Multi-objective optimization of the organic Rankine cycle cascade refrigeration cycle driven by sugar mills waste heat

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Introduction 1.Background
Bioenergy is a large-scale renewable energy source, accounting for 10%-14% of the world's primary energy and potentially reaching 30%-40% by 2050 (Rosillo-Calle, 2016).Currently, over 120 million tons of sugar are produced worldwide each year, with approximately 70% derived from sugarcane (USDA, 2018).The biomass potential of this crop can replace fossil fuels, leading to energy savings (de Matos et al., 2020) and transforming the sugar industry into a more versatile and competitive sector.The untapped waste heat resources in the global sugar industry show great potential.In the production process of sugar mills, a large amount of sugarcane residue, such as bagasse are produced while a substantial amount of recoverable low-temperature waste heat are generated (Birru et al., 2016), making the recovery of waste heat emissions from sugar mills becomes very essential.Mohammadi et al. (2020) investigated the potential of using bagasse as a substitute for natural gas in a sugar factory for the generation of thermal energy and electricity.Singh (2019) analyzed the thermodynamic performance of a 16-megawatt cogeneration system in a sugar mill and found that 6.342% of the fuel energy was lost in the boiler flue gas.The substantial amount of lowtemperature flue gas emitted by sugar mill boilers represents the main portion of heat loss and contains a significant amount of unused low-temperature waste heat.This not only affects the thermal efficiency of the boilers but also imposes significant pressure on the environment, causing ecological damage and contributing to intensified greenhouse effects.Fujii et al. (2019) demonstrated that the high-temperature flue gases produced from sugarcane boilers at approximately 200 °C during the combustion process has been wasted, which could reduce fuel consumption by 29.6% if this portion of energy was effectively utilized.The aforementioned studies indicate that the boiler flue gases from sugar mills have not only high economic benefits, but also considerable thermodynamic potential.

Waste heat recovery technology of sugar factories
Organic Rankine cycle (ORC) system is more prominent in recovering low-temperature waste heat (Mana et al., 2023).ORC system not only converts waste heat into high-grade energy (electricity), but also are widely used due to their simplicity of construction, lower material and sealing costs, and adaptability to heat sources of different temperature levels (Nemati et al., 2017).Zhang et al. (2016) investigated the system properties of organic Rankine cycle (ORC), steam-organic Rankine cycle (S-ORC) as well as steam Rankine cycle (SRC) within the range of 150 °C-350 °C by comparing their performances.The results indicated that more prominent thermodynamic performance and power generation are obtained when ORC is employed in the heat source temperature range of 150 °C-210 °C.Waste heat can be used for refrigeration in addition to electricity generation.Uphade (2021) studied the heat recovery potential of flue gas in the sugar industry and used a vapor absorption cycle instead of the conventional vapor compression cycle, allowing a sugar mill with 2,500 Tons of cane crushed per day capacity to produce 293 Tons of refrigeration cooling, which is sufficient to meet the internal demand of the sugar mill.Singh (2020) recovered waste heat from the boiler flue gases of the sugar mill, resulting in an increase of 375.2135 kW in the net power generation and an increase in the energy efficiency of the sugar mill's cogeneration by 0.3819%.Sugar mills need to consume huge financial and material resources in refrigeration every year (Du et al., 2014;Kapanji et al., 2021).In many heat-driven refrigeration systems, the absorption refrigeration technology is gradually becoming an effective alternative to the conventional vapor compression refrigeration system (Kumar et al., 2018) and is widely used in an increasing number of plants.This is due to its ability in fully utilizing low temperature heat sources to provide cooling capacity and the use of more eco-friendly refrigerants than chlorofluorocarbon refrigerants (CFCs) (Li et al., 2016).Bandgar al (Bandgar et al., 2018).utilized a vapor absorption system for waste heat recovery of excess water removed from the sugar mill for using as cooling in the factory office area.It saved 64,314 kWh per crushing season for the plant, which is equivalent to at least Rs.529,304.22 per season.Chouhan and Chandrakar (2014) suggested the use of the absorption refrigeration system to recover heat sources, including flue gas and boiler emissions, which could save 1,870 tons of bagasse per year in terms of additional cooling capacity for sugar mills.
The separate utilization of ORC and absorption refrigeration has achieved excellent comprehensive benefits in various fields, but the energy generated by individual systems is relatively homogeneous in form and may not be as efficient as an integrated system.Therefore, some researchers have proposed cogeneration systems that integrate waste heat recovery technologies to upgrade the economic efficiency as well as the thermodynamic performance of the system and enrich forms of energy utilization.Dogbe et al. (2019) used absorption heat pump (AHP) technologies as well as organic Rankine cycle (ORC) to improve the energy efficiency in a sugar mill, resulting in a 1.7% improvement in exergy performance and a total bagasse value saving of 0.83%.Zhang et al. (2020) proposed a novel cogeneration system for coal-fired power plants based on ORC as well as AHP and evaluated the thermodynamic as well as economic efficiency of the system.The findings demonstrated that the power generation and heat production were increased by a factor of one, while the general exergy efficiency as well as thermal efficiency were increased by 9.38% and 1.71%, respectively, compared with the conventional CHP system.Wang et al. (2020) designed a new triple generation system consisting of an organic Rankine cycle, an absorption refrigeration cycle as well as a supercritical CO 2 Brayton cycle for waste heat recovery from gas turbines in addition.The results showed that the new system could produce 6.02 MW of cooling capacity, 9.93 MW of heat load, as well as 40.65 MW of net power generation.Tian et al. ( 2018) used an integrated system to increase system efficiency with a newly proposed triple system of CO 2 capture system, ammonia absorption cooler as well as organic Rankine cycle (ORC) integrated with SOFC.The calculation indicated that the exergy efficiency as well as net electrical efficiency of the comprehensive system can reach 59.96% and 52.83%, respectively.

