Abstract
Introduction:
The Bikou area, positioned at the junction of the Qinling orogenic belt and the Yangtze Plate, is critical for understanding both continental orogenesis and regional mineralization in China.
Methods:
To better understand the magmatic and metallogenic processes in this highly active region, we investigated the petrogenesis and tectonic setting of exposed diabase veins using petrological, geochronological, and geochemical methods.
Results:
Zircon U-Pb dating constrains the emplacement of these sub-alkaline tholeiitic diabases to the Late Triassic (201–206 Ma). The rocks display moderate SiO2 (44.57–49.58 wt%) and MgO (3.98–7.46 wt%, Mg# = 56–63), with flat REE patterns ((La/Yb)N = 1.93–2.39) and weak positive Eu anomalies (δEu = 0.85–1.21). Trace element geochemistry reveals Nb-Ta-Pb depletion and Ba-K enrichment, while Sr-Nd isotopes show limited variation (87Sr/86Srᵢ = 0.706627–0.707311; εNd(t) = −1.16 to 0.16). Although the samples retain some arc-related geochemical fingerprints, regional tectonic analysis indicates a post-collisional origin.
Discussion:
We conclude that the Late Triassic diabase magmas were derived from a lithospheric mantle source contaminated by earlier subduction components. Their emplacement was ultimately triggered by lithospheric extension and asthenospheric upwelling in the South Qinling belt. This study refines the current model for the Mesozoic tectonic evolution of the Bikou area.
1 Introduction
The Qinling orogenic belt preserves a long and complex record of geological evolution between the North China Plate and the Yangtze Plate. Having experienced multiple stages of tectonic, magmatic, and thermal events and orogenic processes, it is considered a typical composite orogenic belt (Zhang et al., 2001; Wang Z. Q. et al., 2009a). As an important part of this belt, the South Qinling structural belt is crucial for understanding the regional tectonic evolution. Current models of the tectonic evolution of the South Qinling still differ significantly. For example, some studies suggest that this area underwent rifting in the Devonian, forming a limited ocean basin that subsequently subducted northward and closed in the Triassic (Zhang et al., 2003; Meng and Zhang, 1999; ; ; ). Other scholars propose that an ancient ocean existed in this area during the Precambrian, with southward subduction occurring in the Late Paleozoic and ending in the Triassic (Wang et al., 1999; Wang T. et al., 2009). Nevertheless, various viewpoints generally agree that the orogenic belt entered the collisional stage from the Late Triassic onward, accompanied by a series of tectonic activities and magmatic events (Wang et al., 2021). Meanwhile, mineralization also occurred through different stages following continental collision, forming various regional mineralization types during each orogenic evolution period, thus resulting in a distinctive assemblage of mineral deposits. Recent work on the Wuguan Complex has provided new insights into the Paleozoic evolution of the Qinling orogenic belt (Wang et al., 2025), and the Huichizi granite study has further documented the early Paleozoic evolution of North Qinling ().
Mafic dikes are often regarded as effective indicators for determining the timing of major tectonic transformations and thus hold special continental tectonic significance (). Therefore, investigating the age, type, and petrogenesis of mafic magmatic rocks formed during orogenic processes is of great importance for understanding the tectonic evolution of orogenic belts and their metallogenic background (). The Bikou area, located in the southern part of the South Qinling orogenic belt, represents a key junction where the Qinling orogenic belt, the Songpan-Ganzi orogenic belt, and the Yangtze Plate converge. It is also an important component of the central orogenic system of the Chinese mainland (Zhang G. W. et al., 2001). Meanwhile, this area is also a famous “Golden Triangle” region in Shaanxi Province, hosting a series of small-to medium-sized gold and polymetallic deposits, such as Jianchaling, Dongbagou, Huafanggou, Lijiagou, and Tongchangwan (Zhang et al., 2004; Zhou et al., 2011a; Zhou et al., 2011b; ; ), showing considerable exploration potential. Thus, clarifying the regional tectonic evolution process is not only of theoretical significance but also provides a basis for subsequent exploration planning. Although mafic dikes are well developed in these ore-concentrated areas, current research on their petrogeochemical characteristics and petrogenesis remains relatively insufficient. Conducting studies on these mafic dikes can help to better understand the formation ages and tectonic settings of regional rock units, and provide important clues for reconstructing the ancient tectonic framework of the South Qinling orogenic belt. In addition, the petrogenesis of mafic complexes in the Qinling Orogenic Belt has recently been investigated (Zhu et al., 2025).
