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<front>
<journal-meta>
<journal-id journal-id-type="publisher-id">Front. Energy Res.</journal-id>
<journal-title>Frontiers in Energy Research</journal-title>
<abbrev-journal-title abbrev-type="pubmed">Front. Energy Res.</abbrev-journal-title>
<issn pub-type="epub">2296-598X</issn>
<publisher>
<publisher-name>Frontiers Media S.A.</publisher-name>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="publisher-id">1051417</article-id>
<article-id pub-id-type="doi">10.3389/fenrg.2022.1051417</article-id>
<article-categories>
<subj-group subj-group-type="heading">
<subject>Energy Research</subject>
<subj-group>
<subject>Review</subject>
</subj-group>
</subj-group>
</article-categories>
<title-group>
<article-title>Current status and technology development in implementing low carbon emission energy on underground coal gasification (UCG)</article-title>
<alt-title alt-title-type="left-running-head">Takyi et al.</alt-title>
<alt-title alt-title-type="right-running-head">
<ext-link ext-link-type="uri" xlink:href="https://doi.org/10.3389/fenrg.2022.1051417">10.3389/fenrg.2022.1051417</ext-link>
</alt-title>
</title-group>
<contrib-group>
<contrib contrib-type="author">
<name>
<surname>Takyi</surname>
<given-names>Shadrack Adjei</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
<uri xlink:href="https://loop.frontiersin.org/people/2067809/overview"/>
</contrib>
<contrib contrib-type="author" corresp="yes">
<name>
<surname>Zhang</surname>
<given-names>Yindi</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
<xref ref-type="corresp" rid="c001">&#x2a;</xref>
<uri xlink:href="https://loop.frontiersin.org/people/1969339/overview"/>
</contrib>
<contrib contrib-type="author">
<name>
<surname>Si</surname>
<given-names>Mengting</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author">
<name>
<surname>Zeng</surname>
<given-names>Fanjin</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author">
<name>
<surname>Li</surname>
<given-names>Yingnan</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
<uri xlink:href="https://loop.frontiersin.org/people/2072536/overview"/>
</contrib>
<contrib contrib-type="author">
<name>
<surname>Tontiwachwuthikul</surname>
<given-names>Paitoon</given-names>
</name>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
</contrib>
</contrib-group>
<aff id="aff1">
<sup>1</sup>
<institution>School of Petroleum Engineering</institution>, <institution>Yangtze University</institution>, <addr-line>Wuhan</addr-line>, <addr-line>Hubei</addr-line>, <country>China</country>
</aff>
<aff id="aff2">
<sup>2</sup>
<institution>Measurement Science and Standards</institution>, <institution>National Research Council Canada</institution>, <addr-line>Ottawa</addr-line>, <addr-line>ON</addr-line>, <country>Canada</country>
</aff>
<aff id="aff3">
<sup>3</sup>
<institution>Clean Energy Technologies Research Institute (CETRI)</institution>, <institution>Faculty of Engineering and Applied Science</institution>, <institution>University of Regina</institution>, <addr-line>Regina</addr-line>, <addr-line>SK</addr-line>, <country>Canada</country>
</aff>
<author-notes>
<fn fn-type="edited-by">
<p>
<bold>Edited by:</bold> <ext-link ext-link-type="uri" xlink:href="https://loop.frontiersin.org/people/606567/overview">Hui Zhou</ext-link>, Tsinghua University, China</p>
</fn>
<fn fn-type="edited-by">
<p>
<bold>Reviewed by:</bold> <ext-link ext-link-type="uri" xlink:href="https://loop.frontiersin.org/people/1406082/overview">Yang Xiao</ext-link>, Xi&#x2019;an University of Science and Technology, China</p>
<p>
<ext-link ext-link-type="uri" xlink:href="https://loop.frontiersin.org/people/1644706/overview">Limin Hou</ext-link>, Inner Mongolia University of Science and Technology, China</p>
</fn>
<corresp id="c001">&#x2a;Correspondence: Yindi Zhang, <email>zhangyindihust@foxmail.com</email>
</corresp>
<fn fn-type="other">
<p>This article was submitted to Carbon Capture, Utilization and Storage, a section of the journal Frontiers in Energy Research</p>
</fn>
</author-notes>
<pub-date pub-type="epub">
<day>06</day>
<month>01</month>
<year>2023</year>
</pub-date>
<pub-date pub-type="collection">
<year>2022</year>
</pub-date>
<volume>10</volume>
<elocation-id>1051417</elocation-id>
<history>
<date date-type="received">
<day>22</day>
<month>09</month>
<year>2022</year>
</date>
<date date-type="accepted">
<day>21</day>
<month>11</month>
<year>2022</year>
</date>
</history>
<permissions>
<copyright-statement>Copyright &#xa9; 2023 Takyi, Zhang, Si, Zeng, Li and Tontiwachwuthikul.</copyright-statement>
<copyright-year>2023</copyright-year>
<copyright-holder>Takyi, Zhang, Si, Zeng, Li and Tontiwachwuthikul</copyright-holder>
<license xlink:href="http://creativecommons.org/licenses/by/4.0/">
<p>This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.</p>
</license>
</permissions>
<abstract>
<p>Although coal mining has played a substantial role in world&#x2019;s development as a critical fuel source for at least 25&#xa0;years, its value is partly offset by the massive environmental issues it presents during combustion. The shift to a net-zero CO<sub>2</sub> emission will open unique possibilities for new coal technological models in which progressive studies and policies, development, and modernization will play a significant role. Therefore, a collection of technologies has been proposed, one of which is cost-effective is the Underground Coal Gasification (UCG) coupled with carbon capture storage (CCS) and utilization technology (CCU) UCG-CCS/CCU. This paper reviews the current status and technology development in implementing low carbon emission energy on underground coal gasification. The study, therefore, leads to discussing the modern stage of underground coal gasification and carbon capture storage development, recent pilot operations, and current developments of the growing market. At the same time, it provides a reference for underground coal gasification combined with CCUS technology.</p>
</abstract>
<kwd-group>
<kwd>underground coal gasification (UCG)</kwd>
<kwd>UCG modules</kwd>
<kwd>UCG CCUS</kwd>
<kwd>UCG-ICGCC</kwd>
<kwd>cost</kwd>
</kwd-group>
<contract-sponsor id="cn001">National Natural Science Foundation of China-China Academy of General Technology Joint Fund for Basic Research<named-content content-type="fundref-id">10.13039/501100019492</named-content>
</contract-sponsor>
</article-meta>
</front>
<body>
<sec id="s1">
<title>1 Introduction</title>
<p>Coal is presently an essential energy source throughout the world, except for the middle east and the Former Union of Soviet Socialist Republics (USSR), which have virtually two-thirds or more of the global oil and natural gas reserves (<xref ref-type="bibr" rid="B34">Grimston, 1999</xref>) and will remain for many ages (<xref ref-type="bibr" rid="B23">EIA and International, 2003</xref>; <xref ref-type="bibr" rid="B56">Miller, 2005</xref>). reports a detailed estimate of coal reserves and producing nations for major states worldwide. Research by <xref ref-type="bibr" rid="B22">EIA (2003)</xref> also estimates energy production and consumption primarily by regions and countries. Research by <xref ref-type="bibr" rid="B24">EIA and International (2002)</xref> gives a projected world coal consumption by region for a forecast period to 2020. It is therefore observed that by 2030, future world coal consumption is expected to increase in regions like China, the United States, India, Non-OECD Asia, Japan, Russia, and others (Non-OECD Europe and Eurasia, ex Russia) (<xref ref-type="bibr" rid="B18">Department of Energy EIA Energy Information Administration, 2009</xref>).</p>
<p>Although coal has played a substantial role in world development as an essential fuel source for at least the subsequent quarter-century, its value is partly offset by the massive environmental issues it presents during combustion. According to <xref ref-type="bibr" rid="B41">IEA (2009)</xref>, CO<sub>2</sub> discharges worldwide raised from 1.7% in 2018 to a significant height of 33.1 GtCO<sub>2.</sub> This was the maximum growth rate since 2013 and 70% more than the average increase since 2010. Coal accounts for more than 70% of fuel&#x2019;s total energy-related CO<sub>2</sub> emissions (<xref ref-type="bibr" rid="B75">The World bank, 2014</xref>). Overall, global coal burning is accountable for 46% of the emission of CO<sub>2</sub> and further records for 72% of overall greenhouse gas releases from the electricity section. The common usage of coal evidence this in generating electrical power, and the extremely high CO<sub>2</sub> intensity of coal-fired power. Coal emits significantly more CO<sub>2</sub> emissions per unit of energy produced than oil and more than twice as much as natural gas. Annually, coal burning yields over 14&#xa0;billion tons of atmospheric-released CO<sub>2</sub>, specifically from power generation. As reported by <xref ref-type="bibr" rid="B41">IEA (2009)</xref>, coal consumption for power alone surpassed 10 GtCO<sub>2</sub>, mainly in Asia. China, India, and the United States recorded an 85% increase in net CO<sub>2</sub> emissions, while regions like Germany, Japan, Mexico, France, and the United Kingdom accounted for decreased reductions. <xref ref-type="bibr" rid="B11">CO<sub>2</sub> Earth (2017)</xref> states that by 2,100, the levels of atmospheric CO<sub>2</sub> are estimated to reach about 800&#xa0;ppm resulting in the rise of the earth&#x2019;s surface temperature to about 4&#xb0;C if no immediate and effective actions are taken. Concerning the latest accessible science and the necessity to uplift global climate action, the European Council recommends attaining a climate-neutral EU by 2050, per the aims of the Paris Agreement (<xref ref-type="bibr" rid="B26">EU, 2020</xref>). The shift to a net-zero CO<sub>2</sub> emission will open unique possibilities for new technological models in which progressive research, growth, and modernization policies will have a crucial role. To achieve this aim, a collection of technologies has been projected, one of which is cost-effective (<xref ref-type="bibr" rid="B59">Nakaten et al., 2014</xref>) is the carbon capture (CC), utilization and storage technology (CCUS) (<xref ref-type="bibr" rid="B19">Dixon, 2016</xref>), coupled with Underground Coal Gasification (UCG-CCS/CCU.)</p>
<p>UCG is a coal technology characterized by a high resource utilization rate (<xref ref-type="bibr" rid="B32">Green, 2018</xref>). UCG provides both economic and enviro-friendly approaches to raising coal reserves by utilizing the un-mineable coal deposits by the conventional approach. According to <xref ref-type="bibr" rid="B3">Bhutto et al. (2013)</xref>, UCG alters coal into gas, accompanied by eliminating sulfides and nitrogen oxides, evading the conventional coal-burning process, and has the features of minimum pollution emission, see <xref ref-type="fig" rid="F1">Figure 1</xref>. UCG has numerous economic and environmental benefits (<xref ref-type="bibr" rid="B4">Blinderman and Anderson, 2003</xref>). The technology is much cheaper, eliminates land degradation and mining activity, and sharply permits a functioning UCG plant to increase its syngas production at minimal capital cost. UCG appears to be the leading appropriate technology to be deployed in combination with geological storing of CO<sub>2</sub>&#x2014;geological settings promising for UCG are also promising for CO<sub>2</sub> storing (<xref ref-type="bibr" rid="B28">Friedmann, 2006</xref>). Other applicable technologies can also join UCG to produce synthetic fuel and recover coal bed methane. The rising variability in the worldwide energy condition is bringing out shareholders in nations with primary coal deposits and present or coming energy shortfalls to recommence attention to all technologies with capabilities to raise the use of domestic coal resources (<xref ref-type="bibr" rid="B7">Burton et al., 2006</xref>). For virtually a century of global research and practice, many workshops, practices, and successes have been amassed in the approaches and technologies of UCG.</p>
<fig id="F1" position="float">
<label>FIGURE 1</label>
<caption>
<p>Schematic of UCG process with gas cleaning unit.</p>
</caption>
<graphic xlink:href="fenrg-10-1051417-g001.tif"/>
</fig>
<p>Since the 20th century, over 50 pilot-scale operations of UCG have taken place in Europe, Australia, China, the Former Union of Soviet Socialist Republics (USSR), the United States, and South Africa (see <xref ref-type="table" rid="T1">Tables 1</xref>, <xref ref-type="table" rid="T2">2</xref>). These tests have mainly been commenced at low depths, as seen at the 140&#xa0;m <italic>Chinchilla</italic> in Australia, Angren (110&#xa0;m) in Uzbekistan, Hoe Creek (30&#x2013;40&#xa0;m) in the United States, and Hanna (80&#xa0;m) also in the United States (<xref ref-type="bibr" rid="B66">Prabu and Jayanti, 2012</xref>). The USSR UCG program is believed to have used up 15&#xa0;Mt of coal, and the US research effort to increase regulation and efficiency of the UCG development in about 60 separate tests is projected to have vaporized 100,000&#xa0;tons of coal. However, it was halted shortly by the same minimum prices of natural gas in the 1990&#xa0;s. From 1974 to 1989, scientific investigations and the expansion of UCG rose in the United States. Thirty-three pilot projects of UCG were planned and sited in Texas, Wyoming, Alabama, West Virginia, and Washington (<xref ref-type="bibr" rid="B30">Gem, 2021</xref>). Among them, the most effective was the Rocky Mountain 1 project in Carbon County, Wyoming (<xref ref-type="bibr" rid="B10">Clean Air Task Force Report, 2009</xref>). Many companies worldwide have initiated successful UCG projects that include electric generation and coal-to-liquids. In 2002 (<xref ref-type="bibr" rid="B69">Sasol, 2013</xref>), Eskom initiated its UCG technology development (using Ergo Energy&#x2019;s UCG technology) and successfully piloted it for 5&#xa0;years with proven results. The same technology has been utilized in three UCG projects in the past few years, particularly Linc Energy&#x2019;s initial <italic>Chinchilla</italic> UCG project in Australia, the Huntly West UCG project in New Zealand established by Solid Energy, and Eskom&#x2019;s Majuba pilot project in South Africa. The Ergo Energy&#x2019;s UGC technology is utilized to expand commercialized UCG energy plans in Canada, China, the United States, New Zealand, India, and other nations. In 2006, under the sponsorships of the US-India Energy Dialogue Coal Working Group and the Asia Pacific Partnership, a UCG workshop took place in India Kolkata (<xref ref-type="bibr" rid="B82">US Department of Energy, 2006</xref>) and Houston (<xref ref-type="bibr" rid="B7">Burton et al., 2006</xref>) to accelerate the implementation of UCG and initiate a commercial UCG project set to deliver gas. Studies from esteemed economics have placed power production from UCG Levelized electricity rate at around &#x20ac;49&#xa0;MWh in the absence of CCS and &#x20ac;72&#xa0;MWh with CCS (<xref ref-type="bibr" rid="B59">Nakaten et al., 2014</xref>), which proposes that UCG is highly viable for power generation in both methods of operation. According to <xref ref-type="bibr" rid="B25">Eskom Holdings Ltd (2008)</xref>, the Angren power station in Uzbekistan has generated power from UCG gas for over 50&#xa0;years by co-firing the gas with coal in a boiler. Lately (<xref ref-type="bibr" rid="B16">DECC Report, 2015</xref>) puts the UCG power generation release of CO<sub>2</sub> with combined cycle gas turbine (CCGT) in the range 570&#x2013;785&#xa0;kg CO<sub>2</sub> MWh without resource to CCS, relative to natural gas at 400&#xa0;kg CO<sub>2</sub> MWh. CCS could decrease the emissions of UCG to 100&#xa0;kg CO<sub>2</sub> MWh less. These values are remarkable and therefore put UCG on equivalence to renewable energy sources and the finest fossil fuel discharges with CCS.</p>
