AUTHOR=Salman Muhammad , Beguin Brieuc , Nyssen Thomas , Léonard Grégoire TITLE=Techno-economic analysis of AMP/PZ solvent for CO2 capture in a biomass CHP plant: towards net negative emissions JOURNAL=Frontiers in Energy Research VOLUME=Volume 12 - 2024 YEAR=2024 URL=https://www.frontiersin.org/journals/energy-research/articles/10.3389/fenrg.2024.1325212 DOI=10.3389/fenrg.2024.1325212 ISSN=2296-598X ABSTRACT=Compared to conventional monoethanolamine (MEA), alternative solvents are expected to substantially contribute to reduce the energy demand of post-combustion CO2 capture from flue gases. This study presents a comprehensive techno-economic analysis of a 27 wt% 2-amino-2methyl-1-propanol (AMP) + 13 wt% piperazine (PZ) aqueous solution for CO2 capture, compared to a 30 wt% MEA. The study addresses the retrofit of a carbon capture unit to a biomass-fired combined heat and power (CHP) plant, effectively making it bioenergy with a carbon capture and storage (BECCS) system. The treated flue gas has a flow rate of 23 tons/hour (t/h) with 11.54 vol% CO2 and a 90% capture rate is aimed for. Aspen Plus V14 was employed for process simulations.Initially, binary interaction parameters for AMP/PZ, AMP/H2O, and PZ/H2O are regressed using vapor-liquid equilibrium (VLE) data, which were retrieved from literature along with reaction kinetics. Validation of parameters from available experimental literature yields an average absolute relative deviation (AARD) of only 5.9%. Afterwards, a process simulation model is developed and validated against experimental data from a reference pilot plant, using a similar AMP/PZ blend, resulting in 5% AARD. Next, a sensitivity analysis optimizes operating conditions, including solvent rate, absorber/stripper packing heights, and stripper pressure, based on regeneration energy impact. Optimized results, compared to MEA, reveal that AMP/PZ reduces the energy consumption from 3.61 to 2.86 GJ/tCO2. The retrofitting of the capture unit onto the selected CHP plant is examined through the development of a dedicated model. Two control strategies are compared to address energy unavailability for supplying the capture unit. The analysis spans four months, selected to account for seasonal variations. At nominal capacity, CO2 emissions, rendered negative by biomass combustion and CO2 capture, reach a maximum of -3.4 tCO2/h compared to 0.36 tCO2/h before retrofitting. Depending on the control strategy and CHP plant operating point, the Specific Primary Energy Consumption for CO2 Avoided (SPECCA) ranges from 4.91 MJ/kgCO2 to 1.76 MJ/kgCO2. Finally, an economic comparison based on systematic methodology reveals a 7.87% reduction in capture cost favoring the AMP/PZ blend.Together, these findings highlight AMP/PZ as a highly favorable alternative solvent.