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<front>
<journal-meta>
<journal-id journal-id-type="publisher-id">Front. Mech. Eng</journal-id>
<journal-title>Frontiers in Mechanical Engineering</journal-title>
<abbrev-journal-title abbrev-type="pubmed">Front. Mech. Eng</abbrev-journal-title>
<issn pub-type="epub">2297-3079</issn>
<publisher>
<publisher-name>Frontiers Media S.A.</publisher-name>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="publisher-id">991579</article-id>
<article-id pub-id-type="doi">10.3389/fmech.2022.991579</article-id>
<article-categories>
<subj-group subj-group-type="heading">
<subject>Mechanical Engineering</subject>
<subj-group>
<subject>Original Research</subject>
</subj-group>
</subj-group>
</article-categories>
<title-group>
<article-title>Meeting future NO<sub>X</sub> emission regulations by adding an electrically heated mixer</article-title>
<alt-title alt-title-type="left-running-head">Meruva et al.</alt-title>
<alt-title alt-title-type="right-running-head">
<ext-link ext-link-type="uri" xlink:href="https://doi.org/10.3389/fmech.2022.991579">10.3389/fmech.2022.991579</ext-link>
</alt-title>
</title-group>
<contrib-group>
<contrib contrib-type="author">
<name>
<surname>Meruva</surname>
<given-names>P.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
<uri xlink:href="https://loop.frontiersin.org/people/1868230/overview"/>
</contrib>
<contrib contrib-type="author">
<name>
<surname>Matheaus</surname>
<given-names>A.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
<uri xlink:href="https://loop.frontiersin.org/people/1764951/overview"/>
</contrib>
<contrib contrib-type="author">
<name>
<surname>Sharp</surname>
<given-names>C. A.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author">
<name>
<surname>McCarthy</surname>
<given-names>J. E.</given-names>
<suffix>Jr</suffix>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
<uri xlink:href="https://loop.frontiersin.org/people/258995/overview"/>
</contrib>
<contrib contrib-type="author" corresp="yes">
<name>
<surname>Masoudi</surname>
<given-names>M.</given-names>
</name>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
<xref ref-type="corresp" rid="c001">&#x2a;</xref>
<uri xlink:href="https://loop.frontiersin.org/people/1909732/overview"/>
</contrib>
<contrib contrib-type="author">
<name>
<surname>Poliakov</surname>
<given-names>N.</given-names>
</name>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
</contrib>
<contrib contrib-type="author">
<name>
<surname>Noorfeshan</surname>
<given-names>S.</given-names>
</name>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
</contrib>
</contrib-group>
<aff id="aff1">
<label>
<sup>1</sup>
</label>
<institution>Southwest Research Institute (SwRI)</institution>, <addr-line>San Antonio</addr-line>, <addr-line>TX</addr-line>, <country>United States</country>
</aff>
<aff id="aff2">
<label>
<sup>2</sup>
</label>
<institution>Eaton</institution>, <addr-line>Galesburg</addr-line>, <addr-line>MI</addr-line>, <country>United States</country>
</aff>
<aff id="aff3">
<label>
<sup>3</sup>
</label>
<institution>Emissol LLC</institution>, <addr-line>Mill Creek</addr-line>, <addr-line>WA</addr-line>, <country>United States</country>
</aff>
<author-notes>
<corresp id="c001">&#x2a;Correspondence: M. Masoudi, <email>mansour.masoudi@emissol.com</email>
</corresp>
<fn fn-type="other">
<p>This article was submitted to Engine and Automotive Engineering, a section of the journal Frontiers in Mechanical Engineering</p>
</fn>
<fn fn-type="edited-by">
<p>
<bold>Edited by:</bold> <ext-link ext-link-type="uri" xlink:href="https://loop.frontiersin.org/people/948731/overview">Jinlong Liu</ext-link>, Zhejiang University, China</p>
</fn>
<fn fn-type="edited-by">
<p>
<bold>Reviewed by:</bold> <ext-link ext-link-type="uri" xlink:href="https://loop.frontiersin.org/people/1575181/overview">Ruomiao Yang</ext-link>, Zhejiang Chinese Medical University, China</p>
<p>
<ext-link ext-link-type="uri" xlink:href="https://loop.frontiersin.org/people/1899118/overview">Wanhui Zhao</ext-link>, Civil Aviation University of China, China</p>
<p>
<ext-link ext-link-type="uri" xlink:href="https://loop.frontiersin.org/people/1910776/overview">Juan Ou</ext-link>, Xihua University, China</p>
<p>
<ext-link ext-link-type="uri" xlink:href="https://loop.frontiersin.org/people/1838887/overview">Ziming Yan</ext-link>, Clemson University, United States</p>
</fn>
</author-notes>
<pub-date pub-type="epub">
<day>17</day>
<month>10</month>
<year>2022</year>
</pub-date>
<pub-date pub-type="collection">
<year>2022</year>
</pub-date>
<volume>8</volume>
<elocation-id>991579</elocation-id>
<history>
<date date-type="received">
<day>11</day>
<month>07</month>
<year>2022</year>
</date>
<date date-type="accepted">
<day>02</day>
<month>08</month>
<year>2022</year>
</date>
</history>
<permissions>
<copyright-statement>Copyright &#xa9; 2022 Meruva, Matheaus, Sharp, McCarthy, Masoudi, Poliakov and Noorfeshan.</copyright-statement>
<copyright-year>2022</copyright-year>
<copyright-holder>Meruva, Matheaus, Sharp, McCarthy, Masoudi, Poliakov and Noorfeshan</copyright-holder>
<license xlink:href="http://creativecommons.org/licenses/by/4.0/">
<p>This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.</p>
</license>
</permissions>
<abstract>
<p>New regulations by the California Air Resources Board (CARB) demand a stringent 0.02&#xa0;g/hp-hr tailpipe NO<sub>x</sub> limit by the year 2027, requiring Selective Catalytic Reduction (SCR) catalysts to provide high NO<sub>x</sub> conversions even at low (below 200&#xb0;C) exhaust temperatures. This work describes utilizing an Electrically Heated Mixer System (EHM system) upstream of a Light-Off Selective Catalytic Reduction (LO-SCR) catalyst followed by a conventional aftertreatment (AT) system containing DOC, DPF, and SCR, enabling high NO<sub>x</sub> conversions meeting CARB&#x2019;s NO<sub>x</sub> emission target. The AT catalysts were hydrothermally aged to Full Useful Life. Conventional unheated Diesel Exhaust Fluid (DEF) was injected upstream of both the LO-SCR and primary downstream SCR. The EHM system allowed for DEF to be injected as low as 130&#xb0;C upstream of the LO-SCR, whereas, in previous studies, unheated DEF was injected at 180&#xb0;C or dosed at 130&#xb0;C with heated DEF. The combination of unheated DEF, EHM system, LO-SCR, and downstream SCR enabled the needed increase in NO<sub>x</sub> efficiency in low exhaust temperatures, which was observed in drive cycles such as in cold-FTP, LLC, and World Harmonized Transient Cycle (WHTC). There were several-fold reductions in tailpipe NO<sub>x</sub> using this configuration compared to its baseline: 3.3-fold reduction in FTP, 22-fold in Low Load Cycle (LLC), 38-fold in Beverage Cycle, 8-fold in &#x201c;Stay Hot&#x201d; Cycle, and 10-fold in WHTC. Finally, it is shown that the EHM system can heat the exhaust gas, such as during a cold start, without needing additional heating hardware integrated into the system. These results were observed without performing changes in the engine base calibration.</p>
</abstract>
<kwd-group>
<kwd>heated mixer</kwd>
<kwd>advanced aftertreatment</kwd>
<kwd>reduced NOx emissions</kwd>
<kwd>electric heater</kwd>
<kwd>increase exhaust temperature</kwd>
<kwd>130&#xb0;C DEF injection</kwd>
</kwd-group>
</article-meta>
</front>
<body>
<sec id="s1">
<title>Introduction</title>