<table-wrap id="T1" position="float">
<label>TABLE 1</label>
<caption>
<p>International UCG pilots operations (<xref ref-type="bibr" rid="B66">Prabu and Jayanti, 2012</xref>).</p>
</caption>
<table>
<thead valign="top">
<tr>
<th align="left">Dates</th>
<th align="left">Place (test name)</th>
<th align="left">Duration (days)</th>
<th align="left">Well separation (m)</th>
<th align="left">Coal gasified (tons)</th>
<th align="left">System pressure (kPa)</th>
<th align="left">Feed gas</th>
<th align="left">Coal seam depth (m)</th>
<th align="left">Auspices/comments</th>
</tr>
</thead>
<tbody valign="top">
<tr>
<td align="left">1982&#x2013;1985</td>
<td align="left">Thulin, Belgium</td>
<td align="left">12</td>
<td align="left">35</td>
<td align="left">4</td>
<td align="left">30,000 to 80,000</td>
<td align="left">air; mix of N<sub>2</sub>, O<sub>2</sub>, CO<sub>2</sub>
</td>
<td align="left">860</td>
<td align="left">Institute pour le development de la gazeification souterraine, Belgium</td>
</tr>
<tr>
<td align="left">1983&#x2013;1984</td>
<td align="left">Initially at Bruay en Artois, and later at La Haute Deule, France</td>
<td align="left">75</td>
<td align="left">60</td>
<td align="left">0.3 1st phase 1.5 next phase</td>
<td align="left">45,000</td>
<td align="left">N<sub>2</sub>, O<sub>2</sub>, CO<sub>2</sub>
</td>
<td align="left">880</td>
<td align="left">groupe d&#x2019;etude de la Gazeification souterraine, France (production well plugged by particulates and tar, terminating the tests)</td>
</tr>
<tr>
<td align="left">1992&#x2013;1999</td>
<td align="left">Province of Teruel, NE Spain (El Tremedal)</td>
<td align="left"/>
<td align="left"/>
<td align="left"/>
<td align="left"/>
<td align="left"/>
<td align="left">550</td>
<td align="left">Spain, United Kingdom, Belgium, supported by the European Commission, used CRIP</td>
</tr>
<tr>
<td align="left">1980&#x2014;present</td>
<td align="left">China, 16 separate trails &#x2a;</td>
<td align="left"/>
<td align="left"/>
<td align="left"/>
<td align="left"/>
<td align="left"/>
<td align="left"/>
<td align="left">UCG centre at China Univ. Of mining and technology, Beijing</td>
</tr>
<tr>
<td align="left">1990&#x2014;present</td>
<td align="left">
<italic>Chinchilla</italic>, Queensland, Australia</td>
<td align="left"/>
<td align="left"/>
<td align="left"/>
<td align="left"/>
<td align="left"/>
<td align="left"/>
<td align="left"/>
</tr>
<tr>
<td align="left">1994</td>
<td align="left">Huntley, New Zealand</td>
<td align="left"/>
<td align="left"/>
<td align="left"/>
<td align="left"/>
<td align="left"/>
<td align="left"/>
<td align="left">With US technical assistance</td>
</tr>
</tbody>
</table>
</table-wrap>
<table-wrap id="T2" position="float">
<label>TABLE 2</label>
<caption>
<p>20th century UCG primary projects.</p>
</caption>
<table>
<thead valign="top">
<tr>
<th align="left">Test site</th>
<th align="left">Country</th>
<th align="left">Year</th>
<th align="left">Seam thickness (m)</th>
<th align="left">Seam depth (m)</th>
<th align="left">Coal gasified (ton)</th>
<th align="left">Syngas cv (mj/m<sup>3</sup>)</th>
</tr>
</thead>
<tbody valign="top">
<tr>
<td align="left">Lisichansk</td>
<td align="left">Russia</td>
<td align="left">1934&#x2013;1936</td>
<td align="left">0.75</td>
<td align="left">24</td>
<td align="left"/>
<td align="left">3&#x2013;4</td>
</tr>
<tr>
<td align="left">Lisichansk</td>
<td align="left">Ukraine</td>
<td align="left">1943&#x2013;1963</td>
<td align="left">0.4</td>
<td align="left">400</td>
<td align="left"/>
<td align="left">3.2</td>
</tr>
<tr>
<td align="left">Gorlovka</td>
<td align="left">Russia</td>
<td align="left">1935&#x2013;1941</td>
<td align="left">1.9</td>
<td align="left">40</td>
<td align="left"/>
<td align="left">6&#x2013;10</td>
</tr>
<tr>
<td align="left">Podmoskova</td>
<td align="left">Russia</td>
<td align="left">1940&#x2013;1962</td>
<td align="left">2</td>
<td align="left">40</td>
<td align="left"/>
<td align="left">6 with O<sub>2</sub>
</td>
</tr>
<tr>
<td align="left">Bois-la-dame</td>
<td align="left">Belgium</td>
<td align="left">1948</td>
<td align="left">1</td>
<td align="left"/>
<td align="left"/>
<td align="left"/>
</tr>
<tr>
<td align="left">Newman Spinney</td>
<td align="left">United Kingdom</td>
<td align="left">1949&#x2013;1959</td>
<td align="left">1</td>
<td align="left">75</td>
<td align="left">180</td>
<td align="left">2.6</td>
</tr>
<tr>
<td align="left">Yuzhno-Abinsk</td>
<td align="left">Russia</td>
<td align="left">1955&#x2013;1989</td>
<td align="left">2-September</td>
<td align="left">138</td>
<td align="left">2 &#xd7; 10<sup>6</sup>
</td>
<td align="left">9&#x2013;12.1</td>
</tr>
<tr>
<td align="left">Angren</td>
<td align="left">Uzbekistan</td>
<td align="left">1965&#x2013;now</td>
<td align="left">4</td>
<td align="left">110</td>
<td align="left">&#x3e;1 &#xd7; 10<sup>7</sup>
</td>
<td align="left">3.6</td>
</tr>
<tr>
<td align="left">Hanna 1</td>
<td align="left">United States</td>
<td align="left">1973&#x2013;1974</td>
<td align="left">9.1</td>
<td align="left">120</td>
<td align="left">3,130</td>
<td align="left"/>
</tr>
<tr>
<td align="left">Hanna 2</td>
<td align="left">United States of America</td>
<td align="left">1975&#x2013;1976</td>
<td align="left">9.1</td>
<td align="left">84</td>
<td align="left">7,580</td>
<td align="left">5.3</td>
</tr>
<tr>
<td align="left">Hoe creek 1</td>
<td align="left">United States</td>
<td align="left">1976</td>
<td align="left">7.5</td>
<td align="left">100</td>
<td align="left">112</td>
<td align="left">3.6</td>
</tr>
<tr>
<td align="left">Hanna 3</td>
<td align="left">United States of America</td>
<td align="left">1977</td>
<td align="left">9.1</td>
<td align="left">84</td>
<td align="left">2,370</td>
<td align="left">4.1</td>
</tr>
<tr>
<td align="left">Hoe creek 2A</td>
<td align="left">United States</td>
<td align="left">1977</td>
<td align="left">7.5</td>
<td align="left">100</td>
<td align="left">1820</td>
<td align="left">3.4</td>
</tr>
<tr>
<td align="left">Hoe creek 2B</td>
<td align="left">United States</td>
<td align="left">1977</td>
<td align="left">7.5</td>
<td align="left">100</td>
<td align="left">60</td>
<td align="left">9</td>
</tr>
<tr>
<td align="left">Hanna 4</td>
<td align="left">United States of America</td>
<td align="left">1977&#x2013;1979</td>
<td align="left">9.1</td>
<td align="left">100</td>
<td align="left">4,700</td>
<td align="left">4.1</td>
</tr>
<tr>
<td align="left">Hoe creek 3A</td>
<td align="left">United States</td>
<td align="left">1979</td>
<td align="left">7.5</td>
<td align="left">100</td>
<td align="left">290</td>
<td align="left">3.9</td>
</tr>
<tr>
<td align="left">Hoe creek 3B</td>
<td align="left">United States of America</td>
<td align="left">1979</td>
<td align="left">7.5</td>
<td align="left">100</td>
<td align="left">3,190</td>
<td align="left">6.9</td>
</tr>
<tr>
<td align="left">Pricetown</td>
<td align="left">United States</td>
<td align="left">1979</td>
<td align="left">1.8</td>
<td align="left">270</td>
<td align="left">350</td>
<td align="left">6.1</td>
</tr>
<tr>
<td align="left">Rawlins 1A</td>
<td align="left">United States</td>
<td align="left">1979</td>
<td align="left">18</td>
<td align="left">105</td>
<td align="left">1,330</td>
<td align="left">5.6</td>
</tr>
<tr>
<td align="left">Rawlins 1B</td>
<td align="left">United States</td>
<td align="left">1979</td>
<td align="left">18</td>
<td align="left">105</td>
<td align="left">169</td>
<td align="left">8.1</td>
</tr>
<tr>
<td align="left">Rawlins 2</td>
<td align="left">United States</td>
<td align="left">1979</td>
<td align="left">18</td>
<td align="left">130&#x2013;180</td>
<td align="left">7,760</td>
<td align="left">11.8</td>
</tr>
<tr>
<td align="left">Brauy-en-artois</td>
<td align="left">France</td>
<td align="left">1981</td>
<td align="left">1,200</td>
<td align="left"/>
<td align="left"/>
<td align="left"/>
</tr>
<tr>
<td align="left">Thulin</td>
<td align="left">Belgium</td>
<td align="left">1982&#x2013;1984</td>
<td align="left">860</td>
<td align="left"/>
<td align="left"/>
<td align="left"/>
</tr>
<tr>
<td align="left">Centralia tono A</td>
<td align="left">United States</td>
<td align="left">1984&#x2013;1985</td>
<td align="left">6</td>
<td align="left">75</td>
<td align="left">190</td>
<td align="left">9.7</td>
</tr>
<tr>
<td align="left">Centralia tono B</td>
<td align="left">United States</td>
<td align="left">1984&#x2013;1985</td>
<td align="left">6</td>
<td align="left">75</td>
<td align="left">390</td>
<td align="left">8.4</td>
</tr>
<tr>
<td align="left">Haute-duete</td>
<td align="left">France</td>
<td align="left">1985&#x2013;1986</td>
<td align="left">2</td>
<td align="left">880</td>
<td align="left"/>
<td align="left"/>
</tr>
<tr>
<td align="left">Thulin</td>
<td align="left">Belgium</td>
<td align="left">1986&#x2013;1987</td>
<td align="left">6</td>
<td align="left">860</td>
<td align="left">157</td>
<td align="left"/>
</tr>
<tr>
<td align="left">Rocky mountain 1A</td>
<td align="left">United States</td>
<td align="left">1987&#x2013;1988</td>
<td align="left">7</td>
<td align="left">110</td>
<td align="left">11,200</td>
<td align="left">9.5</td>
</tr>
<tr>
<td align="left">Rocky mountain 1B</td>
<td align="left">United States</td>
<td align="left">1987&#x2013;1988</td>
<td align="left">7</td>
<td align="left">110</td>
<td align="left">4,440</td>
<td align="left">8.8</td>
</tr>
<tr>
<td align="left">EI tremedal</td>
<td align="left">Spain</td>
<td align="left">1997</td>
<td align="left">2</td>
<td align="left">600</td>
<td align="left"/>
<td align="left"/>
</tr>
</tbody>
</table>
</table-wrap>
</sec>
<sec id="s2">
<title>2 Status of UCG configuration modules for initiating UCG reactions</title>
<p>UCG involves compound physical and chemical processes, and the composition and quality of the syngas are affected by many factors. Given the high-temperature humidity and closed setting, it becomes problematic to efficiently monitor and control the overall UCG process to upgrade the quality of the syngas. Studies by <xref ref-type="bibr" rid="B58">Mostade (2014)</xref> confirm that the technical challenge with UCG monitoring and controlling the hot cavity to move safely and reliably along the coal seam and convert as much coal as possible into valuable, sustainable, high-quality syngas. UCG is currently noted as a composite process where engineers are proficient in forecasting the accessibility and dependability of the entire process during the construction, process control, and monitoring of UCG operations together with the post-operation shutdown program (<xref ref-type="bibr" rid="B57">Mojibul and Mohammad, 2015</xref>). All UCG modules (the arrangement of both linked injection and production point) are identical. Thus, they require at least two process points connected within the coal seam to inject the vaporizing agents and begin ignition (injection point) and the other for recovering the syngas that is produced (production point) (<xref ref-type="bibr" rid="B49">Lavis et al., 2013</xref>). Between these two process points, a higher-performance gas circuit needs to be built by increasing the permeability of coal in a process called &#x201c;linking.&#x201d;</p>
<p>Therefore, scholars in many countries have conducted meaningful studies on UCG modules. According to (<xref ref-type="bibr" rid="B57">Mojibul and Mohammad, 2015</xref>), there are various methods, such as hydraulic fracturing, horizontal drilling, reverse combustion, linked vertical well (LVW), electric linkage, and controlled retractable injection point (CRIP) method. Another suitable technology based on the Former Union of Soviet Socialist Republics (USSR) UCG technology is Ergo Energy&#x2019;s UCG technology (<xref ref-type="bibr" rid="B7">Burton et al., 2006</xref>). Other technology development modules are China&#x2019;s Long Tunnel Method (<xref ref-type="bibr" rid="B49">Lavis et al., 2013</xref>), &#x201c;Super Daisy Shaft,&#x201d; and Single Well Flow Tube (SWIFT) technology. Portman Energy established SWIFT technology and uses a single vertical well for oxidant injection and syngas supply (<xref ref-type="bibr" rid="B12">Couch, 2009</xref>).</p>
<sec id="s2-1">
<title>2.1 CRIP method</title>
<p>The Lawrence Livermore National Laboratory developed the CRIP method in the US in 1970 (<xref ref-type="bibr" rid="B48">Kumar, 2014</xref>). The production wells are drilled vertically, and the injection wells are drilled using directional drilling techniques to connect to the production wells. Once the channel is established, a burner attached to the retractable coiled tubing is used to initiate the gasification cavity, which ignites the coal as it burns the borehole casing (<xref ref-type="bibr" rid="B38">Hill, 1983</xref>). CRIP provides a stationary state of the vertical press-in well, but if necessary, the press-in point moves to fresh coal within the coal seam (<xref ref-type="bibr" rid="B38">Hill, 1983</xref>). Studies in <xref ref-type="bibr" rid="B45">Klimenko (2009)</xref> have confirmed that the flash point can be moved along the horizontal injection well to create a new gasification cavity when the coal near the cavity is exhausted. The second combustion begins near the injection well when the first combustion is finished. This way, the progress of gasification can be precisely controlled, and this procedure continues until the seams are burned out. Syngas, more than one-third of hydrogen in many early UCG pilots (the rest are CO<sub>2</sub>, CO, CH<sub>4</sub>, and higher hydrocarbons), is brought to the surface and processed to remove particles, CO<sub>2</sub>, and H<sub>2</sub>S. Moreover, CO is converted. From CH<sub>4</sub> and higher hydrocarbons to more hydrogen (<xref ref-type="bibr" rid="B7">Burton et al., 2006</xref>). See <xref ref-type="fig" rid="F2">Figures 2A, B</xref>.</p>
