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<front>
<journal-meta>
<journal-id journal-id-type="publisher-id">Front. Earth Sci.</journal-id>
<journal-title>Frontiers in Earth Science</journal-title>
<abbrev-journal-title abbrev-type="pubmed">Front. Earth Sci.</abbrev-journal-title>
<issn pub-type="epub">2296-6463</issn>
<publisher>
<publisher-name>Frontiers Media S.A.</publisher-name>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="publisher-id">831405</article-id>
<article-id pub-id-type="doi">10.3389/feart.2022.831405</article-id>
<article-categories>
<subj-group subj-group-type="heading">
<subject>Earth Science</subject>
<subj-group>
<subject>Original Research</subject>
</subj-group>
</subj-group>
</article-categories>
<title-group>
<article-title>Hydrate Attenuation Characteristics Based on the Patchy-Saturation Model</article-title>
<alt-title alt-title-type="left-running-head">Liu et&#x20;al.</alt-title>
<alt-title alt-title-type="right-running-head">Attenuation Characteristics of Gas Hydrate</alt-title>
</title-group>
<contrib-group>
<contrib contrib-type="author">
<name>
<surname>Liu</surname>
<given-names>Pengqi</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
<uri xlink:href="https://loop.frontiersin.org/people/1541668/overview"/>
</contrib>
<contrib contrib-type="author" corresp="yes">
<name>
<surname>Huang</surname>
<given-names>Handong</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
<xref ref-type="corresp" rid="c001">&#x2a;</xref>
</contrib>
<contrib contrib-type="author">
<name>
<surname>Hu</surname>
<given-names>Liguo</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author">
<name>
<surname>Mao</surname>
<given-names>Shuang</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
</contrib>
<contrib contrib-type="author">
<name>
<surname>Tian</surname>
<given-names>Zhongbin</given-names>
</name>
<xref ref-type="aff" rid="aff4">
<sup>4</sup>
</xref>
</contrib>
<contrib contrib-type="author">
<name>
<surname>Shen</surname>
<given-names>Youyi</given-names>
</name>
<xref ref-type="aff" rid="aff4">
<sup>4</sup>
</xref>
</contrib>
</contrib-group>
<aff id="aff1">
<sup>1</sup>
<institution>State Key Laboratory of Petroleum Resources and Prospecting</institution>, <institution>China University of Petroleum-Beijing</institution>, <addr-line>Beijing</addr-line>, <country>China</country>
</aff>
<aff id="aff2">
<sup>2</sup>
<institution>PetroChina Liaohe Oilfield Company</institution>, <addr-line>Panjin</addr-line>, <country>China</country>
</aff>
<aff id="aff3">
<sup>3</sup>
<institution>Yangtze University</institution>, <addr-line>Wuhan</addr-line>, <country>China</country>
</aff>
<aff id="aff4">
<sup>4</sup>
<institution>Shanxi Province Coal Geophysical Prospecting and Surveying and Mapping Institute</institution>, <addr-line>Jinzhong</addr-line>, <country>China</country>
</aff>
<author-notes>
<fn fn-type="edited-by">
<p>
<bold>Edited by:</bold> <ext-link ext-link-type="uri" xlink:href="https://loop.frontiersin.org/people/1446935/overview">Pibo Su</ext-link>, Guangzhou Marine Geological Survey, China</p>
</fn>
<fn fn-type="edited-by">
<p>
<bold>Reviewed by:</bold> <ext-link ext-link-type="uri" xlink:href="https://loop.frontiersin.org/people/1599217/overview">Hua Ning Xu</ext-link>, Qingdao Institute of Marine Geology (QIMG), China</p>
<p>
<ext-link ext-link-type="uri" xlink:href="https://loop.frontiersin.org/people/995327/overview">Jing Ba</ext-link>, Hohai University, China</p>
</fn>
<corresp id="c001">&#x2a;Correspondence: Handong Huang, <email>757542363@qq.com</email>
</corresp>
<fn fn-type="other">
<p>This article was submitted to Marine Geoscience, a section of the journal Frontiers in Earth Science</p>
</fn>
</author-notes>
<pub-date pub-type="epub">
<day>24</day>
<month>02</month>
<year>2022</year>
</pub-date>
<pub-date pub-type="collection">
<year>2022</year>
</pub-date>
<volume>10</volume>
<elocation-id>831405</elocation-id>
<history>
<date date-type="received">
<day>08</day>
<month>12</month>
<year>2021</year>
</date>
<date date-type="accepted">
<day>13</day>
<month>01</month>
<year>2022</year>
</date>
</history>
<permissions>
<copyright-statement>Copyright &#xa9; 2022 Liu, Huang, Hu, Mao, Tian and Shen.</copyright-statement>
<copyright-year>2022</copyright-year>
<copyright-holder>Liu, Huang, Hu, Mao, Tian and Shen</copyright-holder>
<license xlink:href="http://creativecommons.org/licenses/by/4.0/">
<p>This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these&#x20;terms.</p>
</license>
</permissions>
<abstract>
<p>At present, attenuation characteristics of hydrate applicable to the seismic frequency band are still controversial. In this study, the dispersion and attenuation characteristics of hydrate in different occurrence modes were defined from the mesoscale perspective, and the saturation of hydrate in the study area is estimated. Based on effective medium theory and cementation theory, the skeleton elastic modulus of the sedimentary layer was obtained in the present study. The variation of P-wave attenuation with hydrate saturation was obtained by the patchy-saturation theory. P-wave attenuation increased with saturation when hydrate occurred in the suspension mode. P-wave attenuation decreased with saturation when hydrate occurred in the particle-contact or cementation mode. The particle-contact mode and cementation mode hydrate made the P-wave attenuation peak shift to the right. The influence of the cementation mode on attenuation was greater than that of the particle-contact mode. The conclusions of this study are applicable to the frequency range of seismic exploration, thus solving the problems of hydrate saturation prediction and resource quantity calculation assessment in the study&#x20;area.</p>
</abstract>
<kwd-group>
<kwd>patchy-saturation model</kwd>
<kwd>hydrate saturation</kwd>
<kwd>dispersion</kwd>
<kwd>attenuation</kwd>
<kwd>mesoscale</kwd>
</kwd-group>
</article-meta>
</front>
<body>
<sec id="s1">
<title>Introduction</title>
