H.</given-names>
</name>
<etal/>
</person-group> (<year>2020</year>). <article-title>The Second Natural Gas Hydrate Production Test in the South China Sea</article-title>. <source>China Geol.</source> <volume>3</volume>, <fpage>197</fpage>&#x2013;<lpage>209</lpage>. <pub-id pub-id-type="doi">10.31035/cg2020043</pub-id> </citation>
</ref>
</ref-list>
<sec id="s11">
<title>Glossary</title>
<def-list>
<def-item>
<term id="G1-fenrg.2021.702456">
<italic>B</italic>
<sub>
<italic>g</italic>
</sub>
</term>
<def>
<p>gas volume factor</p>
</def>
</def-item>
<def-item>
<term id="G2-fenrg.2021.702456">
<italic>B</italic>
<sub>
<italic>w</italic>
</sub>
</term>
<def>
<p>water volume factor</p>
</def>
</def-item>
<def-item>
<term id="G3-fenrg.2021.702456">
<italic>B</italic>
<sub>
<italic>wi</italic>
</sub>
</term>
<def>
<p>water volume factor at the initial pressure of the bottom water&#x20;layer</p>
</def>
</def-item>
<def-item>
<term id="G4-fenrg.2021.702456">
<italic>c</italic>
<sub>
<italic>f</italic>
</sub>
</term>
<def>
<p>rock compressibility (Pa<sup>-1</sup>)</p>
</def>
</def-item>
<def-item>
<term id="G5-fenrg.2021.702456">
<italic>C</italic>
<sub>
<italic>r</italic>
</sub>
</term>
<def>
<p>rock-specific heat capacity (J/kg/K)</p>
</def>
</def-item>
<def-item>
<term id="G6-fenrg.2021.702456">
<inline-formula id="inf3">
<mml:math id="m15">
<mml:mrow>
<mml:msub>
<mml:mrow>
<mml:mover accent="true">
<mml:mi>F</mml:mi>
<mml:mo>&#x2192;</mml:mo>
</mml:mover>
</mml:mrow>
<mml:mi>&#x3b2;</mml:mi>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula>
</term>
<def>
<p>phase <italic>&#x3b2;</italic> mass flow rate (kg/m<sup>2</sup>/s)</p>
</def>
</def-item>
<def-item>
<term id="G7-fenrg.2021.702456">
<italic>J</italic>
<sub>
<italic>w</italic>
</sub>
</term>
<def>
<p>water productivity index (m<sup>3</sup>/Pa/s)</p>
</def>
</def-item>
<def-item>
<term id="G8-fenrg.2021.702456">
<italic>H</italic>
</term>
<def>
<p>grid thickness (m)</p>
</def>
</def-item>
<def-item>
<term id="G9-fenrg.2021.702456">
<italic>H</italic>
<sub>
<italic>&#x3b2;</italic>
</sub>
</term>
<def>
<p>phase <italic>&#x3b2;</italic> enthalpy (J/kg)</p>
</def>
</def-item>
<def-item>
<term id="G10-fenrg.2021.702456">
<italic>H</italic>
<sub>
<italic>d</italic>
</sub>
</term>
<def>
<p>formation or dissociation enthalpy of HBL (J/m<sup>3</sup>)</p>
</def>
</def-item>
<def-item>
<term id="G11-fenrg.2021.702456">
<italic>k</italic>
</term>
<def>
<p>absolute permeability (m<sup>2</sup>)</p>
</def>
</def-item>
<def-item>
<term id="G12-fenrg.2021.702456">
<italic>K</italic>
<sub>
<italic>r</italic>
</sub>
</term>
<def>
<p>rock thermal conductivity (W/m<sup>2</sup>/C)</p>
</def>
</def-item>
<def-item>
<term id="G13-fenrg.2021.702456">
<italic>k</italic>
<sub>
<italic>rg</italic>
</sub>
</term>
<def>
<p>gas relative permeability</p>
</def>
</def-item>
<def-item>
<term id="G14-fenrg.2021.702456">
<italic>k</italic>
<sub>
<italic>rw</italic>
</sub>
</term>
<def>
<p>water relative permeability</p>