<fig id="F2" position="float">
<label>FIGURE 2</label>
<caption>
<p>
<bold>(A)</bold> Schematic of the CRIP process. <bold>(B)</bold> Chemical process model for simulating CRIP underground layout of (<xref ref-type="bibr" rid="B7">Burton et al., 2006</xref>). <bold>(C)</bold> Gasifier layout for linear CRIP configuration.</p>
</caption>
<graphic xlink:href="fenrg-10-1051417-g002.tif"/>
</fig>
<p>The concept of CRIP can be divided into Linear-CRIP (L-CRIP) (see <xref ref-type="fig" rid="F2">Figure 2C</xref>) and Parallel-CRIP (P-CRIP) configurations. In the L-CRIP configuration, both process points are linked by one intra-seam excursion well. In a P-CRIP configuration, both process wells are drilled into the seam parallel to each other. See <xref ref-type="bibr" rid="B79">UGE (1999)</xref> and <xref ref-type="bibr" rid="B61">Nourozieh et al. (2010)</xref> for more information on the two processes.</p>
<sec id="s2-1-1">
<title>2.1.1 CRIP commercialization developments</title>
<p>The CRIP method was primarily developed in the US in the 1980&#xa0;s during major R &#x26; D stages (<xref ref-type="bibr" rid="B8">Cena et al., 1988</xref>), in Spain (1990s), Australia (late 1990s to present), and currently in Alberta, Canada (from late 2000s to the present) (<xref ref-type="bibr" rid="B49">Lavis et al., 2013</xref>). The L-CRIP configuration has been successfully demonstrated at shallow depth (110&#xa0;m) in the Rocky Mountain 1 (RM-1), Wyoming, US, at intermediate depth (500&#x2013;600&#xa0;m) in the European UCG project at El Tremedal, Teruel, Spain, and is currently being used to produce high-quality syngas at great depth (1,400&#xa0;m) in the Swan Hills UCG project, Alberta, Canada (<xref ref-type="bibr" rid="B37">Hill and Shannon, 1981</xref>). In addition, the P-CRIP configuration was first tested at the partial seam CRIP test (Tono-1) in Centralia, Washington State, US, and has since been used during the RM-1 trial (Tono-2), United States, and by Carbon Energy and LINC at their respective facilities in Queensland, Australia (<xref ref-type="bibr" rid="B58">Mostade, 2014</xref>).</p>
</sec>
</sec>
<sec id="s2-2">
<title>2.2 LVW</title>
<p>SHS(201<xref ref-type="bibr" rid="B71">2)</xref> states that the LVW method is one of UCG&#x2019;s oldest methods and is derived from technology developed in the former Soviet Union. A vertical well is drilled at the coal seam and uses the coal&#x2019;s internal pathways to direct the oxidizer flow and produced gas from the inlet to the exit borehole. Internal pathways can occur naturally or be constructed <italic>via</italic> reverse combustion, electrical coupling, and hydraulic fracturing (<xref ref-type="bibr" rid="B70">Shafirovich and Varma, 2009</xref>).</p>
<p>The injection point is located at the complete base of the vertical injection well, and the production point is at the complete base of the vertical production well (<xref ref-type="bibr" rid="B58">Mostade, 2014</xref>). In the simplest form, the entry and exit drilling positions of the LVW method are stationary throughout the life of the system. However, it has been found that as the coal surface moves during operation and the distance from the coal surface to the oxidant injection point increases, system control, performance, and syngas quality are adversely affected (<xref ref-type="bibr" rid="B50">Liang et al., 1999</xref>). This factor significantly decreases the viability of a simple LVW system. When the coal in the area is exhausted, a new hole will be drilled to replace the new coal, forming new zones. See <xref ref-type="fig" rid="F3">Figures 3A, B</xref>.</p>
<fig id="F3" position="float">
<label>FIGURE 3</label>
<caption>
<p>
<bold>(A)</bold> Upright cross-section of underground LVW gasifier. <bold>(B)</bold> A chemical process model used to simulate the underground layout of LVW (<xref ref-type="bibr" rid="B50">Liang et al., 1999</xref>).</p>
</caption>
<graphic xlink:href="fenrg-10-1051417-g003.tif"/>
</fig>
<sec id="s2-2-1">
<title>2.2.1 LVW commercialization developments</title>
<sec id="s2-2-1-1">
<title>2.2.1.1 Eskom Majuba, South Africa</title>
<p>The Majuba UCG project has produced syngas and coal since January 2007 and the end of 2010. The project contributed approximately 3&#xa0;MW of electricity to the total output of 650&#xa0;MW. Currently, the project is the longest-running UCG test in the Western world. It is planned to expand the facility to an output of 1200&#xa0;MW, and 30% of the plant&#x2019;s fuel will be provided by syngas (<xref ref-type="bibr" rid="B67">Roddy and Younger, 2010</xref>).</p>
<p>LVW configurations have been used at Solid Energy&#x2019;s facility at Huntly, New Zealand, as well as other locations in China and Canada (Laurus Energy). The LVW configuration was also used at Cougar Energy&#x2019;s facility in Kingaroy, Australia (<xref ref-type="bibr" rid="B58">Mostade, 2014</xref>). Alternatives of the LVW method are continuously used today, especially at the UCG facility in Angren, Uzbekistan, which has the longest continuous operation in the world (<xref ref-type="bibr" rid="B49">Lavis et al., 2013</xref>).</p>
</sec>
</sec>
</sec>
<sec id="s2-3">
<title>2.3 The Ergo energy&#x2019;s UCG technology</title>
<p>Ergo Energy&#x2019;s UCG is a proprietary process used by Ergo Exergy and may be based on the former Union of Soviet Socialist Republics (USSR) UCG technology. It relies on using the natural passages at the coal seams and strengthening them as needed to establish a connection between the press-in well and the production well. Ergo Energy&#x2019;s UCG technology is practical and based on the practical experience of operating a commercial UCG factory. The design flexibility and multiple methods and technologies used by Ergo Exergy enable it to be applied to various coal qualities and grades (from lignite to bituminous coal) and geological environments (<xref ref-type="bibr" rid="B7">Burton et al., 2006</xref>).</p>
<p>It employs all currently available drilling methods, including precision directional wells and traditional vertical and sloping (tilted) wells. Its arsenal includes different ways to connect wells, different oxidant injections (air, O<sub>2</sub>/H<sub>2</sub>O.), and different underground vaporizer designs. It can be applied to coal under various geological and hydrogeological conditions. In each geological environment, the specific Ergo Energy&#x2019;s UCG design is tailored to the specific conditions of the coal seam of interest (<xref ref-type="bibr" rid="B65">Power, 2011</xref>).</p>
<sec id="s2-3-1">
<title>2.3.1 Ergo energy&#x2019;s UCG commercialization developments</title>
<p>The Australian <italic>Chinchilla</italic> project has effectively established Ergo Energy&#x2019;s UCG technology. In this project, a projected 35,000 tons of coal were used to produce 80,000,000&#xa0;Nm<sup>3</sup> of syngas at 5&#xa0;MJ/Nm<sup>3</sup>. Ergo Energy&#x2019;s UCG technology is also been reviewed for the projected Powder River Basin UCG project and in a cooperative project between Gas Authority India, Ltd. (GAIL) and Ergo Exergy.</p>
<p>The 1997 to 2006 <italic>Chinchilla</italic> I UCG project in Australia (350&#xa0;km west of Brisbane, Queensland) was the first to establish Ergo Energy&#x2019;s UCG as gas production technology (<xref ref-type="bibr" rid="B52">Maev et al., 2018</xref>). Ergo Exergy supplied the technology for the project and designed and operated the plant. In the past 16&#xa0;years, the technology has been used in four syngas production projects as seen in the 1999 to 2006 <italic>Chinchilla</italic> project (Australia); 2007 to present Eskom (South Africa) project; Kingaroy (Australia), 2010; and the Huntly West (New Zealand), 2012 (<xref ref-type="bibr" rid="B52">Maev et al., 2018</xref>). A Conceptual design of Ergo Energy&#x2019;s UCG IGCC plant is shown in <xref ref-type="fig" rid="F4">Figure 4</xref>. <xref ref-type="table" rid="T3">Table 3</xref> shows the coalfields where Ergo Energy&#x2019;s UCG is used around the world (<xref ref-type="bibr" rid="B65">Power, 2011</xref>).</p>
<fig id="F4" position="float">
<label>FIGURE 4</label>
<caption>
<p>Conceptual design of the ergo energy UCG-IGCC plant.</p>
</caption>
<graphic xlink:href="fenrg-10-1051417-g004.tif"/>
</fig>
<table-wrap id="T3" position="float">
<label>TABLE 3</label>
<caption>
<p>Various ergo energy UCG technology projects.</p>
</caption>
<table>
<thead valign="top">
<tr>
<th align="left">UCG plant</th>
<th align="left">Rank</th>
<th align="left">Thickness, m</th>
<th align="left">Depth, m</th>
<th align="left">Dip, &#x2070;</th>
<th align="left">LHV, MJ/kg</th>
</tr>
</thead>
<tbody valign="top">
<tr>
<td align="left">Lisichansk</td>
<td align="left">Bituminous</td>
<td align="left">0.44&#x2013;2.0</td>
<td align="left">60&#x2013;250</td>
<td align="left">38&#x2013;60</td>
<td align="left">20.1&#x2013;23.0</td>
</tr>
<tr>
<td align="left">Yuzhno-Abinsk</td>
<td align="left">Bituminous</td>
<td align="left">2.2&#x2013;9.0</td>
<td align="left">130&#x2013;380</td>
<td align="left">35&#x2013;58</td>
<td align="left">28.9&#x2013;30.7</td>
</tr>
<tr>
<td align="left">Podmoskovnaya</td>
<td align="left">Lignite</td>
<td align="left">2.5</td>
<td align="left">30&#x2013;80</td>
<td align="left">&#x3c;1</td>
<td align="left">11.8</td>
</tr>
<tr>
<td align="left">Angren</td>
<td align="left">Lignite</td>
<td align="left">3.0&#x2013;24.0</td>
<td align="left">110&#x2013;250</td>
<td align="left">7</td>
<td align="left">15.3</td>
</tr>
<tr>
<td align="left">Shatskaya</td>
<td align="left">Lignite</td>
<td align="left">2.6</td>
<td align="left">30&#x2013;60</td>
<td align="left">&#x3c;1</td>
<td align="left">11.0</td>
</tr>
<tr>
<td align="left">Sinelnikovo</td>
<td align="left">Lignite</td>
<td align="left">3.5&#x2013;6.0</td>
<td align="left">80</td>
<td align="left">&#x3c;1</td>
<td align="left">8.0</td>
</tr>
<tr>
<td align="left">
<italic>Chinchilla</italic>
</td>
<td align="left">Sub-bituminous</td>
<td align="left">10.0</td>
<td align="left">135</td>
<td align="left">&#x3c;1</td>
<td align="left">21.7</td>
</tr>
<tr>
<td align="left">Majuba</td>
<td align="left">Bituminous</td>
<td align="left">3.5&#x2013;4.5</td>
<td align="left">285</td>
<td align="left">3</td>
<td align="left">20.3</td>
</tr>
<tr>
<td align="left">Kingaroy</td>
<td align="left">Sub-bituminous</td>
<td align="left">17.0</td>
<td align="left">200</td>
<td align="left">5</td>
<td align="left">23.5</td>
</tr>
<tr>
<td align="left">Huntly West</td>
<td align="left">Bituminous</td>
<td align="left">4.0&#x2013;22.0</td>
<td align="left">220&#x2013;540</td>
<td align="left">0&#x2013;75</td>
<td align="left">24.5</td>
</tr>
<tr>
<td align="left">CC Alberta</td>
<td align="left">Sub-bituminous</td>
<td align="left">7.0</td>
<td align="left">150&#x2013;260</td>
<td align="left">6</td>
<td align="left">20.5&#x2013;23.0</td>
</tr>
<tr>
<td align="left">Alaska SHR</td>
<td align="left">Lignite/sub-bituminous</td>
<td align="left">1.0&#x2013;12.0</td>
<td align="left">50&#x2013;650</td>
<td align="left">0&#x2013;75</td>
<td align="left">11.0&#x2013;16.5</td>
</tr>
</tbody>
</table>
</table-wrap>
</sec>
</sec>
<sec id="s2-4">
<title>2.4 Current R&#x26;D on UCG monitoring</title>
<p>Early UCG tests applied flow meters, thermocouples, and gas analyzers to monitor temperatures and combustion conditions from the underground (<xref ref-type="bibr" rid="B5">Blinderman and Jones, 2002</xref>). These measurements track underground combustion conditions and their corresponding subsidence but are effective for shallow coal seams and lower resolution for deep coal seams. However, in a hot and humid UCG setting, the accuracy of such sensors may be low and may not work properly. In addition <xref ref-type="bibr" rid="B55">Mellors et al. (2016)</xref> researched and designed a UCG monitoring system based on a self-organizing network of wireless sensors. However, the system has been tested in the laboratory, and the high temperature and high humidity environmental factors were not considered in the design. <xref ref-type="bibr" rid="B83">Wang et al. (2017)</xref> used Siemens S7-300 PLC and Fame View configuration software to develop a real-time monitoring system for UCG. However, the laboratory has tested the system, and the design does not consider the hot and humid environmental factors. Using the Siemens S7-300 PLC and Fame View configuration software, <xref ref-type="bibr" rid="B83">Wang et al. (2017)</xref> developed the UCG real-time monitoring system. However, the system is used for teaching experiments, and the design does not consider environmental factors such as high temperature and humidity (<xref ref-type="bibr" rid="B35">Guan et al., 2016</xref>) built a wireless sensor network and planned a UGS monitoring system to monitor groundwater pollution during gasification. However, its sensor components are inappropriate for the representative UCG high humidity and temperature setting. <xref ref-type="bibr" rid="B2">Barnwal et al. (2017)</xref> proposed a new method of producing coal with high moisture and low calorific value to improve the synthesis gas quality of UCG technology. However, these methods are expensive or temporarily not scalable. On the other hand <xref ref-type="bibr" rid="B46">Kost&#xfa;r et al. (2015)</xref> created the UCG visualization information system to visualize the state of the UCG record. Based on this <xref ref-type="bibr" rid="B62">Nurzynska et al. (2014)</xref> monitors UCG data using GPR and visualizes them in 3D, see <xref ref-type="fig" rid="F5">Figure 5</xref>. However, standard commercial radar systems are used to check the on-site and off-site coal combustion conditions. The results show that this method monitors and visualizes the coal gasification process under off-site combustion conditions. It is not suitable for other situations; that is, it is impossible to control the combustion state of coal in a real gasification process.</p>
<fig id="F5" position="float">
<label>FIGURE 5</label>
<caption>
<p>UCG monitoring system observation platform (<xref ref-type="bibr" rid="B62">Nurzynska et al., 2014</xref>).</p>
</caption>
<graphic xlink:href="fenrg-10-1051417-g005.tif"/>
</fig>
</sec>
<sec id="s2-5">
<title>2.5 Current R&#x26;D on UCG control</title>
