Abstract
Transient compressible gas flow through porous media plays a pivotal role in energy production and storage. Understanding gas flow dynamics is crucial for interpreting subsurface reservoir complexities. Underground formations hold significant potential for natural gas production, or gas storage including CO2 and hydrogen. Traditional steady-state core analysis methods face limitations in tight formations, necessitating the development and utilisation of transient methods to study flow behaviours. This paper introduces two analytical solutions addressing transient highly compressible gas flow through porous media. By incorporating quadratic pressure gradient and variable compressibility terms into the governing equations, more realistic models are proposed, applicable across a wide spectrum of high-pressure gas flow scenarios. These terms transform the linear diffusivity equation into a nonlinear Partial Differential Equation (PDE), which is solved analytically. The research evaluates the developed models, which are required for permeability quantifications. Comparative analysis against more simplified available models reveals discrepancies between the two, particularly in the high-pressure range, demonstrating the unreliability of available models for accurate representation of transient compressible gas flows.
1 Introduction
In the past few decades, the rising global energy demand has driven the exploration and extraction of fossil fuels to more challenging and complex environments (). The drilling of production wells is now more frequent in geologically intricate high-pressure and high-temperature formations. This could be a more challenging process where the operating fluid in the subsurface porous media contains a compressible gas (; ). The presence of a compressible gas under high pressure (or high-pressure gradient) can be problematic under certain circumstances (; ).
Transient compressible gas flow through porous media has various applications in both energy production and storage sectors. Accurate evaluation of gas flow is a critical step in achieving a deep understanding of subsurface reservoirs. Tight and ultra-tight reservoirs have received significant attention during the past decades due to their considerable potential for natural gas production and gas storage (CO2, hydrogen, and air) (; ; ; ; ; ; ). Conventional steady-state core analysis cannot be used for tight cores for samples with <10 mD permeability because of the long time required to reach steady-state. Instead, various transient methods have been proposed to study flow in such rocks.
Transient gas-flow behaviour is also relevant to subsurface CO2 storage, where CO2 is injected into porous formations under high-pressure conditions (Zheng et al., 2025). In particular, the nonlinear pressure response and pressure-dependent compressibility considered in this study can influence the interpretation of transient injection and pressure behaviour in low-permeability storage formations. The generalised analytical framework presented here can therefore be extended to CO2 storage systems beyond conventional hydrocarbon reservoirs.
In recent years, the Pressure Pulse Decay (PPD) approach has become a widely used transient method for the permeability measurement of low-permeability samples. This method is initially presented by (). The experimental setup of this method is straightforward. This method comprises an upstream tank connected to a downstream tank through a core sample in the middle. A pressure pulse is applied at the upstream tank, and the gas moves from the high-pressure tank (i.e., upstream tank) to the low-pressure one (i.e., downstream tank). The schematic of the PPD setup is presented in Figure 1. At the initial condition, the rock sample is in the equilibrium condition. Opening the upstream valve leads to gas flow through the core. The test ends as soon as the pressure difference between the upstream and downstream containers becomes negligible. Analysis of the differential pressure between those two tanks determines the permeability of the sample.
FIGURE 1
After pressure data of a PPD test are recorded, they need to be analysed to obtain permeability. There are analytically based methods for such analysis, albeit with simplifying assumptions (
Several authors tried to increase the accuracy and reliability of the Brace method by reducing the number of simplifying assumptions mentioned above (
Although the definition of pseudo-pressure and pseudo-time consider the compressibility effect, all the mentioned references only consider the linear pressure gradient term within the diffusivity equation (referred to as the linear form of diffusivity equation). In other words, they ignore the quadratic pressure gradient term in the diffusivity equation (referred to as the non-linear form of the diffusivity equation) (
The importance of the quadratic pressure gradient in dual-porosity porous media is highlighted by (
As mentioned above, appropriate data analysis methods for PPD experiments with limited simplifying assumptions are required to achieve the best possible outcome from recorded experimental data. It has been highlighted that several publications have been focused on the importance of quadratic pressure gradient effect that exists in PPD experiments.