</def>
</def-item>
<def-item>
<term id="G15-fenrg.2021.702456">
<italic>K</italic>
<sub>
<italic>&#x3b2;</italic>
</sub>
</term>
<def>
<p>phase <italic>&#x3b2;</italic> thermal conductivity (W/m<sup>2</sup>/C)</p>
</def>
</def-item>
<def-item>
<term id="G16-fenrg.2021.702456">
<italic>n</italic>
<sub>
<italic>G</italic>
</sub>
</term>
<def>
<p>gas relative permeability&#x20;index</p>
</def>
</def-item>
<def-item>
<term id="G17-fenrg.2021.702456">
<italic>n</italic>
<sub>
<italic>w</italic>
</sub>
</term>
<def>
<p>water relative permeability&#x20;index</p>
</def>
</def-item>
<def-item>
<term id="G18-fenrg.2021.702456">
<inline-formula id="inf4">
<mml:math id="m16">
<mml:mrow>
<mml:mover accent="true">
<mml:mi>p</mml:mi>
<mml:mo>&#xaf;</mml:mo>
</mml:mover>
</mml:mrow>
</mml:math>
</inline-formula>
</term>
<def>
<p>current average pressure of the bottom water layer&#x20;(Pa)</p>
</def>
</def-item>
<def-item>
<term id="G19-fenrg.2021.702456">
<inline-formula id="inf5">
<mml:math id="m17">
<mml:mrow>
<mml:msub>
<mml:mrow>
<mml:mover accent="true">
<mml:mi>p</mml:mi>
<mml:mo>&#xaf;</mml:mo>
</mml:mover>
</mml:mrow>
<mml:mrow>
<mml:mi>a</mml:mi>
<mml:mo>,</mml:mo>
<mml:mi>n</mml:mi>
</mml:mrow>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula>
</term>
<def>
<p>aquifer average pressure at timestep n&#x20;(Pa)</p>
</def>
</def-item>
<def-item>
<term id="G20-fenrg.2021.702456">
<inline-formula id="inf6">
<mml:math id="m18">
<mml:mrow>
<mml:msub>
<mml:mrow>
<mml:mover accent="true">
<mml:mi>p</mml:mi>
<mml:mo>&#xaf;</mml:mo>
</mml:mover>
</mml:mrow>
<mml:mrow>
<mml:mi>a</mml:mi>
<mml:mo>,</mml:mo>
<mml:mi>n</mml:mi>
<mml:mo>&#x2212;</mml:mo>
<mml:mn>1</mml:mn>
</mml:mrow>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula>
</term>
<def>
<p>average pressure of aquifer at timestep n&#x2212;1&#x20;(Pa)</p>
</def>
</def-item>
<def-item>
<term id="G21-fenrg.2021.702456">
<italic>P</italic>
<sub>
<italic>cap</italic>
</sub>
</term>
<def>
<p>capillary pressure (Pa)</p>
</def>
</def-item>
<def-item>
<term id="G22-fenrg.2021.702456">
<italic>P</italic>
<sub>
<italic>co</italic>
</sub>
</term>
<def>
<p>parameter in capillary pressure model&#x20;(Pa)</p>
</def>
</def-item>
<def-item>
<term id="G23-fenrg.2021.702456">
<italic>P</italic>
<sub>
<italic>e</italic>
</sub>
</term>
<def>
<p>corresponding equilibrium pressure of temperature <italic>T</italic> (MPa)</p>
</def>
</def-item>
<def-item>
<term id="G24-fenrg.2021.702456">
<inline-formula id="inf7">
<mml:math id="m19">
<mml:mrow>
<mml:msub>
<mml:mrow>
<mml:mover accent="true">
<mml:mi>p</mml:mi>
<mml:mo>&#xaf;</mml:mo>
</mml:mover>
</mml:mrow>
<mml:mi>n</mml:mi>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula>
</term>
<def>
<p>average pressure at the contact area of the aquifer and HBL&#x20;(Pa)</p>
</def>
</def-item>
<def-item>
<term id="G25-fenrg.2021.702456">
<italic>p</italic>
<sub>
<italic>i</italic>
</sub>
</term>
<def>
<p>initial pressure of the bottom water layer&#x20;(Pa)</p>
