Investigation of the Thermal Conductivity, Viscosity, and Thermal Performance of Graphene Nanoplatelet-Alumina Hybrid Nanofluid in a Differentially Heated Cavity

This paper investigates the thermophysical properties and heat transfer performance of graphene nanoplatelet (GNP) and alumina hybrid nanofluids at different mixing ratios. The electrical conductivity and viscosity of the nanofluids were obtained at temperatures between 15–55°C. The thermal conductivity was measured at temperatures between 20–40°C. The natural convection properties, including Nusselt number, Rayleigh number, and heat transfer coefficient, were experimentally obtained at different temperature gradients (20, 25, 30, and 35°C) in a rectangular cavity. The Mouromtseff number was used to theoretically estimate all the nanofluids’ forced convective performance at temperatures between 20–40°C. The results indicated that the thermal conductivity and viscosity of water are increased with the hybrid nanomaterial. On the other hand, the viscosity and thermal conductivity of the hybrid nanofluids are lesser than that of mono-GNP nanofluids. Notwithstanding, of all the hybrid nanofluids, GNP-alumina hybrid nanofluid with a mixing ratio of 50:50 and 75:25 were found to have the highest thermal conductivity and viscosity, enhancing thermal conductivity by 4.23% and increasing viscosity by 15.79%, compared to water. Further, the addition of the hybrid nanomaterials improved the natural convective performance of water while it deteriorates with mono-GNP. The maximum augmentation of 6.44 and 10.48% were obtained for Nuaverage and haverage of GNP-Alumina (50:50) hybrid nanofluid compared to water, respectively. This study shows that hybrid nanofluids are more effective for heat transfer than water and mono-GNP nanofluid.