Another aspect of compressible flow modelling through porous media, which has received significant attention in recent years, is related to Forchheimer and inertial effects. Generally, inertia force implies the force due to the fluid’s momentum and it is added to the momentum equation by the term , which is a generalised term that encompasses the broader effects of fluid motion. The Forchheimer equation, on the other hand, only considers the additional resistance to fluid motion in porous media beyond the prediction of Darcy’s law (
To the best of the authors’ knowledge, an exact analytical solution for highly compressible flow through porous media considering the quadratic pressure gradient term for PPD setup, with time-dependent boundary conditions, has not yet been developed.
This study presents two analytical solutions to the transient nonlinear diffusivity equation: constant compressibility and variable compressibility. The solutions proposed in this research apply to both conventional linear (without quadratic pressure gradients) and nonlinear scenarios (with quadratic pressure gradients). These derivations are analytical solutions in the time domain, with no numerical assumptions during their derivations. The present paper constitutes Part I of this research and focuses on the analytical derivation and theoretical assessment of these solutions, while Part II presents complementary experimental investigations and core-scale numerical simulations to further evaluate and consolidate the findings of the present analytical study (
2 Problem statement and analytical derivations
The general formulation of one-dimensional diffusivity equation for compressible gas flow is derived by combining the continuity equation and Darcy’s law. It is known that combining these equations produce a nonlinear PDE. In the literature, the quadratic pressure gradient term is usually ignored for simplicity. However, as mentioned in the introduction section, this simplifying assumption is not valid for high-velocity compressible gas flow during PPD experiments. This section aims to derive the governing equations without neglecting the quadratic pressure gradient term, which produce a nonlinear PDE.
Figure 1 presented a conceptual schematic view of the laboratory equipment, where the core sample is flooded with the operating fluid (i.e., gas) from the upstream to the downstream container. Similar to other relevant studies on the public domain, the flow paths are often assumed to be straight lines, making Cartesian coordinates the best option to represent flow behaviours. Therefore, continuity and Darcy equations in Cartesian coordinates are provided as follows:
The general 1D continuity equation in is (
The general form of Darcy’s law for 1D flow is:
The combination of these two equations and the definition of compressibility produce the diffusivity equation as follows:
Where P is pressure, is velocity, is density, is porosity, is permeability, and are fluid and total compressibility, respectively. As mentioned in the introduction section, this study presents two different solutions for the constant compressibility and variable compressibility cases in Section 2.1, and Section 2.2, respectively.
2.1 Nonlinear diffusivity equation considering quadratic pressure gradient and constant compressibility
For boundary conditions, the PPD setup is similar to the standard experiment mentioned in the literature (
The corresponding initial and boundary conditions are:
Where is sample (core) pore volume and / are upstream/downstream volumes. These time-dependent boundary conditions specify the rate at which gas flows due to pressure gradient () through the cross-sectional area. Equations 3–7 can be subjected to a variable change to replace P(x,t) with a new dimensionless parameter as follows:
Applying this transformation yields:
The new diffusivity equation using this transformation is:
The modified boundary and initial conditions are:
In this format, is a dimensionless parameter. The following additional dimensionless parameters are employed to convert the diffusivity equation (Equation 10) and its associated boundary conditions (Equations 11 and 12a) into the dimensionless format.
Then:
This nonlinear PDE, Equation 14, can be transformed into a linear one using the following expression:
A new parameter ' ' is defined as:to give
Using the above transformation (Equation 19), one can convert the nonlinear PDE (Equation 14) into the following linear PDE by inserting Equation 19 into Equation 14:
The boundary and initial conditions are re-written as:
Now, the linearised PDE and its boundary and initial conditions are solved. This equation can be solved by the Laplace transform. Applying the Laplace transform (
Introducing two new parameters:
Then the new boundary conditions in the Laplace domain are:
In summary, using the Laplace transform method, a PDE at the time domain is converted into an ODE at the Laplace domain. The solution to this ODE is:
There are two unknown parameters (b and d) in Equation 26, and there are two boundary conditions. The solution of Equation 26 using these two boundary conditions (Equation 25) is:
Assuming and :
Equation 28 is the final solution at the Laplace domain, and a Laplace inverse transformation is needed to shift back from the Laplace domain to the time domain.