<p>Gas hydrate, also known as &#x201c;combustible ice,&#x201d; is a kind of ice-like crystalline substance formed by natural gas and water under high pressure and low temperature, distributed in deep-sea sediments or permafrost soil. Gas hydrate has attracted much attention because of its great importance regarding energy, climate, environment, and disasters. The effect of gas hydrate on the velocity of seismic waves has been well understood. Various theoretical or experimental models have been proposed to estimate hydrate saturation by linking hydrate saturation with velocity (<xref ref-type="bibr" rid="B32">Wyllie et&#x20;al., 1956</xref>; <xref ref-type="bibr" rid="B31">Wood et&#x20;al., 1994</xref>; <xref ref-type="bibr" rid="B14">Lee et&#x20;al., 1996</xref>; <xref ref-type="bibr" rid="B12">Helgerud et&#x20;al., 1999</xref>). The common conclusion is that P-wave and S-wave velocities increase with hydrate saturation. Available theoretical formulae have different conditions of applicability. In areas without well data, it is not possible to calibrate theoretical formulae to guarantee the accuracy of hydrate saturation estimates. Therefore, alternative methods for hydrate saturation estimation are required.</p>
<p>Studies have shown that hydrate saturation is related to seismic wave attenuation. This study, therefore, aims to estimate hydrate saturation using attenuation. The dispersion and attenuation of the hydrate sediment layer have been studied with observational data, simulation experiments, and theoretical derivations. The conclusions obtained by these studies differ significantly. Some studies have concluded that attenuation decreases with hydrate saturation (<xref ref-type="bibr" rid="B30">Wood et&#x20;al., 2000</xref>; <xref ref-type="bibr" rid="B22">Rossi et&#x20;al., 2007</xref>; <xref ref-type="bibr" rid="B13">Jaiswal et&#x20;al., 2012</xref>; <xref ref-type="bibr" rid="B4">Dewangan et&#x20;al., 2014</xref>). Other studies have shown that attenuation increases with hydrate saturation (<xref ref-type="bibr" rid="B26">Sakai 1999</xref>; <xref ref-type="bibr" rid="B10">Guerin and Goldberg 2002</xref>; <xref ref-type="bibr" rid="B7">Dvorkin and Uden, 2004</xref>; <xref ref-type="bibr" rid="B19">Pratt et&#x20;al., 2005</xref>; <xref ref-type="bibr" rid="B9">Gerner et&#x20;al., 2007</xref>; <xref ref-type="bibr" rid="B37">Zhang et&#x20;al., 2016</xref>). However, it has also been argued that the relationship between attenuation and hydrate saturation is more complex than single positive or negative correlations (<xref ref-type="bibr" rid="B21">Priest et&#x20;al., 2006</xref>; <xref ref-type="bibr" rid="B15">Lee and Waite 2007</xref>; <xref ref-type="bibr" rid="B27">Sun et&#x20;al., 2014</xref>; <xref ref-type="bibr" rid="B16">Li 2015</xref>; <xref ref-type="bibr" rid="B24">Sahoo et&#x20;al., 2018</xref>; <xref ref-type="bibr" rid="B25">Sahoo et&#x20;al., 2019</xref>; <xref ref-type="bibr" rid="B11">Guo et&#x20;al., 2021</xref>; <xref ref-type="bibr" rid="B28">Wang et&#x20;al., 2021</xref>).</p>
<p>This study used existing attenuation theories to obtain the relationship between hydrate saturation and seismic wave attenuation. Dispersion and attenuation theories are mainly based on the mesoscale, microscopic, and macroscale perspective. Among them, only the mesoscale is applicable to the frequency domain range of seismic surveys (<xref ref-type="bibr" rid="B20">Pride and Berryman, 2003</xref>; <xref ref-type="bibr" rid="B3">Carcione Jos&#xe9; and Picotti, 2006</xref>; <xref ref-type="bibr" rid="B23">Rubino and Holliger, 2012</xref>). To date, the relationship between dispersion and attenuation and hydrate saturation on the mesoscale has rarely been studied. In this study, three hydrate models were developed for the first time based on the patchy saturation theory applicable to the mesoscale. The relationships between hydrate saturation and dispersion and attenuation were obtained for the suspension mode, particle-contact mode, and cementation mode. In addition, the dispersion and attenuation patterns of each mode were clarified (<xref ref-type="bibr" rid="B29">White, 1975</xref>).</p>
<p>The study area was conducted in a deep-water area on the continental slope of a sea, representing a new field of hydrate research. The geological characteristics, temperature and pressure conditions, gas source conditions, tectonic conditions, and sedimentation conditions met the requirements for gas hydrate formation and preservation. Accordingly, the area had good prospects for gas hydrate resources. However, the study area only had seismic data, and well data were absent, making the calculation of hydrate saturation and resources an urgent problem. In this study, hydrate saturation and resource calculations in the study area were realized, providing a theoretical basis for hydrate resource assessment.</p>
</sec>
<sec id="s2">
<title>Patchy-Saturation Theory and Hydrate Model</title>
<p>White first used the patchy-saturation model to simulate velocity dispersion and attenuation caused by mesoscale heterogeneity (<xref ref-type="bibr" rid="B29">White, 1975</xref>). The patchy-saturation model assumes that a partially saturated water rock consists of several units, each consisting of a pair of concentric spheres. The concentric sphere is filled with a gas sphere of radius <inline-formula id="inf1">
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<p>If the interaction force between the air pockets is not considered using the White model, it must be ensured that the air saturation <inline-formula id="inf13">
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</inline-formula> cannot exceed 0.52. If the value is higher, the units will interact and cause the gas plaques to collapse. When the gas saturation exceeds 0.52, the water-in-air mode should be adopted, that is, the inside of the concentric sphere is water, and the outside is&#x20;air.</p>
<p>The patchy-saturation model discusses the attenuation caused by uneven fluid distribution in the pores. The suspension mode natural gas hydrate in the sediment also has uneven distribution. The gas can replace the gas hydrate in the patchy-saturation theory for attenuation calculation (see <xref ref-type="fig" rid="F1">Figure&#x20;1</xref>). For the three models A, B, and C, the suspension mode hydrates exist in the inner sphere. Model B represents the coexistence of the suspension and particle-support modes. The particle-support mode hydrate and skeleton grains form a new skeleton particle. Model C represents the coexistence of the suspension and cementation modes, and the cementation mode hydrate and skeleton grains form the new skeleton grains.</p>