<p>The concerning issue of pollution requires immediate action for a better global environment. Air pollution is one of the major concerns as it directly impacts our daily lives. One of the prime contributors to air pollution is vehicle emissions. With the ongoing increase in on-road vehicles and the high demand for new vehicles in the future, the California Air Resources Board (CARB) has initiated the Omnibus NO<sub>x</sub> regulations for 2027 with a limit of 0.02&#xa0;g/hp-hr. While current regulations are at 0.2&#xa0;g/hp-hr, the new NO<sub>x</sub> regulations for the year 2027 require a 90% reduction from the current standard (<xref ref-type="bibr" rid="B2">California adopts strong new regulation to further reduce smog-forming pollution from heavy-duty diesel trucks, 2022</xref>). This requires a high NOx conversion on the order of 99.5% from the engine out (EO) NO<sub>x</sub> on a Federal Test Procedure (FTP) cycle in combination with the inclusion of the new Low Load Cycle (LLC). Meeting the NO<sub>x</sub> standards in addition to phase 2 Green House Gas (GHG) regulations (<xref ref-type="bibr" rid="B4">Greenhouse Gas Standards for Medium- and Heavy-Duty Engines and Vehicles, 2022</xref>) is required to move forward.</p>
<p>The current aftertreatment (AT) development shows that Selective Catalytic Reduction (SCR) helps convert the NO<sub>x</sub> in a vehicle. However, it needs to be at optimum temperatures to obtain good NO<sub>x</sub> conversion efficiency (<xref ref-type="bibr" rid="B18">Scott Sluder et al., 2005</xref>). This causes issues at low-temperature conditions such as cold start and Low Load Cycles (LLCs), as the SCR might not be hot enough to convert the incoming NO<sub>x</sub> from the engine. When the temperatures are too low, the possibility of Diesel Exhaust Fluid (DEF) injection reduces as there is a high possibility of deposit formation, which can corrode the system or even block the DEF injection. At this stage, the AT needs additional help from the engine or an external source.</p>
<p>Previous work shows that the addition of passive NO<sub>x</sub> adsorber (PNA) in the AT system was useful in reducing NO<sub>x</sub> emissions during the cold start (<xref ref-type="bibr" rid="B14">Milovanovic et al., 2016</xref>; <xref ref-type="bibr" rid="B1">Berndt, 2019</xref>). However, as the PNA has a limit for the NO<sub>x</sub> adsorption, this might not be very helpful, especially during an LLC where the exhaust temperatures are too low for a prolonged duration. <xref ref-type="bibr" rid="B20">Sharp et al. (2017</xref>) combined PNA with fuel burner technology upstream of a conventional AT system to reduce NO<sub>x</sub> to meet the CARB 2027 NO<sub>x</sub> regulations. The engine calibration was modified in this effort.</p>
<p>There has been modeling work recently to predict a reduction in NO<sub>x</sub> emissions to meet the 2027 regulations by using 48V electrical systems on the engine and AT system. <xref ref-type="bibr" rid="B3">Dhanraj et al. (2022</xref>) used a 48V electric technology package in the engine modeling, which included 48V E-Turbo, 48V EGR pump, friction reduction with down speeding, exhaust variable valve technology, and Cylinder Deactivation (CDA) for thermal management. This, coupled with a hydrocarbon dosing and a 48V Electrical Heater (E-Heater) on an advanced AT system model, achieved 0.015&#xa0;g/hp-hr NO<sub>x</sub> for composite FTP with &#x223c;1% reduction in CO<sub>2</sub> emissions.</p>
<p>Significant work has been done in recent years to meet the 2027 NO<sub>x</sub> regulations and in most of those works engine equipped with CDA projected a viable option (<xref ref-type="bibr" rid="B7">Joshi et al., 2017</xref>; <xref ref-type="bibr" rid="B16">Ramesh et al., 2018</xref>), which can help the AT system reach/maintain the optimum temperature to convert the NO<sub>x</sub>. Work was done in the past using a CDA engine equipped with a heated doser and a 48&#xa0;V electric heater, which has helped in even reducing CO<sub>2</sub> emissions by &#x223c; 2% compared to its baseline system (<xref ref-type="bibr" rid="B22">Zavala et al., 2022</xref>). A 2.4&#xa0;kW electric heater (E-Heater) in this system was proven useful in achieving 0.012&#xa0;g/hp-hr on a composite FTP (40% margin to CARB 2027).</p>
<p>There was another work using a fuel burner upstream of a standard AT system (without a LO-SCR) and equipped on a non-CDA engine where the overall FTP composite tailpipe (TP) NO<sub>x</sub> was at 0.023&#xa0;g/hp-hr, which was 15% above the regulatory limit with less than 1% fuel penalty (<xref ref-type="bibr" rid="B12">McCarthy et al., 2022</xref>). Later, CDA was added to this system, and the results were quantified with and without a LO-SCR; however, this work is not yet published.</p>
<p>The motivation for this work was to meet the 2027 NO<sub>x</sub> regulations with no additional support from a production engine (without CDA or engine calibration change) with an external heat source on an AT system. The recent works on the AT system to meet the 2027 NO<sub>x</sub> regulations include using a LO-SCR (<xref ref-type="bibr" rid="B8">Kasab et al., 2021</xref>; <xref ref-type="bibr" rid="B11">Matheaus et al., 2021</xref>; <xref ref-type="bibr" rid="B19">Sharp et al., 2021</xref>). This catalyst was added to a conventional AT system in this work. The AT was equipped with an Electrically Heated Mixer System (EHM system) upstream of the LO-SCR. The EHM system combines an Electrically Heated Mixer (EHM&#x2122;) and an embedded electric heater (E-heater&#x2122;). With the addition of the EHM System upstream of LO-SCR along with a conventional AT system coupled with a production engine, the CARB NO<sub>x</sub> regulations for the model year 2027 were achieved. This additional heat will also travel downstream of the primary AT system to aid in raising the catalyst temperatures. The following sections contain details about the engine and AT configurations, a description of the EHM system, and the AT controls, followed by the drive cycles tested and the results and conclusions.</p>
</sec>
<sec id="s2">
<title>Experimental setup</title>
<sec id="s2-1">
<title>Engine platform</title>
<p>The test engine used for this program was a production 2018 model year Cummins X15 engine with a 500 hp production calibration. The engine retained the production air handling system, Exhaust Gas Recirculation (EGR) system, internal components, and fuel system. The engine, as shown in <xref ref-type="fig" rid="F1">Figure 1</xref>, is an inline six-cylinder with a bore-to-stroke ratio of 0.8:1, displacement of 15 L, rate power of 373&#xa0;kW at 1,800&#xa0;rpm, and a peak torque of 2,500 Nm at 1,000&#xa0;rpm.</p>
<fig id="F1" position="float">
<label>FIGURE 1</label>
<caption>
<p>Cummins X15 engine platform installed in the test cell.</p>
</caption>
<graphic xlink:href="fmech-08-991579-g001.tif"/>
</fig>
<p>The engine is expected to run mainly in two different operating modes, commonly referred to in this work as thermal management (TM) and fuel economy (FE) modes. The authors attributed the transition between these operating modes of the engine to being triggered based on the downstream primary SCR temperature. As the names suggest, the engine runs on the TM mode when the downstream primary SCR temperature is low. During the TM mode, the engine generates more heat leading to low EO NO<sub>x</sub> and higher fuel consumption and <italic>vice versa</italic> in the case of the FE mode.</p>
</sec>
<sec id="s2-2">
<title>Aftertreatment configurations</title>
<p>The AT system used in this program was a Full Useful Life (FUL) hydrothermally aged system. An accelerated aging protocol (<xref ref-type="bibr" rid="B23">Zavala et al., 2020</xref>) was used to age the AT system by thermal exposure to FUL of 435,000 miles, similar to previous works (<xref ref-type="bibr" rid="B5">Harris et al., 2021</xref>; <xref ref-type="bibr" rid="B11">Matheaus et al., 2021</xref>; <xref ref-type="bibr" rid="B22">Zavala et al., 2022</xref>). These aged catalysts are commonly referred to as &#x201c;Development Aged&#x201d; end-of-life catalysts (<xref ref-type="bibr" rid="B19">Sharp et al., 2021</xref>). These Development Aged catalysts were not exposed to chemical aging such as sulfur and lubricant poisoning.</p>
<p>