This study takes the diabase veins developed in the Bikou area as the research object and systematically conducts petrological observations, geochemical analysis, Sr-Nd isotope analysis, and LA-ICP-MS zircon U-Pb dating. Combined with existing regional research results, this paper discusses the petrogenesis and geodynamic background of these mafic dikes, providing new evidence for studying the tectonic evolution of the South Qinling orogenic belt.
2 Methods
Samples were crushed, washed, and enriched by electromagnetic separation at Langfang City Chengxin Geological Service Co., Ltd. Zircons were then manually selected under a microscope. Subsequently, target mounts were prepared, and cathodoluminescence (CL) imaging was performed by Nanjing Hongchuang Company. Only zircon grains with intact crystal shapes and free of cracks or inclusions were selected for analysis.
U–Pb dating was completed at the Institute of Mineral Resources, Chinese Academy of Geological Sciences, using laser ablation MC-ICP-MS (Finnigan Neptune MC-ICP-MS coupled with a Newwave UP 213 laser system). During analysis, the laser spot size was 35 μm and the repetition rate was 10 Hz. GJ-1 was used as the external standard, and Si as the internal standard. One standard sample was analyzed for every ten sample points. Data processing was performed using ICPMSDataCal, and concordia diagrams were generated using Isoplot 3.0 (Ludwig, 2003). Detailed experimental procedures can be found in .
Whole-rock major and trace element analyses were completed at Beijing Yandu Zhongshi Testing Technology Co., Ltd. Samples were crushed, washed, dried, and ground to 200 mesh. For major element analysis, the powdered samples were mixed with Li2B4O7 as a flux in a 1:8 ratio and then heated in a fusion machine to 1150 °C to form homogeneous glass beads. The glass beads were analyzed using XRF (Zetium, PANalytical) with an analytical error of less than 1%. Trace elements were determined by ICP-MS (M90, Analytik Jena) following high-pressure acid digestion, with the standard reference material GSR-2 used for quality control. Typical analytical errors were <5%, and errors for volatile and very low-abundance elements were <10%.
Sr–Nd isotope analyses were performed on a MAT 262 thermal ionization mass spectrometer at the Radioisotope Geochemistry Laboratory of the University of Science and Technology of China. Sr isotope ratios were mass-bias corrected using 86Sr/88Sr = 0.1194, and the measured value for the NIST 987 standard was 0.710250 ± 7. Nd isotope ratios were corrected using 143Nd/144Nd = 0.7219, and the measured value for the JMC standard was 0.51109 ± 3 (143Nd/144Nd). Based on the zircon U–Pb ages obtained for each gabbroic body, the initial Sr–Nd isotope ratios were calculated for each sample group.
3 Geological background
The Bikou area is one of the major tectonic–magmatic activity zones within the Qinling orogenic belt (Figure 1a). Its spatial distribution is controlled by the NE-trending Mengxian–Yangpingguan Fault and the NW-trending Mengxian–Liuyang Fault, and it generally exhibits a triangular, wedge-shaped geometry that opens to the west and converges to the east (Zhang et al., 1995). In an early study, Ye and Guan (1944) classified the exposed rocks in this area as the Bikou Group in a broad sense and assigned them a Carboniferous–Permian age. Subsequently, various scholars have reclassified and subdivided this group (Qin et al., 1992; Yan et al., 2002; Wang et al., 2019), dividing it, from bottom to top, into the Da’an Formation, the Bikou Group (in a narrow sense), and the Yangtianba Formation. These distinct structural units are generally separated by faults or ductile shear zones (Yang et al., 2017). Except for a relatively lower content of acidic volcanic rocks, the Da’an Formation exhibits bulk rock properties similar to those of the Bikou Group. Both units are mainly distributed between the Tongqianba–Fengxiangyuan Fault and the Mengxian–Yangpingguan Fault (Figure 1b) and consist of lava, volcanic breccia, and normal sedimentary rocks. The lava assemblage includes fine-grained basalt, porphyritic rocks (neither acidic nor basic), andesite, quartz porphyritic rocks (acidic), and rhyolite (Wang Z. Q. et al., 2009b). The Yangtianba Formation is mainly composed of feldspar sandstone and argillaceous slate interbedded with meta-volcanic rocks, characterized by abundant volcanic and feldspar fragments but few quartz fragments (Yan et al., 2004; Wang, 2013). It is generally distributed to the north of the Tongqianba-Fengxiangyuan Fault (Miao et al., 2019). The Carboniferous Nantuo Formation, Doushantuo Formation, and Dengying Formation consist of sandstone, siltstone, and dolomite, and are usually separated from the above rock units by faults or occur as lens-shaped bodies. The Silurian Maoxian Group, mainly composed of argillaceous slate, is primarily located to the southeast of the Mengxian-Yangpingguan Fault.