<fig id="F1" position="float">
<label>FIGURE 1</label>
<caption>
<p>Schematic diagram of hydrate occurrence modes. In <bold>(A-C)</bold>, suspension mode hydrate is part of fluid and distributed in the inner diameter. In <bold>(B)</bold>, particle-contact mode hydrate becomes part of solid frame. In <bold>(C)</bold>, cemented mode hydrate cements the grains evenly.</p>
</caption>
<graphic xlink:href="feart-10-831405-g001.tif"/>
</fig>
<sec id="s2-1">
<title>Model A</title>
<p>Based on Hertz&#x2013;Mindlin theory <xref ref-type="bibr" rid="B18">Mindlin (1949)</xref>, Dvorkin <xref ref-type="bibr" rid="B12">Helgerud et&#x20;al. (1999)</xref> proposed a velocity model for non-cemented, high-porosity, hydrate-bearing deposits, and the equations are as follows:<disp-formula id="e15">
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<label>(15)</label>
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<mml:mi>Z</mml:mi>
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<mml:mo>,</mml:mo>
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<label>(16)</label>
</disp-formula>
<disp-formula id="e17">
<mml:math id="m30">
<mml:mrow>
<mml:mi>Z</mml:mi>
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<label>(17)</label>
</disp-formula>
<disp-formula id="e18">
<mml:math id="m31">
<mml:mrow>
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<mml:mi>K</mml:mi>
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<mml:mi>H</mml:mi>
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<mml:mi>P</mml:mi>
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<mml:mn>1</mml:mn>
<mml:mn>3</mml:mn>
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<mml:mo>,</mml:mo>
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</mml:msup>
<mml:msup>
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</mml:mrow>
<mml:mo>)</mml:mo>
</mml:mrow>
</mml:mrow>
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</mml:msup>
</mml:mrow>
</mml:mfrac>
<mml:mi>P</mml:mi>
</mml:mrow>
<mml:mo>]</mml:mo>
</mml:mrow>
</mml:mrow>
<mml:mrow>
<mml:mfrac>
<mml:mn>1</mml:mn>
<mml:mn>3</mml:mn>
</mml:mfrac>
</mml:mrow>
</mml:msup>
<mml:mo>,</mml:mo>
</mml:mrow>
</mml:math>
<label>(18)</label>
</disp-formula>where <inline-formula id="inf14">
<mml:math id="m32">
<mml:mrow>
<mml:msub>
<mml:mi>&#x3d5;</mml:mi>
<mml:mn>0</mml:mn>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula> is the critical porosity (<inline-formula id="inf15">
<mml:math id="m33">
<mml:mrow>
<mml:msub>
<mml:mi>&#x3d5;</mml:mi>
<mml:mn>0</mml:mn>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula> &#x3d; 0.36&#x2013;0.40); <inline-formula id="inf16">
<mml:math id="m34">
<mml:mrow>
<mml:msub>
<mml:mi>K</mml:mi>
<mml:mrow>
<mml:mi>H</mml:mi>
<mml:mi>M</mml:mi>
</mml:mrow>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula> and <inline-formula id="inf17">
<mml:math id="m35">
<mml:mrow>
<mml:msub>
<mml:mi>G</mml:mi>
<mml:mrow>
<mml:mi>H</mml:mi>
<mml:mi>M</mml:mi>
</mml:mrow>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula> are the effective bulk modulus and shear modulus of dry rock when the rock porosity is at critical porosity, respectively; <inline-formula id="inf18">
<mml:math id="m36">
<mml:mrow>
<mml:msub>
<mml:mi>K</mml:mi>
<mml:mn>0</mml:mn>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula>, <inline-formula id="inf19">
<mml:math id="m37">
<mml:mrow>
<mml:msub>
<mml:mi>G</mml:mi>
<mml:mn>0</mml:mn>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula>, and <inline-formula id="inf20">
<mml:math id="m38">
<mml:mrow>
<mml:msub>
<mml:mi>&#x3c5;</mml:mi>
<mml:mn>0</mml:mn>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula> are the bulk modulus, shear modulus, and Poisson&#x2019;s ratio of the skeleton grains, respectively; n is the average number of particles in contact per unit volume, generally 8 or 9 (<xref ref-type="bibr" rid="B6">Dvorkin and Nur, 1996</xref>); and P is the effective pressure, which is generally calculated according to the following formula:<disp-formula id="e19">
<mml:math id="m39">
<mml:mrow>
<mml:mi>P</mml:mi>
<mml:mo>&#x3d;</mml:mo>
<mml:mrow>
<mml:mo>(</mml:mo>
<mml:mrow>
<mml:mn>1</mml:mn>
<mml:mo>&#x2212;</mml:mo>
<mml:mi>&#x3d5;</mml:mi>
</mml:mrow>
<mml:mo>)</mml:mo>
</mml:mrow>
<mml:mrow>
<mml:mo>(</mml:mo>
<mml:mrow>
<mml:msub>
<mml:mi>&#x3c1;</mml:mi>
<mml:mn>0</mml:mn>
</mml:msub>
<mml:mo>&#x2212;</mml:mo>
<mml:msub>
<mml:mi>&#x3c1;</mml:mi>
<mml:mi>f</mml:mi>
</mml:msub>
</mml:mrow>
<mml:mo>)</mml:mo>
</mml:mrow>
<mml:mi>g</mml:mi>
<mml:mi>h</mml:mi>
<mml:mo>,</mml:mo>
</mml:mrow>
</mml:math>
<label>(19)</label>
</disp-formula>where <inline-formula id="inf21">
<mml:math id="m40">
<mml:mrow>
<mml:msub>
<mml:mi>&#x3c1;</mml:mi>
<mml:mn>0</mml:mn>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula> and <inline-formula id="inf22">
<mml:math id="m41">
<mml:mrow>
<mml:msub>
<mml:mi>&#x3c1;</mml:mi>
<mml:mi>f</mml:mi>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula> are the density of skeleton grains and fluid, respectively; g is the acceleration due to gravity; and h is the depth below the seabed. <inline-formula id="inf23">
<mml:math id="m42">
<mml:mrow>
<mml:msub>
<mml:mi>K</mml:mi>
<mml:mrow>
<mml:mi>D</mml:mi>
<mml:mi>r</mml:mi>
<mml:mi>y</mml:mi>
</mml:mrow>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula> &#x3d; <inline-formula id="inf24">
<mml:math id="m43">
<mml:mrow>
<mml:msub>
<mml:mi>K</mml:mi>
<mml:mrow>
<mml:mi>H</mml:mi>
<mml:mi>M</mml:mi>
</mml:mrow>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula>; <inline-formula id="inf25">
<mml:math id="m44">
<mml:mrow>
<mml:msub>
<mml:mi>G</mml:mi>
<mml:mrow>
<mml:mi>D</mml:mi>
<mml:mi>r</mml:mi>
<mml:mi>y</mml:mi>
</mml:mrow>
</mml:msub>
<mml:mtext>&#x2009;</mml:mtext>
</mml:mrow>
</mml:math>
</inline-formula> &#x3d; <inline-formula id="inf26">
<mml:math id="m45">
<mml:mrow>
<mml:msub>
<mml:mi>G</mml:mi>
<mml:mrow>
<mml:mi>H</mml:mi>
<mml:mi>M</mml:mi>