<xref ref-type="fig" rid="F2">Figure 2A</xref> shows a schematic of the following production-intent AT system in several industry architectures. The AT system consists of a conventional DEF doser, LO-SCR, a Diesel Oxidation Catalyst (DOC), a Diesel Particulate Filter (DPF), and a compact mixer followed by SCR and Ammonia Slip Catalyst (ASC). Generally, such an advanced arrangement for the downstream conventional portion of DOC-DPF-SCR-ASC represents a 2022 production system. This combination of LO-SCR and conventional downstream AT is considered the &#x201c;baseline&#x201d; in this demonstration (<xref ref-type="bibr" rid="B13">Meruva et al., 2022</xref>). Unlike previous studies that used a heated DEF doser upstream of the LO-SCR (<xref ref-type="bibr" rid="B5">Harris et al., 2021</xref>; <xref ref-type="bibr" rid="B11">Matheaus et al., 2021</xref>; <xref ref-type="bibr" rid="B19">Sharp et al., 2021</xref>; <xref ref-type="bibr" rid="B22">Zavala et al., 2022</xref>), this study uses a standard DEF doser in both locations. Catalyst specifications are shown in <xref ref-type="table" rid="T1">Table 1</xref>.</p>
<fig id="F2" position="float">
<label>FIGURE 2</label>
<caption>
<p>
<bold>(A)</bold> Baseline aftertreatment system architecture with LO-SCR positioned close to the engine. <bold>(B)</bold> Aftertreatment system architecture with conventional DEF dosers and EHM system.</p>
</caption>
<graphic xlink:href="fmech-08-991579-g002.tif"/>
</fig>
<table-wrap id="T1" position="float">
<label>TABLE 1</label>
<caption>
<p>Advanced system catalyst specifications.</p>
</caption>
<table>
<thead valign="top">
<tr>
<th align="left">Component</th>
<th align="left">D &#xd7; L</th>
<th align="left">CPSI</th>
<th align="left">Volume (L)</th>
</tr>
</thead>
<tbody valign="top">
<tr>
<td align="left">LO-SCR</td>
<td align="left">13&#x2033; &#xd7; 6&#x2033;</td>
<td align="left">400</td>
<td align="left">13</td>
</tr>
<tr>
<td align="left">DOC</td>
<td align="left">13&#x2033; &#xd7; 5&#x2033;</td>
<td align="left">400</td>
<td align="left">11</td>
</tr>
<tr>
<td align="left">DPF</td>
<td align="left">13&#x2033; &#xd7; 7&#x2033;</td>
<td align="left">300</td>
<td align="left">15</td>
</tr>
<tr>
<td align="left">SCR</td>
<td align="left">13&#x2033; &#xd7; 6&#x2033;</td>
<td align="left">600</td>
<td align="left">13</td>
</tr>
<tr>
<td align="left">SCR-ASC</td>
<td align="left">13&#x2033; &#xd7; 6&#x2033;</td>
<td align="left">600</td>
<td align="left">13</td>
</tr>
</tbody>
</table>
</table-wrap>
<p>The focus of this work was to evaluate the addition of an EHM system upstream of the LO-SCR, with the remaining AT being the same as the baseline, as shown in <xref ref-type="fig" rid="F2">Figure 2B</xref>. The actual setup is pictured in <xref ref-type="fig" rid="F3">Figure 3</xref>. In this setup, the conventional mixer upstream of LO-SCR was replaced with the EHM system. The purpose of adding the EHM system was to heat up and maintain the LO-SCR at an optimal temperature for efficient NO<sub>x</sub> reduction, particularly for rapid heat up during cold start and/or during low-temperature drive cycles.</p>
<fig id="F3" position="float">
<label>FIGURE 3</label>
<caption>
<p>Engine and aftertreatment system, including EHM system and LO-SCR.</p>
</caption>
<graphic xlink:href="fmech-08-991579-g003.tif"/>
</fig>
</sec>
<sec id="s2-3">
<title>EHM system</title>
<p>The EHM system delivers heat to DEF droplets injected in the exhaust pipe, accelerating their conversion to the desired ammonia reductant. It is particularly helpful in lower exhaust temperatures or in low-load cycles while mitigating deposit formation. The EHM system comprises two sections: the EHM and its embedded E-heater. The EHM is the first section of the EHM system, which heats up, enabling DEF injection in exhaust temperatures as low as 130&#xb0;C. AT system might need additional heat depending on several factors such as engine calibration, cold start, or rapid heat up strategy, AT architecture, system demand or certification target. At these instances, the second section of the EHM system, which is the E-heater, helps in heating the exhaust gas and the downstream catalysts, accelerating catalyst warm-up, especially the SCR catalysts (light-off or primary). The EHM system was positioned upstream of the LO-SCR in this study. In this program, along with the E-heater, the heat generated by the EHM was also leveraged to heat the exhaust gas until the turbo-out temperature reached a certain target, after which the EHM would primarily heat the DEF. During the earlier state, the EHM&#x2019;s bed temperature would be higher than the latter.</p>
<p>
<xref ref-type="fig" rid="F4">Figures 4A,B</xref> show the EHM model and an EHM system model, respectively, each schematically connected to the controller. <xref ref-type="fig" rid="F4">Figure 4C</xref> shows an iso view of a model of the EHM system. The EHM system was designed to operate in 12, 24, or 48&#xa0;V systems. The demonstration in this work was conducted on a 48&#xa0;V system, with the first section of the EHM system (<xref ref-type="fig" rid="F4">Figure 4A</xref>) providing 3.8&#x2014;4&#xa0;kW and the second section (<xref ref-type="fig" rid="F4">Figures 4B,C</xref>) providing nearly 2&#xa0;kW, together about 6&#xa0;kW. Similar to the previous works with E-heaters (<xref ref-type="bibr" rid="B3">Dhanraj et al., 2022</xref>; <xref ref-type="bibr" rid="B22">Zavala et al., 2022</xref>), the EHM system also contains an E-heater embedded in it. EHM System was used to replace the conventional DEF doser mixer and heated doser as the EHM could heat the DEF with a conventional doser. The swirl plate at the end of the EHM system is used to distribute the flow into the cone upstream of the LO-SCR.</p>
<fig id="F4" position="float">
<label>FIGURE 4</label>
<caption>
<p>
<bold>(A)</bold> Electrically Heated Mixer (EHM) standalone with its controller. <bold>(B)</bold> EHM with its embedded E-heater (EHM system) with a controller. <bold>(C)</bold> Physical depiction of the EHM system.</p>
</caption>
<graphic xlink:href="fmech-08-991579-g004.tif"/>
</fig>
<p>A control algorithm managed the EHM system for heating the AT system. The controller receives signals from the CAN-bus (e.g., mass flow rate, exhaust temperature, DEF injection rate, and NO<sub>x</sub> sensor signal). The controller (i.e., in real time) readily manages the EHM system operations to minimize the power consumption while yielding the needed reductant concentration (ammonia), maximizing SCR efficiency, and mitigating deposit formation. In this program, the E-heater was controlled by the Model Based Controller (MBC) and the EHM was controlled by a separate controller.</p>
<p>
<xref ref-type="fig" rid="F5">Figure 5</xref> shows a representative control where the EHM and its embedded E-heater are controlled independently to raise the LO-SCR temperature to 130&#xb0;C, where DEF can then be injected. Once this is achieved, the power demand reduces. Actual power traces for this work are shown in the test results section. In this example, the E-heater was targeting 130&#xb0;C at the SCR temperature, and it shuts off once it is achieved. The maximum power capacity of the EHM is 4&#xa0;kW, and its embedded E-heater is 2&#xa0;kW.</p>
<fig id="F5" position="float">
<label>FIGURE 5</label>
<caption>
<p>Example of the EHM system operation during a cold start.</p>
</caption>
<graphic xlink:href="fmech-08-991579-g005.tif"/>
</fig>
</sec>
<sec id="s2-4">
<title>EHM system power</title>
<p>The EHM system is powered up by an external power supply in the engine test cell. The power was calculated by recording the voltage and current transmitted to them. This total power was fed to the dynamometer as a parasitic load onto the engine in real time, assuming an 80% generator efficiency consistent with previous works (<xref ref-type="bibr" rid="B11">Matheaus et al., 2021</xref>). This additional load was not accounted for in the cycle work, but the emissions resulting from this load were included in the test result analysis. <xref ref-type="disp-formula" rid="e1">Eq. 1</xref> shows the formula used for this calculation:<disp-formula id="e1">