FIGURE 1
Regional tectonic structures are well developed in the area. In the northern part, NW–NWW-trending faults predominate, whereas the southern part is mainly characterized by NEE-trending faults. In addition, nearly N–S-trending fault clusters are superimposed on these structures (Xu et al., 2002). From south to north, the main regional faults include the Mengxian–Yangpingguan Fault, the Qingmucun-Guanshuyao Fault, the Yangba-Cangsheping Fault, and the Tongqianba-Fengxiangyuan Fault (Zhang et al., 2017). Faults with different orientations cut across each other, dividing the rock units into multiple blocks. Within each block, the strata are typically present as monoclines or overturned folds. Igneous rocks in the area are mainly mafic, including basalt, dioritic basalt, and dioritic tholeiite, which are mostly distributed as veins or plutons along the fault zones (Figure 1c). Additionally, a small amount of dark gray ultramafic rocks are sporadically exposed in the area (Figure 1c); they are limited in scale and most of them have undergone intense alteration.
The study area is located north of Dahan Town, Ningqiang County, Shaanxi Province, adjacent to the Mengxian–Yangpingguan Fault. This fault strikes nearly NEE and dips steeply toward the NNW. The main rock units exposed in the area include the Bikou Group, the Doushantuo Formation, and the Dengying Formation, with the latter two covering large areas. The Bikou Group consists mainly of basic igneous rocks and igneous sandstones. The Doushantuo Formation is primarily represented by its second and third members: the second member is composed of gray sericite siltstone and sericite-bearing siltstone, whereas the third member consists of gray-black carbonaceous siltstone and gray laminated micritic limestone. The Dengying Formation is most widely exposed in its second member, with the main rock types being medium-to thick-bedded to massive dolomite, gray massive gravelly dolomite, and dolomitic limestone. The most common magmatic rocks in the area are gabbros, which mainly intrude into the third member of the Doushantuo Formation and the second member of the Dengying Formation. Although individual gabbroic bodies are small in size, they are numerous and are often emplaced as apophyses or veins along structural fractures.
4 Rock and mineralogical characteristics
The samples collected in this study are diabase that intruded into the limestone of the Dengying Formation. In the field, a distinct embayment-shaped intrusive contact can be observed between the diabase and the surrounding rock. In some areas, the diabase is seen intruding along later faults, where the contact line is relatively straight. This diabase generally exhibits a massive structure (Figures 2a,b). Microscopic observation indicates that the rock is mainly composed of plagioclase and pyroxene, with secondary minerals including amphibole and biotite. The overall texture is typical of diabase. Plagioclase content ranges from approximately 45%–55%, mostly occurring as euhedral to subhedral laths, with polysynthetic twinning visible and sericite and kaolinite commonly developed (Figure 2c). Pyroxene accounts for about 35%–45%, mostly in subhedral to anhedral forms, typically filling the triangular interstices between plagioclase crystals (Figure 2d); most pyroxene grains have undergone chlorite alteration. The contents of amphibole and biotite are relatively low and are sparsely distributed. Under reflected light, irregular pyrite grains can be observed enclosed within plagioclase pores. A total of five diabase samples were collected. They are relatively fresh, come from different locations of the diabase veins, and can represent the primary characteristics of the original intrusive diabase veins.
FIGURE 2
5 Results
5.1 Zircon age
Zircons from the diabase are mostly colorless, transparent, short prismatic crystals with euhedral to subhedral morphologies. The grains are generally small, with most being less than 100 μm in length. Length-to-width ratios typically range from 1:1 to 2:1, and in some cases up to 3:1. Cathodoluminescence (CL) images show that most zircons exhibit oscillatory zoning (Figure 3a). A total of 13 zircons showing oscillatory zoning were selected for U-Pb isotope analysis, and the results are presented in Table 1 and Figure 3 (CL images and analyzed spots: Figure 3a; probability plot; Figure 3b; concordia diagram; Figure 3c).