INTRODUCTION
Heat transfer enhancement is essential towards reducing the energy consumption of numerous thermal systems, including nuclear cooling, automobile engine cooling, refrigeration, air conditioning systems, etc. Most of these thermal systems use conventional working fluids such as water, engine oil, glycols, etc. Over the last decade, the thermophysical properties of these fluids have been improved for thermal transport with the addition of nanomaterials to form a nanofluid (She and Fan, 2018;Borode et al., 2019). Nanofluids have been extensively studied and shown to exhibit enhanced thermophysical properties compared to conventional working fluids (Yazid et al., 2017;Irandoost Shahrestani et al., 2021). Numerous nanomaterials have been used to develop a nanofluid. However, hybrid nanomaterials are currently attracting more attention for the creation of advanced nanofluids with better thermophysical properties. A hybrid nanofluid is a suspension of two or more nanomaterials in a base fluid, which indicates it is an extension of single or mono nanofluids (Hussein, 2017;Nisar et al., 2020). Numerous studies (Chopkar et al., 2007;Jha and Ramaprabhu, 2009;Suresh et al., 2011;Aravind and Ramaprabhu, 2013;Munkhbayar et al., 2013;Senthilraja et al., 2015;Megatif et al., 2016) have reported a higher thermal conductivity for hybrid nanofluids compared to mono nanofluids, while other studies (Jana et al., 2007;Baghbanzadeh et al., 2012) also reported otherwise. Similarly, some authors observed a reduction in the viscosity of hybrid nanofluids compared to the mono nanofluids, while few studies reported a higher viscosity (Kazemi et al., 2020;Kumar and Sarkar, 2020). This shows that hybrid nanofluids can either increase or decrease the thermophysical properties of mono nanofluids depending on the compatibility of the nanomaterials.
A host of studies have explored the natural convective heat transfer application of hybrid nanofluids and mono nanofluids. Parvin et al. (2012) assessed the natural convection flow of alumina nanofluid in an annulus. They reported a thermal performance augmentation, which is attributed to the presence of alumina in water. This enhancement was further intensified with an increase in the concentration of the nanomaterial. Nasrin et al. (2020) conducted a numerical investigation of the heat transfer performance of single and hybrid nanofluids of Cu with other nanomaterials, including TiO 2 , CuO, alumina and carbon nanotube (CNT), in a cavity. They reported an increase of 8. 1, 9.1, 10.2, 11.4, and 13.6% in the Nu value of nanofluids of Cu, Cu-TiO 2 , Cu-CuO, Cu-alumina and Cu-CNT, respectively, compared to water. This indicates that all the hybrid nanofluids exhibit superior convective heat transfer performance than the single Cu-based nanofluid and water.
The natural convection of alumina-multi-walled carbon nanotube (MWCNT) hybrid nanofluids with mixing ratios of 95:5 and 90:10 were experimentally investigated by (Giwa et al., 2018). They observed an improvement in the convective heat transfer performance of the hybrid nanofluids compared to distilled water and mono-alumina nanofluid. The research group (Giwa et al., 2020a) conducted further studies on the natural convection of alumina-MWCNT hybrid nanofluids with different mixing ratios (80:20, 60:40, 40:60, and 20:80) in a square cavity. They reported an enhancement in the free convection properties of all the hybrid nanofluids compared to water. Alumina-MWCNT hybrid nanofluid with a 60:40 ratio exhibited the highest convective performance at different temperature gradients. Estellé et al. (2017) assessed the free convection of mono-CNT nanofluid in a square cavity. They found that the addition of CNT reduces the Nusselt number (Nu) of the base fluid. Kouloulias et al. (2016) also reported a deterioration in the natural convection of a base fluid with the addition of mono-alumina. This was majorly attributed to nanofluid sedimentation. In contrast to the study by Kouloulias et al. (2016) and Moradi et al. (2020) reported an improvement in the heat transfer with the application of alumina nanofluids. Furthermore, numerous authors (Ghodsinezhad et al., 2016) observed an optimal enhancement in heat transfer using 0.1 vol% nanofluids, after which it starts depreciating at a higher concentration.
The literature reviewed shows a deterioration in the free convection heat transfer of some mono-particle nanofluids. However, hybrid nanofluids with concentrations lesser or equal to 0.1 vol% were found to improve heat transfer compared to the base fluid. Also, heat transfer studies on graphene-based hybrid nanofluids are limited despite the remarkable properties of the nanomaterial. Graphene has been identified to possess outstanding thermal conductivity and low density, making it an exceptional nanomaterial for the preparation of nanofluids (Borode et al., 2019). Furthermore, much like other nanomaterials, suspension of graphene in an aqueous solution tends to increase the viscosity of the base fluid (Rasheed et al., 2016). The viscosity of nanofluids is one of the significant factors that limits or reduces the thermal performance of nanofluids. Thus, compatible hybridization of nanomaterials can produce a nanofluid with exceptional heat transfer performance.
In this study, the comparative effect of different mixing ratios on the thermophysical properties and heat transfer performance of mono-graphene nanoplatelet (GNP) nanofluids and GNPalumina hybrid nanofluids at the same volume concentration of 0.1 vol% was investigated. To the best of our knowledge, there is little to no study on the thermophysical properties and free convective heat transfer performance of GNP-alumina nanofluids. Mono-GNP and GNP-alumina hybrid with mixing ratios of 25:75, 50:50, and 75:25 with volume concentration of 0.1 vol% were loaded into distilled water. The thermal conductivity and viscosity of the prepared nanofluids and distilled water were measured at different temperatures. The natural convective heat transfer of all the thermo-fluids was assessed in a differentially heated cavity at different temperature gradients. Finally, the efficacy of the fluids for forced convection heat transfer was theoretically evaluated using the Mouromtseff number.
In addition, it is essential to note that there are limited experimental studies on the natural convection of nanofluids based on the available literature, with the majority of studies focused on numerical analysis. Hence, this study is significant because it is one of the limited peer-reviewed articles to experimentally evaluate the free convection performance of nanofluids. Also, to the best of our knowledge, this study is one of the first research articles to focus on the thermo-convection performance of GNP-alumina hybrid nanofluids. Furthermore, this study theoretically considers the forced convection performance of the hybrid nanofluids.

MATERIALS AND METHODS
The materials and methods required to fulfil the aim and objectives of this study are presented in this section.