<mml:math id="m1">
<mml:mrow>
<mml:mi>T</mml:mi>
<mml:mi>o</mml:mi>
<mml:mi>t</mml:mi>
<mml:mi>a</mml:mi>
<mml:mi>l</mml:mi>
<mml:mo>&#xa0;</mml:mo>
<mml:mi>E</mml:mi>
<mml:mi>n</mml:mi>
<mml:mi>g</mml:mi>
<mml:mi>i</mml:mi>
<mml:mi>n</mml:mi>
<mml:mi>e</mml:mi>
<mml:mo>&#xa0;</mml:mo>
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<label>(1)</label>
</disp-formula>
</p>
</sec>
<sec id="s2-5">
<title>Model-based SCR controller</title>
<p>This program used a model-based controller (MBC) for the upstream and downstream SCR catalysts (<xref ref-type="bibr" rid="B20">Sharp et al., 2017</xref>; <xref ref-type="bibr" rid="B17">Rao et al., 2020</xref>) to control the DEF injection, which is consistent with the baseline work (<xref ref-type="bibr" rid="B13">Meruva et al., 2022</xref>). The model tracks ammonia storage in each of the SCR bricks and has a target ammonia storage based on temperature. This work adapted the MBC to control the thermal management strategies to power on the flow heating capabilities of E-heater using the average LO-SCR temperature as the feedback.</p>
<p>Conventional DEF dosers were used during this work. The DEF dosing minimum temperature was set to 180&#xb0;C throughout the system for the baseline work (<xref ref-type="bibr" rid="B13">Meruva et al., 2022</xref>). The EHM system upstream of LO-SCR allowed the DEF dosing to begin at a lower temperature, down to 130&#xb0;C for the LO-SCR. The primary downstream SCR maintained a 180&#xb0;C dosing temperature consistent with previous work (<xref ref-type="bibr" rid="B19">Sharp et al., 2021</xref>). The DEF dosing trigger temperature was set to the average gas temperature of LO-SCR and the average gas temperature of the first primary SCR for the respective dosing. In this work, a conventional doser coupled with an EHM system was used to replace the heated DEF doser.</p>
<p>Dosing at low temperatures (130&#xb0;C) can be useful for increasing ammonia storage in the SCR catalyst early in the cycle. It has been demonstrated on both bench testing and engine testing (<xref ref-type="bibr" rid="B10">Masoudi et al., 2022a</xref>; <xref ref-type="bibr" rid="B9">Masoudi et al., 2022b</xref>) that EHM strongly promotes both ammonia storage and increased SCR NO<sub>x</sub> conversion efficiency.</p>
<p>With an advantage of better DEF atomization with the EHM system when compared to the baseline, the DEF injection strategy upstream of LO-SCR was modified to be more aggressive at low temperatures and less aggressive at high temperatures, assuming the primary SCR to be hot enough to help with the NO<sub>x</sub> conversion. This dosing strategy helps reduce NO<sub>x</sub> at lower temperatures while reducing the risk of ammonia slip from the primary SCR during high exhaust temperature operation.</p>
</sec>
<sec id="s2-6">
<title>Emission measurements</title>
<p>Raw exhaust measurements complying with a Code of Federal Regulations Part 1065 were used in this work, which included the following:<list list-type="simple">
<list-item>
<p>&#x2022; A raw Horiba MEXA 7000 series each for the EO and TP emissions sampling.</p>
</list-item>
<list-item>
<p>&#x2022; An FTIR for LO-SCR out NO<sub>x</sub> emission measurements.</p>
</list-item>
</list>
</p>
<p>The NO<sub>x</sub> and CO<sub>2</sub> measurement variability are &#x223c; &#xb1; 0.001&#xa0;and &#x223c; &#xb1; 2&#xa0;g/hp-hr, respectively. This is true for all the test results discussed in this work.</p>
</sec>
<sec id="s2-7">
<title>Drive cycles evaluated</title>
<p>This section describes the different drive cycles used to evaluate the performance of the different AT configurations.</p>
</sec>
<sec id="s2-8">
<title>Federal Test Procedure</title>
<p>The FTP, a regulatory drive cycle in the United States, was tested, also referred to as the heavy-duty transient cycle, which includes a cold and hot cycle. The CARB 2027 NO<sub>x</sub> regulatory standard for the FTP drive cycle drops by 90% from 0.2 to 0.02&#xa0;g/hp-hr (<xref ref-type="bibr" rid="B2">California adopts strong new regulation to further reduce smog-forming pollution from heavy-duty diesel trucks, 2022</xref>).</p>
</sec>
<sec id="s2-9">
<title>Low Load Cycle</title>
<p>The LLC is a real-world drive cycle consisting of data collected from different applications. This cycle is a new regulatory cycle that is approximately 1.5&#xa0;h. This cycle focuses on sustained low load, short and long idles, high accelerations after a pronounced cooling period, and low-speed cruise with motoring (<xref ref-type="bibr" rid="B15">MSPROG, 2022</xref>). The CARB NO<sub>x</sub> regulatory limit is at 0.05&#xa0;g/hp-hr for the year 2027.</p>
</sec>
<sec id="s2-10">
<title>Beverage Cycle</title>
<p>The Beverage Cycle is a subset of the LLC. This cycle is derived from a food service delivering truck (<xref ref-type="bibr" rid="B15">MSPROG, 2022</xref>). The cycle power is less than the LLC, representing a sustained low load condition. It is only 800&#xa0;s in length, much shorter than the LLC. As a result, this cycle was repeated four times in succession for thermal conditioning, and the last two cycles were later analyzed for stable results.</p>
</sec>
<sec id="s2-11">
<title>Stay Hot Cycle</title>
<p>The Stay Hot Cycle focuses on the AT performance after a prolonged period of cooling by idling the engine for 40&#xa0;min. This cycle involves operating at a preset speed and load preceding the long idle for thermal conditioning of the engine and the AT system until the temperatures attain a steady state. The test then drops to idle for a 40 min time period where the effect of the AT cooling and NO<sub>x</sub> reduction can be assessed.</p>
</sec>
<sec id="s2-12">
<title>World Harmonized Transient Cycle</title>
<p>The drive cycle named the World Harmonized Transient Cycle (WHTC) is based on the global pattern of heavy-duty commercial vehicle usage. It is a transient engine dynamometer cycle. Both the cold and hot tests for the WHTC are reported.</p>
</sec>
</sec>
<sec id="s3">
<title>Test results</title>
<p>This section shows the test results for the baseline advanced AT system compared to the EHM system configurations using the above-mentioned drive cycles. This section shows that a production engine coupled with an AT system integrated with an EHM system upstream of a LO-SCR can meet the CARB NO<sub>x</sub> regulations for the model year 2027.</p>
<sec id="s3-1">
<title>FTP composite</title>
<p>
<xref ref-type="table" rid="T2">Table 2</xref> shows the FTP composite values for the baseline AT along with the added EHM system upstream of the LO-SCR. FTP composite brake-specific emissions are calculated based on 1/7 of the cold test and 6/7 of the hot test. The results reveal that the baseline AT system equipped with the EHM system reduces the composite FTP TP Brake Specific NO<sub>x</sub> (BSNO<sub>x</sub>) emission by 3.3-fold (from 0.06 to 0.018) compared with the baseline AT, complying with the NO<sub>x</sub> regulatory limit of 0.02&#xa0;g/hp-hr for the year 2027 California regulations, also now in consideration with the US EPA for 2031 and beyond (<xref ref-type="bibr" rid="B21">Summary of EPA proposal, 2022</xref>).</p>
<table-wrap id="T2" position="float">
<label>TABLE 2</label>
<caption>
<p>FTP Composite test results.</p>
</caption>
<table>
<thead valign="top">
<tr>
<th rowspan="2" align="left">Config</th>
<th colspan="3" align="left">BSNO<sub>x</sub> (g/hp-hr)</th>
<th rowspan="2" align="left">BSCO<sub>2</sub> (g/hp-hr)</th>
</tr>
<tr>
<th align="left">EO</th>
<th align="left">LO-SCR out</th>
<th align="left">TP</th>
</tr>
</thead>
<tbody valign="top">
<tr>
<td align="left">Baseline AT</td>
<td align="left">2.66</td>
<td align="left">0.67</td>
<td align="left">0.060</td>