<p>UCG control is a developing area with few references to theoretical research and laboratory simulations. <xref ref-type="bibr" rid="B47">Kotyrba and Stanczyk. (2017)</xref> established and deduced the mathematical expression of gasified coal particles based on the theory of mass conservation, energy conservation, and chemical thermodynamics based on model tests. The calculated value is the same as the model test value. Some scientists have studied the combustion state of the gasifier based on mathematical models (<xref ref-type="bibr" rid="B85">Yang and Liu, 2010</xref>). These studies are effective in predicting the state of combustion. However, this is necessary in practice to accurately assess the combustion state in real-time (<xref ref-type="bibr" rid="B44">Khan et al., 2015</xref>) provides related properties that affect the combustion state of UCG through laboratory simulation experiments. The team then experimented to determine optimal operating conditions for syngas conversion and studied the effects of numerous operating parameters on changes in the gasified surface (<xref ref-type="bibr" rid="B13">Daggupati et al., 2010</xref>). However, a correct mathematical model was not provided to define these processes. Therefore <xref ref-type="bibr" rid="B72">Stanczyk et al. (2012)</xref> developed a one-dimensional numerical model to study the influence of operating conditions (for example, temperature, pressure, water flow, gas composition) and coal characteristics (for example, thermomechanical exfoliation characteristics, reactivity, composition) on the growth rate of local cavities and energy efficiency. It has been found that the thermal-mechanical cracking of coal, ash behavior, and the amount of carbon incorporated in the coal mainly affect the combustion rate (<xref ref-type="bibr" rid="B64">Perkins and Sahajwalla, 2006</xref>) projected a one-dimensional packed bed model for UCG control, which maintains the expected calorific value of the exhaust gas mixture by controlling the injected gas flow rate. The model can also predict important data parameters such as gas composition and combustion speed. However, in these control models, it is necessary to assume that the total concentration of all gases in the entire active chamber is constant. Uppal afterward improved the design of the simplified UCG model sliding mode control algorithm to ensure the stability of the thermal output value of the entire system (<xref ref-type="bibr" rid="B81">Uppal et al., 2014</xref>; <xref ref-type="bibr" rid="B80">Uppal et al., 2018</xref>; <xref ref-type="bibr" rid="B68">Saravanan et al., 2018</xref>).</p>
</sec>
</sec>
<sec id="s3">
<title>3 Power production with UCG</title>
<p>For over 50&#xa0;years, the Angren power station in Uzbekistan has been utilizing UCG to generate power by co-firing the gas with coal in a boiler (<xref ref-type="bibr" rid="B54">Marques et al., 2018</xref>). However, this method is based on old technology and does not realize all the advantages of UCG syngas power generation. Recently, many countries have proposed different UCG power generation projects as the next phase of UCG commercialization using modern technologies such as gas turbines (<xref ref-type="bibr" rid="B51">Linc Energy, 2015</xref>). Large-scale commercial UCG power plants are proposed to use combined cycle power plant technology due to their high thermal efficiency, low nitrogen oxide emissions, and low specific capital expenditures, see <xref ref-type="table" rid="T4">Table 4</xref>. The application of commercial syngas purification technology in the IGCC plant and Linc Energy&#x2019;s <italic>Chinchilla</italic> GTL facility (see <xref ref-type="fig" rid="F6">Figure 6</xref>) is expected to reduce air pollutant emissions from UCG power plants to levels similar to those of IGCC plants. Applying carbon dioxide capture and storage can further reduce carbon dioxide intensity to a level similar to natural gas power generation (<xref ref-type="bibr" rid="B25">Eskom Holdings Ltd, 2008</xref>). It is expected that in the next 10&#x2013;15&#xa0;years, coal power generation in most developed countries and China will decrease or stabilize, but many developing countries, especially Southern Africa, Southeast Asia, and India, are expected to expand the use of coal due to its low cost and abundant domestic supply is used for power generation (<xref ref-type="bibr" rid="B33">Gregg et al., 1976</xref>). However, it is well known that traditional coal-fired power generation has the highest levels of air pollutants and carbon emissions compared with other alternative energy sources such as natural gas or renewable energy. For decades, clean coal technologies such as IGCC have been developing to reduce the environmental impact of coal-fired power generation. IGCC technology has been successfully proven to produce extremely low air pollutant emissions, and the first plant using carbon capture is about to be completed (<xref ref-type="bibr" rid="B40">IEA, 2015</xref>). However, mainly due to high capital costs, the level of commercialization of IGCC has been low. There are significant opportunities to develop cost-effective clean coal technologies (such as UCG) as an alternative to traditional coal-fired power generation, especially for developing countries. By avoiding coal mining and surface gasification, UCG power generation has the potential to provide environmental performance similar to IGCC technology at a lower cost.</p>
<table-wrap id="T4" position="float">
<label>TABLE 4</label>
<caption>
<p>21st century UCG power projects (<xref ref-type="bibr" rid="B51">Linc Energy, 2015</xref>).</p>
</caption>
<table>
<thead valign="top">
<tr>
<th align="left">Countries</th>
<th align="left">Year of project commencement</th>
<th align="left">Company organization</th>
<th align="left">Objective</th>
</tr>
</thead>
<tbody valign="top">
<tr>
<td align="left">China</td>
<td align="left">2011</td>
<td align="left">UCG research centers (Beijing) Seamwell, China energy conservation and environmental protection corporation Zhengzhou coal industry Co., Ltd.</td>
<td align="left">Power generation H<sub>2</sub> for fuel cells</td>
</tr>
<tr>
<td align="left">India</td>
<td align="left">2005</td>
<td align="left">Neyvell lignite corporation limited central mine planning and design institute limited central coalfields Ltd., western oalfields Ltd.</td>
<td align="left">Power generation study and evaluate the calorific value of the gas generated</td>
</tr>
<tr>
<td align="left">Pakistan</td>
<td align="left">2009</td>
<td align="left">Thar coal and energy board</td>
<td align="left">Power generation</td>
</tr>
<tr>
<td align="left">United States</td>
<td align="left">2005</td>
<td align="left">Lawrence livermore national laboratories linc energy, carbon energy and ergo energy</td>
<td align="left">Natural gas liquefaction, developing 3d cavity growth simulators</td>
</tr>
<tr>
<td align="left">Australia</td>
<td align="left">2007</td>
<td align="left">Linc energy company</td>
<td align="left">UCG-CCS, UCG-IGCC power generation</td>
</tr>
<tr>
<td align="left">Poland</td>
<td align="left">2007</td>
<td align="left">Central mining institute of poland</td>
<td align="left">Environmental and safety issues related to UCG processes</td>
</tr>
</tbody>
</table>
</table-wrap>
<fig id="F6" position="float">
<label>FIGURE 6</label>
<caption>
<p>Conceptual design of the chinchilla project.</p>
</caption>
<graphic xlink:href="fenrg-10-1051417-g006.tif"/>
</fig>
<p>The UCG process occurs at relatively low temperatures compared to surface gases, and its properties are similar to a low-temperature fixed bed gas, such as a Lurgi FBDB gasifier (<xref ref-type="bibr" rid="B21">DOE/NETL, 2015a</xref>). Compared with high-temperature gasifiers, low-temperature gasifiers generally have higher cooling efficiency, lower oxygen demand, and can produce more hydrocarbon products (<xref ref-type="bibr" rid="B76">Thorsness and Britten, 1989</xref>). All modern IGCC plants are based on medium-temperature or high-temperature gasification technology. Compared with UCG-based plants, there are several key differences in gas purification and performance. Typical examples of IGCC plants that have recently adopted medium and high-temperature gasification include Kemper County (TRIG vaporizer), Buggenum (Shell vaporizer), and Edwardsport (GE vaporizer) (<xref ref-type="bibr" rid="B17">DOE/NETL Dennis, 2006</xref>). The advantage of medium-high temperature gasification is that synthesis gas composition is simpler, and the content of higher hydrocarbons and tar components is lower. The disadvantage is that high-temperature gasification requires a large amount of oxygen supply, and in order to achieve high thermal efficiency, heat recovery downstream of the gasifier under harsh conditions (<xref ref-type="bibr" rid="B20">DOE/NETL, 2015b</xref>). The UCG power generation process is similar to the surface-based IGCC, in which the UCG process replaces the coal mining process, surface gasification islands, and ash treatment plants. The air separation unit (ASU) supplies oxygen to the underground gasifier and produces crude syngas. The raw syngas is cooled and purified before being sent to the combined cycle gas turbine. The water separated from the gas is processed and reused, and the liquid hydrocarbon by-product (coal condensate) can be processed for sale or used as supplementary fuel. See <xref ref-type="fig" rid="F7">Figure 7</xref> for a Schematic of the UCG-IGCC 200&#xa0;MW power plant.</p>
<fig id="F7" position="float">
<label>FIGURE 7</label>
<caption>
<p>Schematic of UCG-IGCC 200&#xa0;MW power plant (<xref ref-type="bibr" rid="B20">DOE/NETL, 2015b</xref>).</p>
</caption>
<graphic xlink:href="fenrg-10-1051417-g007.tif"/>
</fig>
</sec>
<sec id="s4">
<title>4 UGC and CCS/CCUS</title>
<p>A robust interaction exists between UCG and the sequestration of carbon. Often, the high temperature and high pressure from the UCG syngas stream can significantly save the cost of carbon recovery and separation. In addition, as stated previously, the cavity formed in the UCG process can be used to store supercritical carbon dioxide. In either case, adjacent rocks may contain depleted oil and gas fields suitable for salinity (non-drinkable aquifers) or carbon dioxide storage (<xref ref-type="bibr" rid="B7">Burton et al., 2006</xref>). <xref ref-type="fig" rid="F8">Figure 8</xref> is a cost-determining practical and financial model for the comprehensive UCG and CCS/CCU scenario with reference from (<xref ref-type="bibr" rid="B36">Higman and van der Burgt, 2008</xref>).</p>
<fig id="F8" position="float">
<label>FIGURE 8</label>
<caption>
<p>Technical and economic model for determining the cost of UCG, CCS and CCU.</p>
</caption>
<graphic xlink:href="fenrg-10-1051417-g008.tif"/>
</fig>
<p>CCS technologies can be implemented using various methods: post-combustion (PCC), pre-combustion, and oxyfuel capture (<xref ref-type="bibr" rid="B59">Nakaten et al., 2014</xref>). All of these technologies are currently in commercial demonstration, except chemical cycle combustion technologies, which are still in development (<xref ref-type="bibr" rid="B84">Wang et al., 2011</xref>).</p>
<p>When considering the potential to capture CO<sub>2</sub> from UCG, it is important to understand the carbon distribution between gas composition and gas species. For deeper coal with greater pressure, it is well known that methane formation will increase (<xref ref-type="bibr" rid="B1">APEC, 2019</xref>). The carbon contained in methane can only be captured by reforming the gas, applying oxy-fuel combustion, or using post-combustion capture. Other ongoing developments aim to embrace CO<sub>2</sub> sequestration in the voids from which coal has been extracted (<xref ref-type="bibr" rid="B73">Synfuels, 2012</xref>). CO<sub>2</sub> capture occurs at high pressure in front of the combustion plant and is separated and stored using the same drilling and completion techniques as UCG. Even at depths of 1,000&#xa0;m and above, it operates at the same pressure required for the high-density storage stage of CO<sub>2</sub>. The synergistic effect would be even greater if the same process in the gasification well could be modified and reused for storage.</p>
<p>Therefore, if a series of wells are open in the UCG chamber to produce syngas, the CO<sub>2</sub> content is separated and reinjected from the abandoned well into a suitable underground structure for permanent storage. Fuel is efficiently produced for use in a combined cycle or fuel cell gas turbines, resulting in zero emissions for hydrogen and near-zero emissions for hydrogen-methane mixtures (<xref ref-type="bibr" rid="B74">The Trades Union Congress, 2014</xref>). Underground storage of CO<sub>2</sub> can meet all minimum standards for leakage prevention. Therefore, it can be proved that the deep well UCG can be reused, regardless of whether it has been modified or not, it can be used for CO<sub>2</sub> injection and permanent storage. Storage targets can also be placed in coal seams, upper layers, or abandoned UCG cavities. Primary estimations specify that at depths above 1,500&#xa0;m, all CO<sub>2</sub> produced by coal can be recovered (<xref ref-type="bibr" rid="B74">The Trades Union Congress, 2014</xref>).</p>
<p>It is necessary to separate and concentrate CO<sub>2</sub> with a purity greater than 95% for injection. Most UCG applications yield a CO<sub>2</sub> by-product stream of this purity level appropriate for GCS. For power generation, the Selexol or Rectisol process can be used to separate CO<sub>2</sub> from the pre-combustion of syngas at a comparatively low cost of about $0.01&#xa0;kWh. This will enable the carbon footprint of traditional NGCC facilities to generate electricity from UCG syngas (<xref ref-type="bibr" rid="B7">Burton et al., 2006</xref>). The syngas flow reaches the surface under severe pressure for deep UCG operations of depths greater than 600&#xa0;m. For certain marketable applications (such as methanol and DME formulations), pressure can be used to reduce operating costs and energy loss. Equally, some CO<sub>2</sub> capture technologies deliver well at high pressures (such as fluorinated solvents and Nexant&#x2019;s CO<sub>2</sub> hydrate process). These methods can further reduce the cost of capture and isolation. But, not all of these methods have been tested on a bulky profitable scale and need additional analysis before to deployment (<xref ref-type="bibr" rid="B7">Burton et al., 2006</xref>).</p>
<sec id="s4-1">
<title>4.1 Pre-combustion CO<sub>2</sub> capture</title>