Motivation and contribution
Currently, there is relatively little research on the construction and optimization of waste heat recovery systems in sugar factories, with most studies focused on cogeneration and single systems.In order to provide both electric and cooling power, and achieve efficient energy utilization, this study adopts the cascade Organic Rankine Cycle (ORC) and Absorption Refrigeration Cycle (ARC) waste heat recovery system.Sugar factories require a certain cooling system during sugar processing to control process temperatures, ensuring product quality and normal equipment operation, such as crystalline sugar particles and sugar storage.Therefore, using ORC-ARC to achieve combined cooling and power has significant significance.First, the ORC system is suitable for medium and low temperature waste heat recovery, with lower cost and simpler operation compared to other systems, such as reheating, reheat, and bypass.The ARC uses an absorbent to absorb and desorb the solute for cooling, and steam refrigeration cycles require compressors to compress steam, consuming more energy.At the same time, the absorbent used by ARC is more environmentally friendly than traditional refrigerants such as fluorine.Furthermore, both the ORC and ARC systems possess high flexibility, allowing for efficient energy conversion by adjusting system parameters according to the requirements of the heat source and environment.Finally, by cascading ORC and ARC systems, not only can a large amount of "green" electricity be generated, but also sufficient cooling capacity provided for sugar factories, achieving efficient energy utilization and comprehensive recycling.Therefore, adopting the ORC-ARC system provides a feasible solution for waste heat recovery in sugar factories with higher economic and environmental performance.
This study compares the performance and environmental friendliness of nine working fluids in the ORC system, and determines the best organic working fluid in the integrated system based on comprehensive performance comparison, which helps optimize the operation of the entire integrated system.The performance of the ORC and absorption refrigeration cycle after integration is evaluated through thermodynamics and economic analysis, and the influence of key operating parameters such as evaporator temperature and generator temperature on the entire waste heat recovery system is studied.The economic efficiency of the system is evaluated using LCOE.Finally, NSGA-II is used to determine the system's optimal operating environment.