</mml:mrow>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula>. When <inline-formula id="inf27">
<mml:math id="m46">
<mml:mi>&#x3d5;</mml:mi>
</mml:math>
</inline-formula> &#x3d; <inline-formula id="inf28">
<mml:math id="m47">
<mml:mrow>
<mml:msub>
<mml:mi>&#x3d5;</mml:mi>
<mml:mn>0</mml:mn>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula>, the bulk modulus and shear modulus of the dry rock were calculated by <xref ref-type="disp-formula" rid="e18">Eq. 18</xref>, that is, <inline-formula id="inf29">
<mml:math id="m48">
<mml:mrow>
<mml:msub>
<mml:mi>K</mml:mi>
<mml:mrow>
<mml:mi>D</mml:mi>
<mml:mi>r</mml:mi>
<mml:mi>y</mml:mi>
</mml:mrow>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula> &#x3d; <inline-formula id="inf30">
<mml:math id="m49">
<mml:mrow>
<mml:msub>
<mml:mi>K</mml:mi>
<mml:mrow>
<mml:mi>H</mml:mi>
<mml:mi>M</mml:mi>
</mml:mrow>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula>, <inline-formula id="inf31">
<mml:math id="m50">
<mml:mrow>
<mml:msub>
<mml:mi>G</mml:mi>
<mml:mrow>
<mml:mi>D</mml:mi>
<mml:mi>r</mml:mi>
<mml:mi>y</mml:mi>
</mml:mrow>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula> &#x3d; <inline-formula id="inf32">
<mml:math id="m51">
<mml:mrow>
<mml:msub>
<mml:mi>G</mml:mi>
<mml:mrow>
<mml:mi>H</mml:mi>
<mml:mi>M</mml:mi>
</mml:mrow>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula>. <inline-formula id="inf33">
<mml:math id="m52">
<mml:mi>&#x3d5;</mml:mi>
</mml:math>
</inline-formula> <inline-formula id="inf34">
<mml:math id="m53">
<mml:mo>&#x2260;</mml:mo>
</mml:math>
</inline-formula> <inline-formula id="inf35">
<mml:math id="m54">
<mml:mrow>
<mml:msub>
<mml:mi>&#x3d5;</mml:mi>
<mml:mn>0</mml:mn>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula>, <inline-formula id="inf36">
<mml:math id="m55">
<mml:mrow>
<mml:msub>
<mml:mi>K</mml:mi>
<mml:mrow>
<mml:mi>D</mml:mi>
<mml:mi>r</mml:mi>
<mml:mi>y</mml:mi>
</mml:mrow>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula>, and <inline-formula id="inf37">
<mml:math id="m56">
<mml:mrow>
<mml:msub>
<mml:mi>G</mml:mi>
<mml:mrow>
<mml:mi>D</mml:mi>
<mml:mi>r</mml:mi>
<mml:mi>y</mml:mi>
</mml:mrow>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula>were calculated by <xref ref-type="disp-formula" rid="e15">Eq. 15</xref> to <xref ref-type="disp-formula" rid="e17">Eq.&#x20;17</xref>.</p>
<p>The bulk modulus of the fluid in the inner sphere is as follows:<disp-formula id="e20">
<mml:math id="m57">
<mml:mrow>
<mml:msub>
<mml:mi>K</mml:mi>
<mml:mrow>
<mml:mi>f</mml:mi>
<mml:mn>1</mml:mn>
</mml:mrow>
</mml:msub>
<mml:mo>&#x3d;</mml:mo>
<mml:msup>
<mml:mrow>
<mml:mrow>
<mml:mo>[</mml:mo>
<mml:mrow>
<mml:mfrac>
<mml:mrow>
<mml:mrow>
<mml:mo>(</mml:mo>
<mml:mrow>
<mml:mn>1</mml:mn>
<mml:mo>&#x2212;</mml:mo>
<mml:msub>
<mml:mi>S</mml:mi>
<mml:mrow>
<mml:mi>h</mml:mi>
<mml:mn>1</mml:mn>
</mml:mrow>
</mml:msub>
</mml:mrow>
<mml:mo>)</mml:mo>
</mml:mrow>
</mml:mrow>
<mml:mrow>
<mml:msub>
<mml:mi>K</mml:mi>
<mml:mi>w</mml:mi>
</mml:msub>
</mml:mrow>
</mml:mfrac>
<mml:mo>&#x2b;</mml:mo>
<mml:mfrac>
<mml:mrow>
<mml:msub>
<mml:mi>S</mml:mi>
<mml:mrow>
<mml:mi>h</mml:mi>
<mml:mn>1</mml:mn>
</mml:mrow>
</mml:msub>
</mml:mrow>
<mml:mrow>
<mml:msub>
<mml:mi>K</mml:mi>
<mml:mi>h</mml:mi>
</mml:msub>
</mml:mrow>
</mml:mfrac>
</mml:mrow>
<mml:mo>]</mml:mo>
</mml:mrow>
</mml:mrow>
<mml:mrow>
<mml:mo>&#x2212;</mml:mo>
<mml:mn>1</mml:mn>
</mml:mrow>
</mml:msup>
<mml:mo>.</mml:mo>
</mml:mrow>
</mml:math>
<label>(20)</label>
</disp-formula>
<inline-formula id="inf38">
<mml:math id="m58">
<mml:mrow>
<mml:msub>
<mml:mi>K</mml:mi>
<mml:mi>w</mml:mi>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula> and <inline-formula id="inf39">
<mml:math id="m59">
<mml:mrow>
<mml:msub>
<mml:mi>K</mml:mi>
<mml:mi>h</mml:mi>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula> represent the bulk modulus of formation water and hydrate, respectively; and <inline-formula id="inf40">
<mml:math id="m60">
<mml:mrow>
<mml:msub>
<mml:mi>S</mml:mi>
<mml:mrow>
<mml:mi>h</mml:mi>
<mml:mn>1</mml:mn>
</mml:mrow>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula> is the saturation of the hydrate in the suspension mode in the inner sphere.</p>
<p>The fluid viscosity in the internal region was calculated using Balakin&#x2019;s experimental data fitting (<xref ref-type="bibr" rid="B2">Balakin et&#x20;al., 2010</xref>):<disp-formula id="e21">
<mml:math id="m61">
<mml:mrow>
<mml:msub>
<mml:mi>&#x3b7;</mml:mi>
<mml:mrow>
<mml:mi>f</mml:mi>
<mml:mn>1</mml:mn>
</mml:mrow>
</mml:msub>
<mml:mo>&#x3d;</mml:mo>
<mml:msub>
<mml:mi>&#x3b7;</mml:mi>
<mml:mi>w</mml:mi>
</mml:msub>
<mml:msup>
<mml:mrow>
<mml:mrow>
<mml:mo>(</mml:mo>
<mml:mrow>
<mml:mn>1</mml:mn>
<mml:mo>&#x2212;</mml:mo>
<mml:msub>
<mml:mi>S</mml:mi>
<mml:mrow>
<mml:mi>h</mml:mi>
<mml:mn>1</mml:mn>
</mml:mrow>
</mml:msub>
</mml:mrow>
<mml:mo>)</mml:mo>
</mml:mrow>
</mml:mrow>
<mml:mrow>
<mml:mo>&#x2212;</mml:mo>
<mml:mn>2.55</mml:mn>
</mml:mrow>
</mml:msup>
<mml:mo>,</mml:mo>
</mml:mrow>
</mml:math>
<label>(21)</label>
</disp-formula>where <inline-formula id="inf41">
<mml:math id="m62">
<mml:mrow>
<mml:msub>
<mml:mi>&#x3b7;</mml:mi>
<mml:mi>w</mml:mi>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula> is the viscosity of formation&#x20;water.</p>
</sec>
<sec id="s2-2">
<title>Model B</title>
<p>Compared with the suspension mode, the hydrate was considered part of the rock skeleton in the particle-contact mode, which had two effects: one was to change the bulk modulus and shear modulus of the skeleton, and the other was to reduce the formation&#x2019;s porosity. The skeleton&#x2019;s bulk modulus and shear modulus were calculated using the method mentioned in the study by <xref ref-type="bibr" rid="B17">Liu et&#x20;al. (2019)</xref>. The particle-contact mode hydrate saturation is&#x20;<inline-formula id="inf42">
<mml:math id="m63">
<mml:mrow>
<mml:msub>
<mml:mi>S</mml:mi>
<mml:mrow>
<mml:mi>h</mml:mi>
<mml:mn>2</mml:mn>
</mml:mrow>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula>.</p>
<p>The remaining porosity is as follows:<disp-formula id="e22">
<mml:math id="m64">
<mml:mrow>
<mml:msub>
<mml:mi>&#x3d5;</mml:mi>
<mml:mi>r</mml:mi>
</mml:msub>
<mml:mo>&#x3d;</mml:mo>
<mml:mi>&#x3d5;</mml:mi>
<mml:mrow>