<p>Pre-combustion CO<sub>2</sub> capture is largely employed in IGCC and coal gasification-based polygeneration systems. IGCC and CCS/CCUS are currently one of the most promising directions. In the pre-combustion capture process, the fuel is changed into synthesis gas in the reformer or gasifier and then undergoes a shift reaction to yield a mixture of CO<sub>2</sub> and H<sub>2</sub>. CO<sub>2</sub> is mainly captured from this gas blend containing H<sub>2</sub> at high pressure of 10&#x2013;80&#xa0;bar and moderate CO<sub>2</sub> content of 15%&#x2013;40%. In addition to CO<sub>2</sub>/H<sub>2</sub> separation, the gas supply also contains CO, H<sub>2</sub>S, and, other sulfur components. The high pressure of this generated gas stream promotes the removal of CO<sub>2</sub>. The main CO<sub>2</sub> removal technology is the absorption process, and the solvent can be a chemical or physical solvent. Removing u sulfur components, such as H2S, is also necessary from the gas stream (<xref ref-type="bibr" rid="B27">European Technology, 2005</xref>). See <xref ref-type="fig" rid="F9">Figure 9</xref>.</p>
<fig id="F9" position="float">
<label>FIGURE 9</label>
<caption>
<p>Carbon capture approaches and technology options (<xref ref-type="bibr" rid="B78">Tollefson, 2011</xref>).</p>
</caption>
<graphic xlink:href="fenrg-10-1051417-g009.tif"/>
</fig>
<sec id="s4-1-1">
<title>4.1.1 RD&#x26;D proceedings on pre-combustion CO<sub>2</sub> capture</title>
<p>The Project GreenGen, introduced by CHNG, is China&#x2019;s foremost IGCC power plant. GreenGen in Tianjin develops, demonstrates, and promotes power plants with near-zero emissions, improves the efficiency of coal-fired power generation, and emits pollutants (sulfur dioxide, nitrogen oxides, particulate matter) and carbon dioxide. The project is grouped into three phases. The first phase is constructing a 250&#xa0;MW level IGCC demonstration plant and the Greengen lab with a CO<sub>2</sub> capture capacity of 30,000&#xa0;tons/year. The second phase is the main IGCC technology and coal chemistry R&#x26;D (such as SNG and fuel cell application). The final phase involves the construction of a 400&#xa0;MW IGCC demonstration power plant to capture and store 60% of carbon dioxide. According to the project&#x2019;s first phase, a 250&#xa0;MW IGCC power plant was constructed and passed the full trial operation on 6 November 2012 (<xref ref-type="bibr" rid="B27">European Technology, 2005</xref>).</p>
</sec>
</sec>
<sec id="s4-2">
<title>4.2 Post-combustion PCC CO<sub>2</sub> capture</title>
<p>PCC CO<sub>2</sub> capture removes CO<sub>2</sub> in flue gas discharged after combustion. Many first-generation CCS projects are expected to be implemented through PCC based on chemical absorption (<xref ref-type="bibr" rid="B59">Nakaten et al., 2014</xref>), as seen in <xref ref-type="fig" rid="F10">Figure 10</xref>. Amine-based post-combustion capture is the most developed of the CO<sub>2</sub> capture options. PCC CO<sub>2</sub> recovery after combustion can remove CO<sub>2</sub> in the flue gas emitted. As shown in <xref ref-type="fig" rid="F10">Figure 10</xref>, numerous first-generation CCS developments are projected to be carried out through PCC connected with chemical absorption (<xref ref-type="bibr" rid="B59">Nakaten et al., 2014</xref>). Currently, the utmost advanced CO<sub>2</sub> capture selection is the amine-based PCC.</p>
<fig id="F10" position="float">
<label>FIGURE 10</label>
<caption>
<p>PCC based chemical absorption process.</p>
</caption>
<graphic xlink:href="fenrg-10-1051417-g010.tif"/>
</fig>
<sec id="s4-2-1">
<title>4.2.1 RD&#x26;D proceedings</title>
<p>In July 2008, the China Huaneng Group (CHNG) planned and manufactured the first capture test equipment for PCC CO<sub>2</sub>. The PCC system&#x2019;s capture capacity for CO<sub>2</sub> is 3,000 to 5,000&#xa0;tons per year (<xref ref-type="bibr" rid="B42">Jinyi and Shisen, 2014</xref>). A year later, an annual CO<sub>2</sub> capture demonstration device of 120,000&#xa0;tons was completed in Shanghai and started operation in December 2009 (<xref ref-type="bibr" rid="B77">Tollefson, 2008</xref>). The first commercial-scale recovery power plant for PCC in the world is the Canada Boundary Dam Unit 3. It went into operation in 2014 and can recover 1 million tons of CO<sub>2</sub> annually (<xref ref-type="bibr" rid="B84">Wang et al., 2011</xref>). Chemical absorption-based PCC developments using traditional amino solvents are currently at different technological levels. See <xref ref-type="table" rid="T5">Table 5</xref> for commercial PCC based on the chemical absorption process.</p>
<table-wrap id="T5" position="float">
<label>TABLE 5</label>
<caption>
<p>Chemical absorption-based PCC processes (<xref ref-type="bibr" rid="B84">Wang et al., 2011</xref>).</p>
</caption>
<table>
<thead valign="top">
<tr>
<th align="left">PCC process</th>
<th align="left">Developer</th>
<th align="left">Solvent</th>
<th align="left">Demonstration</th>
<th align="left">Commercial project</th>
</tr>
</thead>
<tbody valign="top">
<tr>
<td align="left">CanSolv</td>
<td align="left">Shell</td>
<td align="left">Amine-based</td>
<td align="left">TCM Norway Aberthaw PCC Wales</td>
<td align="left">Boundary Dam Canada (Operational) bow city Canada (Planning)</td>
</tr>
<tr>
<td align="left">Advanced capture process (Nustad)</td>
<td align="left">Aker clean carbon</td>
<td align="left">Amine-based</td>
<td align="left">TCM Norway</td>
<td align="left">Longannet United Kingdom (Cancelled) Porto Tolle Italy (Cancelled)</td>
</tr>
<tr>
<td align="left">PostCap&#x2122;</td>
<td align="left">Siemens</td>
<td align="left">Amino acid salt</td>
<td align="left">TCM norway big bend pcc florida</td>
<td align="left">ROAD Netherlands (Planning) Masdar Abu Dhabi (Planning)</td>
</tr>
<tr>
<td align="left">Econamine FG Plus<sup>SM</sup>
</td>
<td align="left">FLOUR</td>
<td align="left">Amine-based</td>
<td align="left">TCM Norway Wilhelmshaven PCC Germany</td>
<td align="left">Trailblazer, Texas (Cancelled)</td>
</tr>
<tr>
<td align="left">Advanced amine process</td>
<td align="left">Alstom power/dow chemical</td>
<td align="left">DOW UCARSOL&#x2122; FGC 3000</td>
<td align="left">EDF PCC Le Havre, France Charleston PCC, West Virginia</td>
<td align="left">Elektownia Belchatow, Poland (planning) GETICA Romania (on-hold)</td>
</tr>
<tr>
<td align="left">CAP</td>
<td align="left">Alstom power</td>
<td align="left">Chilled ammonia</td>
<td align="left">TCM Norway pleasant prairie PCC Milwaukee Karlshamn PCC Sweden Mountaineer CCS phase I, West Virginia</td>
<td align="left">AEP Mountaineer CCS Phase II, West Virginia (Cancelled) Project Pioneer Alberta (Cancelled)</td>
</tr>
<tr>
<td align="left">KM-CDR<sup>TM</sup>
</td>
<td align="left">MHI/KEPCO</td>
<td align="left">KS-1 (Hindered amine)</td>
<td align="left">plant barry, alabama plant yates, georgia</td>
<td align="left">Petro-Nova CCS, Texas (On-going)</td>
</tr>
<tr>
<td align="left">ECO<sub>2</sub>&#x2122;</td>
<td align="left">Powerspan</td>
<td align="left">Amine-based</td>
<td align="left">Burger PCC, Ohio</td>
<td align="left"/>
</tr>
<tr>
<td align="left">HTC</td>
<td align="left">HTC Purenergy/doosan babcock</td>
<td align="left">Amine-based</td>
<td align="left">international test centre, Canada</td>
<td align="left">Antelope Valley CCS, North Dakota</td>
</tr>
<tr>
<td align="left">CO<sub>2</sub> Solution</td>
<td align="left">CO<sub>2</sub> solutions Ltd.</td>
<td align="left">Enzyme-based solvent</td>
<td align="left">Pikes Peak South PCC, Saskatchewan, Canada</td>
<td align="left"/>
</tr>
<tr>
<td align="left">DMX&#x2122;</td>
<td align="left">IFPEN/PROSERNA</td>
<td align="left">Biphasic solvent</td>
<td align="left">ENEL&#x2019;s Brindisi Pilot PCC, Italy</td>
<td align="left"/>
</tr>
<tr>
<td align="left">RSAT&#x2122;</td>
<td align="left">Babcock and wilcox</td>
<td align="left">OptiCap</td>
<td align="left"/>
<td align="left"/>
</tr>
</tbody>
</table>
</table-wrap>
</sec>
</sec>
<sec id="s4-3">
<title>4.3 Oxy-fuel combustion</title>
<p>Combustion enhancement, characterized by oxy-fuel combustion, has been effectively applied in minor pilot projects. For example, the Schwarze Pumpe (30&#xa0;MW) in Germany, Callide (30&#xa0;MW) in Australia, and the 35&#xa0;MW oxy-combustion test unit in Yingcheng, Huazhong University of Science are successful applications (<xref ref-type="bibr" rid="B78">Tollefson, 2011</xref>). See <xref ref-type="fig" rid="F9">Figure 9</xref>.</p>
</sec>
<sec id="s4-4">
<title>4.4 CO<sub>2</sub> storage and transport</title>
<p>Captured CO<sub>2</sub> is typically pumped into deep saline and undeveloped deep coal or oil and gas-depleted fields (see <xref ref-type="fig" rid="F11">Figure 11</xref>). Recently developed CO<sub>2</sub> utilization technologies include chemical, geological, and bio utilization (<xref ref-type="bibr" rid="B84">Wang et al., 2011</xref>). However, traditional storage operations such as in brine formations and oil and gas fields are well known. These technologies are not expected to pose additional risks to the operation of UCG and should be considered the initial project development target. In contrast, storage in non-traditional units (oil shale, basalt) requires more scientific knowledge than is currently available (<xref ref-type="bibr" rid="B7">Burton et al., 2006</xref>).</p>
<fig id="F11" position="float">
<label>FIGURE 11</label>
<caption>
<p>Cross-sectional diagram of underground CO<sub>2</sub> storage (<xref ref-type="bibr" rid="B84">Wang et al., 2011</xref>).</p>
</caption>
<graphic xlink:href="fenrg-10-1051417-g011.tif"/>
</fig>
<p>CO<sub>2</sub> transport methods primarily include tankers, vessels, and pipelines, and transporting CO<sub>2</sub> over pipelines is considered the most cost-effective and consistent method for bulk and long-distance transport (<xref ref-type="bibr" rid="B84">Wang et al., 2011</xref>). <xref ref-type="fig" rid="F12">Figure 12</xref> shows a schematic flowchart of CCS and transportation.</p>
<fig id="F12" position="float">
<label>FIGURE 12</label>
<caption>
<p>Schematic diagram of CO<sub>2</sub> capture, storage and transportation (<xref ref-type="bibr" rid="B78">Tollefson, 2011</xref>).</p>
</caption>
<graphic xlink:href="fenrg-10-1051417-g012.tif"/>
</fig>
</sec>
<sec id="s4-5">
<title>4.5 The effect of CO<sub>2</sub> as a gasification medium on UCG</title>
<p>
<xref ref-type="bibr" rid="B14">Daggupati et al. (2011)</xref> and <xref ref-type="bibr" rid="B39">IEA (2016)</xref> carried out research scale UCG tests utilizing superheated steam as a gasifying medium. The advent of steam at a low temperature of 150&#xb0;C to UCG combustion depth quenches the fire front and leads to unproductive gasification (<xref ref-type="bibr" rid="B39">IEA, 2016</xref>). Especially in the light of high ash Indian coals, steam dissemination through an ash deposit within the cavity may decrease the temperature. Furthermore, superheated steam transportation to deep underground cavities (&#x3e;300&#xa0;m) is challenging due to heat loss <italic>via</italic> pipelines. The linings of the pipelines result in extensive energy demand in the steam-based UCG process. Thus, according to (<xref ref-type="bibr" rid="B72">Stanczyk et al., 2012</xref>), UCG oxygen gasification is deliberate for coals with excessive ash content, and research shows the viability of creating a medium calorific product gas with enhanced CO (&#x223c;210&#xa0;kJ/mol) in the absence of steam to the UCG input stream.</p>
<p>In UCG oxygen gasification, the integral moisture reactivity with char enhances the steam gasification reaction at the early stages of combustion; in any case, combustion-generated CO<sub>2</sub> improves the Boudouard equation (Eq. <xref ref-type="disp-formula" rid="e1">1</xref>) by reacting it with the adjoining char sites at the moisture depleted conditions of the coal seam.</p>
<p>Boudouard equation: <disp-formula id="e1">
<mml:math id="m1">
<mml:mrow>
<mml:mi mathvariant="normal">C</mml:mi>
<mml:mo>&#x2b;</mml:mo>
<mml:mi mathvariant="normal">C</mml:mi>
<mml:mi mathvariant="normal">O</mml:mi>
<mml:mn>2</mml:mn>
<mml:mtext>&#x2009;</mml:mtext>
<mml:mo>&#x2192;</mml:mo>
<mml:mtext>&#x2009;</mml:mtext>
<mml:mn>2</mml:mn>
<mml:mi mathvariant="normal">C</mml:mi>
<mml:mi mathvariant="normal">O</mml:mi>
<mml:mtext>&#x2009;</mml:mtext>
<mml:mo>&#x394;</mml:mo>
<mml:mi mathvariant="normal">H</mml:mi>
<mml:mo>&#x3d;</mml:mo>
<mml:mo>&#x2b;</mml:mo>
<mml:mn>168.9</mml:mn>
<mml:mtext>&#x2009;</mml:mtext>
<mml:mi mathvariant="normal">K</mml:mi>
<mml:mi mathvariant="normal">j</mml:mi>
<mml:mo>/</mml:mo>
<mml:mi mathvariant="normal">m</mml:mi>
<mml:mi mathvariant="normal">o</mml:mi>
<mml:mi mathvariant="normal">l</mml:mi>
</mml:mrow>
</mml:math>
<label>(1)</label>
</disp-formula>
</p>
<p>Therefore, research results from (<xref ref-type="bibr" rid="B72">Stanczyk et al., 2012</xref>) show high UCG practicability to be carried out in a CO<sub>2</sub> mode, which is a promptly accessible enhancer for gasification. In addition <xref ref-type="bibr" rid="B66">Prabu and Jayanti (2012)</xref>, examined Indian coal inherent gasification kinetic parameters in the temperature range of 800&#x2013;1,050&#xb0;C given CO<sub>2</sub> based UCG with a thermogravimetric analyzer (<xref ref-type="bibr" rid="B53">Mandapati et al., 2012</xref>) experimented on O<sub>2</sub>/CO<sub>2</sub> UCG gasification with different CO<sub>2</sub> concentrations in a virtual coal seam. It was observed that CO<sub>2</sub> UCG gasification increases the CO/H<sub>2</sub> product gas ratio and improves gas calorific content. For proficient gasification, preheating the CO<sub>2</sub> as a gasifying medium to high temperatures is cost-effective relative to the generation of superheated steam in a UCG steam-based operation. Furthermore, CO<sub>2</sub> gas can be delivered at room temperature to the profound underground cavities for <italic>in-situ</italic> gasification.</p>
<p>Several works of literature have outlined ongoing research that uses CO<sub>2</sub> gas as a key coal gasifying agent (<xref ref-type="bibr" rid="B9">Chen et al., 2013</xref>) carried out two-stage underground coal gasification using CO<sub>2</sub> air as the gasifying medium. It was observed that with a rise in the CO<sub>2</sub>/oxidant molar ratio, the calorific content of the syngas reduced progressively. At 0.5&#xa0;M proportion of CO<sub>2</sub>/oxidant, a syngas with a least standard calorific value of 65&#xa0;kJ/mol is delivered. <xref ref-type="fig" rid="F12">Figure 12</xref> shows the calorific value of the product gas for the experiment in (<xref ref-type="bibr" rid="B9">Chen et al., 2013</xref>). Thus, it was established that the ideal stream rate of CO<sub>2</sub> is 0.2&#xa0;LPM for the O<sub>2</sub>/air molar proportion of 0.11 for coals with low ash. However, relative to high ash coals, the rise in the CO<sub>2</sub> stream rate to 0.3&#xa0;LPM led to quenching within the borehole combustion front. In this way, 0.2 is the ideal molar ratio of CO<sub>2</sub>/oxidant for high ash coals at the O<sub>2</sub>/air molar ratio of 1.</p>