FIGURE 3
TABLE 1
| Spot No. | ωB/ppm | Th/U | Ratio | Age/Ma | |||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| Th | U | 207Pb/206Pb | 2δ | 207Pb/235U | 2δ | 206Pb/238U | 2δ | 207Pb/206Pb | 2δ | 207Pb/235U | 2δ | 206Pb/238U | 2δ | ||
| 1 | 91 | 827 | 0.11 | 0.0625 | 0.0025 | 0.7102 | 0.0217 | 0.0810 | 0.0020 | 685 | 86 | 545 | 13 | 502 | 12 |
| 2 | 259 | 215 | 1.21 | 0.0652 | 0.0034 | 1.0259 | 0.0564 | 0.1125 | 0.0039 | 762 | 112 | 715 | 28 | 687 | 23 |
| 3 | 277 | 748 | 0.37 | 0.0557 | 0.0025 | 0.4129 | 0.0195 | 0.0529 | 0.0014 | 421 | 100 | 350 | 14 | 332 | 9 |
| 4 | 20 | 625 | 0.03 | 0.0543 | 0.0043 | 0.2431 | 0.0279 | 0.0317 | 0.0017 | 361 | 180 | 220 | 23 | 201 | 10 |
| 5 | 129 | 133 | 0.97 | 0.0726 | 0.0039 | 1.3318 | 0.0847 | 0.1309 | 0.0039 | 978 | 117 | 856 | 37 | 793 | 22 |
| 6 | 117 | 146 | 0.80 | 0.0682 | 0.0034 | 1.3467 | 0.0786 | 0.1411 | 0.0041 | 853 | 101 | 863 | 33 | 851 | 23 |
| 7 | 74 | 95 | 0.78 | 0.0760 | 0.0040 | 1.6734 | 0.0873 | 0.1580 | 0.0038 | 1,109 | 91 | 1,007 | 26 | 946 | 21 |
| 8 | 68 | 644 | 0.11 | 0.0552 | 0.0032 | 0.2918 | 0.0284 | 0.0378 | 0.0027 | 386 | 134 | 259 | 22 | 239 | 17 |
| 9 | 306 | 564 | 0.54 | 0.0541 | 0.0030 | 0.3533 | 0.0190 | 0.0470 | 0.0013 | 344 | 132 | 307 | 14 | 296 | 8 |
| 10 | 127 | 135 | 0.94 | 0.0642 | 0.0048 | 1.1979 | 0.0925 | 0.1338 | 0.0034 | 695 | 169 | 794 | 43 | 809 | 19 |
| 11 | 138 | 210 | 0.66 | 0.0767 | 0.0031 | 1.5317 | 0.0892 | 0.1432 | 0.0061 | 1,098 | 82 | 939 | 36 | 862 | 34 |
| 12 | 661 | 1,393 | 0.47 | 0.0556 | 0.0023 | 0.3311 | 0.0127 | 0.0427 | 0.0007 | 418 | 96 | 290 | 10 | 270 | 4 |
| 13 | 13 | 373 | 0.04 | 0.0545 | 0.0060 | 0.2447 | 0.0244 | 0.0324 | 0.0009 | 339 | 252 | 221 | 20 | 206 | 6 |
U-Pb isotopic analyses for zircon from diabase in Bikou area.
Among the 13 analyzed spots, the Th content ranges from 13 to 661 ppm, the U content ranges from 95 to 1,393 ppm, and the corresponding Th/U ratios are mostly >0.1, ranging from 0.11 to 1.21. Based on their magmatic oscillatory zoning, crystal morphology, and CL features, these zircons can be classified as typical magmatic zircons. The obtained ages are relatively dispersed, ranging from 239 to 946 Ma. In addition, two zircons with Th/U ratios <0.1 also display oscillatory zoning and yield ages of 201 Ma and 206 Ma. On the U-Pb concordia diagram (Figure 3c), the two youngest analyses plot near the concordia curve, indicating negligible Pb loss and supporting the reliability of the 201–206 Ma age as the crystallization age of the diabase.
5.2 Major elements of whole rocks
The major and trace element compositions of the diabase are presented in Table 2. The SiO2 contents of the samples range from 44.57 wt% to 49.58 wt%, MgO contents from 3.98 wt% to 7.46 wt% (Mg# = 56–63), TiO2 contents from 0.66 wt% to 1.09 wt%, and FeOt contents from 5.67 wt% to 7.89 wt%. The ranges of other major elements are as follows: Na2O = 1.37–4.41 wt%, K2O = 0.36–1.04 wt%, CaO = 10.92–13.51 wt%, Al2O3 = 15.72–18.58 wt%, and P2O5 = 0.08–0.25 wt%. Overall, the total alkali contents are relatively low (Na2O + K2O = 2.15–4.77 wt%). In the Zr/TiO2 × 0.0001 versus SiO2 diagram (Figure 4a), most samples still plot within the sub-alkaline series field, whereas in the AFM diagram (Figure 4b), most samples fall into the sub-alkaline tholeiitic basalt series field.
