AUTHOR=Luo Chunsheng , Jiang Yilong , Liu Yangqin , Wang Yang , Sun Junhui , Qian Linmao , Chen Lei TITLE=Role of Interfacial Bonding in Tribochemical Wear JOURNAL=Frontiers in Chemistry VOLUME=Volume 10 - 2022 YEAR=2022 URL=https://www.frontiersin.org/journals/chemistry/articles/10.3389/fchem.2022.852371 DOI=10.3389/fchem.2022.852371 ISSN=2296-2646 ABSTRACT=Tribochemical wear of contact materials is an important issue in science and engineering. Understanding the mechanisms of tribochemical wear at atomic-scale are favorable to avoid device failure, improve the durability of materials, and even achieve the ultra-precision manufacturing. Hence, this paper reviews some of the latest developments of tribochemical wear of typical materials at the atomic-scale that commonly used as solid lubricants, tribo-elements, or structural materials of micro-electromechanical devices, focusing on their universal mechanisms based on the studies from experiments and numerical simulations. Particular focus is given that the friction-induced formation of interfacial bonding plays a critical role in the wear of frictional systems at atomic-scale.