AUTHOR=Wu Yu-Cheng , Yang Yu , Tan Xiao-Yue , Luo Laima , Zan Xiang , Zhu Xiao-Yong , Xu Qiu , Cheng Ji-Gui 

TITLE=Preparation Technology of Ultra-Fine Tungsten Carbide Powders: An Overview

JOURNAL=Frontiers in Materials

VOLUME=Volume 7 - 2020

YEAR=2020

URL=https://www.frontiersin.org/journals/materials/articles/10.3389/fmats.2020.00094

DOI=10.3389/fmats.2020.00094

ISSN=2296-8016

ABSTRACT=Ultra-fine tungsten carbide (WC) powder refers to WC powders with a particle size between 100 to 500 nm. Researchers have improved the comprehensive properties of WC-based cemented carbides by preparing ultra-fine WC powders. Because of the preparation and application of nano-scale WC powders, ultrafine-grain cemented carbides with excellent hardness and wear resistance have been successfully produced. In this paper, the preparation methods of ultra-fine WC powder are divided into solid-phase, liquid-phase, and vapor-phase methods according to the state of the raw materials (i.e., the W or C source). The liquid-phase methods could realize the preparation of WC at the temperature between 500 - 800 °C. The purity of WC prepared by vapor-phase method is the highest. The solid-phase reduction carbonization method has potential industrial application.