TABLE 2
| Component | SM76-6 | SM76-7 | SM76-8 | SM76-9 | SM76-10 |
|---|---|---|---|---|---|
| Major element (wt%) | |||||
| SiO2 | 44.57 | 45.14 | 45.88 | 49.58 | 45.10 |
| TiO2 | 0.66 | 0.73 | 0.72 | 1.09 | 0.64 |
| Al2O3 | 17.37 | 16.08 | 16.67 | 15.72 | 18.58 |
| TFe2O3 | 7.71 | 8.44 | 8.77 | 6.30 | 7.71 |
| MnO | 0.11 | 0.12 | 0.13 | 0.10 | 0.12 |
| MgO | 6.67 | 7.27 | 7.46 | 3.98 | 6.44 |
| CaO | 13.51 | 13.30 | 11.35 | 10.92 | 12.68 |
| Na2O | 1.37 | 1.54 | 2.16 | 4.41 | 1.58 |
| K2O | 0.78 | 0.67 | 0.72 | 0.36 | 1.04 |
| P2O5 | 0.08 | 0.08 | 0.08 | 0.25 | 0.08 |
| LOI | 6.54 | 5.95 | 6.03 | 7.25 | 5.36 |
| Total | 99.37 | 99.34 | 99.96 | 99.96 | 99.33 |
| FeOT | 6.94 | 7.59 | 7.89 | 5.67 | 6.94 |
| Mg# | 63 | 63 | 63 | 56 | 62 |
| FeOT/MgO | 0.96 | 0.97 | 0.99 | 1.31 | 1.01 |
| Trace element (ppm) | |||||
| Li | 13.61 | 11.92 | 13.61 | 11.81 | 10.74 |
| Sc | 53.11 | 58.30 | 55.29 | 23.56 | 48.46 |
| V | 278.81 | 310.48 | 304.05 | 169.07 | 277.97 |
| Ni | 66.39 | 75.57 | 65.23 | 26.35 | 62.84 |
| Co | 45.47 | 49.39 | 43.85 | 41.58 | 43.46 |
| Cu | 54.86 | 81.62 | 79.19 | 140.77 | 46.02 |
| Ga | 15.46 | 15.78 | 14.36 | 18.98 | 15.85 |
| Rb | 20.11 | 17.33 | 18.20 | 10.75 | 26.70 |
| Sr | 157.20 | 158.06 | 153.74 | 148.22 | 212.40 |
| Y | 15.20 | 17.08 | 14.86 | 41.86 | 14.78 |
| Zr | 44.82 | 50.86 | 44.83 | 135.89 | 45.70 |
| Nb | 1.41 | 1.69 | 1.47 | 5.47 | 1.41 |
| Cs | 0.29 | 0.26 | 0.27 | 0.19 | 0.44 |
| Ba | 165.39 | 254.77 | 211.68 | 124.96 | 176.82 |
| La | 3.43 | 3.80 | 3.94 | 11.72 | 3.77 |
| Ce | 7.46 | 8.20 | 8.26 | 27.32 | 7.80 |
| Pr | 1.16 | 1.25 | 1.21 | 3.53 | 1.17 |
| Nd | 5.24 | 5.70 | 5.40 | 15.99 | 5.26 |
| Sm | 1.53 | 1.64 | 1.58 | 4.42 | 1.54 |
| Eu | 0.63 | 0.68 | 0.61 | 1.41 | 0.68 |
| Gd | 1.99 | 2.09 | 1.99 | 5.77 | 1.94 |
| Tb | 0.35 | 0.37 | 0.35 | 1.01 | 0.35 |
| Dy | 2.09 | 2.22 | 2.06 | 5.75 | 2.03 |
| Ho | 0.47 | 0.50 | 0.46 | 1.28 | 0.46 |
| Er | 1.34 | 1.41 | 1.30 | 3.68 | 1.28 |
| Tm | 0.18 | 0.20 | 0.18 | 0.51 | 0.18 |
| Yb | 1.20 | 1.30 | 1.17 | 3.31 | 1.16 |
| Lu | 0.18 | 0.20 | 0.18 | 0.49 | 0.18 |
| Hf | 1.16 | 1.32 | 1.15 | 3.31 | 1.15 |
| Ta | 0.11 | 0.12 | 0.11 | 0.33 | 0.11 |
| Pb | 0.46 | 0.46 | 0.55 | 0.75 | 0.51 |
| Th | 0.44 | 0.51 | 0.43 | 1.72 | 0.45 |
| U | 0.08 | 0.17 | 0.13 | 0.33 | 0.09 |
| ∑REE | 27.25 | 29.55 | 28.70 | 86.20 | 27.80 |
| LREE | 19.45 | 21.28 | 21.00 | 64.39 | 20.23 |
| HREE | 7.80 | 8.27 | 7.70 | 21.80 | 7.57 |
| LREE/HREE | 2.49 | 2.57 | 2.73 | 2.95 | 2.67 |
| (La/Yb)N | 1.93 | 1.98 | 2.27 | 2.39 | 2.20 |
| (La/Sm)N | 1.41 | 1.46 | 1.57 | 1.67 | 1.54 |
| (Gd/Yb)N | 1.34 | 1.30 | 1.37 | 1.41 | 1.35 |
| δEu | 1.10 | 1.13 | 1.04 | 0.85 | 1.21 |
| δCe | 0.90 | 0.90 | 0.90 | 1.01 | 0.89 |
Major/% and trace element/ppm contents of diabase in Bikou area.