Nanofluid Preparation and Stability
The mono GNP and GNP-alumina hybrid nanofluids used in this study were prepared using a two-step technique. The GNP (15 nm thickness and 50-80 m 2 /g specific surface area) and gamma-alumina (20-30 nm diameter, 180 m 2 /g specific surface area) were purchased from Sigma Aldrich (Germany) and Nanostructured and Amorphous Materials Inc. (United States), respectively. Sodium dodecyl sulfate obtained from Sigma Aldrich (Germany) was used as surfactants to suspend the nanomaterials in distilled water stably. The hybrid nanofluids with a volume concentration of 0.1 vol% were prepared with different GNP and alumina (Al 2 O 3 ) mixing ratios (25:75, 50:50, and 75:25). The weight of the nanomaterials was calculated using Eq. 1 (1) All measurements were done using Radwag AS 220. R2 digital weighing balance (±0.01 g accuracy, Poland). The sodium dodecyl sulfate surfactant at a nanomaterialsurfactant ratio of 1:1 was first added to the distilled water, and the mixture was agitated using a magnetic stirrer for 5 min. The mono or hybrid nanomaterial was then added, followed by further agitation for 10 min. Finally, the agitated nanofluid mixture was further sonicated for 45 min using a Q-700 Qsonica ultrasonicator (700 W, 20 kHz). To prevent overheating and evaporation of the nanofluid during sonication, the temperature of the nanofluid was maintained at a constant temperature of 20°C using a LAUDA ECO RE1225 water bath.

Measurement of the Thermophysical Properties
Different instruments were used to measure the thermophysical properties of the prepared nanofluids at different temperatures. The temperature of the nanofluids was controlled using the LAUDA ECO RE1225 water bath. All the instruments were first calibrated before the collection of data. The electrical conductivity of the nanofluids was measured using CON700 EUTECH electrical conductivity meter (±1% accuracy). The pH of the nanofluids was obtained using Jenway 3510 pH meter (±0.003 accuracy). SV-10 Vibro-viscometer (A and D, Japan; ±3% accuracy) was employed to determine the viscosity of the nanofluids. Finally, the thermal conductivity of the nanofluids was obtained using the DECAGON KD2 Pro thermal meter (±5% accuracy) with the aid of a KS-1 hot wire needle sensor.

Cavity Set-Up
The free convection heat transfer of GNP-alumina hybrid nanofluids was studied in a 99.7 mm × 113.2 mm × 120.8 mm rectangular cavity at different temperature gradients (20°C, 25°C, 30°C, and 35°C). The set-up for the study is presented in Figure 1. The set-up includes two PR20R Polyscience digital-controlled water baths (0.005°C accuracy) and isothermal shell and tube heat exchangers to achieve the cavity's differential heating by maintaining the temperature of the cold and hot walls. In addition, Burkert 8,081 flow meter (accuracy ±0.01%) was employed to obtain the flow rate of water flowing through the heat exchangers. The temperatures in the cavity were measured using T-type thermocouples (Omega Engineering, United States, accuracy of 0.1°C) connected to Data Logger (SCXI-1303 National instrument).
The experimental data for the natural convection were collected after the nanofluids prepared were charged into the cavity and allowed to reach a steady-state after 1 h at different temperature gradients.

Data Reduction
The average heat transfer rate, average heat transfer coefficient, Rayleigh number, and Nusselt number were calculated by measuring the flow rates, internal and external temperatures of the cavity. The model for the experimental values of the viscosity and thermal conductivity for the examined nanofluids were used in the calculations. The density, specific heat capacity, and coefficient of thermal expansion of the different nanofluid samples were estimated using Eqs 2, 3, 4. The thermophysical properties of the base fluid and nanomaterials are presented in Table 1.
The Rayleigh number, Ra, was estimated using Eq. 5 After that, the average heat transfer rate, Q, and average convection heat transfer coefficient, h, was calculated using Eqs 6, 7, respectively.
Where _ m is the mass flow rate, T h is the temperature of the hot wall, T c is the cold wall temperature, and A is the heat transfer area of the cavity.
The average Nusselt number, Nu, was evaluated using Eq. 8.