</sec>
</sec>
<sec id="s5">
<title>5 CCS demonstration projects in major economies</title>
<p>At present, economies such as the United States, Norway, Australia, France, and China have all carried out CCS demonstration projects, some of which have reached the commercial scale. By October 2017, there were 37 large CCS/CCUS integration projects (<xref ref-type="bibr" rid="B14">Daggupati et al., 2011</xref>) (each with a capture capacity of over 400,000&#xa0;tons/year). Among them, 17 large-scale projects are in operation with a total CO<sub>2</sub> capture capacity of 30&#xa0;million tons/year: 10 EOR projects in North America, two saline formation storage projects in Norway, 1 EOR project in Brazil, 2 EOR projects in the Middle East and two saline formation storage projects in North America. CCS/CCUS is also developing rapidly in China, with several commercial demonstration projects successfully carried out (<xref ref-type="bibr" rid="B84">Wang et al., 2011</xref>). See <xref ref-type="table" rid="T6">Table 6</xref>.</p>
<table-wrap id="T6" position="float">
<label>TABLE 6</label>
<caption>
<p>A. Industrial CCS large-scale projects (&#x3e;0.4&#xa0;Mt/yr) (<xref ref-type="bibr" rid="B84">Wang et al., 2011</xref>).</p>
</caption>
<table>
<thead valign="top">
<tr>
<th align="left">Facility name</th>
<th align="left">Facility status</th>
<th align="left">Country</th>
<th align="left">Operation date</th>
<th align="left">Facility industry</th>
<th align="left">Capture capacity (Mtpa)</th>
<th align="left">Summary</th>
</tr>
</thead>
<tbody valign="top">
<tr>
<td colspan="7" align="left">Steel Industry</td>
</tr>
<tr>
<td align="left">&#x2003;Abu Dhabi CCS (Phase 1 being Emirates steel industries)</td>
<td align="left">Operating</td>
<td align="left">UAE</td>
<td align="left">2016</td>
<td align="left">Iron and Steel</td>
<td align="left">0.80&#x2013;0.80</td>
<td align="left">EOR application</td>
</tr>
<tr>
<td colspan="7" align="left">chemicals and petrochemicals</td>
</tr>
<tr>
<td align="left">&#x2003;Illinois industrial carbon capture and Storage</td>
<td align="left">Operating</td>
<td align="left">United States</td>
<td align="left">2017</td>
<td align="left">Ethanol production</td>
<td align="left">1.00&#x2013;1.00</td>
<td align="left">Geological Storage</td>
</tr>
<tr>
<td align="left">&#x2003;Lake charles methanol</td>
<td align="left">In development</td>
<td align="left">United States</td>
<td align="left">2022 (estimated)</td>
<td align="left">Chemical production</td>
<td align="left">4.20&#x2013;4.20</td>
<td align="left">EOR application</td>
</tr>
<tr>
<td align="left">&#x2003;Sinopec Qilu petrochemical CCS</td>
<td align="left">In construction</td>
<td align="left">China</td>
<td align="left">2019</td>
<td align="left">Chemical production</td>
<td align="left">0.40&#x2013;0.40</td>
<td align="left">EOR application</td>
</tr>
<tr>
<td align="left">&#x2003;Yanchang integrated carbon capture and storage demonstration</td>
<td align="left">In construction</td>
<td align="left">China</td>
<td align="left">2020&#x2013;2021</td>
<td align="left">Chemical production</td>
<td align="left">0.41&#x2013;0.41</td>
<td align="left">EOR application</td>
</tr>
<tr>
<td align="left">&#x2003;Shenhua Ningxia CTL</td>
<td align="left">In development</td>
<td align="left">China</td>
<td align="left">2020 (estimated)</td>
<td align="left">Coal&#x2010;to&#x2010;liquids (CTL)</td>
<td align="left">2.00&#x2013;2.00</td>
<td align="left"/>
</tr>
<tr>
<td colspan="7" align="left">Refining Industry</td>
</tr>
<tr>
<td align="left">&#x2003;Acorn scalable CCS development</td>
<td align="left">In development</td>
<td align="left">United Kingdom</td>
<td align="left">2020 (estimated)</td>
<td align="left">Oil refining</td>
<td align="left">3.00&#x2013;4.00</td>
<td align="left">Geological storage</td>
</tr>
<tr>
<td align="left">&#x2003;Alberta carbon trunk line (ACTL) with North West redwater partnership&#x2019;s sturgeon refinery CO<sub>2</sub> stream</td>
<td align="left">In construction</td>
<td align="left">Canada</td>
<td align="left">2019</td>
<td align="left">Oil refining</td>
<td align="left">1.20&#x2013;1.40</td>
<td align="left">EOR application</td>
</tr>
<tr>
<td colspan="7" align="left">Hydrogen Production</td>
</tr>
<tr>
<td align="left">&#x2003;Air products steam methane reformer</td>
<td align="left">Operating</td>
<td align="left">United States</td>
<td align="left">2013</td>
<td align="left">Hydrogen production</td>
<td align="left">1.00&#x2013;1.00</td>
<td align="left">EOR application</td>
</tr>
<tr>
<td align="left">&#x2003;HyNet North West</td>
<td align="left">In development</td>
<td align="left">United Kingdom</td>
<td align="left">2020 (estimated)</td>
<td align="left">Hydrogen production</td>
<td align="left">1.50&#x2013;1.50</td>
<td align="left">Geological storage</td>
</tr>
<tr>
<td align="left">&#x2003;Northern Gas Network H21 North of England</td>
<td align="left">In development</td>
<td align="left">United Kingdom</td>
<td align="left">2026</td>
<td align="left">Hydrogen production</td>
<td align="left">1.50&#x2013;1.50</td>
<td align="left"/>
</tr>
<tr>
<td align="left">&#x2003;Quest</td>
<td align="left">Operating</td>
<td align="left">Canada</td>
<td align="left">2015</td>
<td align="left">Hydrogen production</td>
<td align="left">1.00&#x2013;1.00</td>
<td align="left">Geological storage</td>
</tr>
<tr>
<td colspan="7" align="left">Natural Gas Production</td>
</tr>
<tr>
<td align="left">&#x2003;Century plant</td>
<td align="left">Operating</td>
<td align="left">United States</td>
<td align="left">2010</td>
<td align="left">Natural Gas processing</td>
<td align="left">8.40&#x2013;8.40</td>
<td align="left">EOR application</td>
</tr>
<tr>
<td align="left">&#x2003;CNPC Jilin Oil Field CO<sub>2</sub> EOR</td>
<td align="left">Operating</td>
<td align="left">China</td>
<td align="left">2018</td>
<td align="left">Natural Gas processing</td>
<td align="left">0.60&#x2013;0.60</td>
<td align="left">EOR application</td>
</tr>
<tr>
<td align="left">&#x2003;Gorgon carbon dioxide injection</td>
<td align="left">In Construction</td>
<td align="left">Australia</td>
<td align="left">2019</td>
<td align="left">Natural gas processing</td>
<td align="left">3.40&#x2013;4.00</td>
<td align="left">Geological Storage</td>
</tr>
<tr>
<td align="left">&#x2003;Great plains synfuels plant and weyburn&#x2010;midale</td>
<td align="left">Operating</td>
<td align="left">Canada</td>
<td align="left">2000</td>
<td align="left">Synthetic natural gas</td>
<td align="left">3.00&#x2013;3.00</td>
<td align="left">EOR application</td>
</tr>
<tr>
<td align="left">&#x2003;In Salah CO<sub>2</sub> storage</td>
<td align="left">Completed</td>
<td align="left">Algeria</td>
<td align="left">2004</td>
<td align="left">Natural gas processing</td>
<td align="left">0.00&#x2013;0.00</td>
<td align="left">Storage in depleted gas reservoir</td>
</tr>
<tr>
<td align="left">&#x2003;Lost cabin gas plant</td>
<td align="left">Operating</td>
<td align="left">United States</td>
<td align="left">2013</td>
<td align="left">Natural gas Processing</td>
<td align="left">0.90&#x2013;0.90</td>
<td align="left">EOR application</td>
</tr>
<tr>
<td align="left">&#x2003;Petrobras santos basin pre&#x2010;salt oil field ccs</td>
<td align="left">Operating</td>
<td align="left">Brazil</td>
<td align="left">2013</td>
<td align="left">Natural gas processing</td>
<td align="left">1.00&#x2013;2.50</td>
<td align="left">EOR application</td>
</tr>
<tr>
<td align="left">&#x2003;Shute creek gas processing plant</td>
<td align="left">Operating</td>
<td align="left">United States</td>
<td align="left">1986</td>
<td align="left">Natural gas processing</td>
<td align="left">7.00&#x2013;7.00</td>
<td align="left">EOR application</td>
</tr>
<tr>
<td align="left">&#x2003;Sleipner CO<sub>2</sub> storage</td>
<td align="left">Operating</td>
<td align="left">Norway</td>
<td align="left">1996</td>
<td align="left">Natural gas processing</td>
<td align="left">1.00&#x2013;1.00</td>
<td align="left">Geological storage</td>
</tr>
<tr>
<td align="left">&#x2003;Sn&#xf8;hvit CO<sub>2</sub> storage</td>
<td align="left">Operating</td>
<td align="left">Norway</td>
<td align="left">2008</td>
<td align="left">Natural gas processing</td>
<td align="left">0.70&#x2013;0.70</td>
<td align="left">Geological storage</td>
</tr>
<tr>
<td align="left">&#x2003;Terrell natural gas processing plant (formerly val verde natural gas plants)</td>
<td align="left">Operating</td>
<td align="left">United States</td>
<td align="left">1972</td>
<td align="left">Natural gas processing</td>
<td align="left">0.40&#x2013;0.50</td>
<td align="left">EOR application</td>
</tr>
<tr>
<td align="left">&#x2003;Uthmaniyah CO<sub>2</sub>&#x2010;EOR demonstration</td>
<td align="left">Operating</td>
<td align="left">Saudi Arabia</td>
<td align="left">2015</td>
<td align="left">Natural gas processing</td>
<td align="left">0.80&#x2013;0.80</td>
<td align="left">EOR application</td>
</tr>
<tr>
<td colspan="7" align="left">Fertilizer Production</td>
</tr>
<tr>
<td align="left">&#x2003;Alberta carbon trunk line (actl) with agrium CO<sub>2</sub> stream</td>
<td align="left">In construction</td>
<td align="left">Canada</td>
<td align="left">2019</td>
<td align="left">Fertilizer production</td>
<td align="left">0.30&#x2013;0.60</td>
<td align="left">EOR application</td>
</tr>
<tr>
<td align="left">&#x2003;Coffeyville gasification plant</td>
<td align="left">Operating</td>
<td align="left">United States</td>
<td align="left">2013</td>
<td align="left">Fertilizer production</td>
<td align="left">1.00&#x2013;1.00</td>
<td align="left">EOR application</td>
</tr>
<tr>
<td align="left">&#x2003;Enid fertilizer</td>
<td align="left">Operating</td>
<td align="left">United States</td>
<td align="left">1982</td>
<td align="left">Fertilizer production</td>
<td align="left">0.70&#x2013;0.70</td>
<td align="left">EOR application</td>
</tr>
<tr>
<td align="left">&#x2003;Sinopec eastern China CCS</td>
<td align="left">In development</td>
<td align="left">China</td>
<td align="left">2020&#x2013;2021</td>
<td align="left">Fertilizer production</td>
<td align="left">0.50&#x2013;0.50</td>
<td align="left">EOR application</td>
</tr>
</tbody>
</table>
<table>
<thead valign="top">
<tr>
<td colspan="7" align="center">B Key CCUS pilot projects in China (<xref ref-type="bibr" rid="B31">Global CCS Institute, 2017</xref>)</td>
</tr>
<tr>
<td align="left"/>
<td align="center">Project name</td>
<td align="center">Capacity (ton/year)</td>
<td align="center">CCS source</td>
<td align="center">Technology for final storage</td>
<td colspan="2" align="center">Construction/Operation status</td>
</tr>
</thead>
<tbody valign="top">
<tr>
<td align="center">1</td>
<td align="center">CHNG Shanghai Shidongkou CCS project</td>
<td align="center">120,000</td>
<td align="center">Shanghai Shidongkou No. 2 power plant, phase ii project, USC unit</td>
<td align="center">Industrial utilization and food</td>
<td colspan="2" align="center">Commissioning in 2009, intermittent operation</td>
</tr>
<tr>
<td align="center">2</td>
<td align="center">CHNG Tianjin green coal power project</td>
<td align="center">100,000</td>
<td align="center">Tianjin, Binhai New District, 400&#xa0;MW IGCC unit</td>
<td align="center">Mostly for abandoned land oil and gas reservoirs</td>
<td colspan="2" align="center">Capture facility completed; storage facility delayed</td>
</tr>
<tr>
<td align="center">3</td>
<td align="center">Sinopec Shengli Oilfield CO<sub>2</sub> CCS and flooding demonstration</td>
<td align="center">Phase I: 40,000 Phase II: 1 million</td>
<td align="center">Shengli Power Plant Unit No. 5</td>
<td align="center">EOR</td>
<td colspan="2" align="center">Phase 1: operation in 2010</td>
</tr>
<tr>
<td align="center">4</td>
<td align="center">Sinopec Qilu petrochemical CCS project</td>
<td align="center">Phase I: 350,000 Phase II: 500,000</td>
<td align="center">Sinopec Qilu Petrochemical Co., Ltd. Coal Gasification Plant</td>
<td align="center">EOR</td>
<td colspan="2" align="center">Phase 1: CCS unit completed in 2017</td>
</tr>
<tr>
<td align="center">5</td>
<td align="center">Sinopec ZPEB CO<sub>2</sub>-EOR Project</td>
<td align="center">100,000</td>
<td align="center">Zhongyuan Refinery Flue Gas</td>
<td align="center">EOR</td>
<td colspan="2" align="center">CCS facility completed in 2015</td>
</tr>
<tr>
<td align="center">6</td>
<td align="center">Yanchang petroleum yulin chemical CCS</td>
<td align="center">50,000</td>
<td align="center">Shaanxi Yanchang Petroleum Yulin Coal Chemical Co., Ltd. gasification plant</td>
<td align="center">EOR</td>
<td colspan="2" align="center">Completed in 2012 in operation</td>
</tr>
<tr>
<td align="center">7</td>
<td align="center">Shenhua Erdos full process demonstration</td>
<td align="center">100,000</td>
<td align="center">Shenhua Coal-to-Liquid Chemical Co., Ltd.</td>
<td align="center">CO<sub>2</sub> storage in saline aquifers</td>
<td colspan="2" align="center">Commissioning in 2011, intermittent operation</td>
</tr>
<tr>
<td rowspan="2" align="center">8</td>
<td rowspan="2" align="center">PetroChina Jilin Oilfield EOR demonstration</td>
<td align="center">Phase I: 150,000</td>
<td rowspan="2" align="center">New Natural Gas Plant in Songyuan City, Jilin Province</td>
<td rowspan="2" align="center">EOR</td>
<td colspan="2" align="center">Phase I: commissioning in 2007</td>
</tr>
<tr>
<td align="center">Phase II 500,000</td>
<td colspan="2" align="center">Phase II: commissioning in 2017, with size reduced</td>
</tr>
<tr>
<td align="center">9</td>
<td align="center">CPI Chongqing Shuangyu Power Plant CCS demonstration project</td>
<td align="center">10,000</td>
<td align="center">Chongqing Hechuan Shuangyu Power Plant Phase I 1&#x23; 300&#xa0;MW unit boiler</td>
<td align="center">Welding protection, hydrogen cooling replacement for generatoretc.</td>
<td colspan="2" align="center">Commissioning in 2010, in operation</td>
</tr>
<tr>
<td align="center">10</td>
<td align="center">HUST 35&#xa0;MW oxyfuel combustion project</td>
<td align="center">100,000</td>
<td align="center">Hubei Jiuda (Yingcheng) Co., Ltd. Thermal Power Plant II</td>
<td align="center">industrial application</td>
<td colspan="2" align="center">Completed in 2014, operation suspended</td>
</tr>
<tr>
<td align="center">11</td>
<td align="center">Lianyungang clean coal energy power system research facilities</td>