In the above equation, the Laplace parameter () is assumed to be complex, and the constant parameter (c) is a real positive that is large enough to cover all the singularities of the function .
To calculate the above integral, Cauchy’s residue theorem (
Where are the poles and are the associated residues. Now poles of the integrand should be examined. There is a simple pole at s = 0. The remaining poles can be determined using Equation 27:
It seems a complicated equation, but with a deeper look, one can conclude that the only solution to this equation occurs if is imaginary:
Where is a real number. Then the following equation can be derived:
Then:
The above equation has an infinite number of roots; therefore, the integrand has unlimited poles in addition to the poles at the origin. First, the residue of the pole at s = 0 should be determined:
Now, the residues of the remaining poles should be determined. Let’s assume:
It is known that is non-zero; therefore, all other remaining poles are simple poles, and their residue can be calculated by:
Then:
Now, all the residues are calculated, and one can compute the Laplace inverse transform using Equation 30:
At this stage, the equation can be transformed back to its original parameters form:
Introducing three new parameters to compress the final solution:
The final solution is obtained as:
In this form, the final pressure decay () is presented as a function of dimensionless time (), θ, , , and .
2.2 Nonlinear diffusivity equation considering quadratic pressure gradient and variable compressibility
In the previous section, it was assumed that compressibility was constant. This section aims to eliminate that simplifying assumption and make the solution more realistic, which could be applied to a broad range of applications with varying compressibility. Assuming gas compressibility is much higher than rock compressibility (), and the gas is an ideal gas (), Equation 3 would be converted to the following equation:
With the initial and boundary conditions:
To improve the readability of the article, detailed derivation has been provided in Supplementary Appendix A. Following the procedure mentioned in the appendix yields:
Where:
The results of the two different solutions presented in this and previous sections are compared and discussed in the next section.
3 Result and discussion
This study presents two analytical solutions to the generalised diffusivity equation for transient compressible flow through one-dimensional porous media, considering quadratic pressure term and with constant and variable compressibility assumptions. Since these two analytical solutions consist of an infinite series, two sets of MATLAB codes have been developed for the post-processing and data analysis. Results are validated against conventional diffusivity equation solution methods to determine the deviations between different models. In particular and for the verification section, the results are also compared with those of the (
It must be noted that complementary experimental and numerical investigations that further verify and consolidate the findings of this research are available in a separate publication, as Part 2 of this research (
The exciting feature of the presented solution is that it depends on the initial absolute pressure of the containers and the pressure difference value. All previously presented analytical solutions are independent of initial absolute pressure conditions. It should be noted that the solutions provided here apply to continuum flows, where slip flows and net stress effects are negligible.
3.1 Solution 1: constant compressibility
In this section, the results of a parametric study to observe the impacts of different input parameters on the flow behaviour for the first solution (presented in Section 2.1) is discussed. This solution requires three input parameters: 1) gas compressibility, 2) initial upstream and downstream pressure, and 3) pore/container volume ratios. The results of different cases with different operational pressure conditions all with constant gas compressibility have been plotted in Figures 2–4 to investigate the importance of operating pressure on several parameters, including the pressure decay (), logarithm of pressure decay (), and the slope of logarithmic pressure decay versus time (i.e., α), used for analysing the PPD results. It has been assumed that both containers are identical and ten times bigger than core pore volume; therefore, . The definition of Lambda is presented in Equation 24. In this section, the arithmetic average of upstream and downstream containers pressure has been used to calculate the compressibility of an ideal gas expressed by .
FIGURE 2

Pressure decay versus dimensionless time for different initial pressure difference conditions.
FIGURE 3

Logarithm of pressure decay versus dimensionless time for different initial pressure difference conditions.
FIGURE 4

α (slope of logarithmic pressure decay versus pseudo time) versus dimensionless time for different initial pressure conditions.
