AUTHOR=Yang Chao , Han Qing , Liu Haibo , Wang Yuanyuan , Cheng Ran TITLE=Ignition characteristics of methane-air mixture at low initial temperature JOURNAL=Frontiers in Energy Research VOLUME=Volume 10 - 2022 YEAR=2023 URL=https://www.frontiersin.org/journals/energy-research/articles/10.3389/fenrg.2022.1003470 DOI=10.3389/fenrg.2022.1003470 ISSN=2296-598X ABSTRACT=

In this paper, FLUENT software coupled with the chemical reaction mechanism is used to study the ignition characteristics of methane-air mixtures at low temperature. Variations of the main free radical concentrations, the critical conditions for a successful ignition and the chemical reaction rate of each elementary reaction for a failure ignition are obtained, respectively. Results indicate that the consumption of methane immediately affects the concentration distribution of carbon monoxide, which presents the opposite relationship with that of methane. Mass fractions of the intermediate products and H, O free radicals are low in the burnt zone and unburnt zone, whereas reach the maximum on the flame front. OH is not only the intermediate free radical, but also the combustion product remained by the intermediate reactions. At a low temperature of 150 K, the critical radius and temperature of methane ignition are 4.6 mm and 1180 K, respectively. When ignition radius is smaller than the critical value, the failed ignition of methane is caused by the termination of the elementary reactions: R8: H + O2 = OH + O, R9: OH + O = O2 + H, R12: O + H2O = 2OH and R13: 2OH = O + H2O. However, when ignition temperature is lower than the critical value, because of the failed initiation of elementary reaction R1: CH4 = CH3 + H, the combustion of methane is not occurred.