<td align="center">30,000</td>
<td align="center">Lianyungang 400&#xa0;MW IGCC</td>
<td align="center">CO<sub>2</sub> storage in saline aquifers</td>
<td colspan="2" align="center">Commissioning in 2011, in operation</td>
</tr>
<tr>
<td align="center">12</td>
<td align="center">Xinjiang Dunhua Oil Co., Ltd. Project</td>
<td align="center">60,000</td>
<td align="center">Xinjiang Dunhua Oil, Refinery Exhaust</td>
<td align="center">EOR</td>
<td colspan="2" align="center">Commissioning in 2015, in operation</td>
</tr>
<tr>
<td align="center">13</td>
<td align="center">China energy Guohua Jinjie power plant CCS full process demonstration project</td>
<td align="center">150,000</td>
<td align="center">Coal-fired power plant flue gas</td>
<td align="center">Storage/EOR</td>
<td colspan="2" align="center">To be completed in 2019</td>
</tr>
<tr>
<td align="center">14</td>
<td align="center">CR Haifeng project</td>
<td align="center">20,000</td>
<td align="center">Guangdong coal-fired power plant flue gas</td>
<td align="center">CO<sub>2</sub> food grade/industrial grade</td>
<td colspan="2" align="center">Commissioning in 2019</td>
</tr>
</tbody>
</table>
</table-wrap>
<p>Major economies have implemented CCS demonstration projects and gained commercial scale. These are evidenced in Australia, the US France, Norway, and China. There were 37 large-scale CCS/CCUS integrated projects, each having a recycling capacity of more than 400,000&#xa0;tons/year as of October 2017 (<xref ref-type="bibr" rid="B29">Geeta and Prabu, 2017</xref>). Seventeen of them operate with an overall CO<sub>2</sub> capture capacity of 30&#xa0;million tons/year. In North America, there are 10 EOR projects and 2 salt storage projects. In South America, particularly Brazil, there is 1 EOR project, Norway has 2 salt storage developments, and the Middle East has 2 salt storage projects. CCS/CCUS technology is emerging quickly in China, and numerous marketable demonstration projects are being effectively implemented (<xref ref-type="bibr" rid="B84">Wang et al., 2011</xref>). See <xref ref-type="table" rid="T7">Table 7</xref>.</p>
<table-wrap id="T7" position="float">
<label>TABLE 7</label>
<caption>
<p>CO<sub>2</sub> Utilization Projects and Key UCG projects and developments in 2017.</p>
</caption>
<table>
<thead valign="top">
<tr>
<th colspan="7" align="center">A CO<sub>2</sub> utilization projects</th>
</tr>
<tr>
<th align="left">Facility name</th>
<th align="left">Facility status</th>
<th align="left">Country</th>
<th align="left">Operation date</th>
<th align="left">Facility industry</th>
<th align="left">Capture capacity (Mtpa)</th>
<th align="left">Summary (CO<sub>2</sub> utilization)</th>
</tr>
</thead>
<tbody valign="top">
<tr>
<td colspan="7" align="left">Steel Industry</td>
</tr>
<tr>
<td align="left">&#x2003;Arcelor mittal steelanol</td>
<td align="left">In construction</td>
<td align="left">Belgium</td>
<td align="left">mid&#x2010;2020s</td>
<td align="left">Iron and steel</td>
<td align="left">0.15&#x2013;0.15</td>
<td align="left">Bioethanol</td>
</tr>
<tr>
<td colspan="7" align="left">Cement Industry</td>
</tr>
<tr>
<td align="left">&#x2003;Skyonic carbon capture and mineralisation project</td>
<td align="left">Operational</td>
<td align="left">United States</td>
<td align="left"/>
<td align="left">Cement production</td>
<td align="left"/>
<td align="left">Sodium bicarbonate production</td>
</tr>
<tr>
<td colspan="7" align="left">Chemicals and petrochemicals</td>
</tr>
<tr>
<td align="left">&#x2003;SABIC carbon capture and Utilisation Project</td>
<td align="left">Operational</td>
<td align="left">Saudi Arabia</td>
<td align="left"/>
<td align="left">Chemical production</td>
<td align="left">0.40&#x2013;0.50</td>
<td align="left">Methanol, chemical and Urea production</td>
</tr>
<tr>
<td align="left">&#x2003;The valorisation carbone Qu&#xe9;bec (VCQ) Projec</td>
<td align="left">In construction</td>
<td align="left">Canada</td>
<td align="left">2019</td>
<td align="left">Chemical production</td>
<td align="left">0.00&#x2013;0.00</td>
<td align="left"/>
</tr>
<tr>
<td align="left">&#x2003;CO<sub>2</sub> Utilisation plants using the KM CDR process<sup>&#xae;</sup>
</td>
<td align="left">Operational</td>
<td align="left">Multiple</td>
<td align="left"/>
<td align="left">Industrial applications</td>
<td align="left"/>
<td align="left">Industrial/methanol production</td>
</tr>
<tr>
<td colspan="7" align="left">Hydrogen Production</td>
</tr>
<tr>
<td align="left">&#x2003;Port J&#xe9;r&#xf4;me CO<sub>2</sub> capture plant</td>
<td align="left">Operational</td>
<td align="left">France</td>
<td align="left">2015</td>
<td align="left">Hydrogen production</td>
<td align="left">0.10&#x2013;0.10</td>
<td align="left"/>
</tr>
<tr>
<td colspan="7" align="left">Fertilizer Production</td>
</tr>
<tr>
<td align="left">&#x2003;Alcoa kwinana carbonation plant</td>
<td align="left">Operational</td>
<td align="left">Australia</td>
<td align="left"/>
<td align="left">Fertilizer production</td>
<td align="left"/>
<td align="left">Carbonation</td>
</tr>
<tr>
<td colspan="7" align="left">Waste to energy (wte) industry</td>
</tr>
<tr>
<td align="left">&#x2003;Saga city waste incineration plant</td>
<td align="left">Operational</td>
<td align="left">Japan</td>
<td align="left">2016</td>
<td align="left">Waste Incineration</td>
<td align="left">0.00&#x2013;0.00</td>
<td align="left">Crop cultivation and algae culture</td>
</tr>
<tr>
<td align="left">&#x2003;Twence Waste&#x2010;to&#x2010;energy CO<sub>2</sub> capture and utilisation</td>
<td align="left">Operational</td>
<td align="left">Netherlands</td>
<td align="left">2014</td>
<td align="left">Waste Incineration</td>
<td align="left">0.00&#x2013;0.00</td>
<td align="left">Sodium bicarbonate production</td>
</tr>
<tr>
<td colspan="7" align="left">Other Industries</td>
</tr>
<tr>
<td align="left">&#x2003;CO<sub>2</sub> Utilisation Plants&#x2014;Europe</td>
<td align="left">Operational</td>
<td align="left">Multiple</td>
<td align="left"/>
<td align="left">Industrial applications</td>
<td align="left"/>
<td align="left"/>
</tr>
<tr>
<td align="left">&#x2003;CO<sub>2</sub> Recovery Plants in China</td>
<td align="left">Operational</td>
<td align="left">China</td>
<td align="left"/>
<td align="left">Industrial applications</td>
<td align="left"/>
<td align="left">Food and beverage</td>
</tr>
<tr>
<td align="left">&#x2003;CO<sub>2</sub> Utilisation plants&#x2014;North America</td>
<td align="left">Operational</td>
<td align="left">Multiple</td>
<td align="left"/>
<td align="left">Industrial applications</td>
<td align="left"/>
<td align="left"/>
</tr>
<tr>
<td align="left">&#x2003;CO<sub>2</sub> Utilisation plants&#x2014;Oceania Region</td>
<td align="left">Operating</td>
<td align="left">Multiple</td>
<td align="left"/>
<td align="left">Various</td>
<td align="left"/>
<td align="left">Food and beverage and industrial application</td>
</tr>
<tr>
<td align="left">&#x2003;CO<sub>2</sub> Utilisation plants using the Fluor Econamine FG process</td>
<td align="left">Operational</td>
<td align="left">Multiple</td>
<td align="left"/>
<td align="left">Various</td>
<td align="left"/>
<td align="left"/>
</tr>
<tr>
<td align="left">&#x2003;Saint&#x2010;Felicien pulp mill and greenhouse carbon capture project</td>
<td align="left">Operational</td>
<td align="left">Canada</td>
<td align="left">2018</td>
<td align="left">Pulp and paper production</td>
<td align="left">0.01&#x2013;0.01</td>
<td align="left">Vegetable greenhouse</td>
</tr>
</tbody>
</table>
<table>
<thead valign="top">
<tr>
<td colspan="4" align="center">B Key UCG projects and developments in 2017</td>
</tr>
<tr>
<td align="left">Company organisation</td>
<td align="left">Countries</td>
<td align="left">End product</td>
<td align="left">Scale</td>
</tr>
</thead>
<tbody valign="top">
<tr>
<td align="left">UCG Research Centres &#x2b;, Sino-coking, ENN Xinao, Seamwell, Honghi</td>
<td align="left">China</td>
<td align="left">Power generation, and chemicals, H2 for fuel cells</td>
<td align="left">25PJ/y, (792&#xa0;MWt)</td>
</tr>
<tr>
<td align="left">EU&#x2014;E4.1M Tops</td>
<td align="left">UK, Pl, NL, SA, CH, AU, US</td>
<td align="left">Coupled UCG_CCS Site Characterisation and risk</td>
<td align="left">Feasibility modelling, environment</td>
</tr>
<tr>
<td align="left">Coal of India, CMPDIL</td>
<td align="left">India</td>
<td align="left">Issuing Coal Blocks for UCG New Pilot study announced Mar17</td>
<td align="left">166MT and 178&#xa0;Mt &#x2b;5MWe pilot</td>
</tr>
<tr>
<td align="left">Mining/power companies</td>
<td align="left">Mongolia/Kazakhstan/Indonesia</td>
<td align="left">Power production</td>
<td align="left">not specified</td>
</tr>
<tr>
<td align="left">Polish national project</td>
<td align="left">Poland</td>
<td align="left">Awaiting new commercial partner</td>
<td align="left">1400&#xa0;h Pilot Scale</td>
</tr>
<tr>
<td align="left">Linc energy/carbon energy (in administration)</td>
<td align="left">Australia China</td>
<td align="left">Power, SNG and CTL applications (technology available)</td>
<td align="left">400&#xa0;MW&#x2013;750&#xa0;MW</td>
</tr>
<tr>
<td align="left">Leigh Creek Ltd., South Australia</td>
<td align="left">Australia</td>
<td align="left">Site characterisation complete. approval of pilot underway</td>
<td align="left">Power, SNG and fertilizers</td>
</tr>
<tr>
<td align="left">Yerostigas, Angren</td>
<td align="left">Uzbekistan</td>
<td align="left">Commercial steam for power plant continuous operation since 1960s</td>
<td align="left">100&#xa0;MW&#x2013;1200&#xa0;MW</td>
</tr>
<tr>
<td align="left">Eskom (also, Africa)</td>
<td align="left">S Africa</td>
<td align="left">Power generation, co firing and CCGT, further pilot work</td>
<td align="left">400&#xa0;MW</td>
</tr>
</tbody>
</table>
</table-wrap>
<sec id="s5-1">
<title>5.1 Industrial demonstration and application of CCS/CCUS in China</title>
<p>Under the guidance of national policy and with the support of government departments at all levels, China has built more than a dozen CCS demonstration facilities with a CO<sub>2</sub> capture capacity of over ten thousand tons in coal-fired power plants and coal chemical plants. The largest CO<sub>2</sub> capture capacity in these facilities is over 10&#xa0;million tons per year. In addition, CO<sub>2</sub> injection demonstrations have been conducted in the enhanced oil recovery and carbon storage industry, with the largest reserves exceeding 15&#xa0;million tons per year. Completed demonstration projects include 10&#xa0;million tons per year for brackish terrestrial CO<sub>2</sub> storage projects, microalgae carbon capture projects (<xref ref-type="bibr" rid="B31">Global CCS Institute, 2017</xref>). See <xref ref-type="table" rid="T6">Table 6</xref> for an overview of major CCUS pilot demonstration projects in China. <xref ref-type="table" rid="T8">Table 8</xref> shows key project events and the budget for the Shenhua CCS project.</p>
<table-wrap id="T8" position="float">
<label>TABLE 8</label>
<caption>
<p>Important procedures and cost of the Shenhua CCS project.</p>
</caption>
<table>
<thead valign="top">
<tr>
<th colspan="3" align="center">A important procedures of the shenhua CCS project</th>
</tr>
<tr>
<th align="center">Time of event [dd/mm/yyyy]</th>
<th colspan="2" align="center">Project key events</th>
</tr>
</thead>
<tbody valign="top">
<tr>
<td align="left">2007</td>
<td colspan="2" align="left">Approval of the pre-feasibility study proposal by US-DOE</td>
</tr>
<tr>
<td align="left">10/2008</td>
<td colspan="2" align="left">Initiation of the feasibility study</td>
</tr>
<tr>
<td align="left">08/06/2009</td>
<td colspan="2" align="left">Foundation of the project group</td>
</tr>
<tr>
<td align="left">25/12/2009</td>
<td colspan="2" align="left">Approval of the feasibility study report</td>
</tr>
<tr>
<td align="left">07/04/2010</td>
<td colspan="2" align="left">Completion of 3D seismic data field acquisition</td>
</tr>
<tr>
<td align="left">01/08/2010</td>
<td colspan="2" align="left">Completion of engineering design</td>
</tr>
<tr>
<td align="left">10/10/2010</td>
<td colspan="2" align="left">Cementing of the injection well</td>
</tr>
<tr>
<td align="left">18/11/2010</td>
<td colspan="2" align="left">Formation test in the injection well</td>
</tr>
<tr>
<td align="left">26/11/2010</td>
<td colspan="2" align="left">Completion of well test in the Majiagou formation</td>
</tr>
<tr>
<td align="left">02/12/2010</td>
<td colspan="2" align="left">Completion of acid fracturing and fluid drainage for the Majiagou formation</td>
</tr>
<tr>
<td align="left">06/12/2010</td>
<td colspan="2" align="left">Completion of well test in the Shanxi formation</td>
</tr>
<tr>
<td align="left">13/12/2010</td>
<td colspan="2" align="left">Completion of hydraulic fracturing and fluid drainage for the Shanxi formation</td>
</tr>
<tr>
<td align="left">22/12/2010</td>
<td colspan="2" align="left">Completion of well test in the Shihezi formation</td>
</tr>
<tr>
<td align="left">27/12/2010</td>
<td colspan="2" align="left">Completion of the monitoring well 1 (MW1)</td>
</tr>
<tr>
<td align="left">01&#x2212;06/01/2011</td>
<td colspan="2" align="left">Trial injection into the Shanxi and Shihezi formation</td>
</tr>
<tr>
<td align="left">09&#x2212;23/05/2011</td>
<td colspan="2" align="left">The 1st testing injection</td>
</tr>
<tr>
<td align="left">30/05/2011</td>
<td colspan="2" align="left">Start of the 1st formal injection</td>
</tr>
<tr>
<td align="left">16/09/2011</td>
<td colspan="2" align="left">Start of the 2nd formal injection</td>
</tr>
<tr>
<td align="left">23/06/2012&#x2212;03/07/2012</td>
<td colspan="2" align="left">The 2nd testing injection</td>
</tr>
<tr>
<td align="left">09/2013</td>
<td colspan="2" align="left">The 3rd testing injection</td>
</tr>
<tr>
<td align="left">09/2014</td>
<td colspan="2" align="left">The 4th testing injection</td>
</tr>
<tr>
<td align="left">04/2015</td>
<td colspan="2" align="left">End of injection and close of the injection well</td>
</tr>
</tbody>
</table>
<table>
<thead valign="top">
<tr>
<td colspan="3" align="center">B Cost of the Shenhua CCS project (<xref ref-type="bibr" rid="B31">Global CCS Institute, 2017</xref>)</td>
</tr>
<tr>
<td align="left">Budget terms</td>
<td align="left">Cost [USD]</td>
<td align="left">Percent [%]</td>
</tr>
</thead>
<tbody>
<tr>
<td align="left">Construction</td>
<td align="left">5,620,796</td>
<td align="char" char=".">18.32</td>
</tr>
<tr>
<td align="left">Materials</td>
<td align="left">4,635,547</td>
<td align="char" char=".">15.11</td>
</tr>
<tr>
<td align="left">Installation</td>
<td align="left">919,237</td>