Figure 2 presents pressure decay () versus dimensionless time (Equation 13). First, for a case with infinitesimal pressure difference (between upstream and downstream containers), the solution of this research is compared with that of the conventional Dicker and Smiths method. For this case, the quadratic pressure gradient term is negligible; therefore, the solution proposed here and that of the Dicker and Smits method should be similar, as demonstrated in this figure. These results confirm the accuracy of the developed generalised analytical solution producing the same results as those of the Dicker and Smits method. There is only a minor difference in the early times, caused by simplifying an infinite series to only the first parameter (
After this verification step, three more cases were considered with larger pressure difference values but the same average pressure value (to ensure that compressibility factor based on average pressure is constant). In this figure, the legend 3–1 refers to inlet and outlet pressure values of 3 and 1 bars, respectively. The same goes for other legends and the rest of this research. It can be observed that increasing the pressure difference leads to deviations from the first two plots, which demonstrates the impact of the initial pressure difference and the quadratic pressure term on the gas flow.
In the literature, the slope of logarithmic pressure decay () versus time/dimensionless time is used to determine the core sample properties (
As shown in Figure 4, Dicker and Smits method produces a constant α (slope of logarithmic pressure decay versus pseudo time) versus time which means the permeability is constant with time. The case generated for verification purposes of the proposed solution also generated the same trendline, which means that the analytical solution proposed here produces a constant permeability value for scenarios with infinitesimal pressure differences. However, a deviation from the flat line is observed for other cases, suggesting the permeability is not constant with time, and it converges to that flat line at later times when the pressure difference is diminished. There is not a huge difference between the 2.4–1.6 bar case and the flat line because the pressure difference between the two containers is small enough to neglect the quadratic pressure gradient term. On the contrary, for the 3–1 bar scenario, the pressure difference is comparatively high; therefore, the deviation from the flat line at the early time is considerable, and at later times (dimensionless time = 5), it converges to that of the flat line. Other investigators (e.g. (
As mentioned before, gas compressibility is an input parameter and should be defined accordingly. Figure 5 depicts α versus dimensionless time for 3–1 bar case with three different pressure values used to determine compressibility factor according to (). These cases are: 1) Arithmetic average of upstream and downstream pressure (i.e., (1 + 3)/2 = 2 bar) 2) Upstream pressure (i.e., 3 bar), 3) Downstream pressure (i.e., 1 bar). These three cases are compared with the Dicker and Smits method results, as shown in Figure 5. This figure shows that the α value varies significantly between cases with different compressibility values, especially at early times. This suggests that the magnitude of α strongly depends on the compressibility factor, especially at earlier times, when the pressure difference is considerably high. Figure 5 also highlights the importance of correctly estimating gas compressibility for PPD data analysis. In this solution and for simplification purposes, the compressibility factor is constant. However, the results of Figure 5 highlight the importance of accurate compressibility factor estimation.
FIGURE 5

α (slope of logarithmic pressure decay versus pseudo time) versus dimensionless time when gas compressibility factors are calculated at different pressure values. Initial pressure condition is 3–1 bar.
In the literature, it is common to apply core final equilibrium pressure (i.e., average core pressure) for further data analysis calculation (
FIGURE 6

α (slope of logarithmic pressure decay versus pseudo time) versus dimensionless time for different initial pressure conditions (High operating condition scenarios).
It can be concluded from Figure 6 that although the magnitude of the impact of compressibility factor reduces at higher pressure values, the impact of the quadratic pressure term is not negligible, i.e., the same early time deviation noted in Figure 5 is also observed here. These results suggest that ignoring this parameter leads to a considerable error, even at high operational pressure conditions, with several applications in various geological environments.
3.2 Solution 2: variable compressibility
The results of the constant compressibility analytical solution presented in Section 2.1 were discussed in the previous section. The conducted sensitivity study demonstrated the considerable impact of the compressibility factor on gas flow behaviour. As described before, Section 2.2 relaxed the constant compressibility assumption and presented a new analytical solution considering variable compressibility. Before showing the corresponding results of this solution, the difference between these two solutions should be highlighted. For Solution #1, dimensionless time () is used, while Solution #2 utilises the pseudo dimensionless time () to capture the compressibility effect. As explained before, the definition of pseudo-time is not physical, since it is a function of both time and space. Without an additional simplifying assumption, the results of those two solutions are not comparable in a 2D plot due to the physical nature of pseudo-time. However, if is substituted with a constant (e.g., average core pressure), the pseudo-time and dimensionless time are similar.