System description and assumptions
In this study, a new waste heat recovery system based on the flue gas of boilers in sugar mills is proposed.A specific analysis of the exergy in sugar mills has been carried out in the literature (Dogbe et al., 2018), and it was found that only 23.4% of the exergy in sugar mills leaves through the product during the whole production process, in which 3.5% of exergy is lost through waste and 73.1% is wasted during the production process due to various irreversible factors.The production process of a sugar mill is shown in Figure 1.
The significant energy loss caused by the waste heat from boiler flue gas during the production process can be effectively reduced by recovering this waste heat, thereby improving the economic performance and energy efficiency of the sugar factory.Considering that the recovered waste heat is around 190 °C, an Organic Rankine Cycle (ORC) is used as the base cycle.Conventional steam refrigeration cycles require higher temperatures and pressures, making them less suitable for handling low-temperature waste heat (Li et al., 2014).ORC utilizes organic working fluids that can evaporate and condense at relatively low temperatures, making it particularly suitable for recovering low-temperature waste heat.Additionally, the Absorption Refrigeration Cycle (ARC) replaces traditional refrigerants with organic working fluids, which usually have minimal negative impact on the atmosphere.When the flue gas passes through the first round of energy recovery in the ORC, its temperature drops to a range suitable for capturing and utilizing by ARC, providing the sugar factory with additional refrigeration capacity.There are various areas in the sugar factory that require significant cooling, such as syrup cooling and crystallization cooling.By combining ORC with ARC, the waste heat from the boiler flue gas can be fully utilized.This not only converts waste heat into electrical energy but also provides additional refrigeration capacity, thereby improving the overall system performance and efficiency.The sugar factory can achieve efficient energy utilization, reduce energy consumption and emissions, and lower production costs.This is not only economically beneficial for the sugar factory itself but also aligns with environmental protection and sustainable development requirements.This research has achieved gradient utilization of boiler flue gas from sugar mills by integrating ORC and ARC, enabling multiform conversion of energy to cooling and electricity.
Figure 2 illustrates a schematic diagram of the complete waste heat recovery system.The principal components of the proposed system are the evaporator, condenser, turbine, absorber, pump, solution heat exchanger, and generator.The work process is: In the ORC system, the working fluid is pressurized by pump 1 to the heat exchanger (02-03) and absorbs heat from the energy source fed to the heat exchanger, which is heated to high-temperature high-pressure vapor, which enters the Turbine to expand and generate electricity (03-04).Afterwards, it flows into the condenser 1 (04-01) and is condensed into a liquid by the refrigeration water, which then circulates through the ORC system again by pump 1 (01-02).In the absorption refrigeration cycle, water is the absorbent and ammonia is the refrigerant.We utilize waste heat from the heat exchanger to drive the heat source for the ARC system into the generator, where a concentrated solution of ammonia-water mixture is heated to evaporation, leaving a high temperature dilute solution.The high-pressure vapor is then condensed into a low temperature saturated liquid as it passes through condenser 2 (10-11), which is depressurized by the throttle valve and proceeds to the evaporator, which provides cooling through evaporation (11-13).The low-pressure ammonia steam is fed to the absorber (13-07) where it is diluted and absorbed into a concentrated solution into a concentrated solution of ammonia saturated water, which is sent under pressure to SHE via pump 2 to reclaim the waste heat of the concentrated solution in the generator (07-08).The dilute ammoniawater mixture remaining in the generator after the ammonia evaporation passes through SHE and returns to the absorber through a reduced pressure throttle valve (15-16).
3 Mathematical model

Thermodynamic model
The simulations of the waste heat recovery system in this study were implemented in MATLAB and all reactions were in thermodynamic equilibrium.The thermodynamic properties of the flue gas were calculated by REFPROP9.1 based on its basic composition: 58.14% N 2 , 10.42% H 2 O, 26.27% CO 2 and 5.17% O 2 .The added system is composed of ORC and absorption refrigeration cycles, respectively, and the two subsystems are thermodynamically balanced for the new system by mass flow equilibrium on the generator and heat exchanger.Table 1 summarizes all the key input data of the system.In order to improve the effect of the system in practical application, the system parameters are rationalized.In order to ensure that the turbine can reach the target state in practical applications, the turbine efficiency is set to 70%, while the actual value is around 80% (Cai et al., 2016;Pethurajan et al., 2018).Men et al. (2021) compared the performance of different heat exchangers in practical applications, and the results showed the EW heat exchange efficiency was higher than 85%.In the theoretical design of this paper, the efficiency of the heat exchanger is set at 70%, lower than the actual value.
In the sub-section, a mathematical model based on thermodynamics as well as economics is established for the system.In order to streamline the model, some essential assumptions are defined: (1) The subsystems operate at a steady state.
(2) The pumps and turbines operate at a specific isentropic efficiency.
(3) The pressure drop of piping is negligible.(4) The low-temperature waste heat comes from the sugar mill exhaust gas at a temperature of about 190 °C (Dogbe et al., 2018).( 5) The generator outlet refrigerant in ARC is superheated.

Energy analysis
On the basis of the mass balance equation (Eq. 1) and energy balance equation (Eq.2) (Nami et al., 2019), the thermodynamic model of all parts of the subsystem was studied and the corresponding mass and energy equations were listed to easily analyze the system later, as shown in Table 2.The flowchart of the proposed system.

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Where out and in represent the outlet and inlet of the component, respectively._ W as well as _ Q denote the power and heat transfer rate, respectively.

Exergy analysis
Exergy analysis has been widely used in the economic analysis of thermal systems that reveals the location, as well as the extent of process inefficiencies to optimize their capabilities and complements traditional mass flow analysis (Ghannadzadeh and Sadeqzadeh, 2017).The thermodynamic model of each component can be identified from the energy balance equation.
The exergy balance equation for the individual component is represented as Eq. 3 (Pan et al., 2021b): The exergy value for each point is determined as Eq. 4 (Ebrahimi-Moghadam et al., 2021):

Component Energy balance equation
Frontiers in Energy Research frontiersin.org The detailed exergy equations for each component are concluded in Table 3.