</def>
</def-item>
<def-item>
<term id="G26-fenrg.2021.702456">
<italic>p</italic>
<sub>
<italic>wf</italic>
</sub>
</term>
<def>
<p>aquifer internal boundary pressure&#x20;(Pa)</p>
</def>
</def-item>
<def-item>
<term id="G27-fenrg.2021.702456">
<inline-formula id="inf8">
<mml:math id="m20">
<mml:mrow>
<mml:msup>
<mml:mi>q</mml:mi>
<mml:mi>&#x3ba;</mml:mi>
</mml:msup>
</mml:mrow>
</mml:math>
</inline-formula>
</term>
<def>
<p>component <italic>&#x3ba;</italic> source and sink term of (kg/m<sup>3</sup>/s)</p>
</def>
</def-item>
<def-item>
<term id="G28-fenrg.2021.702456">
<italic>q</italic>
<sub>
<italic>h</italic>
</sub>
</term>
<def>
<p>heat source and sink terms (J/m<sup>3</sup>/s)</p>
</def>
</def-item>
<def-item>
<term id="G29-fenrg.2021.702456">
<italic>q</italic>
<sub>
<italic>w</italic>
</sub>
</term>
<def>
<p>water invasion rate (m<sup>3</sup>/s)</p>
</def>
</def-item>
<def-item>
<term id="G30-fenrg.2021.702456">
<italic>q</italic>
<sub>
<italic>wj</italic>
</sub>
</term>
<def>
<p>water mass flow rate from the aquifer to the adjacent grid <italic>j</italic> (kg/m<sup>3</sup>/s)</p>
</def>
</def-item>
<def-item>
<term id="G31-fenrg.2021.702456">(<italic>q</italic>
<sub>
<italic>wi</italic>
</sub>)<sub>max</sub>
</term>
<def>
<p>initial time maximum water invasion rate (m<sup>3</sup>/s)</p>
</def>
</def-item>
<def-item>
<term id="G32-fenrg.2021.702456">
<italic>r</italic>
<sub>
<italic>e</italic>
</sub>
</term>
<def>
<p>radius of outer boundary&#x20;(m)</p>
</def>
</def-item>
<def-item>
<term id="G33-fenrg.2021.702456">
<italic>r</italic>
<sub>
<italic>w</italic>
</sub>
</term>
<def>
<p>radius of wellbore&#x20;(m)</p>
</def>
</def-item>
<def-item>
<term id="G34-fenrg.2021.702456">
<italic>S</italic>
</term>
<def>
<p>skin factor</p>
</def>
</def-item>
<def-item>
<term id="G35-fenrg.2021.702456">
<italic>S</italic>
<sub>
<italic>G</italic>
</sub>
</term>
<def>
<p>gas saturation</p>
</def>
</def-item>
<def-item>
<term id="G36-fenrg.2021.702456">
<italic>S</italic>
<sub>
<italic>irG</italic>
</sub>
</term>
<def>
<p>irreducible gas saturation</p>
</def>
</def-item>
<def-item>
<term id="G37-fenrg.2021.702456">
<italic>S</italic>
<sub>
<italic>irW</italic>
</sub>
</term>
<def>
<p>irreducible water saturation</p>
</def>
</def-item>
<def-item>
<term id="G38-fenrg.2021.702456">
<italic>S</italic>
<sub>
<italic>W</italic>
</sub>
</term>
<def>
<p>water saturation</p>
</def>
</def-item>
<def-item>
<term id="G39-fenrg.2021.702456">
<italic>S</italic>
<sub>
<italic>&#x3b2;</italic>
</sub>
</term>
<def>
<p>phase <italic>&#x3b2;</italic> saturation</p>
</def>
</def-item>
<def-item>
<term id="G40-fenrg.2021.702456">
<italic>t</italic>
</term>
<def>
<p>time (s)</p>
</def>
</def-item>
<def-item>
<term id="G41-fenrg.2021.702456">
<italic>T</italic>
</term>
<def>
<p>temperature (K)</p>
</def>
</def-item>
<def-item>
<term id="G42-fenrg.2021.702456">
<italic>V</italic>
<sub>
<italic>B</italic>
</sub>
</term>
<def>