<mml:mo>(</mml:mo>
<mml:mrow>
<mml:mn>1</mml:mn>
<mml:mo>&#x2212;</mml:mo>
<mml:msub>
<mml:mi>S</mml:mi>
<mml:mrow>
<mml:mi>h</mml:mi>
<mml:mn>2</mml:mn>
</mml:mrow>
</mml:msub>
</mml:mrow>
<mml:mo>)</mml:mo>
</mml:mrow>
<mml:mo>.</mml:mo>
</mml:mrow>
</mml:math>
<label>(22)</label>
</disp-formula>
</p>
<p>The hydrate saturation in the suspension mode in the remaining pores is <inline-formula id="inf43">
<mml:math id="m65">
<mml:mrow>
<mml:msub>
<mml:mi>S</mml:mi>
<mml:mrow>
<mml:mi>h</mml:mi>
<mml:mn>1</mml:mn>
</mml:mrow>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula>&#x3002;</p>
<p>The bulk modulus of the fluid in the inner sphere is expressed by <xref ref-type="disp-formula" rid="e20">Eq. 20</xref>. The fluid&#x2019;s viscosity in the inner sphere is expressed by <xref ref-type="disp-formula" rid="e21">Eq.&#x20;21</xref>.</p>
</sec>
<sec id="s2-3">
<title>Model C</title>
<p>When the coexistence of suspension and cementation modes of the hydrate occurs, the skeleton&#x2019;s bulk modulus and shear modulus were calculated using the method mentioned in the study by <xref ref-type="bibr" rid="B17">Liu et&#x20;al. (2019)</xref>. The hydrate saturation of the cementation mode is <inline-formula id="inf44">
<mml:math id="m66">
<mml:mrow>
<mml:msub>
<mml:mi>S</mml:mi>
<mml:mrow>
<mml:mi>h</mml:mi>
<mml:mn>2</mml:mn>
</mml:mrow>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula>. The calculation method of residual porosity <inline-formula id="inf45">
<mml:math id="m67">
<mml:mrow>
<mml:msub>
<mml:mi>&#x3d5;</mml:mi>
<mml:mi>r</mml:mi>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula>, fluid bulk modulus <inline-formula id="inf46">
<mml:math id="m68">
<mml:mrow>
<mml:msub>
<mml:mi>K</mml:mi>
<mml:mrow>
<mml:mi>f</mml:mi>
<mml:mn>1</mml:mn>
</mml:mrow>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula>, and fluid viscosity <inline-formula id="inf47">
<mml:math id="m69">
<mml:mrow>
<mml:msub>
<mml:mi>&#x3b7;</mml:mi>
<mml:mrow>
<mml:mi>f</mml:mi>
<mml:mn>1</mml:mn>
</mml:mrow>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula> in the inner sphere is the same as that of model&#x20;B.</p>
</sec>
</sec>
<sec sec-type="results" id="s3">
<title>Results</title>
<sec id="s3-1">
<title>The Relationship Between Hydrate Saturation and Attenuation</title>
<p>At high hydrate concentrations (hydrate saturation exceeding 0.4), the hydrate greatly strengthens the skeleton of the sediments, bonds to adjacent porous medium particles, and causes sediments to solidify. Thus, the suspension mode hydrate changes into particle-contact mode or cemented mode hydrate (<xref ref-type="bibr" rid="B34">Yun et&#x20;al., 2005</xref>; <xref ref-type="bibr" rid="B35">Yun et&#x20;al., 2007</xref>; <xref ref-type="bibr" rid="B33">Xue 2016</xref>). Therefore, the upper limit of hydrate saturation for the suspension mode used in this study was 0.4. Attenuation is not only related to fluid distribution heterogeneity but also fabric heterogeneity (<xref ref-type="bibr" rid="B1">Ba et&#x20;al., 2017</xref>; <xref ref-type="bibr" rid="B36">Zhang et&#x20;al., 2021</xref>). In this study, uniform spherical particles were used as skeleton particles for simplicity. The parameters in <xref ref-type="table" rid="T1">Table&#x20;1</xref> are used to calculate the relationship between hydrate saturation and attenuation for the three models.</p>
<table-wrap id="T1" position="float">
<label>TABLE 1</label>
<caption>
<p>Parameters.</p>
</caption>
<table>
<thead valign="top">
<tr>
<th align="left">Parameter</th>
<th align="center">Symbol</th>
<th align="center">Value</th>
</tr>
</thead>
<tbody valign="top">
<tr>
<td align="left">Bulk modulus of skeleton particles/GPa</td>
<td align="center">
<inline-formula id="inf48">
<mml:math id="m70">
<mml:mrow>
<mml:msub>
<mml:mi>K</mml:mi>
<mml:mn>0</mml:mn>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula>
</td>
<td align="char" char=".">22.91</td>
</tr>
<tr>
<td align="left">Shear modulus of skeleton particles/GPa</td>
<td align="center">
<inline-formula id="inf49">
<mml:math id="m71">
<mml:mrow>
<mml:msub>
<mml:mi>G</mml:mi>
<mml:mn>0</mml:mn>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula>
</td>
<td align="char" char=".">20.78</td>
</tr>
<tr>
<td align="left">Density of skeleton particles/kg/m<sup>3</sup>
</td>
<td align="center">
<inline-formula id="inf50">
<mml:math id="m72">
<mml:mrow>
<mml:msub>
<mml:mi>&#x3c1;</mml:mi>
<mml:mn>0</mml:mn>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula>
</td>
<td align="char" char=".">2650</td>
</tr>
<tr>
<td align="left">Bulk modulus of hydrate/GPa</td>
<td align="center">
<inline-formula id="inf51">
<mml:math id="m73">
<mml:mrow>
<mml:msub>
<mml:mi>K</mml:mi>
<mml:mi>h</mml:mi>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula>
</td>
<td align="char" char=".">6.41</td>
</tr>
<tr>
<td align="left">Shear modulus of hydrate/GPa</td>
<td align="center">
<inline-formula id="inf52">
<mml:math id="m74">
<mml:mrow>
<mml:msub>
<mml:mi>G</mml:mi>
<mml:mi>h</mml:mi>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula>
</td>
<td align="char" char=".">2.55</td>
</tr>
<tr>
<td align="left">Density of hydrate/kg/m<sup>3</sup>
</td>
<td align="center">
<inline-formula id="inf53">
<mml:math id="m75">
<mml:mrow>
<mml:msub>
<mml:mi>&#x3c1;</mml:mi>
<mml:mi>h</mml:mi>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula>
</td>
<td align="char" char=".">900</td>
</tr>
<tr>
<td align="left">Bulk modulus of formation water/GPa</td>
<td align="center">
<inline-formula id="inf54">
<mml:math id="m76">
<mml:mrow>
<mml:msub>
<mml:mi>K</mml:mi>
<mml:mi>w</mml:mi>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula>
</td>
<td align="char" char=".">2.25</td>
</tr>
<tr>
<td align="left">Shear modulus of formation water/GPa</td>
<td align="center">
<inline-formula id="inf55">
<mml:math id="m77">
<mml:mrow>
<mml:msub>
<mml:mi>G</mml:mi>
<mml:mi>w</mml:mi>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula>
</td>
<td align="char" char=".">0</td>
</tr>
<tr>
<td align="left">Density of formation water/kg/m<sup>3</sup>
</td>
<td align="center">
<inline-formula id="inf56">
<mml:math id="m78">
<mml:mrow>
<mml:msub>
<mml:mi>&#x3c1;</mml:mi>