Economic analysis
Integrated sugar mill flue gas waste heat recovery system should consider not only thermodynamic aspects but also matters such as economic costs.The Levelized Cost Of Energy (LCOE) is one of the more extensively employed criteria in the feasibility analysis of evaluating new generation systems and power plants (Boukelia et al., 2016).The relationship between LCOE and annual system power generation and input costs is calculated using Eq.5: Where Z investment is the overall investment cost of the system ($), Z OM is the operation and maintenance cost ($).To estimate the annual operation as well as maintenance cost, the maintenance factor was chosen as 0.04 (Bhattacharyya and Quoc Thang, 2004).
CRF indicates the capital recovery factor calculated by Eq. 6: Where i and n are the interest rate (i = 0.1) as well as the lifetime of the system (n = 20 years) (Zhang et al., 2018), respectively.Z investment is composed of the investment cost data for the whole system components.Some cost equations from references (Khaljani et al., 2015;Lu et al., 2020;Nami and Anvari-Moghaddam, 2020;Pan et al., 2021a;Pan et al., 2021b) are applied to the main equipment of this system: turbine, pump and Generator, etc.The investment cost of each component can be calculated by the cost function given in Table 4.It is worth mentioning that the value of the valves is small compared to the other components, so their investment cost is ignored for procurement.
Considering the Chemical Engineering Plant Cost Index (CEPCI) of 699.97 in 2021 (The Chemical Engineering Plant Cost Index, n.d.), the cost function in Table 4 was updated to the year 2021 according to Eq. 7.
Based on the total investment cost and annual net income, the system's investment payback cycle PP can be estimated as Eq. 8 (Wang et al., 2015): Where Z tot is the total cost, NE is the annual net income.Z tot is composed of equipment investment cost (Z B ) and maintenance cost (Z OM ), which is calculated using Eq.9: The annual net income (NE) is determined by the net output power, electricity price, refrigeration capacity, and cooling water price, which is calculated using Eq.10: Where p e is the price of electricity, with a value of 0.11 $/kWh, p cw is the price of cooling water, with a value of 0.35 $/GJ (Liu et al., 2020).

Component
The cost functions of each component.

Component Cost function Year
Heat Exchanger Z 309.14AFor the heat transfer area of each component, the calculation is performed by Eq. 11 (Li et al., 2019): _ Q k is the heat transfer rate of each component, and U k is given specifically in Table 5. ΔT LMTD is the logarithmic mean temperature difference (Eq.12): Where ΔT k,A and ΔT k,B represent the temperature difference between the cooling and heating streams for each component, respectively.

Performance evaluation
To evaluate the capacity of the waste heat recovery system, some concepts is calcluated using Eqs 13-15: _ W net and _ Q e represent the net power output of the whole system and the heat transfer rate of the evaporator, respectively._ W ORCT is the net power output of the turbine, _ W P1 and _ W P2 are the power consumption of pump1 and pump2, respectively._ Q g is the heat transfer rate delivered to the ARC.
The cooling exergy of the system is defined as Eq.16: The equation for the thermal efficiency of the systemis defined as Eq.17: The exergy efficiency formula for the system is defined as Eq.18: _ E go is the input exergy of the system, which is the boiler flue gas exergy for the sugar mill._ E gout is the output exergy of the whole system.

Multi-objective optimization
To resolve the conflict between economic factors and the thermodynamic performance of the cycle, a non-dominated ranking genetic algorithm II (NSGA-II) is adopted for the multiobjective optimization of the cascaded system (Tan et al., 2023).As in Figure 3, the objective function, decision variables and constraints are the three elements of the optimization problem, and η Ex and LCOE are taken as the objectives to achieve the lowest cost optimum exergy efficiency η Ex and to obtain the appropriate system operating conditions.The decision-making variables and the range of values are shown in Table 6.The parameters of the genetic algorithm are summarized in Table 7.The flow chart of NSGA-II is shown in Figure 4.

Validation
To confirm the accuracy of the system model, the key subsystems of the built system were verified.The key subsystems include the ORC and the absorption refrigeration cycle, and the modeling of each subsystem were validated individually using experimental data from the literature.To validate the ORC model, results from the literature (Vaja and Gambarotta, 2010) were used for comparison.The ARC model was also validated using the literature (Zare, 2020).As shown in Tables 8, 9, there is excellent concordance between the findings of the current study and the data presented in the literature (Vaja and Gambarotta, 2010;Zare, 2020).Therefore, the accuracy of the current study results was verified.As can be seen from Figure 5, the simulation results of this study are in excellent consistency with references.Graphical representation of the Pareto front of an objective optimization problem.This section discusses and analyzes a new system developed based on waste flue gas from sugar mills after bagasse combustion with ORC and absorption refrigeration system composition.The analysis is carried out for parameters such as evaporation temperature and generator temperature to summarize the conclusions.Bagasse is composed of 0.8% wax, 2.3% ash, 18.1% lignin, 33.8% hemicellulose, as well as 43.6% cellulose (Nemomsa et al., 2022).Bagasse is burned in the sugar mill to provide steam for the sugar mill process, however a significant quantity of lowtemperature heat is still emitted to the atmosphere with the flue gas.The heat source in the ORC system is the flue gas from the sugar mill (190 °C) (Dogbe et al., 2018), and has a high exergy content of 11.95 MW.This paper presents the system's exergy, mass flow rate, distribution of fire loss of each component, and multi-objective optimization results.