Mg# = MgO/(MgO + FeOT) for molecular ratio.
FIGURE 4
The total rare earth element contents (ΣREE) of the diabase samples are relatively low, ranging from 27.25 ppm to 86.20 ppm. The light-to-heavy REE ratio (LREE/HREE) ranges from 2.49 to 2.95 (Table 2). On the chondrite-normalized REE distribution diagram (Figure 5a), the samples generally exhibit a nearly flat pattern, with (La/Yb)N = 1.93–2.39 and δEu = 0.85–1.21. These values indicate weak fractionation between light and heavy REE and a weak positive Eu anomaly, suggesting that fractional crystallization during magma evolution was not significant. Overall, the REE distribution patterns of the samples are similar to those of island-arc tholeiitic basalts (Figure 5a). On the primitive mantle-normalized trace element spider diagram (Figure 5b), the samples show marked depletion in elements such as Nb, Ta, and Pb, and relative enrichment in Ba and K. This element association is also comparable to that of island-arc tholeiitic basalts.
FIGURE 5

Chondrite-normalized REE diagrams (a) and primitive mantle-normalized spider diagrams (b) of diabases in the Bikou area (Chondrite, primitive mantle are from Sun and McDonough, 1989).
5.3 Sr-Nd isotopes
The diabase formed at ca. 200 Ma has 87Rb/86Sr ratios ranging from 0.20986 to 0.37017 and 147Sm/144Nd ratios from 0.1671 to 0.1770 (Table 3). The initial Sr isotope ratios are relatively low, with (87Sr/86Sr)i ranging from 0.706627 to 0.707311, whereas εNd(t) values vary within a narrow range from −1.16 to 0.16. The two-stage Nd model ages (T2DM) range from 972 to 1,079 Ma.
TABLE 3
| Sample No. | Age (Ma) | Rb (ppm) | Sr (ppm) | 87Rb/ 86Sr | 87Sr/ 86Sr | 2σ | (87Sr/ 86Sr)i | Sm (ppm) | Nd (ppm) | 147Sm/ 144Nd | 143Nd/ 144Nd | 2σ | (143Nd/ 144Nd)i | εNd (t) | TDM (Ma) | TDM2 (Ma) |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| SM76-6 | 201 | 20 | 157 | 0.37017 | 0.708297 | 0.000011 | 0.707256 | 1.53 | 5.24 | 0.1765 | 0.512620 | 0.000007 | 0.512388 | 0.16 | 2,176 | 972 |
| SM76-7 | 201 | 17 | 158 | 0.31726 | 0.708027 | 0.000010 | 0.707135 | 1.64 | 5.70 | 0.1739 | 0.512607 | 0.000008 | 0.512379 | −0.01 | 2083 | 986 |
| SM76-8 | 201 | 18 | 154 | 0.34255 | 0.707591 | 0.000009 | 0.706627 | 1.58 | 5.40 | 0.1769 | 0.512615 | 0.000009 | 0.512383 | 0.06 | 2,217 | 980 |
| SM76-9 | 201 | 11 | 148 | 0.20986 | 0.707591 | 0.000010 | 0.707000 | 4.42 | 15.99 | 0.1671 | 0.512540 | 0.000008 | 0.512321 | −1.16 | 1999 | 1,079 |
| SM76-10 | 201 | 27 | 212 | 0.36374 | 0.708334 | 0.000011 | 0.707311 | 1.54 | 5.26 | 0.1770 | 0.512606 | 0.000009 | 0.512374 | −0.12 | 2,260 | 994 |
Sr-Nd isotopic composition of whole rock content of diabase in Bikou area.
