AUTHOR=Chen Jiayu , Wu Anni , Zhang Yumin , Xie Yongfeng , Zheng Hu , Teng Wei 

TITLE=A mini-review on high-entropy alloy nanomaterials for electrocatalysis: advances and prospects

JOURNAL=Frontiers in Materials

VOLUME=Volume 12 - 2025

YEAR=2025

URL=https://www.frontiersin.org/journals/materials/articles/10.3389/fmats.2025.1613997

DOI=10.3389/fmats.2025.1613997

ISSN=2296-8016

ABSTRACT=High-entropy alloy nanomaterials (HEA-NMs), composed of multiple metallic elements, offer tunable electronic structures, abundant active sites, and excellent stability, making them highly promising for electrocatalysis. This mini-review summarizes their structural effects influencing electrocatalytic behavior, recent advances in synthesis strategies, and electrocatalytic applications, including the hydrogen evolution reaction (HER), oxygen evolution reaction (OER), oxygen reduction reaction (ORR), carbon dioxide reduction reaction (CO2RR), and nitrate reduction reaction (NO3RR). Challenges in synthesis scalability and mechanistic probing are discussed, along with future directions for atomic-level design and data-driven catalyst optimization. HEA-NMs offer a versatile platform for sustainable energy and environmental electrocatalysis.