<td align="left">508.5</td>
</tr>
<tr>
<td align="left">AT &#x2b;EHM System</td>
<td align="left">2.48</td>
<td align="left">0.83</td>
<td align="left">0.018</td>
<td align="left">518.9</td>
</tr>
</tbody>
</table>
</table-wrap>
<p>The rise in Brake Specific CO<sub>2</sub> (BSCO<sub>2</sub>) of &#x223c;2% compared with the baseline AT testing is due to the fuel penalty for powering the EHM system. Further optimization is warranted to improve the NO<sub>x</sub> and CO<sub>2</sub> tradeoff.</p>
</sec>
<sec id="s3-2">
<title>Cold FTP</title>
<p>
<xref ref-type="table" rid="T3">Table 3</xref> shows that the AT equipped with the EHM system helps reduce NO<sub>x</sub> in cold FTP twofold compared with the baseline AT with approximately a 2% fuel penalty. The higher LO-SCR out NO<sub>x</sub> for the test with EHM system configuration was because of the change in the DEF injection strategy to support better NO<sub>x</sub> conversion at low-temperature conditions and to reduce the ammonia slip at high-temperature conditions. The EHM system energy consumption was 0.47&#xa0;kW-hr, which comprises EHM and its embedded E-heater consuming 0.235&#xa0;and 0.235&#xa0;kW-hr, respectively. Each element of the EHM system uses the same amount of power on the Cold FTP.</p>
<table-wrap id="T3" position="float">
<label>TABLE 3</label>
<caption>
<p>Cold FTP test results.</p>
</caption>
<table>
<thead valign="top">
<tr>
<th rowspan="2" align="left">Config</th>
<th colspan="3" align="left">BSNO<sub>x</sub> (g/hp-hr)</th>
<th rowspan="2" align="left">BSCO<sub>2</sub> (g/hp-hr)</th>
<th rowspan="2" align="left">EHM system energy (kW-hr)</th>
</tr>
<tr>
<th align="left">EO</th>
<th align="left">LO-SCR out</th>
<th align="left">TP</th>
</tr>
</thead>
<tbody valign="top">
<tr>
<td align="left">Baseline AT</td>
<td align="left">2.00</td>
<td align="left">0.45</td>
<td align="left">0.159</td>
<td align="left">529.5</td>
<td align="left">--</td>
</tr>
<tr>
<td align="left">AT &#x2b;EHM System</td>
<td align="left">1.92</td>
<td align="left">0.71</td>
<td align="left">0.078</td>
<td align="left">541.2</td>
<td align="left">0.47</td>
</tr>
</tbody>
</table>
</table-wrap>
<p>The EHM was set to a maximum of approximately 4&#xa0;kW, and it tries to heat the exhaust gases until the turbine out temperature is at 200&#xb0;C. Then, it primarily heats the DEF. Its embedded E-heater was set to a maximum of 2&#xa0;kW, and it targets the LO-SCR average temperature to reach 235&#xb0;C. Once the target temperatures were reached, the EHM system was turned off.</p>
<p>
<xref ref-type="fig" rid="F6">Figure 6</xref> shows a graphical comparison of the baseline AT and the AT &#x2b; EHM system configurations using LO-SCR average temperature, primary SCR inlet temperature, EO NO<sub>x</sub>, LO-SCR out NO<sub>x</sub>, TP NO<sub>x</sub>, the heater power consumption, and BSCO<sub>2</sub> as the parameters for the cold FTP cycle.</p>
<fig id="F6" position="float">
<label>FIGURE 6</label>
<caption>
<p>Comparing the baseline AT to the same equipped with the EHM system on a cold FTP cycle for the LO-SCR average temperature, primary SCR inlet temperature, EO NO<sub>x</sub>, LO-SCR out NO<sub>x</sub>, TP NO<sub>x</sub>, heater power consumption, and BSCO<sub>2</sub>.</p>
</caption>
<graphic xlink:href="fmech-08-991579-g006.tif"/>
</fig>
<p>As observed from the average LO-SCR temperature plot, the catalyst temperature cools down in the baseline run during an idle event in the baseline configuration, which is avoided with the AT &#x2b; EHM system configuration. This helps the LO-SCR convert more NO<sub>x</sub> during the initial 500 s of the cycle by increasing the LO-SCR temperature; however, this also adds to the fuel penalty for powering up the EHM system by about 2%. As mentioned earlier, during 800&#x2013;1000&#xa0;s of the cycle, the DEF dosing strategy reduces the DEF injection at the LO-SCR, allowing the primary SCR to convert most of the NO<sub>x</sub> as the primary SCRs are hot enough to convert NO<sub>x</sub> at these regions.</p>
</sec>
<sec id="s3-3">
<title>Hot FTP</title>
<p>
<xref ref-type="table" rid="T4">Table 4</xref> shows the numerical comparison of the baseline AT and AT &#x2b; EHM system configurations for the hot FTP cycle. The EHM system control strategies were the same between the hot FTP and the cold FTP cycles, except that, in the hot FTP cycle, the heating function of the E-heater targeted 225 &#xb0;C as the LO-SCR average temperature. The table displays that the AT equipped with an EHM system helps drop the TP NO<sub>x</sub> by almost 5.5-fold (from 0.043 to 0.008) with a fuel penalty of approximately 2%. The EHM system energy consumption for the hot FTP was 0.3&#xa0;kW-hr, which comprises EHM and its embedded E-heater consuming 0.2&#xa0;and 0.10&#xa0;kW-hr, respectively. About two-thirds of the energy is used by the EHM, whereas its embedded E-heater contributes the remaining third. Note that even the hot FTP requires power to the EHM system, which is about 36% less than the cold FTP.</p>
<table-wrap id="T4" position="float">
<label>TABLE 4</label>
<caption>
<p>Hot FTP test results.</p>
</caption>
<table>
<thead valign="top">
<tr>
<th rowspan="2" align="left">Config</th>
<th colspan="3" align="left">BSNOx (g/hp-hr)</th>
<th rowspan="2" align="left">CO<sub>2</sub> (g/hp-hr)</th>
<th rowspan="2" align="left">EHM system energy (kW-hr)</th>
</tr>
<tr>
<th align="left">EO</th>
<th align="left">LO-SCR out</th>
<th align="left">TP</th>
</tr>
</thead>
<tbody valign="top">
<tr>
<td align="left">Baseline AT</td>
<td align="left">2.77</td>
<td align="left">0.71</td>
<td align="left">0.043</td>
<td align="left">504.9</td>
<td align="left">--</td>
</tr>
<tr>
<td align="left">AT &#x2b; EHM system</td>
<td align="left">2.58</td>
<td align="left">0.85</td>
<td align="left">0.008</td>
<td align="left">515.1</td>
<td align="left">0.3</td>
</tr>
</tbody>
</table>
</table-wrap>
<p>
<xref ref-type="fig" rid="F7">Figure 7</xref> compares the baseline AT and the AT &#x2b; EHM system configurations using LO-SCR average temperature, primary SCR inlet temperature, EO NO<sub>x</sub>, LO-SCR out NO<sub>x</sub>, TP NO<sub>x</sub>, the heater power consumption, and BSCO<sub>2</sub> as the parameters for the hot FTP cycle.</p>
<fig id="F7" position="float">
<label>FIGURE 7</label>
<caption>
<p>Comparing the baseline AT to the same equipped with the EHM system on a hot FTP cycle for the LO-SCR average temperature, primary SCR inlet temperature, EO NO<sub>x</sub>, LO-SCR out NO<sub>x</sub>, TP NO<sub>x</sub>, heater power consumption, and BSCO<sub>2</sub>.</p>
</caption>
<graphic xlink:href="fmech-08-991579-g007.tif"/>
</fig>
<p>The hot FTP test results show that, unlike the baseline configuration, the AT &#x2b; EHM system configuration sustains the LO-SCR operational temperatures during the idling events until 400&#xa0;s. This heat at the LO-SCR helps the primary SCR retain the temperature from the previous cycle enabling improved TP NO<sub>x</sub> conversion performance by more than fourfold or more than 80%. The DEF injection strategy was the same across all the AT &#x2b; EHM system configuration tests, which explains the lower LO-SCR NO<sub>x</sub> conversion during 800&#x2014;1,000 s of the cycle, such as the cold FTP.</p>
</sec>
<sec id="s3-4">
<title>Low Load Cycle</title>
<p>