The exact average pore pressure within the core evolves throughout a pressure pulse decay (PPD) test and cannot be measured directly using conventional experimental setups, where only the upstream and downstream reservoir pressures are recorded. Consequently, the average core pressure is commonly approximated by assuming a linear pressure distribution between the two ends of the core, which leads to a constant average pressure equal to the arithmetic mean of the boundary pressures. This assumption is widely adopted in pseudo-pressure and pseudo-time formulations (
It should be noted that this does not mean the results of the first solution and those of the second one with the higher accuracy are similar. They have different simplifying assumptions with different derivations, and the second solution is more accurate.
Figure 7 depicts pressure decay for both solutions versus pseudo time at high operating pressure conditions. As expected, the higher the pressure difference, the higher the deviation from the Dicker and Smits method, which as mentioned before, is an analytical solution that ignores the quadratic term of diffusivity equation. Moreover, one can detect a considerable difference between Solution #1 (i.e., constant compressibility) and Solution #2 (i.e., variable compressibility) for the same operating pressure. It proves the importance of considering variable compressibility and the error arising from the constant gas compressibility assumption.
FIGURE 7

Pressure decay versus dimensionless/pseudo time for high operating pressure conditions: different variable and constant gas compressibility cases.
Figure 8 presents the slope of logarithmic pressure decay versus pseudo time (i.e., α) for the cases noted in Figure 7. As mentioned before, this parameter is used for further data analysis to obtain permeability. Figure 8 reveals a considerable gap between variable compressibility and constant compressibility models, leading to a substantial error during permeability calculation. For example, for 80–10 bar scenario, the predicted α from Solution #2 is ∼30% higher than the calculated one from Solution #1. This error could incorrectly be attributed to other physical phenomena (e.g., pressure-dependent permeability or sorption effect) for real experimental data if an unsuitable data analysis method is implemented.
FIGURE 8

α (slope of logarithmic pressure decay versus pseudo time) versus dimensionless/pseudo time for high operating pressure conditions: different variable and constant gas compressibility cases.
The results presented in Figures 7, 8 demonstrate that the compressibility effect at high operating pressure conditions plays a crucial role and significantly affects the flow behaviours. At this stage, its impact under low operating pressure conditions is examined. To this end, three low-pressure scenarios have been designed, and the results of both constant compressibility and variable compressibility methods have been compared.
Figure 9 depicts pressure decay versus pseudo time for those low operating pressure condition cases. Although the gap between different cases is smaller compared to those in Figure 7, it cannot be neglected. α versus pseudo time data is presented in Figure 10. It is noted that here the error arising from neglecting variable compressibility is around 15%, which is again lower than 30% noted in Figure 8 between the constant and variable compressibility cases. Thus, the reported percentage should be interpreted as the maximum deviation over the simulated transient response rather than as a single representative error.
FIGURE 9

Pressure decay versus dimensionless/pseudo time for low operating pressure conditions: different variable and constant gas compressibility cases.
FIGURE 10

α (slope of logarithmic pressure decay versus pseudo time) versus dimensionless/pseudo time for low operating pressure conditions: different variable and constant gas compressibility cases.
It should be noted that there are several complex physical behaviours associated with the dynamics of gas flow, but these results highlight the impacts of variable compressibility that should not be neglected to avoid any potential misinterpretations.
4 Conclusion
This research presented two analytical solutions to transient highly compressible gas flow through porous media. Quadratic pressure gradient term and variable compressibility terms were considered in the governing equations to propose more realistic solutions that apply to a broad range of cases dealing with high-pressure gas flows. These two terms convert the linear diffusivity equation into a nonlinear Partial Differential Equation (PDE). This nonlinear PDE was solved analytically, and an analytical solution in the time domain was presented.