<mml:mi>w</mml:mi>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula>
</td>
<td align="char" char=".">1,000</td>
</tr>
<tr>
<td align="left">Critical porosity/f</td>
<td align="center">
<inline-formula id="inf57">
<mml:math id="m79">
<mml:mrow>
<mml:msub>
<mml:mi>&#x3d5;</mml:mi>
<mml:mn>0</mml:mn>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula>
</td>
<td align="char" char=".">0.36</td>
</tr>
<tr>
<td align="left">Porosity/f</td>
<td align="center">
<inline-formula id="inf58">
<mml:math id="m80">
<mml:mi>&#x3d5;</mml:mi>
</mml:math>
</inline-formula>
</td>
<td align="char" char=".">0.4</td>
</tr>
<tr>
<td align="left">Acceleration of gravity/m/s<sup>2</sup>
</td>
<td align="center">
<inline-formula id="inf59">
<mml:math id="m81">
<mml:mi>g</mml:mi>
</mml:math>
</inline-formula>
</td>
<td align="char" char=".">9.8</td>
</tr>
<tr>
<td align="left">Depth below the sea floor/m</td>
<td align="center">
<inline-formula id="inf60">
<mml:math id="m82">
<mml:mi>h</mml:mi>
</mml:math>
</inline-formula>
</td>
<td align="char" char=".">300</td>
</tr>
<tr>
<td align="left">Average number of particles in contact per unit volume</td>
<td align="center">
<inline-formula id="inf61">
<mml:math id="m83">
<mml:mi>n</mml:mi>
</mml:math>
</inline-formula>
</td>
<td align="char" char=".">9</td>
</tr>
<tr>
<td align="left">Particle diameter/ <inline-formula id="inf62">
<mml:math id="m84">
<mml:mrow>
<mml:mi>&#x3bc;</mml:mi>
<mml:mi>m</mml:mi>
</mml:mrow>
</mml:math>
</inline-formula>
</td>
<td align="center">
<inline-formula id="inf63">
<mml:math id="m85">
<mml:mi>d</mml:mi>
</mml:math>
</inline-formula>
</td>
<td align="char" char=".">20</td>
</tr>
<tr>
<td align="left">Viscosity of formation water/cp</td>
<td align="center">
<inline-formula id="inf64">
<mml:math id="m86">
<mml:mrow>
<mml:msub>
<mml:mi>&#x3b7;</mml:mi>
<mml:mi>w</mml:mi>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula>
</td>
<td align="char" char=".">1</td>
</tr>
<tr>
<td align="left">Permeability/mD</td>
<td align="center">
<inline-formula id="inf65">
<mml:math id="m87">
<mml:mi>&#x3ba;</mml:mi>
</mml:math>
</inline-formula>
</td>
<td align="char" char=".">500</td>
</tr>
<tr>
<td align="left">Outer diameter/m</td>
<td align="center">
<inline-formula id="inf66">
<mml:math id="m88">
<mml:mrow>
<mml:msub>
<mml:mi>r</mml:mi>
<mml:mrow>
<mml:mi>o</mml:mi>
<mml:mi>u</mml:mi>
<mml:mi>t</mml:mi>
</mml:mrow>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula>
</td>
<td align="char" char=".">0.05</td>
</tr>
<tr>
<td align="left">Inside diameter/m</td>
<td align="center">
<inline-formula id="inf67">
<mml:math id="m89">
<mml:mrow>
<mml:msub>
<mml:mi>r</mml:mi>
<mml:mrow>
<mml:mi>i</mml:mi>
<mml:mi>n</mml:mi>
</mml:mrow>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula>
</td>
<td align="char" char=".">0.03</td>
</tr>
</tbody>
</table>
</table-wrap>
<p>
<xref ref-type="fig" rid="F2">Figure&#x20;2</xref> shows the variation in P-wave velocity and attenuation with frequency in model A. For different hydrate saturation, the P-wave velocity increased nonlinearly with frequency, and the P-wave velocity shifted upward overall with hydrate saturation. The P-wave velocity increased rapidly to a certain value near the characteristic frequency, and the increase was positively correlated with hydrate saturation (<xref ref-type="fig" rid="F2">Figure&#x20;2A</xref>). <xref ref-type="fig" rid="F2">Figure&#x20;2B</xref> shows the variation of the P-wave attenuation coefficient with frequency. The attenuation tended to increase and then decrease with hydrate saturation, reaching a peak at the characteristic frequency. The peak value of the attenuation versus the frequency curve gradually increased with saturation.</p>
<fig id="F2" position="float">
<label>FIGURE 2</label>
<caption>
<p>P-wave velocity <bold>(A)</bold> and P-wave attenuation <bold>(B)</bold> vs. frequency curves at different hydrate contents in model A.</p>
</caption>
<graphic xlink:href="feart-10-831405-g002.tif"/>
</fig>
<p>
<xref ref-type="fig" rid="F3">Figure&#x20;3</xref> shows the variation of P-wave velocity and attenuation with frequency in model B. The P-wave velocity increased with saturation in both the suspension and particle-contact modes, assuming hydrate saturations of 0.1, 0.2, and 0.3 in the particle-contact mode and 0, 0.1, 0.2, 0.3, and 0.4 in the suspension mode. When the hydrate saturation in the suspension mode was 0, the P-wave velocity was constant, that is, it did not vary with frequency (<xref ref-type="fig" rid="F3">Figures&#x20;3A-C</xref>). As shown in <xref ref-type="fig" rid="F3">Figure&#x20;3D</xref>, attenuation increased with hydrate saturation in the suspension mode and decreased with hydrate saturation in the particle-contact mode. The peak of P-wave attenuation shifted to the right as hydrate saturation increased in the particle-contact&#x20;mode.</p>
<fig id="F3" position="float">
<label>FIGURE 3</label>
<caption>
<p>P-wave velocity <bold>(A-C)</bold> and P-wave attenuation <bold>(D)</bold> vs. frequency curves at different hydrate contents in mode B.</p>
</caption>
<graphic xlink:href="feart-10-831405-g003.tif"/>
</fig>
<p>
<xref ref-type="fig" rid="F4">Figure&#x20;4</xref> shows the variation of P-wave velocity and attenuation with frequency in model C. The effects on velocity and dispersion were roughly the same for cemented and particle-contact hydrates. However, the effect of the cementation mode hydrate on P-wave velocity and P-wave attenuation was greater. When hydrate saturation was the same, the increase in velocity was greater for the cemented mode hydrates than for particle-contact mode hydrates. The decrease in attenuation was greater for cemented mode hydrates than for particle-contact mode hydrates.</p>
<fig id="F4" position="float">
<label>FIGURE 4</label>
<caption>
<p>P-wave velocity <bold>(A-C)</bold> and P-wave attenuation <bold>(D)</bold> vs. frequency curves at different hydrate contents in mode C.</p>
</caption>
<graphic xlink:href="feart-10-831405-g004.tif"/>
</fig>
</sec>
<sec id="s3-2">
<title>Estimation of Hydrate Resources</title>