Cavity Validation
The experimental result was validated by examining the Nu of distilled water in the cavity as a function of Ra at different temperature gradients of 20°C, 25°C, 30°C, and 35°C. Furthermore, the results obtained were compared with that of the model proposed by Berkovsky and Polevikov (1977) and Leong et al. (1998). The Berkovsky model and Leong model are presented in Eqs. 9, 10.

Uncertainty Analysis
Uncertainty analysis of Q, h, and Nu was done to quantify the data's reliability due to the inputs' variability. The inputs, which are a source of error, include temperature and flow rates. The  values of uncertainty were obtained using Eqs. 11, 12, 13 (Giwa et al., 2020a).
The maximum uncertainty for Q, h, and Nu are 5.96, 6.03, and 6.33%, respectively.

RESULTS AND DISCUSSION
This section covers the results obtained with the application of the materials and methods. Also, keys findings of the study were discussed.

Nanofluid Stability
The stability of the nanofluid samples used for this study was studied using a transmission electron microscope, viscosity measurement, and visual technique. The transmission electron microscope images of the mono-GNP nanofluid and hybrid GNP-alumina (50:50) nanofluid are presented in Figure 2. The alumina particles can be observed on the surface of the GNP, which indicates the stability of the hybrid nanofluid. The stability of the nanofluids was further analyzed by taking the viscosity of the nanofluids over 24 h, which is more than the total time taken to carry out the experiments. The viscosity of all the nanofluids as a function of time is illustrated in Figure 3. The almost linear measurements of all the nanofluids indicate that the nanofluids remain relatively stable for at least 24 h. Also, the visual analysis displayed in Figure 4 shows that the nanofluids are stable for at least 3 weeks without any visible sedimentation.

Electrical Conductivity and pH
The effects of temperature on the electrical conductivity (σ NF ) of the hybrid nanofluids are depicted in Figure 5A. The σ NF of all the nanofluids and distilled water was found to increase as the temperature increases. This is in concordance with numerous studies (Mehrali et al., 2014;Giwa et al., 2020a). This can be attributed to the enhancement in the random movement of liquid molecules at elevated temperatures. Also, the σ NF all the nanofluids is higher than that of water, which shows the addition of GNP and alumina tends to improve the electrical conductivity of water. Further observation shows  that nanofluids with a higher ratio of alumina tend to have higher σ NF . This indicates that alumina contributes the most to the σ NF of the hybrid nanofluids. This is clearly evident in the plot of σ relative as a function of temperature illustrated in Figure 5B. The σ relative is an indicator of the increase in electrical conductivity of nanofluid in relation to that of water. σ relative is a ratio of σ NF to that of σ water . From Figure 5B, GNP-alumina (25:75) has a higher σ relative , followed by GNP-alumina (50:50) and GNP-alumina (75: 25), while mono GNP nanofluid has the least increase. The measured pH of water, mono-GNP nanofluid, GNPalumina nanofluids with mixing ratios of 75:25, 50:50, and 25: 75 were observed to range from 7. 69-7.46, 8.06-7.01, 7.10-5.95, 8.19-6.87, and 8.25-7.41, respectively as the temperatures increase 15°C-55°C. This indicates that the pH of all the samples reduces at elevated temperatures. Further observation revealed that the hybrid GNP-alumina nanofluids have a lesser pH than mono GNP nanofluids. This shows that the addition of alumina causes a reduction in the H + concentration of the GNP nanofluids.

