*Correspondence:
This article was submitted to Plasma Physics, a section of the journal Frontiers in Physics.
Edited by: Antonio D'Angola, Università della Basilicata, Italy
Reviewed by: Antonio D'Angola, Università della Basilicata, Italy; Agnes Granier, Centre National de la Recherche Scientifique, France
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A plasma is a hot ionized gas and classification of this fourth state of matter can be initially done using the basic concept of temperature. A prime example is the Sun which exhibits a very hot plasma in its core with temperatures of about 1.5 × 107 K (a result of fusion reactions with a proton density of ~1026 cm−3) and cooler surface temperatures of about 6000 K [
Plasmas in which fusion reactions take place are often referred to as “hot” plasmas. The high-temperature plasma community has a well-defined aim of triggering and controlling fusion plasmas (as can be found in the Sun's core) for energy production, with various worldwide large scale programs or experiments in place (i.e., the International Thermonuclear Experimental Reactor ITER, the National Ignition Facility ICF…) [
Amongst thousands of plasma applications processes, a few examples are presented to show the past, present and future key role cold plasma physics must play in addressing the challenges facing the modern world: predicted energy crisis, environmental issues and ecosystems, global climate variation, population growth and biomedical concerns. In addressing those issues we must better understand the physics of the atmosphere, ionosphere and magnetosphere, the physics of the plasma interacting with a boundary and develop new clean sources of energy.
Successful operation of satellites in Low Earth Orbits within the ionosphere (the inner plasma layer in the Earth's atmosphere) plays a key role not only in international global security but also in climate change and weather monitoring. In addition to space weather related communications glitches (from temporal to catastrophic failure) there is a growing and fierce international competition for access to “premium” Earth orbits especially geostationary, and increasing concern for collisions with other satellites or space debris. It takes 2 years to build a large telecommunication satellite for a “commercially guaranteed” lifetime of 15 years, interestingly similar to the slowest dynamic scale of solar activity, defined as the solar cycle. However, solar processes with shorter time scales are largely responsible for day to day variation of space weather with a reported link between solar geomagnetic variation, solar-wind velocity and solar-wind energy density [
The energy stored in the dynamical behavior of the Sun's complex magnetic field structures is occasionally released in dramatic disruptions (Coronal Mass Ejections) producing large space storms in the magnetosphere of the Earth and investigated in the laboratory for nearly a century in “Terrella experiments” [
A surprising and unresolved mystery of the cosmos is the spectroscopically measured acceleration (over a short distance of about 300 km within the low density solar corona) of the electrically neutral solar wind plasma to proton temperatures of up to 1–1.5 × 106 K, approaching that of the Sun's core [
Interestingly, the main parameter ranges of the solar corona (electron and ion densities, temperatures and magnetic field strength) can be experimentally created in terrestrial laboratory plasmas, although we have to recognize that a spatial scaling about six orders down is necessary [
Perhaps these research areas could be grouped as plasma challenges in which the boundary is a gas, a discontinuity (shock) with the plasma or another plasma. It includes the topic of plasma thrusters, a “laboratory plasma” expanding in the ionosphere. Most of the areas reviewed below focus on the interaction between a plasma and a solid or liquid boundary.
The interaction between a reactive or non-reactive laboratory plasma and any solid or liquid surface is complex and consequently offers an extremely wide range of applications [
The development of “plasma” or “dry” processes for the miniaturization of integrated circuits (ICs) from the 1970s has revolutionized the high-tech microelectronics industry based on the invention of the transistor in 1947. It typically takes 2 months and about thirty plasma processes for the manufacturing in a fabrication line of a semi-conductor IC: such processes include material etching and deposition of metals, insulators and semi-conductors. Over the past 40 years, plasma technology has reduced the size of electronic components by a factor of 250,000 while allowing processes over increasingly large wafers. Highest quality features and lowest price are now key drivers for access to laptop computers, mobiles phones, digital cameras and GPS systems with nearly all industries having efficient and reliable computerized control systems to provide their services. Here low pressure plasmas (a few orders of magnitude lower than atmospheric pressure) not in thermal equilibrium (the gas temperature is much lower than the electron temperature) are commonly used which require the use of expensive vacuum systems and clean rooms, the use of highly reactive and often toxic gases necessitating safety equipment and procedures and the use of state of the art precision tools and materials bulk or surface diagnostics [
Current challenges of the microelectronics industry include the move from 300 to 450 mm in diameter silicon wafers, the development of three-dimensional silicon-based integrated circuits (a first approach is the integration of two “flipped” wafers necessitating “Through Silicon Vias,” dielectric etching with large aspect ratios, extended mask lifetime), integrated opto-electronics (merging of III-V and silicon semi-conductor technologies), further development and integration of new materials in communications devices (quantum transistors and nanotechnology) or in Micro-ElectroMechanical Systems (MEMS) or more recently in BioMEMS.