The analysis of ORC working fluid
The operational performance of waste heat recovery systems is affected by the properties of the organic working fluid.Examples of ideal working fluid properties include suitable boiling point temperature, lower latent heat, higher critical temperature and pressure, appropriate specific volume, higher thermal conductivity, lower density and surface tension, non-corrosive, higher thermal stability, non-toxic, zero ODP, as well as low GWP (Hung et al., 1997;Luo et al., 2015).In addition, the closer the critical temperature of the working fluid is to the temperature of the heat source, the higher the performance of the system will be (Lu et al., 2020).Based on the aforementioned conditions, nine organic working fluids were screened, as shown in Table 10.By comparing the operation results under the same working conditions, the ORC working fluids with more ideal conditions were obtained.
The net power output of ORC is reflective of the performance of the waste heat recovery system.Therefore, in the present research, the net power output was determined as the target value, and the net power output ( _ W orc net ) was tested by varying the evaporator temperature of the ORC system (P orc eva ).The net power output of the ORC system ( _ W orc net ) at nine organic working fluids was analyzed by setting the evaporator pressure in the organic Rankine cycle from 900 to 2,200 kPa.As shown in Figure 6, Pentane, Isopentane and R245ca can reach the highest point of _ W orc net at the lowest pressure operating conditions, for example, when the working fluid is Pentane, P orc eva = 900 kPa, _ W orc net = 569.43kW, as the evaporator pressure continues to increase, the performance of the three working fluids gradually decreases, indicating that the working fluids are not suitable for operation in this pressure region.The six organic working fluids except for Pentane, Isopentane and R245ca gradually increase with increasing evaporator pressure in the constrained region, and the net power gradually moves toward the highest point.The increase in evaporator pressure P orc eva , although it raises _ W orc net , also puts an additional burden on the system, which in return causes to an increase in cost, so a suitable value The flow chart of NSGA-II.

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needs to be found between evaporator pressure and _ W orc net .When considering the specific application of the working fluid, attention needs to be paid to its latent heat properties Pentane, Isopentane and R245ca have the highest net power upfront in the ORC system, but as P orc eva increases, their latent heat decreases more rapidly than other working fluids, leading to a more rapid reduction in system efficiency and a decrease in heat transfer between the flue gas as well as the organic working fluid.Both Butane and R245fa have relatively close critical temperatures, but Butane has a slightly lower critical temperature, which is closer to the waste heat temperature.Additionally, Butane has a lower triple point temperature, which may contribute to better liquefaction performance.Selecting Butane as the working fluid in the ORC can reduce energy waste within the system and provide additional thermal energy for the ARC, potentially offering enhanced refrigeration effects.Furthermore, Butane exhibits better energy efficiency and has a lesser impact on the environment due to its lower ozone depletion potential (ODP) and global warming potential (GWP).

Parametric study 4.2.1 High pressure in ORC analysis
The outlet pressure of Pump1, as the highest pressure in the ORC system, affects many factors in the system, for example, the heat load of the heat exchanger.Therefore, it is an important TABLE 8 The results of comparison between present work and Ref. (Vaja and Gambarotta, 2010).

Present work
References (Vaja and Gambarotta, 2010) Error (%) Model authentication between present study with Ref.
object of study in this research.As shown in Figures 7A-F, this study analyzes the effect of Pump1 outlet pressure on _ W net for different T ARC Eva operating conditions.For the same Pump1 outlet pressure, the higher the evaporator temperature, the greater the variation in the values of _ W net and η Ex , For example, when the working fluid is R236ea and Pump1 outlet pressure = 1,400 kPa, _ W net = 419.62KW (T ARC Eva = 1 °C), _ W net = 420.15KW (T ARC Eva = 3 °C), _ W net = 420.65KW (T ARC Eva = 5 °C).After Pentane, Isopentane and R245ca reached the peak early relative to the other six working fluids, the increasing trend gradually disappeared with the increase of pressure.The remaining six organic working fluids show a slowly increasing trend in general.If the isentropic efficiency of the turbine is kept constant, _ W net can be increased by increasing the maximum pressure, but with the pressurization of Pump1, it is difficult to sustain the consistency of turbine efficiency, which eventually leads to increased destruction in other components.
As shown in Figure 7F, when Pump1 outlet pressure = 2,100 kPa and other working conditions are the same, the total exergy system efficiency η Ex from largest to smallest is R245fa, Butane, R236ea, R245ca, Isobutane, R236fa, R1234ze, Isopentane, and Pentane, moreover, the _ W net and η Ex of Butane showed an increasing trend with continuous pressurization, verifying the choice of Butane as the best working fluid.