Viscosity
The effects of temperature on the viscosity (μ NF ) of the hybrid nanofluids are depicted in Figure 6A. The μ NF of all the nanofluids and distilled water was found to decrease as the temperature is elevated. This is in concordance with numerous studies (Said et al., 2015;Taherian et al., 2018). This temperature-induced diminution of nanofluid's viscosity can be attributed to the reduction in the particle-particle and particle-molecules forces due to Brownian motion, which consequently lessens the resistance to flow. The μ NF of all the  nanofluids are higher than that of water, which shows that the addition of GNP and alumina tends to increase the viscosity of water. The study further shows that GNP nanofluid has a higher viscosity than that of the hybrid nanofluids. Also, it can be observed that the increase in the mixing ratio of GNP produces an increase in the viscosity of the hybrid nanofluids. This can be confirmed in Figure 6B, which presents the relative viscosity (μ relative ) of the nanofluids at different temperature. μ relative , which is the ratio of μ NF to that of μ water , indicates the increase in μ water with the addition of mono or hybrid nanomaterials. From Figure 6B, it can be observed that the nanofluids with higher ratio of GNP tend to have a higher μ NF . Mono-GNP nanofluid has the highest μ relative , followed by GNPalumina (75:25) and GNP-alumina (50:50) nanofluid, while GNP-alumina (25:75) nanofluid has the least μ relative . The μ water increased by 5.31-10.53%, 7.08-12.28%, 7.96-15.79%, and 9.73-17.54% with the addition of GNP-alumina (25:75), GNP-alumina (50:50), GNP-alumina (75:25) and mono-GNP, respectively at the examined temperature. The higher viscosity of mono-GNP nanofluid compared to that of its hybrid nanofluids is similar to the observation made Kumar and Sarkar (2020) in a study on another carbon-based hybrid nanofluids. They investigated the effect of particle ratio on the thermophysical properties of alumina-MWCNT hybrid nanofluids. They found that an increase in the MWCNT fraction increases the viscosity of the hybrid nanofluids. However, this disagrees with the study by Giwa et al. (2020a), as they observed a reduction in the viscosity of the alumina-MWCNT hybrid nanofluids as the MWCNT fraction increases. Also, the result of this present study agrees with the observation by Dezfulizadeh et al. (2021) that the addition of metal oxides in hybrid nanofluids prevent an increase in viscosity and also controls the viscosity at low pressure. The higher viscosity associated with a high ratio of GNP could be attributed to the higher intra-molecular force of GNP and the tendency of its particles to clump together. This clumpiness consequently increases the resistance of the layers of fluid to flow. It can be assumed that this flow resistance is improved due to Brownian motion at elevated temperatures, which results in a reduction in viscosity.

Thermal Conductivity
The effects of temperature on the thermal conductivity (λ NF ) of the hybrid nanofluids are illustrated in Figure 7. An augmentation in the λ NF of all the nanofluids and distilled water was observed as the temperature is elevated. This observation agrees with numerous studies (Said et al., 2015;Taherian et al., 2018). The temperature-induced intensification of λ NF can be ascribed to the enhancement in Brownian motion of particles, which then causes more  collision between molecules, thus transferring energy. The λ NF all the nanofluids is higher than that of water, which shows that the addition of GNP and alumina tends to increase the thermal conductivity of water (λ water ). Furthermore, the study shows that mono-GNP nanofluid has a higher thermal conductivity than that of the hybrid nanofluids. Also, it can be observed that the increase in the mixing ratio of GNP produces an increase in the thermal conductivity of the hybrid nanofluids. Thus, it is noteworthy to state that mono-GNP has the highest thermal conductivity enhancement, followed by GNP-alumina (50:50) and GNPalumina (75:25), while GNP-alumina (25:75) has the least enhancement. The λ water increased by 1.66-3.09%, 1.99-4.23%, 1.83-3.42%, and 4.48-5.62% with the addition of GNP-alumina (25:75), GNP-alumina (50:50), GNPalumina (75:25) and GNP, respectively at the examined temperatures. The higher λ NF of mono nanofluid agrees with the study by Kumar and Sarkar (2020) and Wang et al. (2021).

Correlation
A new correlation for the electrical conductivity (σ HNF ), viscosity (μ HNF ), and thermal conductivity (λ HNF ) of the hybrid nanofluids was developed based on the experimental data (φ 0.1 vol%). The developed correlation with a coefficient of determination (R 2 ) of 98.86, 97.68, and 94.31% is presented, respectively, in Eqs 14, 15, 16 as a function of temperature (T) and hybrid mixing ratio (R).
Where R, which is the ratio of the weight of GNP to the total weight of GNP-alumina, ranges from 0.25 to 1. Figures 8A-C shows that the developed correlation for the predicted values of σ HNF , μ HNF , and λ HNF highly corresponds with their experimental values. The developed correlation for σ HNF and μ HNF was observed to predict the experimental values with a margin of error which ranges from -2.79 to 2.63% and -5.93-5.28%, respectively. The margin of deviation between the predicted values and the experimental values of λ HNF lies between 1.24 and 0.78%.

