AUTHOR=Knafelc Joseph , Bryan Scott E. , Gust David , Cathey Henrietta E. 

TITLE=Defining Pre-eruptive Conditions of the Havre 2012 Submarine Rhyolite Eruption Using Crystal Archives

JOURNAL=Frontiers in Earth Science

VOLUME=Volume 8 - 2020

YEAR=2020

URL=https://www.frontiersin.org/journals/earth-science/articles/10.3389/feart.2020.00310

DOI=10.3389/feart.2020.00310

ISSN=2296-6463

ABSTRACT=The 2012 Havre eruption evacuated a crystal-poor rhyolite (~3-7 % crystals) producing a volumetrically dominant (~1.4 km3 ) pumice raft, as well as seafloor giant pumice (5-8 %) and lavas (12-14%) at the vent (~0.1 km3), both of which have subtly higher phenocryst contents. For crystal-poor rhyolites like the Havre pumice, it can often remain ambiguous as to whether the few phenocrysts present, in this case, plagioclase, orthopyroxene, clinopyroxene, Fe-Ti oxides +/- quartz, are: a) autocrysts crystallising from the surrounding melt, b) antecrysts being sourced from mush and the magma plumbing system, or c) xenocrysts derived from source materials or chamber walls, or d) possibly a combination of all of the above. In crystal-poor magmas, the few crystals present are strongly relied upon to constrain pre-eruptive conditions such as magmatic temperatures, pressures, water content and fO2. A detailed textural and compositional analysis combined with a range of equilibrium tests and rhyolite-MELTS modelling provide the basis for distinguishing autocrystic vs inherited crystal populations in the Havre eruption. An autocrystic mineral assemblage of andesine plagioclase, enstatite and Fe-Ti oxides constrains the pre-eruptive conditions of the Havre rhyolite magma: magmatic temperatures of 890 ± 27°C, crystallisation pressures at 2-4 kbars, oxygen fugacity of NNO +0.4 and water concentrations (5.6 ± 1.1 wt.%). Inherited phases not in equilibrium with the host melt composition are clinopyroxene, An-rich plagioclase (>An53) and quartz. Rhyolite-MELTs modelling indicates the clinopyroxene and quartz have most likely been sourced from cooler, silicic mush zones in the Havre magmatic system. This study demonstrates that even in crystal-poor rhyolites it cannot be assumed that all crystals are autocrystic and can be used to constrain pre-eruptive magmatic conditions.