Beam extraction from plasmas include neutral beam injection in fusion experiments, ion beam extraction (from low to high energy) and acceleration, and electron beams used as neutralizers in electric propulsion in space (i.e., ion gridded and Hall effect thrusters). Focused ion beams are key diagnostics tools for reverse engineering, materials science and the emerging field of nuclear forensic. Many challenges related to the development of ICs such as process uniformity and substrate charging are also relevant to thin film coatings for aerospace applications or even the control of electrical charging of satellites. The inter-connectivity between applications is an exciting aspect of cold plasma physics and engineering. Similarly, impressive advances in laser-driven plasma accelerators have yield the generation of very high energy electron (MeV-GeV), proton (MeV) and X-ray beams [
Human activity on Earth over the past two centuries and human space use over the past 55 years have expanded by using non-renewable supplies of fossil fuels with a large hydrocarbon content (coal, petroleum, natural gas): initially with coal and steam engines, then with petrol and combustion engines, and also with electricity (which can be produced in various ways). The fixed supply of hydrocarbon fuels cannot indefinitely feed the population growth and individual energy needs. Deforestation, soil erosion, ocean pollution on Earth, carbon dioxide emission in the Earth' atmosphere and space debris orbiting the Earth increasing affect the Earth's fragile ecosystems and equilibrium. Can low-temperature plasmas contribute to a better transport, storage and management of our energy resources, and to a better control of waste products on Earth and in space? The diversity of energy-related plasma applications implies that the fourth state of matter will be a key player in sustainability and waste management.
An iconic example is the evolution of lighting devices: at night and from space, Earth appears as an illuminated sphere and the energy consumption related to lighting is significant. One of the cheapest plasma devices making direct use of the photons in the plasma is the fluorescent tube, essentially a plasma lamp containing neon gas with a small amount of mercury vapor confined between electrodes at both ends. It has taken two decades for this technology to mature and provide a good electrical to light conversion efficiency and new developments aiming at moving away from the use of mercury while maintaining good conversion efficiency are proving difficult [
Power generation from fusion reactors is still a long way off and the inclusion of renewable energy (solar, wind) into the grid creates a set of new challenges. A large fraction of the population in developing countries has no access to modern affordable energy services and small scale systems can provide access to “off-grid” energy: solar technology, fuel cell technology, wind technology and perhaps artificial photosynthesis in the future. Could the latter produce a sustainable global hydrogen economy in the developing world? Plasma technology usually finds its way in most applications and an important challenge will be to take into account the “real” net energy cost and environmental impact.
Electric arcs, plasma jets or torches are very widely used in the industry and these are “thermal” plasmas operating at or near atmospheric pressure. Both the electrons and heavy species are at high temperature and the intense heat of the arc is used to melt and fuse the metals edges (arc welding) or to cut through metals (plasma cutting). Electric arc furnaces are used to produce metals such as steel. The intense heat of the arc is increasingly used for waste treatment (from household garbage to highly-toxic chemicals) to convert organic liquids, ozone-depleting substances and fluorocarbon greenhouse gases into harmless substances. In some cases useful products, such as syngas (a mixture of hydrogen and carbon monoxide), can be combusted to produce electricity. Overall the process may be costly and not energy efficient but can solve important problems. Wear- or thermally-resistant coatings (the coating of jet engine turbine blades with zirconia) can be sprayed by injected particles into the plasma jet where they partially melt before being blasted onto the surface. Plasma spraying can be reduced down to the nano-scale by tailoring the plasma type and parameters: metallic nano-clusters can be deposited on a variety of substrates for catalytic purposes (e.g., low-temperature fuel cell for transportation or autonomous power units) but plasma-based processes at the nano-scale usually require low pressure plasmas which are costly compared to near-atmospheric pressure plasmas [
Judicious sequences of cold plasma processes (i.e., plasma-enhanced chemical vapor deposition, plasma-electrochemical deposition, low pressure radiofrequency plasmas, microdischarges, plasma-liquid interface systems) can also provide innovative routes for the synthesis of nanoparticles and nanomaterials yielding increased active surface areas, attachment of functional groups on surfaces or other material properties [
