AUTHOR=Kuhnert Eveline , Heidinger Mathias , Bernroitner Anna , Kiziltan Özge , Berger Erwin , Hacker Viktor , Bodner Merit TITLE=Fluoride emission rate analysis in proton exchange membrane water electrolyzer cells JOURNAL=Frontiers in Energy Research VOLUME=Volume 12 - 2024 YEAR=2024 URL=https://www.frontiersin.org/journals/energy-research/articles/10.3389/fenrg.2024.1457310 DOI=10.3389/fenrg.2024.1457310 ISSN=2296-598X ABSTRACT=

The assessment of PEM water electrolyzer (PEMWE) degradation is essential for understanding their long-term durability and performance under real-world conditions. This research focuses on the fluoride emission rate (FER) as a crucial parameter during PEMWE operation. Two different FER analysis methods were evaluated, considering their feasibility and ease of integration into a PEMWE system. Various stressors were examined to gain insights into membrane degradation and explore potential mitigation strategies. The utilization of a photometric detection method allowed for the quantification of FER in each test. Results highlight a noteworthy correlation between applied stressors and FER, with variations depending on specific test conditions. An accelerated stress test conducted for 100 hours revealed a high FER at the anode of 0.83 μg h−1 cm−2 during the initial phase. Correspondingly, energy dispersive X-ray (EDX) mapping showed a reduction in Nafion™ content on the catalyst-coated membrane (CCM) surfaces, likely impacting proton conductivity and performance. Electrochemical results further support these findings, indicating performance changes corresponding to the observed membrane degradation.