The effect of evaporator temperature
Based on the comprehensive research on the performance impact of various organic working fluids on the ORC system, it was found that Butane provides superior benefits compared to other fluids.Therefore, in the subsequent analysis, we have chosen Butane as the working fluid for the ORC system.The evaporator temperature in the absorption refrigeration cycle is a key design parameter, and Figure 8 presents the impact of evaporator temperature on the exergy efficiency (η Ex ) and the net system output power ( _ W net ) under the condition where the heat source temperature is set at 190 °C and the ORC working fluid is Butane.It is evident that _ W net and η Ex improves with the increase of evaporator temperature.When the temperature of the evaporator falls within the range of 274.15 °C-279.15°C, enhancing the evaporator temperature enhances the efficacy of the waste heat recovery system.This is because of the simultaneous rise in both evaporator pressure and temperature, resulting in a substantial augmentation in the absorption efficiency of the diluted solution, leading to a noteworthy enhancement in effectiveness.

The effect of generator temperature
The temperature of the generator is also an important parameter to study when designing the ARC system, heat transfer rate of condenser2 ( _ Q cond2 ), and the total net output of the system _ W net as well as the exergy efficiency η Ex are plotted in Figure 9.The graph shows that the generator temperature changes from 349.15 K to 355.15 K, as the generator temperature increases, the exergy efficiency of the system η Ex gradually improves, while the net output power varies in the opposite trend.The reason is that as the temperature of the generator continues to rise, the solubility of the absorber is greater, the amount of solution circulation is reduced, the power consumption of the pump is Net output power of ORC system by different organic working substances.
lessened, and the evaporator absorbs more heat, resulting in a reduction in the thermal load of the component, ultimately increasing η Ex and reducing the net output power.For example, as shown in Figure 9, the variation trend of the heat transfer rate of the condenser is listed.As the temperature of the generator rises, _ Q cond2 gradually decreases, so the η Ex increases and the _ W net decreases.

The effect of ORC evaporator pressure and condenser temperature
In an organic Rankine cycle (ORC) system, the maximum working pressure (P max ) and condenser temperature (T cond1 ) have a significant impact on several performance parameters of the whole system, as depicted in Figures 10A-D.The results indicate that increasing the maximum working pressure of the ORC system Frontiers in Energy Research frontiersin.org11 can markedly enhance the net power output and exergy efficiency (η Ex ) of the system.When maintaining a constant condenser temperature, elevating the maximum pressure results in an increase in turbine efficiency, with the net turbine power growing at a rate faster than the energy consumption of the pumps, thereby augmenting the net output power of the system.This series of enhancements will exert a positive influence on the input costs and LCOE of the system, thereby enhancing the system's economic viability.The input cost experiences a significant decrease when T cond1 exceeds 304 K.The primary reason for this phenomenon is that the temperature of the T cond1 leads to a greater temperature differential for the working fluid in ORC during the expansion process, consequently enhancing power generation performance.Furthermore, the higher condenser temperature signifies a reduction in the surface area of the heat exchanger, reducing the size and cost of the heat exchanger within the system, subsequently lowering the energy recovery costs, resulting in a reduction in the LCOE.

The effect of ARC evaporator temperature and condenser temperature
The effects of ARC evaporator temperature and condenser temperature on the net output power, exergy efficiency, total investment, and LCOE of the system are shown in Figures 11A-D.The results indicate that decreasing the condenser temperature (T cond2 ) and increasing the evaporator temperature (T evaporator ) in the ARC system enhance the net power output and exergy efficiency.As the ARC condenser temperature rises, the entry temperature of the working fluid must also increase to match the heat source, leading to increased operating costs for the system.Although investment generally shows a downward trend, the additional cost of increasing the temperature outweighs the benefits of heat recovery, resulting in an increase in LCOE.To ensure optimal system performance and economics, it is crucial to have an economically viable energy recovery solution available for the system and select the appropriate turning point of the LCOE versus input cost surface, for example, T cond2 = 303.15.