A key driver of Twenty first century science, technology and world economy will be “access to space,” based on 55 years of success in the development of satellites starting with the first 83 kg satellite (Sputnik in 1957), the first meteorology satellite (Titos in 1960) and the first telecommunications satellite (Telstar in 1962). The largest human-made spacecraft is the International Space Station, which was initiated in 1983, now weighs 400 tons and cost over 100 billion US dollars. The NASA Voyager 1 exploratory spacecraft, which was launched in 1977, has now traveled in space further than any other human-made craft and has left our solar system. Our daily life strongly relies on successful operation of hundreds of satellites placed on Low Earth Orbits and Geostationary Orbits. Political, economical and military interest drive an unprecedented number of countries to invest in space activities leading to increasing concern for collisions between satellites and space debris. New regulations are being implemented such as a required placement of satellites on graveyard orbits at the end of their lifetime, an enhanced control of toxic propellants used in chemical propulsion engines such as hydrazine or of expensive propellant used in electric propulsion such as xenon (permanently depleting the small reserve available on Earth). The development of new plasma thruster technologies which operate at very low pressure for various types of propellants and could use normally unused residual liquids and gases to provide additional velocity increment would, for example, allow the nominal mission to be extended to the “last drop of fuel” with the capability to still be able to de-orbit a spacecraft. In addition, with the emergence of CubeSat satellites and a variety of new remote sensing technologies providing cheaper access to space, there is increasing demand for low-cost small propulsion systems which can be operated with “greener” or cheaper propellants.
The chemical properties of plasma discharges can be used to produce active species with some very simple processes in place. Population health starts with clean water. Drinking water disinfection using ozone, a powerful oxidizer, is one of the oldest plasma processes usually involving a corona discharge in pure oxygen or air. Although ozone is an air pollutant (harmful under prolonged exposure), it is widely used to kill microorganisms in water (i.e., swimming pools), on food or on contact surfaces (laundries in hospitals, health care facilities) and also in the preparation of pharmaceuticals.
The thermal properties of plasmas have also been extensively used in medicine for cauterization: the plasma scalpel is a “thermal knife” which generates almost no blood loss and allows enhanced precision and simultaneous division and coagulation with less damage (area and intensity) to the surrounding tissues compared to a steel or electrosurgical scalpel. Cauterization occurs on tissue in direct contact with the argon plasma jet with limited heat transferred to the surrounding tissues. This type of jet can also be used for coagulation of bleeding lesions. In addition to this physical interaction between plasma and tissue, therapeutic effects related to numerous components of plasma, such as reactive species (O, NOx, etc.), charged particles, electric fields and even UV light may occur [
There are many reviews which highlight the current challenges and breakthroughs in Plasma Medicine [
Other fast developing areas of relevance to plasma-based technology for medical applications include biomedical transducers, microfluidics, medical implants, microsurgical tools and tissue engineering [
Whether for convenience (esthetic and art) or necessity (food and shelter), a growing population means growing needs and this is bound to dictate the direction of some future developments. Examples include the deposition of inorganic barrier coatings (SiOx) on a variety of substrates (nylon, PET) for food packaging of liquids or complete meals, the treatment of protective clothing and even the deposition of esthetically pleasing coatings.
In the area of plasma physics, there is overall a need for, rather than an abundance of, available data spanning from the atomic to the macroscopic and intergalactic scale.
One iconic grand challenge for cold plasma physics is the unexplained acceleration of the Solar Wind. It clearly shows the necessity to further develop our understanding of complex mechanisms occurring in space, and somewhat harnessed on Earth, by the use of novel approaches to experimental, modeling and theoretical work. This should be facilitated by the development of computational power, of new infrastructure and diagnostic tools and the ability to link expertise in various areas via platforms on the World Wide Web.
Over the past few decades the development of low-temperature plasmas and their applications has directly impacted on our daily lives through major development in electronic, communication and lighting devices to name a few. There is a critical need for further development in most technologies as the Earth's fragile equilibrium is increasingly threatened by human activities and needs. Many challenges relate to the cross-disciplinary nature of most developments and a few key themes have been reviewed.
Low-temperature plasma physics has already demonstrated its ability to contribute to a wide range of areas of science as it often lies at the “boundaries” between these areas. These boundaries and their fluctuations are at the heart of inter-connectivity between many traditional and emerging areas of science. The overall challenge perhaps lies in awareness of the connectivity to ensure long term creativity and readiness for changes ahead in society, industry and science.
The author declares that the research was conducted in the absence of any commercial or financial relationships that could be construed as a potential conflict of interest.