Free Convection Performance
Natural thermo-convection are employed for numerous applications where heat transfer without forced or external motion is required. This section focused on the experimental results of the study on the natural convection of GNP-based nanofluids in a cavity.

Cavity Validation
The validation of the cavity was done with the experimental values of Nu as a function of Ra. The experimentally obtained Nu values of the distilled water were compared with the Nu values estimated using the Berkovsky model (Berkovsky and Polevikov, 1977) and the model from Leong et al. (1998), as presented in Figure 9. It was found that the two models cannot accurately predict the experimental values of the Nu in the cavity with the Ra values estimated in this study. The Berkovsky model overestimates the Nu values while the Leong Model underestimates the Nu values. This observation agrees with a host of a previous study (Ghodsinezhad et al., 2016;Giwa et al., 2020a) on the natural convection of nanofluids in a cavity.

Natural Convective Heat Transfer Analysis
The free convective heat transfer performance of GNP-alumina hybrid nanofluids was studied by evaluating the Ra, Nu average , and h average . Figure 10A presents the Nu average of all the thermo-fluids as a function of Ra. The Ra of the base fluid ranges from 3.05 × 10 8 -6.56 × 10 8 , while that of the nanofluids ranges from 2.72 × 10 8 -6.08 × 10 8 . This shows that the addition of mono or hybrid nanomaterials causes a reduction in the Ra values of water. This could be ascribed to the changes in the thermophysical properties of water associated with the suspension of nanomaterials. Notwithstanding, despite the lower nanofluid's Ra values, the addition of hybrid nanofluids augments the Nu average of water while that of mono-GNP nanofluid deteriorates. This observation is consistent with previous studies (Giwa et al., 2020b). The effects of the hybrid mixture ratios and temperature gradient on the Nu average are illustrated in Figure 10B. The figure shows that the Nu average increases as the temperature gradient is elevated for all the samples. Further observation reveals that the GNP-alumina (50: 50) hybrid nanofluid has the highest Nu average , followed by GNPalumina (75:25) and GNP-alumina (25:75) hybrid nanofluids. In addition, the Nu average of mono-GNP nanofluid was observed to be lower than that of water. This clearly shows that the addition of mono-GNP causes a deterioration in the convective heat transfer of water in a cavity. In contrast, the hybridization of GNP with alumina causes an enhancement in heat transfer. This enhancement could be attributed to the lower viscosity of the hybrid nanofluids compared to the mono-GNP's viscosity. This indicates that the higher viscosity of mono-GNP nanofluid causes a reduction in the buoyant force-induced bulk fluid flow, which subsequently reduces heat transfer due to advection.
The Nu average of water is enhanced by 1.61-3.17%, 3.33-6.44%, and 3.23-5.43% with the addition of GNP-alumina with mixing ratios of 25:75, 50:50, and 75:25, respectively. In contrast, the addition of mono-GNP reduces the Nu average by 5.67-9.81% at the temperature gradients considered in this study.
The experimental data of the hybrid nanofluids were used to derive a correlation for the average Nusselt number as a function of Ra and R, as shown in Eq. 17. In addition, the developed correlation with a coefficient of determination (R 2 ) of 96.36% is presented in Eq. 17.
The Nu predicted using the model conforms with the experimental results with a margin of deviation between -1.35 and 1.26%. The variation between the predicted and experimental Nu is illustrated in Figure 11. The comparison between the experimental value of Nu average with the developed correlation and the existing correlation by Giwa et al. (2020a) is illustrated in Figure 12. The figure confirms that the experimental values highly match the developed correlation. Furthermore, the developed correlation does not conform with the model by Giwa et al. (2020a), but they exhibit a similar trend.
The h average of all the samples at different temperature gradients is illustrated in Figure 13. An increase in the temperature results in an enhancement in the h average of all the samples examined in this study. Similar to the Nu average results, the maximum h average was achieved with GNP-alumina (50:50) hybrid nanofluid. This was followed by All the hybrid nanofluids exhibit a higher h average than water, while the h average of mono-GNP nanofluid is lesser than that of water. The h average of water is enhanced by 4.79-5.96%, 7.58-10.48%, and 7.02-8.88% with GNP-alumina with mixing ratios of 25:75, 50:50, and 75:25, respectively. However, the addition of mono-GNP diminished the h average of water by 0.78-5.30% at the temperature gradients considered in this study. Also, it is noteworthy to state that the optimum hybrid mixture ratio of GNP-alumina for maximum heat transfer augmentation is found at a ratio of 50:50. Also, the free convective heat transfer enhancement observed in this experimental study is consistent with numerous studies on the heat transfer performance of hybrid nanofluids (Giwa et al., 2020a;2020b). The higher h average of the hybrid nanofluids compared to water can be attributed to the higher thermal conductivity of the nanofluids, which improves heat transfer through conduction. On the other hand, the poor heat transfer performance of the mono-nanofluid is strongly linked to its higher viscosity compared to water and hybrid nanofluids. The higher viscosity of the mononanofluid lowers buoyant fluid flow from the hot side of the cavity to the cold side, which consequently reduces heat transfer through advection. The impact of this high viscosity coupled with high thermal conductivity causes the heat transfer with mono-nanofluid to be dependent on heat transfer through diffusion rather than advection. This resulted in a lower Nu value than water and hybrid nanofluids, as Nu is the ratio of heat transfer through advection (convection) to diffusion (conduction).  Furthermore, it is noteworthy to provide an insight into the difference in the heat transfer performance of the examined mono and hybrid nanofluids. To better comprehend the result of this study, Ra values exhibit an influence on the heat transfer performance of the nanofluids. The higher Ra and lower viscosity of the hybrid nanofluids has an effect on the augmentation of the Nu average and h average compared to mono-nanofluid. This indicates that there is an intensification in the buoyant convective force and fluid flow from the hot side to the cold side of the cavity. An enhanced buoyant force causes an intensification in the motion of fluid particles and thermal transport to the boundary walls. This made heat transfer to be more dependent on advection rather than diffusion. Thus, resulting in a higher Nu average and h average with the hybrid nanofluids compared to the mono-nanofluid.
Also, viscosity and thermal conductivity results show that these properties are strongly related to temperature and hybrid mixing ratio. The impact of lower viscosity and enhanced thermal conductivity at elevated temperatures was strongly pronounced in the heat transfer study. The h average and Nu average were found to increase for the different nanofluids with increased temperature gradients.