The effect of generator temperature and condenser temperature
Figures 12A-D illustrates the impact of ARC generator temperature and condenser temperature on the net output power, exergy efficiency, total investment, and LCOE of the overall system.While keeping T cond2 constant, the system's exergy efficiency improves with an increase in generator temperature.As depicted in Figs.c-d, the rise in generator temperature necessitates the use of costlier materials to withstand the high-temperature environment, leading to a concomitant increase in both total investment and LCOE.

The analysis of exergy destruction in the component
Figure 13 presents the findings of the exergy analysis based on the design conditions for the waste heat recovery system.The primary function of Pump2 is to enhance heat transfer efficiency, rather than being the primary workload in the circulation system, Effect of ARC evaporator temperature on the net system output power _ W net and the exergy efficiency η Ex .
Effects of generator temperature on _ Q cond2 , _ W net and η Ex .
hence the negligible impact of Pump2 can be neglected.50.8% of exergy destruction in the system occurs in the generator, followed by the evaporator and absorber.This is because of the high-temperature ammonia mixture solution under isobaric conditions, which causes the generator to operate at elevated temperatures.As a result, it concentrated most exergy destruction in the generator and absorber.These irreversibilities are mainly due to mixing destruction in the generator and absorber as well as to concentration gradients, temperature gradients and external forces (Nami et al., 2017).The exergy destruction in the ORC system occurs mainly in the HE (6.79%), and the high value of energy destruction is primarily caused by the large temperature discrepancy that exists between the cold and hot flows in the component (Aman et al., 2014).This figure shows the need to consider the design of the generator, absorber and Heat Exchanger to reduce exergy destruction by them.The thermodynamic properties of the system are shown in Table 11.

The results of economic analysis
The economic efficiency is an effective factor to judge the sustainability of the system, which depends not only on the exergy efficiency of the system but also on the net output efficiency and the LCOE, as shown in Table 12 for the new sugar plant.The investment cost of the new system is 2.94 million dollars (M$).It can be concluded from Figure 14 that the overall cost of the ORC cycle is based higher than the cost of the ARC cycle.In addition, the ORC system has the highest heat exchanger cost.However, by recycling the system, the net power output is increased by 0.5385 MW, providing 4717.26MW of renewable electricity and 15,820.56MW of space cooling capacity for the sugar plant per year.The payback period of the system is 5.79 years.The economic performance of the system is highly dependent on the price of renewable electricity, and the higher the price, the more investment potential the project has.The results of the economic analysis of the system illustrate that the waste heat recovery system of the sugar mill has a great economic potential, and the project is economically feasible.

Multi-objective optimization results
In this study, we employ NSGA-II to identify optimal system operation parameters in order to address the trade-off between LCOE and exergy efficiency η Ex Figure 15 illustrates the Pareto front solutions for both the ORC and ARC systems.The Pareto Frontier represents potential executable plans at various points, typically selected based on the decision maker's objectives.Points A and B correspond to two optimal solutions, one with the minimum LCOE and the other with the maximum η Ex , respectively.Point C represents an ideal scenario that satisfies both the minimum LCOE and the maximum η Ex .However, due to the inherent conflict between these two objectives, they cannot be simultaneously achieved.Therefore, we employ the results of the TOPSIS analysis to identify point D, which is closest to point C and thus considered the best available solution.This solution represents the optimal system operation parameters, as detailed in Table 12.The results after running are shown in Table 13.The optimized η Ex achieved a significant increase to 31.57%, demonstrating substantial improvement.Notably, in terms of economic indicators, the LCOE has effectively converged with the electricity price, reaching a reduced value of 0.0406$/kWh.This clearly indicates the waste heat recovery system's slight but discernible economic advantage.In order to comprehensively assess the economic returns of the entire system, the purchase prices for electricity and cooling have been set at an average annual rate of €30 per MWh and €20 per MWh (Nami and Anvari-Moghaddam, 2020).Furthermore, the implementation of the optimized system is expected to yield an annual revenue of $136,300 from electricity sales, while also resulting in substantial savings of around $308,600 in cooling expenses.When considering the overall outcomes, these optimization results establish a viable solution characterized by both remarkable economic efficiency and notable technical advantages.

Comparison of multiple systems and single system
Malwe et al. ( 2021) proposed a VCRS-ORC system aiming to achieve waste heat recovery, cooling, and electricity generation.The final exergy efficiency of this system was determined to be 17.95%, with a net output power of 0.296 kW.In this study, an ORC-ARC system was introduced to achieve higher energy utilization efficiency.Compared to the former, the exergy efficiency of this system increased by 14.175%, reaching a net output power of   The exergy destruction rate of each component of the system.
Frontiers in Energy Research frontiersin.org15 5,385 kW.Significantly improved system efficiency and power output were achieved by studying the optimal working fluid in the ORC and analyzing key factors within the system.

