AUTHOR=Bai Fan , Kakimoto Kouichi , Shang Xuefu , Mori Daisuke , Taminato Sou , Matsumoto Mitsuhiro , Takeda Yasuo , Yamamoto Osamu , Izumi Hiroaki , Minami Hironari , Imanishi Nobuyuki 

TITLE=Water-Stable High Lithium-Ion Conducting Solid Electrolyte of Li1.4Al0.4Ge0.2Ti1.4(PO4)3–LiCl for Aqueous Lithium-Air Batteries

JOURNAL=Frontiers in Energy Research

VOLUME=Volume 8 - 2020

YEAR=2020

URL=https://www.frontiersin.org/journals/energy-research/articles/10.3389/fenrg.2020.00187

DOI=10.3389/fenrg.2020.00187

ISSN=2296-598X

ABSTRACT=Aqueous lithium-air batteries are one of the most promising batteries for electric vehicles because of its high energy and power density. The battery system consists of a lithium anode and an aqueous solution catholyte, which are separated by a water-stable lithium-ion conducting solid electrolyte, and an air electrode. The theoretical energy density of this system is 1910 Wh kg-1, which is around 5 times higher than that of conventional lithium-ion batteries. A key component of this system is the water-stable lithium-ion conducting solid electrolyte. In this work, we have developed a water-stable and water-impermeable solid electrolyte with a high lithium-ion conductivity of around 10-3 S cm-1 at room temperature by the addition of epoxy resin and LiCl into a tape-cast NASICON-type Li1.4Al0.4Ge0.2Ti1.4(PO4)3 film. The aqueous lithium-air battery with the solid electrolyte separator was successfully cycled at 0.5 mA cm-2 and 25 ℃ in an air atmosphere.