6 Discussion
6.1 The formation age of diabase
Mafic to ultramafic rocks generally have low Si and Zr contents, and thus it is often difficult for them to grow abundant zircons. Nevertheless, in many orogenic belts, both mafic and ultramafic rocks may contain variable amounts of zircon grains. These zircons could be inherited grains derived from crustal materials that have been recycled into the mantle source region, zircons modified by mantle-derived melts or fluids, or zircons crystallized directly from basaltic magmas (
Zircons in mafic rocks also include inherited grains, and sometimes yield ages significantly younger than those of the host rocks or related structural units. Several explanations exist for these young zircons: (1) the basalts are younger products, and the youngest zircon population records the intrusion and crystallization age of the basalts (Song et al., 2014); (2) the ages of young zircons represent the timing of late metamorphic, magmatic, tectonic, or hydrothermal events (
LA-ICP-MS U–Pb dating of zircons from diabase veins in the Bikou area yielded a minimum age of 201–206 Ma. The exposed volcanic–sedimentary rock series in the Bikou area has a metamorphic grade mainly corresponding to the low chlorite–garnet facies. Most of the ultramafic to mafic rocks within this series have undergone intense hydrothermal alteration but not medium-grade metamorphism. Consequently, typical metamorphic zircons are not developed. However, zircons that have been overprinted and modified by hydrothermal fluids commonly exhibit complex internal structures, appearing porous or spongy, containing abundant hydrothermal mineral inclusions and fluid inclusions, and showing relics of primary textures. The young zircons investigated in this study from the Bikou area occur as short prismatic crystals with well-developed oscillatory zoning. Based on these morphological features, the ages of 201–206 Ma (weighted mean 206Pb/238U age of 203.5 ± 3.5 Ma, n = 2) are interpreted to represent the formation age of the diabase.
Field geological relationships show that the diabase veins either intrude directly into dolomite or are emplaced along brittle fractures within the dolomite. The contact interface between the diabase and dolomite is mostly embayed or nearly straight, indicating that the intrusion and brittle fracturing were roughly synchronous or that the intrusion occurred shortly after fracturing. The brittle fractures in the Bikou area were mostly controlled by the Mianxian–Yangpingguan Fault, belonging to a unified fault system. As the bounding fault of the Bikou block, the Mianxian–Yangpingguan Fault formed during the interaction between the Bikou block and its surrounding blocks. Previous studies have shown that in the Late Triassic, the Bikou block began to interact with the Qinling orogenic belt, leading to the formation of the Mianxian–Yangpingguan Fault (Wang E. Q. et al., 2001;
6.2 The origin of diabase
The whole-rock composition of the basalt in the Bikou area exhibits sub-alkaline tholeiitic characteristics. Since porphyritic basalt can form in various tectonic settings, including oceanic islands, mid-ocean ridges, island arcs, marginal basins, active continental margins, and stable continental margins, further discrimination using geochemical diagrams is necessary. The SiO2 (44.57–49.58 wt%), TiO2 (0.66–1.09 wt%), and FeOt/MgO (0.96–1.31) contents of the basalt in this area are similar to those of island-arc porphyritic basalts (Miyashiro, 1975). On the 2Nb–Zr/4–Y and Hf/3–Th–Ta diagrams (Figures 6a,b), the sample points plot near the volcanic-arc basalt and island-arc basalt fields. On the Ta/Hf–Th/Hf and Ta/Yb–Th/Yb diagrams (Figures 6c,d), the samples fall within the oceanic island-arc field. The REE and trace element patterns (Figure 5) of the basalt are distinctly different from those of most intra-oceanic basalts (e.g., MORB and OIB) but are similar to those of island-arc porphyritic basalts related to oceanic plate subduction. In addition, pronounced negative Nb and Ta anomalies in the trace element patterns indicate significant involvement of continental materials in the magma genesis (
FIGURE 6

Tectonic setting discrimination diagrams of diabases in the Bikou area. (a) 2Nb-Zr/4-Y (after Meschede, 1986); (b) Hf/3-Th-Ta (after Wood, 1980); (c) Th/Hf-Ta/Hf (after Wang Y. L. et al., 2001); (d) Ta/Yb-Th/Yb (after Pearce, 2008).