<td align="char" char=".">3.00</td>
</tr>
<tr>
<td align="left">Capture and transportation</td>
<td align="left">766,762</td>
<td align="char" char=".">2.50</td>
</tr>
<tr>
<td align="left">Surface storage equipment</td>
<td align="left">448,859</td>
<td align="char" char=".">1.46</td>
</tr>
<tr>
<td align="left">Subsurface equipment</td>
<td align="left">12,703,810</td>
<td align="char" char=".">41.40</td>
</tr>
<tr>
<td align="left">Supporting system</td>
<td align="left">259,241</td>
<td align="char" char=".">0.84</td>
</tr>
<tr>
<td align="left">Miscellaneous</td>
<td align="left">5,329,545</td>
<td align="char" char=".">17.37</td>
</tr>
<tr>
<td align="left">Total</td>
<td align="left">30,683,797</td>
<td align="char" char=".">100.00</td>
</tr>
</tbody>
</table>
</table-wrap>
</sec>
<sec id="s5-2">
<title>5.2 Comparison of UCG generation costs with NGCC, IGCC, UCGCC and PC methods</title>
<sec id="s5-2-1">
<title>5.2.1 UGC base case cost evaluation without CCS</title>
<p>When UCG is fused with a CCS system, there is a reduction in the cost associated with CO<sub>2</sub> capture and compression. Therefore, one of the policies for sustaining worldwide energy demand is the effective application of UCG technology. Research by <xref ref-type="bibr" rid="B60">Ni and Jiang (2016)</xref> Shows the base case cost evaluation and relates the power generation cost of theoretical plants of NGCC, IGCC, UCGCC and PC lacking the installation of CCS systems. It was established that IGCC generated the maximum cost with a range from $104&#x2013;117/MWh. When the coal price dropped to $10/ton, the generation costs of PC and UCGCC were similar, at about $45/MWh.</p>
<p>Conversely, PC showed further coal price sensitivity and its price was more than the UCGCC when the coal price was higher than $10/ton. NGCC would show massive competitiveness with a price lower than UCGCC if the natural gas price was less than $4.50/GJ, or $4.85/kscf. Overall, the UCGCC generation cost was low ($45&#x2013;50/MWh) and showed less sensitivity towards the fuel price. The reason is that UCG joins both coal mining and utilization processes and evaluates only the royalties and severance fees. Thus, this saves substantial prices in obtaining coal, its storage, and handling.</p>
</sec>
<sec id="s5-2-2">
<title>5.2.2 Cost evaluation&#x2014;with CO<sub>2</sub> capture system (CCS)</title>
<p>
<xref ref-type="bibr" rid="B60">Ni and Jiang (2016)</xref> further conducted an experiment to relate the generation cost ($/MWh) and the cost of captured CO<sub>2</sub> by installing a Selexol pre-combustion capture system on IGCC and UCGCC plants. In addition, an amine post-combustion capture system was installed on the NGCC and PC plants. It was observed that IGCC-CCS had the peak cost. The cost gap between the IGCC and UCGCC was more significant in the CCS case than in the base case. This means there is a significant impact on the PC relative to the UCGCC when setting up the CCS system. Low fuel prices were recorded for the NGCC-CCS (below $4.50/GJ). Conversely, the UCGCC-CCS recorded decreased generation cost than the NGCC-CCS at increased fuel prices (above $4.50/GJ). It is evidenced that the highest CO<sub>2</sub> capture cost was recorded for the NGCC-CCS, followed by the IGCC-CCS and PC-CCS. UCGCC-CCS recorded the least cost for CO<sub>2</sub> capture. Decreased CO<sub>2</sub> capture cost obtained by the UCGCC process makes it a massive benefit in the CO<sub>2</sub> consumption market.</p>
</sec>
</sec>
<sec id="s5-3">
<title>5.3 UCG cost comparison with electricity and IGCC</title>
<p>UCG-based power plants are similar to IGCC power plants, except for surface gasifiers (<xref ref-type="bibr" rid="B7">Burton et al., 2006</xref>). A simplified comparison of the capital costs of UCG power plants and IGCC can be made by comparing the required process units and capacity. The published cost estimate of the IGCC process unit is based on the analysis of a GE airflow gasifier with a carbon capture function (<xref ref-type="bibr" rid="B7">Burton et al., 2006</xref>). According to the design configuration and simulation results, the main differences between UCG and IGCC ground equipment. By eliminating the surface gasification device and reducing the size of the ASU, the overall capital cost of the UCG power plant is expected to be saved by 33%.</p>
<p>Several studies have been published on the economics of IGCC power plants and pulverized coal power plants, the current standard. According to the information developed by <xref ref-type="bibr" rid="B7">Burton et al. (2006)</xref>, the cost of a supercritical pulverized coal (SCPC) power plant ranges from $1200 to $1460/kW. The same study estimates that the next-generation of IGCC power plants will be about 10% more expensive than the SCPC plants (vs. the current 20&#x2013;25% premium). These places the cost of IGCC plants at $1440 to $1750/kW current technology, and $1320 to $1600/kW (advanced technology). <xref ref-type="bibr" rid="B63">Peng et al. (2016)</xref> has estimated the cost of an IGCC plant at $1,350/kW, which is in the same range as that estimated by <xref ref-type="bibr" rid="B7">Burton et al. (2006)</xref> for the advanced technology IGCC plants.</p>
<p>Much research has been published on the economics of IGCC power plants and the current standard pulverized coal power plants (<xref ref-type="bibr" rid="B7">Burton et al., 2006</xref>) states that the charge range of supercritical pulverized coal (SCPC) power plants are between $1200 to $1460/kW. Furthermore, future IGCC power plants will be approximately 10% cost higher than the SCPC power plants. These bring the cost of the IGCC plant to current technology from $1440 to $1750/kW and $1320 to $1600/kW (advanced technology). <xref ref-type="bibr" rid="B63">Peng et al. (2016)</xref> and (<xref ref-type="bibr" rid="B7">Burton et al., 2006</xref>) estimates a similar cost range of the IGCC plant or the advanced technology IGCC plant to be $1350/kW.</p>
<p>Another indicator of cost competitiveness is electricity prices (COE). Estimates by <xref ref-type="bibr" rid="B63">Peng et al. (2016)</xref> place COE for IGCC plants and SCPC at $46.6/MWh and $49.9/MWh. An advanced competitive economic study (<xref ref-type="bibr" rid="B59">Nakaten et al., 2014</xref>) indicates that for UCG power generation, the Levelized COE is estimated at &#x20ac;49/MWh without CCS and &#x20ac;72/MWh with CCS. Regarding figures released by Ergo Exergy (<xref ref-type="bibr" rid="B52">Maev et al., 2018</xref>), UCG-IGCC plants significantly have lower COE and construction costs. The cost of capital for a 177&#xa0;MW plant presented by <xref ref-type="bibr" rid="B52">Maev et al. (2018)</xref> is approximately $600/KW and $450/KW for a 280&#xa0;MW plant. The COE is projected to be around $12/MWh. According to <xref ref-type="bibr" rid="B32">Green (2018)</xref>, CO<sub>2</sub> emissions from UCG power generation using combined cycle gas turbine (CCGT) range from 570 to 785&#xa0;kg CO<sub>2</sub>/MWh without resources to CCS, compared to 400&#xa0;kg CO<sub>2</sub>/MWh natural gas. CCS can decrease UCG emissions to less than 100&#xa0;kg CO<sub>2</sub>/MWh. These remarkable figures make UCG comparable to renewable energy and achieve the highest fossil fuel emissions in CCS.</p>
</sec>
<sec id="s5-4">
<title>5.4 Recent and key UCG developments worldwide</title>
<p>Recently, UCG projects are common in China, South Africa, and Australia. These projects have chemical plants or operating power plants powered by UCG syngas. However, in Canada and the US, these projects are still in their development stages (<xref ref-type="bibr" rid="B10">Clean Air Task Force Report, 2009</xref>). Studies by <xref ref-type="bibr" rid="B7">Burton et al. (2006)</xref> state that the recent promising blend of technological features offers a commercially viable opportunity for the UCG process by enhancing the UCG technical variables and lowering the extreme effect on the environment. The same studies indicate that the first nation to introduce a general program for UCG R&#x26;D was USSR. By 1928, different national research projects had been organized, and in 1933 underground experiments began in Kurtova, Tula, Shati, Rennis-Kuznets, Korevka, and Lysychansk. While carrying out the experimental plan, theoretical plan and laboratory research were also carried out.</p>
<p>Currently, in the US, there are no UCG facilities in operation, and no major company is working on UCG research, but many other research projects are underway. In other regions, UCG projects have set off a new upsurge (<xref ref-type="bibr" rid="B15">Dalton, 2004</xref>) demonstrates the primary UCG projects overseas in the 20th century (from 1934 to 1997). Primary UCG projects from 2007 to 2011. In 2017, <xref ref-type="bibr" rid="B29">Geeta and Prabu (2017)</xref> pointed out that UCG activities were intense in many countries, which signifies a reduction in global UCG development 3&#xa0;years ago. <xref ref-type="table" rid="T7">Table 7</xref> shows the major UCG schemes and progresses in 2017.</p>
<p>The Chinese government has decided to develop the UCG project to reduce the pollution of coal-fired power plants, Private companies, like Seamwell Int. Hongli Clean Energy and others continue to maintain an interest in UCG feasibility and semi-commercial studies, mainly in Inner Mongolia, for the production of chemicals and power from UCG syngas (<xref ref-type="bibr" rid="B43">Khadse et al., 2007</xref>). According to <xref ref-type="bibr" rid="B13">Daggupati et al. (2010)</xref>, this places UCG test centers in China to approximately 15 (<xref ref-type="bibr" rid="B6">Blinderman, 2005</xref>).</p>
</sec>
</sec>
<sec id="s6">
<title>6 Concluding remarks and future works</title>
<p>This paper has provided an overview of UCG coupled with the CCS/CCUS technology process. These technologies emerge as excellent green technology which will keep global warming in check along with securing energy demands. From the above study, the following conclusions can be drawn;<list list-type="simple">
<list-item>
<p>&#x2022; Although the knowledge of UCG is not current and can be traced back about 100&#xa0;years ago, most global coal-producing regions have recently renewed interest in UCG technology. UCG is an integrative process because it involves different engineering phases (chemical, drilling, geotechnical) and connected disciplines (hydrogeology, hydrology).</p>
</list-item>
<list-item>
<p>&#x2022; The processes by which UCG promotes carbon capture are identical to surface-based IGCC. However, UCG has no ash treatment plants, coal mining, or surface gasification. Therefore, under equal settings, the general thermal efficiency of the UCG power plant is higher than the equivalent surface IGCC, and the CO<sub>2</sub> intensity is lower, especially considering the general CO<sub>2</sub> emissions, including CO<sub>2</sub> emissions from coal mining.</p>
</list-item>
<list-item>
<p>&#x2022; Countries most interested and active in R&#x26;D UCG projects are the US, China, South Africa, United Kingdom, India, Poland, Canada, Australia, and Hungary.</p>
</list-item>
<list-item>
<p>&#x2022; The Countries closest to UCG commercialization are China, South Africa, and North America. Presently, South Africa is ahead of the commercialization of UCG, investing more than $100&#xa0;million in three major electricity projects.</p>
</list-item>
<list-item>
<p>&#x2022; Many developments in the aforesaid countries rely on CRIP UCG technology developed in the United States in 1975 by the Lawrence Livermore National Laboratory. However, most UCG projects, both in operation and presently under expansion over the last 20&#xa0;years, use UCG technology from Canadas Ergo Exergy Technologies. In addition, several Ergo Energy&#x2019;s UCG projects are under consideration in Canada, India, Turkey, <italic>Argentina</italic>, and Pakistan.</p>
</list-item>
<list-item>
<p>&#x2022; High UCG practicability to be carried out in a CO<sub>2</sub> mode is a promptly accessible enhancer for gasification. For proficient gasification, preheating the CO<sub>2</sub> as a gasifying medium to high temperatures is cost-effective relative to the generation of superheated steam in a UCG steam-based operation.</p>
</list-item>
<list-item>
<p>&#x2022; Chemical absorption-based PCC technology is a short-term practical option for deploying marketable CCS. This technology has been widely validated through pilot plant testing, and various aspects of the technology have been investigated through modeling and simulation. Marketable products for modeling and simulating such developments are now available along with the technology and can be store-bought from various vendors such as Alstom, Shell, and Siemens.</p>
</list-item>
</list>
</p>
</sec>
</body>
<back>
<sec id="s7">
<title>Author contributions</title>
<p>ST: data curation and writing&#x2014;original draft preparation. YZ: supervision. MS: conceptualization, methodology, software, and investigation. FZ: formal analysis and revision. YL: english language modification. PT: writing&#x2014;reviewing and editing.</p>
</sec>
<sec id="s8">
<title>Funding</title>
<p>The authors acknowledge the financial supports of the National Natural Science Foundation of China (51974033, 52274060, 52206218), the National Overseas Study Foundation of China (201708420106), the Yangtze Youth Talents Fund (No. 2015cqt01) and the Natural Science and Engineering Research Council of Canada.</p>
</sec>
<sec sec-type="COI-statement" id="s9">
<title>Conflict of interest</title>
<p>The authors declare that the research was conducted in the absence of any commercial or financial relationships that could be construed as a potential conflict of interest.</p>
</sec>
<sec sec-type="disclaimer" id="s10">
<title>Publisher&#x2019;s note</title>
<p>All claims expressed in this article are solely those of the authors and do not necessarily represent those of their affiliated organizations, or those of the publisher, the editors and the reviewers. Any product that may be evaluated in this article, or claim that may be made by its manufacturer, is not guaranteed or endorsed by the publisher.</p>
</sec>
<ref-list>
<title>References</title>
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<citation citation-type="book">
<collab>APEC</collab> (<year>2019</year>). <source>APEC energy working Group 2019 exchange and training on clean coal technology and clean energy policy</source>. <publisher-loc>Beijing, China</publisher-loc>: <publisher-name>SOM Steering Committee on Economic and Technical Cooperation (SCE), Energy Working Group (EWG)</publisher-name>.</citation>
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