Forced Convection Performance
In order to assess the forced convective heat transfer performance of the nanofluids in a thermal system, Mouromtseff Number (Mo) was employed. Mo is an indicator of the efficacy of a thermo-fluid in a thermal system. It is noteworthy to state that higher Mo values indicate higher thermal performance. The Mo of the samples was estimated using Eq. 18 (Minea and Moldoveanu, 2017). Mo Where the constants a 0.8, b 0.33, c 0.67 and d 0.47 for the nanofluids' turbulent flow regime, while a 0.8, b 0.33, c 0.8 and d 0.47 for that of water (Huminic and Huminic, 2018;Leena and Srinivasan, 2018;Kumar et al., 2021). Figure 14A shows Mo for the different hybrid nanofluids at different temperatures. All the nanofluids were found to display better heat transfer efficiency than water as the Mo of all the nanofluids is greater than water. It is noteworthy to state that all the GNP-alumina hybrid nanofluids exhibit better performance than the single GNP nanofluid. Also, the Mo results show that the nanofluid's viscosity greatly influences the efficiency of a thermal system. This is evident as the hybrid nanofluids with the lowest viscosity exhibit the best performance. GNP-alumina (25:75) nanofluid displayed the best performance, followed by GNPalumina (50:50) and .
It is important to note that viscosity significantly influences the pumping power of a thermal system. A higher viscosity is expected to increase the pumping power. Thus, the pumping power for the turbulent flow will be evaluated using Eq. 19 (Huminic and Huminic, 2018).
The pumping power ratio, W NF Wwater is a measure of the heat transfer usefulness of a thermo-fluid. If the W NF Wwater is less than 1, then the nanofluid is deemed to be suitable for heat transfer application. The pumping power ratio of the nanofluids at different temperatures is illustrated in Figure 14B. All the nanofluids were found to have a pumping power ratio of less than 1, which indicates that they are all useful for heat transfer applications. It can also be seen that GNP-alumina (25:75) nanofluids have the lowest power ratio, followed by GNPalumina (50:50) and GNP-GNP-alumina (75:25) nanofluids, with GNP nanofluid having the higher pumping power ratio. The forced convection and the natural convection results show that the hybrid nanofluids offer more beneficial thermal performance than mono GNP nanofluids and water.