<p>grid volume (m<sup>3</sup>)</p>
</def>
</def-item>
<def-item>
<term id="G43-fenrg.2021.702456">
<italic>W</italic>
</term>
<def>
<p>initial volume of bottom water in surface conditions&#x20;(m<sup>3</sup>)</p>
</def>
</def-item>
<def-item>
<term id="G44-fenrg.2021.702456">
<italic>W</italic>
<sub>
<italic>e</italic>
</sub>
</term>
<def>
<p>volume of invasion water in reservoir condition&#x20;(m<sup>3</sup>)</p>
</def>
</def-item>
<def-item>
<term id="G45-fenrg.2021.702456">
<italic>W</italic>
<sub>
<italic>ei</italic>
</sub>
</term>
<def>
<p>total volume of invasion water when aquifer pressure decreases to zero&#x20;(m<sup>3</sup>)</p>
</def>
</def-item>
<def-item>
<term id="G46-fenrg.2021.702456">
<inline-formula id="inf9">
<mml:math id="m21">
<mml:mrow>
<mml:msubsup>
<mml:mi>X</mml:mi>
<mml:mi>&#x3b2;</mml:mi>
<mml:mi>&#x3ba;</mml:mi>
</mml:msubsup>
</mml:mrow>
</mml:math>
</inline-formula>
</term>
<def>
<p>mass fraction of component <italic>&#x3ba;</italic> in phase <italic>&#x3b2;</italic>
</p>
</def>
</def-item>
<def-item>
<term id="G47-fenrg.2021.702456">Greek symbols: <italic>&#x3d5;</italic>
</term>
<def>
<p>porosity</p>
</def>
</def-item>
<def-item>
<term id="G48-fenrg.2021.702456">
<italic>&#x3ba;</italic>
</term>
<def>
<p>component of the HBL&#x20;model</p>
</def>
</def-item>
<def-item>
<term id="G49-fenrg.2021.702456">
<italic>&#x3c1;</italic>
<sub>
<italic>r</italic>
</sub>
</term>
<def>
<p>rock density (kg/m<sup>3</sup>)</p>
</def>
</def-item>
<def-item>
<term id="G50-fenrg.2021.702456">
<italic>&#x3c1;</italic>
<sub>
<italic>&#x3b2;</italic>
</sub>
</term>
<def>
<p>phase <italic>&#x3b2;</italic> density (kg/m<sup>3</sup>)</p>
</def>
</def-item>
<def-item>
<term id="G51-fenrg.2021.702456">
<italic>&#x3c1;</italic>
<sub>
<italic>w</italic>
</sub>
</term>
<def>
<p>water density (kg/m<sup>3</sup>)</p>
</def>
</def-item>
<def-item>
<term id="G52-fenrg.2021.702456">
<italic>&#x3b5;</italic>
</term>
<def>
<p>blackness</p>
</def>
</def-item>
<def-item>
<term id="G53-fenrg.2021.702456">
<italic>&#x3c3;</italic>
</term>
<def>
<p>Stefan-Boltzmann constant (W/m<sup>2</sup>/K<sup>4</sup>)</p>
</def>
</def-item>
<def-item>
<term id="G54-fenrg.2021.702456">
<inline-formula id="inf10">
<mml:math id="m22">
<mml:mi>&#x3bb;</mml:mi>
</mml:math>
</inline-formula>
</term>
<def>
<p>capillary pressure&#x20;index</p>
</def>
</def-item>
<def-item>
<term id="G55-fenrg.2021.702456">
<inline-formula id="inf11">
<mml:math id="m23">
<mml:mrow>
<mml:msub>
<mml:mi>&#x3bb;</mml:mi>
<mml:mi>w</mml:mi>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula>
</term>
<def>
<p>water phase relative mobility (1/Pa/s)</p>
</def>
</def-item>
<def-item>
<term id="G56-fenrg.2021.702456">
<inline-formula id="inf12">
<mml:math id="m24">
<mml:mrow>
<mml:msub>
<mml:mi>&#x3bb;</mml:mi>
<mml:mi>g</mml:mi>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula>
</term>
<def>
<p>gas phase relative mobility (1/Pa/s)</p>
</def>
</def-item>
</def-list>
</sec>
</back>
</article>