<xref ref-type="table" rid="T5">Table 5</xref> shows the numerical comparison of the baseline AT and AT &#x2b; EHM system configurations for the LLC. It reveals the AT &#x2b; EHM system helps reduce the TP NO<sub>x</sub> emission by 22-fold, which is a cycle-averaged TP NO<sub>x</sub> conversion efficiency of 99.3%, relative to 82.5% in the baseline. The EO NO<sub>x</sub> is higher for the AT &#x2b; EHM system configuration test as the heat generated from the EHM system is gradually transmitted across the AT system heating the primary SCR, and this enables the engine to run in FE mode. A certain threshold of primary SCR temperature helps the engine stay in FE mode for a longer duration, reducing the CO<sub>2</sub> penalty and increasing the EO NO<sub>x</sub>, but as the EHM system was powered on for most of the test, the overall CO<sub>2</sub> penalty was still higher by approximately 5%. The EHM system energy consumption was 4.3&#xa0;kW-hr, which comprises EHM and its embedded E-heater consuming 3.04&#xa0;and 1.26&#xa0;kW-hr, respectively. Approximately 70% of the electrical energy is put into the EHM and the remaining into its embedded E-heater for the LLC.</p>
<table-wrap id="T5" position="float">
<label>TABLE 5</label>
<caption>
<p>LLC test results.</p>
</caption>
<table>
<thead valign="top">
<tr>
<th rowspan="2" align="left">Config</th>
<th colspan="3" align="left">BSNO<sub>x</sub> (g/hp-hr)</th>
<th rowspan="2" align="left">CO<sub>2</sub> (g/hp-hr)</th>
<th rowspan="2" align="left">EHM system energy (kW-hr)</th>
</tr>
<tr>
<th align="left">EO</th>
<th align="left">LO-SCR out</th>
<th align="left">TP</th>
</tr>
</thead>
<tbody valign="top">
<tr>
<td align="left">Baseline AT</td>
<td align="left">4.10</td>
<td align="left">2.68</td>
<td align="left">0.716</td>
<td align="left">614.9</td>
<td align="left">--</td>
</tr>
<tr>
<td align="left">AT &#x2b; EHM system</td>
<td align="left">4.64</td>
<td align="left">0.70</td>
<td align="left">0.032</td>
<td align="left">647.2</td>
<td align="left">4.30</td>
</tr>
</tbody>
</table>
</table-wrap>
<p>The heating strategy controlled by the MBC targeted the average LO-SCR temperature based on the inlet temperature of the downstream SCR 1, as shown in <xref ref-type="table" rid="T6">Table 6</xref>. The EHM control strategy was the same as the FTP cycles, except that it tried to heat the exhaust gas until the turbo-out was at 180&#xb0;C.</p>
<table-wrap id="T6" position="float">
<label>TABLE 6</label>
<caption>
<p>Control strategy for the E-heater component in the EHM system for LLC and beverage drive cycles.</p>
</caption>
<table>
<thead valign="top">
<tr>
<th align="left">Average LO-SCR target temp. (&#xb0;C)</th>
<th align="left">Maximum power (kW)</th>
<th align="left">Downstream SCR1 in temp. (&#xb0;C)</th>
</tr>
</thead>
<tbody valign="top">
<tr>
<td align="left">225</td>
<td align="left">2</td>
<td align="left">0</td>
</tr>
<tr>
<td align="left">220</td>
<td align="left">2</td>
<td align="left">150</td>
</tr>
<tr>
<td align="left">210</td>
<td align="left">2</td>
<td align="left">190</td>
</tr>
<tr>
<td align="left">200</td>
<td align="left">2</td>
<td align="left">&#x2265;200</td>
</tr>
</tbody>
</table>
</table-wrap>
<p>
<xref ref-type="fig" rid="F8">Figure 8</xref> compares the LLC between baseline AT and the AT &#x2b; EHM system configurations. Control parameters are LO-SCR average temperature, primary SCR inlet temperature, EO NO<sub>x</sub>, LO-SCR out NO<sub>x</sub>, TP NO<sub>x</sub>, the heater power consumption, and BSCO<sub>2</sub>.</p>
<fig id="F8" position="float">
<label>FIGURE 8</label>
<caption>
<p>Comparing the baseline AT to the same equipped with the EHM system on an LLC for the LO-SCR average temperature, primary SCR inlet temperature, EO NO<sub>x</sub>, LO-SCR out NO<sub>x</sub>, TP NO<sub>x</sub>, heater power consumption, and BSCO<sub>2</sub>.</p>
</caption>
<graphic xlink:href="fmech-08-991579-g008.tif"/>
</fig>
<p>The baseline results show that the LO-SCR was ineffective for most of the cycle in converting the EO NO<sub>x</sub> due to the extremely low-temperature range. However, with the AT &#x2b; EHM system configuration, the average LO-SCR temperature was mostly &#x3e;200&#xb0;C over the entire cycle, helping it convert NO<sub>x</sub> even after long idles, which normally cools down the AT system (as it did in the baseline run). Furthermore, in the AT &#x2b; EHM system, the heat from the upstream catalyst was gradually transferred to the downstream SCR, which helped reduce the TP NO<sub>x</sub> by 22-fold or an additional &#x223c;96% to a net TP NO<sub>x</sub> efficiency of 99.3% in this configuration compared to the baseline helping the system to maintain the TP NO<sub>x</sub> within the California 2027 regulatory limit.</p>
</sec>
<sec id="s3-5">
<title>Beverage Cycle</title>
<p>
<xref ref-type="table" rid="T7">Table 7</xref> shows the numerical comparison of the baseline AT and AT &#x2b; EHM system configurations for the Beverage Cycle. The EHM system control strategy was the same as the LLC. The AT &#x2b; EHM system reduces the baseline TP NO<sub>x</sub> by 38-fold (from 1.669 to 0.044). It produces a cycle-averaged NO<sub>x</sub> reduction efficiency of 99.2% <italic>versus</italic> 58.9% in baseline configuration. Similar to the LLC, the engine runs a lot more in the FE mode in the configuration with the EHM system, which explains the drastic difference in the EO NO<sub>x</sub> values. The EHM system energy consumption was 1.76&#xa0;kW-hr, which comprises EHM and its embedded E-heater, consuming 1.08&#xa0;and 0.68&#xa0;kW-hr, respectively. The EHM requires 62% of the electrical energy, whereas its embedded E-heater uses 38%.</p>
<table-wrap id="T7" position="float">
<label>TABLE 7</label>
<caption>
<p>Beverage Cycle test results.</p>
</caption>
<table>
<thead valign="top">
<tr>
<th rowspan="2" align="left">Config</th>
<th colspan="3" align="left">BSNO<sub>x</sub> (g/hp-hr)</th>
<th rowspan="2" align="left">CO<sub>2</sub> (g/hp-hr)</th>
<th rowspan="2" align="left">EHM system energy (kW-hr)</th>
</tr>
<tr>
<th align="left">EO</th>
<th align="left">LO-SCR out</th>
<th align="left">TP</th>
</tr>
</thead>
<tbody valign="top">
<tr>
<td align="left">Baseline AT</td>
<td align="left">4.06</td>
<td align="left">3.60</td>
<td align="left">1.669</td>
<td align="left">686.3</td>
<td align="left">--</td>
</tr>
<tr>
<td align="left">AT &#x2b; EHM system</td>
<td align="left">5.87</td>
<td align="left">0.93</td>
<td align="left">0.044</td>
<td align="left">754.9</td>
<td align="left">1.76</td>
</tr>
</tbody>
</table>
</table-wrap>
<p>
<xref ref-type="fig" rid="F9">Figure 9</xref> compares the Beverage Cycle with baseline AT and the same with EHM system configurations using control parameters LO-SCR average temperature, primary SCR inlet temperature, EO NO<sub>x</sub>, LO-SCR out NO<sub>x</sub>, TP NO<sub>x</sub>, the heater power consumption, and BSCO<sub>2</sub>.</p>
<fig id="F9" position="float">
<label>FIGURE 9</label>
<caption>
<p>Comparing the baseline AT to the same equipped with the EHM system on a Beverage Cycle for the LO-SCR average temperature, primary SCR inlet temperature, EO NO<sub>x</sub>, LO-SCR out NO<sub>x</sub>, TP NO<sub>x</sub>, heater power consumption, and BSCO<sub>2</sub>.</p>
</caption>
<graphic xlink:href="fmech-08-991579-g009.tif"/>
</fig>
<p>The LO-SCR NO<sub>x</sub> conversion increases in the AT &#x2b; EHM system configuration compared to baseline by maintaining the temperature above 200&#xb0;C for most of the cycle. This heat transferred onto the downstream SCR helped in the overall reduction in TP NO<sub>x</sub> compared to baseline. Though the Beverage Cycle is not a regulatory cycle, the TP NO<sub>x</sub> emission values were within 0.05&#xa0;g/hp-hr with the AT &#x2b; EHM system configuration, even with an increased EO NO<sub>x</sub>. The net fuel penalty for powering the EHM system was approximately 10%. The primary SCR temperature shown in <xref ref-type="fig" rid="F9">Figure 9</xref> is the inlet gas temperature. The actual catalyst bed temperature is expected to be a little hotter, which might help reduce the outlet NO<sub>x</sub> from the LO-SCR.</p>
</sec>
<sec id="s3-6">
<title>Stay Hot Cycle</title>
<p>