High-field-strength elements (e.g., Ti, Zr, Y, Nb, Ta, Hf, Th) and rare earth elements are less affected by later alteration, and their geochemical characteristics can effectively reflect the nature of the magma source (Taylor and Mclennan, 1985; Rudnick and Gao, 2003). Crustal material can enter the lithospheric mantle during subduction and undergo partial melting and modification, or it can be added to mantle-derived magma via crustal contamination during magma ascent. The Ba/Nb and La/Nb ratios of the studied samples range from 23 to 151 and from 2.1 to 2.7, respectively, which are significantly higher than the corresponding ranges for MORB, OIB, alkaline basalt, and kimberlite (1–20 and 0.5–2.5), indicating that continental material played an important role in the evolution of the basaltic magma (
However, it is worth noting that if crustal contamination occurred during magma ascent, significant variations in La/Nb and Th/Nb ratios would be expected (
6.3 Implications of tectonic
A complete collisional orogeny typically includes a compression stage, a transition stage from compression to extension, and an extensional stage. During the compression-to-extension transition, the orogenic belt generally experiences a special tectonic regime of reduced pressure and increased temperature, which facilitates melting and enhances crust–mantle interaction and magmatic activity (Zhu et al., 2009). During the Late Triassic, the stress state of the Qinling orogenic belt changed, and it entered the compression-to-extension transition stage (
Although the geochemical characteristics indicate that the diabase in the Bikou area has a composition similar to continental margin arc basalt, previous studies have pointed out that magmatic rocks with volcanic arc signatures do not necessarily form in a typical subduction environment (Peccerillo, 1998; Xia, 2014). Mafic to intermediate rocks formed during the post-collisional stage often exhibit geochemical compositions resembling island-arc basalts because they inherit the geochemical fingerprint of a mantle source that was previously metasomatized by subducted slab-derived components (
7 Conclusion
LA-ICP-MS zircon U–Pb dating of diabase veins in the Bikou area yields a crystallization age of 201–206 Ma (Late Triassic). The zircons exhibit oscillatory zoning and magmatic Th/U ratios (>0.1), confirming a magmatic origin. This age represents the emplacement time of the diabase and corresponds to the post-collisional stage of the Qinling orogenic belt.
The diabases have low SiO2 (44.57–49.58 wt%), high MgO (3.98–7.46 wt%, Mg# = 56–63), and show subalkaline tholeiitic affinities. They are enriched in Ba and K, depleted in Nb, Ta, and Pb, and exhibit nearly flat REE patterns ((La/Yb)N = 1.93–2.39) with weak positive Eu anomalies (δEu = 0.85–1.21). Their geochemical compositions resemble those of island-arc tholeiites but are interpreted as post-collisional rather than arc-related.
The diabases have initial (87Sr/86Sr)ᵢ ratios of 0.706627–0.707311 and εNd(t) values from −1.16 to 0.16, with two-stage Nd model ages of 972–1,079 Ma. Combined with constant La/Nb, Th/Nb ratios and positive Zr–Hf anomalies, crustal contamination during magma ascent is negligible. The magma most likely originated from partial melting of depleted asthenospheric mantle that had been metasomatized by subducted slab-derived components.
Regional tectonic studies indicate that the Qinling orogenic belt entered the post-collisional stage at ca. 200 Ma. The diabase veins in the Bikou area formed during the transition from compression to extension, triggered by pressure release and asthenospheric upwelling. This Late Triassic tectono-magmatic event is consistent with the brittle deformation along the Mianxian–Yangpingguan Fault and provides new evidence for the post-collisional evolution of the South Qinling orogenic belt.
Statements
Data availability statement
The original contributions presented in the study are included in the article/supplementary material, further inquiries can be directed to the corresponding author.
Author contributions
JW: Investigation, Conceptualization, Funding acquisition, Writing – original draft. XG: Methodology, Investigation, Data curation, Writing – original draft. ZL: Writing – original draft, Investigation. GW: Writing – review and editing. ZC: Investigation, Writing – original draft.
Funding
The author(s) declared that financial support was received for this work and/or its publication. This research was supported by projects from the Shanxi Province Key Laboratory of Metallogeny and Assessment of Strategic Mineral Resources (No. 2025ZZ02) and Special Funds Projects for Basic Scientific Research Business Expenses of Mineral Resources Research Institutes in Chinese Academy of Geological Sciences (KK2217).
Acknowledgments
We would like to thank the editor and the reviewers for their constructive reviews of this paper’s early version.
Conflict of interest
Authors JW and ZC were employed by Shanxi Key Laboratory of Metallogeny and Assessment of Strategic Mineral Resources, Shanxi Institute of Geological Survey CO., LTD.
The remaining author(s) declared that this work was conducted in the absence of any commercial or financial relationships that could be construed as a potential conflict of interest.
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Summary
Keywords
Bikou area, diabase, geochemistry, south Qinling, zircon U-Pb dating
Citation
Wang J, Gao X, Li Z, Wang G and Chen Z (2026) Unraveling the mesozoic tectonic transition of the bikou area: a case study of Late Triassic diabase veins. Front. Earth Sci. 14:1900148. doi: 10.3389/feart.2026.1900148
Received
04 June 2026
Revised
21 June 2026
Accepted
23 June 2026
Published
11 August 2026
Volume
14 - 2026
Edited by
Hongjian Zhu, Yanshan University, China
Reviewed by
Pengfei Zhang, China University of Geosciences Wuhan, China
Nie Xiao, Chinese Academy of Geological Sciences, China
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© 2026 Wang, Gao, Li, Wang and Chen.
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*Correspondence: Jiawei Wang, wangjiawei0824@163.com
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