Possible differences in real exploitation conditions
First, in the actual operation process, the heat exchanger may not reach the ideal pinch point designed, resulting in a large temperature difference and failure to achieve the desired performance.Second, the efficiency of pumps and turbines depends on variable operating conditions.The optimal working conditions of the pump and the turbine may be difficult to achieve, resulting in reduced system performance.The characteristics of the heat source affect the performance of ORC.In the actual operation process, heat source fluctuations will reduce the efficiency of the steam turbine and the effectiveness of the heat exchanger, so the performance may be reduced.Cascade system component cost.

Frontiers in Energy Research frontiersin.org
This research presents a novel waste heat recovery system composed of an absorption refrigeration cycle and an organic Rankine cycle, which is applied for the recovery of boiler flue gas in a sugar factory.By taking the utilization of flue gas, considerable power generation and refrigeration output are obtained, resulting in improvements in system irreversibility and exhaust emissions.An economic and thermodynamic analysis of the entire system are conducted.The main conclusions are summarized as: (1) In this research, nine working fluids were adopted and among which Butane was identified as the most appropriate working fluid for ORC.(2) With an investment of 2.94 million dollars (M$), the system has a high exergy efficiency of 32.125%, with an increased power output of 4717.26MW h and an increased space cooling capacity of 15,820.56MW per year for the sugar mill.Additionally, the payback period of the system can be shortened to 5.79 years.
(3) Through multi-objective optimization, the optimal operating parameters of the system are obtained.The LCOE at the optimum working condition is as low as 0.0406$/kWh, and the exergy efficiency is 31.57%.The annual revenue from electricity sales and the saving cost for cooling are $136,300 and $308,600, respectively.(4) ORC and ARC were used for waste heat gradient utilization from boiler exhaust gas.The system has achieved multi-forms conversion of energy to cooling and generating electricity through cascade utilization of waste heat.(5) The highest exergy destruction occurs in the generator, accounting for 50.8% of the overall system.
To expand this research in the future, it is necessary to evaluate the system by combining environmental factors.Second, it is crucial to consider the optimization of the heat exchanger model.There are various working fluids that can be used in absorption refrigeration cycles, and it is possible to conduct thermodynamic analysis by switching between them to optimize the system.In addition, it is essential to study different refrigeration systems and thus achieving a more efficient energy conversion system.

Publisher's note
All claims expressed in this article are solely those of the authors and do not necessarily represent those of their affiliated organizations, or those of the publisher, the editors and the reviewers.Any product that may be evaluated in this article, or claim that may be made by its manufacturer, is not guaranteed or endorsed by the publisher.ΔT LMTD log mean temperature difference (K) Frontiers in Energy Research frontiersin.org20 Wang et al. 10.3389/fenrg.2024.1308519

FIGURE 1
FIGURE 1Process flow of sugar mill.

FIGURE 7
FIGURE 7 Effect of high pressure in ORC on _ W net .(A) ARC Evaporator temperature of 1 °C.(B) ARC Evaporator temperature of 1 °C.(C) ARC Evaporator temperature of 3 °C.(D) ARC Evaporator temperature of 3 °C.(E) ARC Evaporator temperature of 5 °C.(F) ARC Evaporator temperature of 5 °C.

FIGURE 10
FIGURE 10Effects of ORC evaporator pressure and condenser temperature on the system.(A) Net power output of new system.(B) The exergy efficiency of new system.(C) The total investment of new system.(D) LCOE of the new system.

FIGURE 11
FIGURE 11Effects of ARC evaporator pressure and condenser temperature on the system.(A) Net power output of new system.(B) The exergy efficiency of new system.(C) The total investment of new system.(D) LCOE of the new system.

FIGURE 12
FIGURE 12Effects of ARC Generator pressure and condenser temperature on the system.(A) Net power output of new system.(B) The exergy efficiency of new system.(C) The total investment of new system.(D) LCOE of the new system.

TABLE 1
Basic input parameters for ORC and ARC systems.

TABLE 2
Control equations for each component of ORC and ARC.

TABLE 3
Exergy equations for each component of the system.

TABLE 5
Total heat transfer coefficient of each component.

TABLE 6
Decision variables and their ranges.

TABLE 7
Adjustable parameters used for the optimization.

TABLE 10
The thermodynamic properties of selected organic fluids.

TABLE 11
The parameters of each stream.

TABLE 12
The economic analysis of the new system.
TABLE 13 Pareto-optimal solutions for the system operation.Ex as the objective function.
FIGURE 15System Pareto front solution with LCOE and exergy efficiency η