<p>The simulation experiment of the hydrate aggregation and dispersion process showed that the hydrate formed by free methane mainly occurred in sediment particles in the cemented mode. The hydrate particles formed by dissolved methane were relatively small and mainly occurred among the sediment particles in the suspension mode. The study area was located in the deep-water area of the continental slope. The analysis of seismic data and metallogenic conditions in the study area showed that the hydrate ore bodies in the study area were derived from dissolved methane.</p>
<p>The suspension mode hydrate model was also used to study saturation. Mode A was suitable for the study area. <xref ref-type="fig" rid="F5">Figure&#x20;5A</xref> shows the seismic profile of the research area. The wave impedance between the peak (black axis) and trough (red axis) with strong energy in the black dotted line box should be high, which was the target layer of the research area. The attenuation data were calculated by the inversion technique (<xref ref-type="fig" rid="F5">Figure&#x20;5B</xref>). The attenuation of the target layer showed a high value, which further showed that the target layer developed hydrate. The dominant frequency of the target layer in the study area was 35&#xa0;Hz. The hydrate saturation data volume was calculated using the relationship between hydrate attenuation and saturation in Mode A (<xref ref-type="fig" rid="F5">Figure&#x20;5C</xref>). The maximum value of the hydrate was 38%, and the average value was 28%. The area and the effective thickness of the hydrate in the target layer were determined. The formula for calculating hydrate resources is as follows:<disp-formula id="e23">
<mml:math id="m90">
<mml:mrow>
<mml:mi>Q</mml:mi>
<mml:mo>&#x3d;</mml:mo>
<mml:mi>&#x3d5;</mml:mi>
<mml:mo>&#x22c5;</mml:mo>
<mml:msub>
<mml:mi>S</mml:mi>
<mml:mi>h</mml:mi>
</mml:msub>
<mml:mo>&#x22c5;</mml:mo>
<mml:mi>f</mml:mi>
<mml:mo>&#x22c5;</mml:mo>
<mml:mi>A</mml:mi>
<mml:mo>&#x22c5;</mml:mo>
<mml:mi>T</mml:mi>
<mml:mo>,</mml:mo>
</mml:mrow>
</mml:math>
<label>(23)</label>
</disp-formula>where <inline-formula id="inf68">
<mml:math id="m91">
<mml:mi>&#x3d5;</mml:mi>
</mml:math>
</inline-formula> is the porosity, <inline-formula id="inf69">
<mml:math id="m92">
<mml:mrow>
<mml:msub>
<mml:mi>S</mml:mi>
<mml:mi>h</mml:mi>
</mml:msub>
</mml:mrow>
</mml:math>
</inline-formula> is the hydrate saturation, <inline-formula id="inf70">
<mml:math id="m93">
<mml:mi>f</mml:mi>
</mml:math>
</inline-formula> is the volume coefficient, <inline-formula id="inf71">
<mml:math id="m94">
<mml:mi>A</mml:mi>
</mml:math>
</inline-formula> is the area, and <inline-formula id="inf72">
<mml:math id="m95">
<mml:mi>T</mml:mi>
</mml:math>
</inline-formula> is the thickness.</p>
<fig id="F5" position="float">
<label>FIGURE 5</label>
<caption>
<p>Seismic <bold>(A)</bold>, attenuation <bold>(B)</bold>, and hydrate saturation <bold>(C)</bold> profiles of the study area. The white dotted line is the base of the gas hydrate stability zone (BGHSZ), above which hydrates usually develop. The black dotted line box is the boundary of the target layer. The target layer is between the peak (black axis) and trough (red axis) with strong energy in the black dotted line box.</p>
</caption>
<graphic xlink:href="feart-10-831405-g005.tif"/>
</fig>
<p>According to the adjacent area data, the porosity of the target layer was 0.4. The target layer area was 1.96&#x2a;107&#xa0;m<sup>2</sup> square meters. The average thickness of the target layer was 14&#xa0;m. The volume factor was 164; that is, one volume of hydrate released 164 volumes of methane gas. Based on this estimation, the hydrate resources in the study area were 5.05&#x2a;10<sup>9</sup>&#xa0;m<sup>3</sup>.</p>
</sec>
</sec>
<sec sec-type="discussion" id="s4">
<title>Discussion</title>
<p>In this study, three hydrate models were developed based on the patchy-saturation theory applicable at the mesoscale (<xref ref-type="bibr" rid="B29">White, 1975</xref>), and the relationships between hydrate saturation and dispersion and attenuation were obtained for different models. Furthermore, hydrate saturation and resource calculation in the study area were completed using attenuation inversion data. Three hydrate models were developed to assess the hydrate dispersion and attenuation characteristics under the patchy-saturation theory. Finally, hydrate saturation and resource estimates for the study area were presented.</p>
<p>The patchy-saturation model discusses attenuation due to the inhomogenous distribution of fluids within the pore space. Suspension mode hydrates in the sediment layer are in a flowing state and have a nonuniform distribution. For this reason, suspension mode hydrates are used instead of fluids in the patchy-saturation model. The three hydrate models developed for the first time in this study represent 1) the suspension mode, 2) coexistence of the suspension mode and particle-contact mode, and 3) coexistence of the suspension mode and cementation mode. The suspension-mode hydrate was distributed in the inner sphere, while the particle-contact and cementation-mode hydrates were uniformly distributed as part of the skeleton in both the inner sphere and the outer spherical shell. The skeleton properties were similar in both regions. The purpose of the three models was to clarify the effects on dispersion and attenuation caused by the suspension mode hydrate as a fluid and the particle-contact and cemented mode hydrates as a skeleton, respectively.</p>
<p>The results of our study support the view that the relationship between attenuation and hydrate saturation is more complex than single positive or negative correlations. Hydrate attenuation characteristics in the sediment layer depended on the hydrate reservoir state. P-wave attenuation increased with saturation when the hydrate reservoir was in the suspension mode because as hydrate saturation increased in the suspension mode, the nonequilibrium pore pressure between different fluid zones increased, causing an increase in pore fluid flow velocity, which in turn led to an increase in seismic attenuation. Conversely, P-wave attenuation decreased with saturation when the hydrate reservoir state in the sediment layer was in both particle-contact and cemented modes because the particle-contact and cemented-mode hydrates increased the cementation of the sediment layer, leading to an increase in its strength, which in turn led to a decrease in seismic attenuation. The cementation mode had a greater effect on attenuation than the particle-contact mode because increases in skeleton bulk modulus, shear modulus, and strength were greater for the cemented mode than for the particle-contact mode hydrates when hydrate saturation is the&#x20;same.</p>