CONCLUSION
In this paper, the thermophysical properties and natural convection properties of 0.1 vol% of mono-GNP and hybrid GNP-alumina at different mixing ratios (25:75, 50:50, and 75:25) were experimentally studied. Also, the forced convection heat transfer was theoretically explored using the Mouromtseff number. The following conclusion can be deduced from the results of this study: i. The electrical conductivity and thermal conductivity of all the samples (water, mono-GNP nanofluid, and hybrid nanofluids) are augmented at elevated temperatures while the viscosity and pH reduce. ii. The electrical conductivity of water is improved with the addition of mono GNP and hybrid nanomaterials. Nanofluids with higher concentrations of alumina exhibit a higher electrical conductivity. GNP-alumina (25:75) hybrid nanofluid has the highest electrical conductivity of all the samples, with a maximum enhancement of 135.74%. iii. With the addition of nanomaterials, the viscosity and thermal conductivity of water are augmented. The highest viscosity and thermal conductivity increase were obtained with the addition of mono-GNP. The maximum thermal conductivity enhancement of 5.62% was obtained for mono-GNP nanofluid at 40°C, while the maximum increase in viscosity is 17.54%. iv. Among the GNP-alumina hybrid nanofluids, the highest thermal conductivity was recorded at a mixing ratio of 50:50. Also, hybrid nanofluids with a higher ratio of alumina tend to possess lower viscosity. This is evident as GNP-alumina hybrid nanofluids with a mixing ratio of 25:75 exhibit the lowest viscosity followed by that of 50:50. v. Among all the samples, mono-GNP nanofluid is the least effective fluid regarding natural convective heat transfer performance, while GNP-alumina (50:50) hybrid nanofluid is the most effective. Compared to water, maximum enhancements of 3.17, 6.44, and 5.43% were obtained for Nu average of GNP-alumina hybrid nanofluid with mixing ratios of 25:75, 50:50 and 75:25, respectively. In a similar trend, the h average is enhanced by 5.96, 10.48, and 8.88%. On the other hand, the Nu average and h average deteriorated by 9.81 and 5.30% with mono-GNP nanofluid. vi. Compared to water, the superior heat transfer performance of the hybrid nanofluids can be attributed to their superior thermal conductivity. However, a high viscosity can be ascribed to the poor thermal performance of mono-GNP nanofluids, which causes loss of buoyancy and made heat transfer dependent mainly on conduction. vii. The theoretical analysis of the forced convection performance revealed that all the nanofluids (mono and hybrid) have a higher heat transfer efficiency than water. This shows that mono-GNP nanofluid is not suitable for heat transfer without an external motion. viii. Further, in contrast to the free convection performance, GNPalumina hybrid nanofluids with a mixing ratio of 25:75 have the best efficiency, followed by that of 50:50 and 75:25, while the mono-GNP nanofluid has the lowest efficiency. ix. The correlation developed for the electrical conductivity, thermal conductivity, viscosity, and Nuaverage are in good agreement with the experimental data.

DATA AVAILABILITY STATEMENT
The raw data supporting the conclusions of this article will be made available by the authors, without undue reservation.