<xref ref-type="table" rid="T8">Table 8</xref> shows the numerical comparison of the baseline AT and AT &#x2b; EHM system configurations for the Stay Hot Cycle. The cycle used the EHM to provide extra heat to the system. This reduced fuel penalty, relying solely on the EHM to heat the AT system. The EHM control strategy is the same as that described in the LLC. As observed in <xref ref-type="table" rid="T8">Table 8</xref>, the AT &#x2b; EHM system configuration reduces the TP NO<sub>x</sub> by almost eightfold (from 0.238 to 0.031) with a fuel penalty of approximately 5%. The EHM system energy consumption was 1.30&#xa0;kW-hr, which was consumed completely by the EHM as its embedded E-heater was turned off during this cycle.</p>
<table-wrap id="T8" position="float">
<label>TABLE 8</label>
<caption>
<p>Stay Hot test results.</p>
</caption>
<table>
<thead valign="top">
<tr>
<th rowspan="2" align="left">Config</th>
<th colspan="3" align="left">BSNO<sub>x</sub> (g/hp-hr)</th>
<th rowspan="2" align="left">CO<sub>2</sub> (g/hp-hr)</th>
<th rowspan="2" align="left">EHM system energy (kW-hr)</th>
</tr>
<tr>
<th align="left">EO</th>
<th align="left">LO-SCR out</th>
<th align="left">TP</th>
</tr>
</thead>
<tbody valign="top">
<tr>
<td align="left">Baseline AT</td>
<td align="left">3.14</td>
<td align="left">1.37</td>
<td align="left">0.238</td>
<td align="left">655.9</td>
<td align="left">--</td>
</tr>
<tr>
<td align="left">AT &#x2b; EHM system</td>
<td align="left">3.22</td>
<td align="left">0.11</td>
<td align="left">0.031</td>
<td align="left">687.2</td>
<td align="left">1.30</td>
</tr>
</tbody>
</table>
</table-wrap>
<p>
<xref ref-type="fig" rid="F10">Figure 10</xref> compares the baseline AT and the AT &#x2b; EHM system configurations using LO-SCR average temperature, primary SCR inlet temperature, EO NO<sub>x</sub>, LO-SCR out NO<sub>x</sub>, TP NO<sub>x</sub>, the heater power consumption, and BSCO<sub>2</sub> as the parameters for the Stay Hot Cycle.</p>
<fig id="F10" position="float">
<label>FIGURE 10</label>
<caption>
<p>Comparing the baseline AT to the same equipped with the EHM system on a Stay Hot Cycle for the LO-SCR average temperature, EO NO<sub>x</sub>, LO-SCR out NO<sub>x</sub>, TP NO<sub>x</sub>, heater power consumption, and BSCO<sub>2</sub>.</p>
</caption>
<graphic xlink:href="fmech-08-991579-g010.tif"/>
</fig>
<p>Though the EHM is mostly advantageous for converting DEF to reductants, it was used in this Stay Hot Cycle to provide enough heat to retain the LO-SCR temperature for long durations to keep the NO<sub>x</sub> conversion active, which does not happen in the case of the baseline, as the LO-SCR temperature drops down to &#x223c;120&#xb0;C where it likely cannot respond to any incoming EO NO<sub>x</sub>.</p>
</sec>
<sec id="s3-7">
<title>World Harmonized Transient Cycle</title>
<p>The WHTC Composite is provided first, followed by details on the WHTC cold and then the hot cycles.</p>
<sec id="s3-7-1">
<title>WHTC Composite</title>
<p>The WHTC Composite brake-specific emissions are calculated based on 14% of the cold test and 86% of the hot test. <xref ref-type="table" rid="T9">Table 9</xref> shows the WHTC composite values comparison of the baseline AT and AT &#x2b; EHM system configurations. The results show that compared to baseline, the AT &#x2b; EHM system configuration reduces the transient TP NO<sub>x</sub> emissions from 0.142 to 0.014&#xa0;g/kW-hr or by 10-fold. This is 32-fold below the EURO-VI NO<sub>x</sub> regulatory limit of 0.46&#xa0;g/kW-hr (0.34&#xa0;g/hp-hr). The fuel penalty for powering up the EHM system is only about 0.5% relative to the baseline.</p>
<table-wrap id="T9" position="float">
<label>TABLE 9</label>
<caption>
<p>WHTC Composite test results.</p>
</caption>
<table>
<thead valign="top">
<tr>
<th rowspan="2" align="left">Configuration</th>
<th colspan="3" align="left">BSNO<sub>x</sub> (g/kw-hr)</th>
<th rowspan="2" align="left">BSCO<sub>2</sub> (g/kw-hr)</th>
</tr>
<tr>
<th align="left">EO</th>
<th align="left">LO-SCR out</th>
<th align="left">TP</th>
</tr>
</thead>
<tbody valign="top">
<tr>
<td align="left">Baseline AT</td>
<td align="left">4.86</td>
<td align="left">2.01</td>
<td align="left">0.142</td>
<td align="left">661.9</td>
</tr>
<tr>
<td align="left">AT &#x2b; EHM system</td>
<td align="left">5.27</td>
<td align="left">0.67</td>
<td align="left">0.014</td>
<td align="left">666.0</td>
</tr>
</tbody>
</table>
</table-wrap>
</sec>
<sec id="s3-7-2">
<title>Cold WHTC</title>
<p>
<xref ref-type="table" rid="T10">Table 10</xref> shows the numerical comparison of the baseline AT and AT &#x2b; EHM system configurations for the cold WHTC. The EHM system control strategies are exactly like the cold FTP cycle. The results show that both LO-SCR out NO<sub>x</sub> and the TP NO<sub>x</sub> dropped by almost threefold relative to baseline compared to the AT &#x2b; EHM system configuration. The increase in the EO NO<sub>x</sub> in the AT &#x2b; EHM system configuration test might be because the engine might have switched to the FE mode at an earlier state than the baseline after the start of the engine as the AT temperatures had risen faster when the EHM system was turned on. The EHM system energy consumption was 0.80&#xa0;kW-hr, which comprises EHM and its embedded E-heater, consuming 0.48&#xa0;and 0.32&#xa0;kW-hr, respectively. Approximately 60% of the electrical heating occurred in the EHM.</p>
<table-wrap id="T10" position="float">
<label>TABLE 10</label>
<caption>
<p>Cold WHTC test results.</p>
</caption>
<table>
<thead valign="top">
<tr>
<th rowspan="2" align="left">Config</th>
<th colspan="3" align="left">BSNO<sub>x</sub> (g/kW-hr)</th>
<th rowspan="2" align="left">CO<sub>2</sub> (g/kW-hr)</th>
<th rowspan="2" align="left">EHM system energy (kW-hr)</th>
</tr>
<tr>
<th align="left">EO</th>
<th align="left">LO-SCR out</th>
<th align="left">TP</th>
</tr>
</thead>
<tbody valign="top">
<tr>
<td align="left">Baseline AT</td>
<td align="left">3.98</td>
<td align="left">1.53</td>
<td align="left">0.245</td>
<td align="left">678.8</td>
<td align="left">--</td>
</tr>
<tr>
<td align="left">AT &#x2b; EHM system</td>
<td align="left">4.28</td>
<td align="left">0.56</td>
<td align="left">0.091</td>
<td align="left">686.5</td>
<td align="left">0.80</td>
</tr>
</tbody>
</table>
</table-wrap>
<p>
<xref ref-type="fig" rid="F11">Figure 11</xref> compares the baseline AT and the AT &#x2b; EHM system configurations using LO-SCR average temperature, primary SCR inlet temperature, EO NO<sub>x</sub>, LO-SCR out NO<sub>x</sub>, TP NO<sub>x</sub>, the heater power consumption, and BSCO<sub>2</sub> as the parameters for the cold WHTC. Adding heat during the cold start for NOx reduction is advantageous as the baseline LO-SCR is too cold to convert NOx for the first 400&#xa0;s of the cycle. As observed in <xref ref-type="fig" rid="F11">Figure 11</xref>, after 100 s, the AT starts to convert more NO<sub>x</sub> at the LO-SCR when it is equipped with the EHM system compared to the baseline configuration, which in turn helps reduce the overall TP NO<sub>x</sub> emissions by &#x223c; 63%. The overall NO<sub>x</sub> reduction efficiency with the AT &#x2b; EHM system configuration for this cold cycle was 98%, with a 1% fuel penalty.</p>
<fig id="F11" position="float">
<label>FIGURE 11</label>
<caption>
<p>Comparing the baseline AT to the same equipped with the EHM system on a cold WHTC for the LO-SCR average temperature, primary SCR inlet temperature, EO NO<sub>x</sub>, LO-SCR out NO<sub>x</sub>, TP NO<sub>x</sub>, heater power consumption, and BSCO<sub>2</sub>.</p>
</caption>
<graphic xlink:href="fmech-08-991579-g011.tif"/>
</fig>
</sec>
<sec id="s3-7-3">
<title>Hot WHTC</title>
<p>
<xref ref-type="table" rid="T11">Table 11</xref> shows the numerical comparison of the baseline AT and AT &#x2b; EHM system configurations for the hot WHTC. As observed, LO-SCR NO<sub>x</sub> out dropped by an additional threefold using the AT configuration equipped with the EHM system relative to the baseline and TP NO<sub>x</sub> by 125-fold. The EHM system control strategies are exactly like those described for the hot FTP cycle. The EHM system energy consumption was 0.57&#xa0;kW-hr, which comprises of EHM and its embedded E-heater consuming 0.42&#xa0;and 0.15&#xa0;kW-hr, respectively. The EHM system uses 74% of the electrical energy for the EHM and 26% for its embedded E-heater.</p>