The results of the developed models were used to determine the slope of logarithmic pressure decay versus time, which is required for permeability quantifications. Compared to prior simplified models, an error in the range of 30% for very high-pressure scenarios (i.e., 80–10 bar) was detected. In addition, neglecting quadratic pressure gradient term and variable compressibility for lower-pressure cases (e.g., 3–1 bar) caused around 15% error, proving those nonlinear terms cannot be ignored for transient compressible gas flows under higher pressure differences.
The developed equations and presented results improve our understanding of transient highly compressible gas flow through porous media. However, additional work is required to consolidate these findings. Several designed PPD experiments have been performed in our laboratory to investigate the reliability of the presented solutions. To avoid having a lengthy paper, the results of these experiments are included in a separate publication (i.e., Part 2 of this research). In addition, Part 2 will present some core-scale numerical simulations, which are complementary to these analytical and experimental investigations.
Statements
Data availability statement
The raw data supporting the conclusions of this article will be made available by the authors, without undue reservation.
Author contributions
AN: Validation, Investigation, Methodology, Conceptualization, Writing – review and editing, Visualization, Writing – original draft, Data curation. MJ: Funding acquisition, Project administration, Supervision, Writing – review and editing. HD: Data curation, Resources, Validation, Visualization, Writing – review and editing.
Funding
The author(s) declared that financial support was received for this work and/or its publication. This work was partially supported by the Natural Environment Research Council (NERC) under grant number NE/R018022/1.
Acknowledgments
All authors confirm that this paper is a transparent and honest account of the reported research. This study is related to a previous publication by the same authors titled “High-velocity compressible gas flow modelling through porous media considering the quadratic pressure gradient: Part 2. experimental investigations and numerical analysis.” However, both papers were prepared as standalone and independent contributions within the same broader research area. The other study focused on experimental investigations and numerical simulations, whereas the current submission focuses on analytical derivations and the fundamental theoretical aspects of the problem. While the two studies are complementary in scope, there is no overlap in the reported analyses or results, and each paper can be understood independently without reference to the other.
Conflict of interest
The author(s) declared that this work was conducted in the absence of any commercial or financial relationships that could be construed as a potential conflict of interest.
Generative AI statement
The author(s) declared that generative AI was not used in the creation of this manuscript.
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Supplementary material
The Supplementary Material for this article can be found online at: https://www.frontiersin.org/articles/10.3389/feart.2026.1859293/full#supplementary-material
Glossary
Permeability
Velocity
Pressure
Time
Container volume
Total compressibility
Length
Cross sectional area
Fluid compressibility
Temperature
- h
Variable change parameter
- w
Variable change parameter
Density
Slope of logarithmic pressure decay versus time
Viscosity
First root of the equations
Porosity
Ratio of upstream/downstream volume to pore volume
- PDE
Partial Differential Equation
- PPD
Pressure Pulse Decay
- GCR
Gas-Condensate Recovery
- 1D
One dimensional
- 2D
Two dimensional
Dimensionless
Upstream container
Downstream container
- 1
Upstream container
- 2
Downstream container
- s
Sample (core)
Pseudo dimensionless (Time)
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Summary
Keywords
analytical derivation, compressible gas flow, gas dynamic, nonlinear flow behavior, porous media
Citation
Nabizadeh A, Jamiolahmady M and Doryani H (2026) High-velocity compressible gas flow modelling through porous media considering the quadratic pressure gradient: a generalised analytical solution. Front. Earth Sci. 14:1859293. doi: 10.3389/feart.2026.1859293
Received
18 April 2026
Revised
30 August 2026
Accepted
04 September 2026
Published
08 October 2026
Volume
14 - 2026
Edited by
Mehrdad Vasheghani Farahani, The University of Manchester, United Kingdom
Reviewed by
Amirsaman Rezaeyan, ETH Zürich, Switzerland
Tongke Zhou, The University of Manchester, United Kingdom
Puyan Bakhshi, Helmholtz Association of German Research Centres (HZ), Germany
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© 2026 Nabizadeh, Jamiolahmady and Doryani.
This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.
*Correspondence: Mahmoud Jamiolahmady, m.jamiolahmady@hw.ac.uk
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