<p>Hydrates formed from dissolved methane are small and mainly suspended between the sediment particles. The analysis of seismic data and metallogenic conditions in the study area indicated that the hydrate in the study area originated from dissolved methane. Therefore, the suspension mode hydrate model (Model A) was used for the saturation study. An inversion of the study area was carried out to obtain attenuation data, and the model A relationship was used to calculate the hydrate saturation data body in the study area, which in turn led to the calculation of study area resources. The attenuation theory was chosen to predict hydrate saturation because it had the following advantages. First, attenuation data equivalent to seismic attributes were derived from seismic data, and the process of obtaining them was uninterrupted and reliable. Second, the method was less dependent on well data than the velocity method and did not require well data to be calibrated to obtain hydrate saturation. Third, the patchy-saturation theory used in this study was applicable to the exploration frequency domain and could solve practical problems in the study area. Finally, the method utilized was an effective solution for the currently available data in the study area and may provide insights into hydrate quantification in other similar&#x20;areas.</p>
<p>This study used only seismic data and metallogenic conditions, combined with data from neighboring areas, to determine the hydrate reservoir model as a suspension model. There was no logging data in the study area to determine the specific hydrate storage state. It is also unlikely that there is a single model for the hydrate reservoir in the sediment layer. Therefore, there is insufficient evidence for the suspension model, and further drilling is required to confirm it. When the hydrate reservoir state in a sedimentary formation follows Model B or Model C, or when all three reservoir modes coexist, it is not possible to accurately calculate the hydrate saturation profile from the attenuation profile using the relational equation. This is because the suspension model hydrate increases the attenuation, and particle-contact and cementation mode hydrate saturation decreases the attenuation, making it impossible to calculate hydrate directly from the attenuation profile when the respective content is unknown.</p>
<p>The next step in this line of research is calculating hydrate saturation when the hydrate state follows either model B or model C. The core of this is to determine the respective contents of hydrate in the sediment layer for the suspension, particle-contact, and cementation models.</p>
</sec>
<sec sec-type="conclusion" id="s5">
<title>Conclusion</title>
<p>In this study, the theoretical relationships between the dispersion and attenuation of the three models and the hydrate saturation were derived from a mesoscale perspective for the first time. Moreover, the influence of hydrates with different occurrence modes on dispersion and attenuation was clarified. When the hydrate occurrence in the sedimentary layer was in the suspension mode, the P-wave attenuation increased with saturation. When the hydrate occurrence in the sedimentary layer was particle-contact and cementation mode, the P-wave attenuation decreased with saturation. The particle-contact mode and the cementation mode hydrate moved the attenuation peak of the P-wave to the right. The degree of influence of the cementation mode on attenuation was greater than that of the particle-contact mode. The conclusions obtained in this study are applicable to the frequency range of seismic exploration, thus solving the problems of hydrate saturation prediction and resource estimation in the study area. When the hydrate occurrence in the formation follows model B or C, or the three occurrence modes coexist, it is still impossible to accurately calculate hydrate saturation based on attenuation, and further research is needed.</p>
</sec>
</body>
<back>
<sec id="s6">
<title>Data Availability Statement</title>
<p>The original contributions presented in the study are included in the article/Supplementary Material; further inquiries can be directed to the corresponding author.</p>
</sec>
<sec id="s7">
<title>Author Contributions</title>
<p>PL: modeling and writing. HH: communication and guidance. SM: translation and suggestion. LH: guidance. ZT: suggestion and verification. YS: suggestion and verification. All authors contributed to the article and approved the submitted version.</p>
</sec>
<sec id="s8">
<title>Funding</title>
<p>The authors were grateful to the support of the Natural Science Foundation of China (No. 41974124).</p>
</sec>
<sec sec-type="COI-statement" id="s9">
<title>Conflict of Interest</title>
<p>Author PL was employed by the company PetroChina.</p>
<p>The remaining authors declare that the research was conducted in the absence of any commercial or financial relationships that could be construed as a potential conflict of interest.</p>
</sec>
<sec sec-type="disclaimer" id="s10">
<title>Publisher&#x2019;s Note</title>
<p>All claims expressed in this article are solely those of the authors and do not necessarily represent those of their affiliated organizations, or those of the publisher, the editors, and the reviewers. Any product that may be evaluated in this article, or claim that may be made by its manufacturer, is not guaranteed or endorsed by the publisher.</p>
</sec>
<ack>
<p>The authors would like to express their gratitude to EditSprings (<ext-link ext-link-type="uri" xlink:href="https://www.editsprings.cn/">https://www.editsprings.cn/</ext-link>) for the expert linguistic services provided.</p>
</ack>
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