<table-wrap id="T11" position="float">
<label>TABLE 11</label>
<caption>
<p>Hot WHTC test results.</p>
</caption>
<table>
<thead valign="top">
<tr>
<th rowspan="2" align="left">Config</th>
<th colspan="3" align="left">BSNO<sub>x</sub> (g/kW-hr)</th>
<th rowspan="2" align="left">CO<sub>2</sub> (g/kW-hr)</th>
<th rowspan="2" align="left">EHM system energy (kW-hr)</th>
</tr>
<tr>
<th align="left">EO</th>
<th align="left">LO-SCR out</th>
<th align="left">TP</th>
</tr>
</thead>
<tbody valign="top">
<tr>
<td align="left">Baseline AT</td>
<td align="left">5.00</td>
<td align="left">2.08</td>
<td align="left">0.125</td>
<td align="left">659.2</td>
<td align="left">--</td>
</tr>
<tr>
<td align="left">AT &#x2b; EHM system</td>
<td align="left">5.43</td>
<td align="left">0.69</td>
<td align="left">0.001</td>
<td align="left">662.7</td>
<td align="left">0.57</td>
</tr>
</tbody>
</table>
</table-wrap>
<p>
<xref ref-type="fig" rid="F12">Figure 12</xref> compares the baseline AT and the AT &#x2b; EHM system configurations using LO-SCR average temperature, primary SCR inlet temperature, EO NO<sub>x</sub>, LO-SCR out NO<sub>x</sub>, TP NO<sub>x</sub>, the heater power consumption, and BSCO<sub>2</sub> as the parameters for the hot WHTC.</p>
<fig id="F12" position="float">
<label>FIGURE 12</label>
<caption>
<p>Comparing the baseline AT to the same equipped with the EHM system on a hot WHTC for the LO-SCR average temperature, primary SCR inlet temperature, EO NO<sub>x</sub>, LO-SCR out NO<sub>x</sub>, TP NO<sub>x</sub>, heater power consumption, and BSCO<sub>2</sub>.</p>
</caption>
<graphic xlink:href="fmech-08-991579-g012.tif"/>
</fig>
<p>
<xref ref-type="fig" rid="F12">Figure 12</xref> reveals a drastic difference observed in the TP NO<sub>x</sub> values between the baseline and the AT equipped with EHM system configurations. Similar to the hot FTP cycle, the downstream primary SCR does not lose the thermal heat from the previous cycle in the AT &#x2b; EHM system configuration as the exhaust gases are heated up before reaching the primary SCR helping achieve a near zero TP NO<sub>x</sub> on a hot WHTC with less than 1% fuel penalty. The low fuel penalty is because the engine was running more on the FE mode due to the AT temperatures, increasing the EO NO<sub>x</sub> and compensating the fuel penalty for powering the EHM system.</p>
</sec>
</sec>
</sec>
<sec id="s4">
<title>Summary of results</title>
<p>An EHM system added to a LO-SCR and conventional AT system was investigated on a 15 L heavy-duty diesel engine. The technology has a flexible control strategy embedded in a microcontroller (supplied by Emissol), providing ample opportunities for DEF injection well below 200&#xb0;C in low-temperature operations and prolonged low-load cycles. In the study performed here, the EHM system was used on a hydrothermally aged Full Useful Life-aged catalyst AT system for optimal system NO<sub>x</sub> conversion, targeting to meet future NO<sub>x</sub> emission regulations, including California 2027 (0.02&#xa0;g/hp-hr tailpipe NO<sub>x</sub>).</p>
<p>
<xref ref-type="table" rid="T12">Tables 12</xref> and <xref ref-type="table" rid="T13">13</xref> show the summary of all the test results for both the baseline AT and the AT &#x2b; EHM system configurations during this work. Results with AT equipped with EHM system along with LO-SCR indicate the following:<list list-type="simple">
<list-item>
<p>&#x2022; TP NO<sub>x</sub> in the FTP cycle was reduced by 3.3-fold (to 0.018&#xa0;g/hp-hr) compared to the baseline, meeting CARB 2027 target.</p>
</list-item>
<list-item>
<p>&#x2022; Likewise, TP NO<sub>x</sub> in LLC was reduced by 22.4-fold.</p>
</list-item>
<list-item>
<p>&#x2022; In Beverage Cycle, TP NO<sub>x</sub> was reduced by 38-fold.</p>
</list-item>
<list-item>
<p>&#x2022; In the Stay Hot cycle, TP NO<sub>x</sub> was reduced by 7.7-fold.</p>
</list-item>
<list-item>
<p>&#x2022; TP NO<sub>x</sub> in WHTC was reduced by 10-fold to 0.014&#xa0;g/kW-hr, likely meeting the upcoming EURO VII limit, which is expected to be &#x223c;0.03&#x2013;0.05&#xa0;g/kW-hr (<xref ref-type="bibr" rid="B6">ICCT Comments and Technical Recommendations on Future Euro-7/VII Emission Standard, 2021</xref>).</p>
</list-item>
</list>
</p>
<table-wrap id="T12" position="float">
<label>TABLE 12</label>
<caption>
<p>Test results summary of drive cycles.</p>
</caption>
<table>
<thead valign="top">
<tr>
<th rowspan="2" align="left">Config</th>
<th rowspan="2" align="left">Cycle</th>
<th colspan="3" align="left">BS NO<sub>x</sub> (g/hp-hr)</th>
<th rowspan="2" align="left">BSCO<sub>2</sub> (g/hp-hr)</th>
</tr>
<tr>
<th align="left">EO</th>
<th align="left">LO-SCR out</th>
<th align="left">TP</th>
</tr>
</thead>
<tbody valign="top">
<tr>
<td rowspan="6" align="left">Baseline AT</td>
<td align="left">Cold FTP</td>
<td align="left">2.00</td>
<td align="left">0.45</td>
<td align="left">0.159</td>
<td align="left">529.5</td>
</tr>
<tr>
<td align="left">Hot FTP</td>
<td align="left">2.77</td>
<td align="left">0.71</td>
<td align="left">0.043</td>
<td align="left">504.9</td>
</tr>
<tr>
<td align="left">
<bold>FTP Composite</bold>
</td>
<td align="left">
<bold>2.68</bold>
</td>
<td align="left">
<bold>0.67</bold>
</td>
<td align="left">
<bold>0.060</bold>
</td>
<td align="left">
<bold>508.5</bold>
</td>
</tr>
<tr>
<td align="left">LLC</td>
<td align="left">4.10</td>
<td align="left">2.68</td>
<td align="left">0.716</td>
<td align="left">614.9</td>
</tr>
<tr>
<td align="left">Beverage</td>
<td align="left">4.06</td>
<td align="left">3.60</td>
<td align="left">1.669</td>
<td align="left">686.3</td>
</tr>
<tr>
<td align="left">Stay Hot</td>
<td align="left">3.14</td>
<td align="left">1.37</td>
<td align="left">0.238</td>
<td align="left">655.9</td>
</tr>
<tr>
<td rowspan="6" align="left">AT &#x2b; EHM system</td>
<td align="left">Cold FTP</td>
<td align="left">1.92</td>
<td align="left">0.71</td>
<td align="left">0.078</td>
<td align="left">541.2</td>
</tr>
<tr>
<td align="left">Hot FTP</td>
<td align="left">2.58</td>
<td align="left">0.85</td>
<td align="left">0.008</td>
<td align="left">515.1</td>
</tr>
<tr>
<td align="left">
<bold>FTP Composite</bold>
</td>
<td align="left">
<bold>2.48</bold>
</td>
<td align="left">
<bold>0.83</bold>
</td>
<td align="left">
<bold>0.018</bold>
</td>
<td align="left">
<bold>518.9</bold>
</td>
</tr>
<tr>
<td align="left">LLC</td>
<td align="left">4.64</td>
<td align="left">0.70</td>
<td align="left">0.032</td>
<td align="left">647.2</td>
</tr>
<tr>
<td align="left">Beverage</td>
<td align="left">5.87</td>
<td align="left">0.93</td>
<td align="left">0.044</td>
<td align="left">754.9</td>
</tr>
<tr>
<td align="left">Stay Hot</td>
<td align="left">3.22</td>
<td align="left">0.11</td>
<td align="left">0.031</td>
<td align="left">687.2</td>
</tr>
</tbody>
</table>
<table-wrap-foot>
<fn>
<p>FTP Composite is the composite value of the cold FTP and hot FTP in the ratio of 1:7 and 6:7 respectively as per regulatory standards.</p>
</fn>
</table-wrap-foot>
</table-wrap>
<table-wrap id="T13" position="float">
<label>TABLE 13</label>
<caption>
<p>Test results summary of European Regulatory Test Cycle WHTC.</p>
</caption>
<table>
<thead valign="top">
<tr>
<th rowspan="2" align="left">Config</th>
<th rowspan="2" align="left">WHTC</th>
<th colspan="3" align="left">BS NO<sub>x</sub> (g/kw-hr)</th>
<th rowspan="2" align="left">BSCO<sub>2</sub> (g/ kW-hr)</th>
</tr>
<tr>
<th align="left">EO</th>
<th align="left">LO-SCR out</th>
<th align="left">TP</th>
</tr>
</thead>
<tbody valign="top">
<tr>
<td rowspan="3" align="left">Baseline AT</td>
<td align="left">Cold</td>
<td align="left">3.98</td>
<td align="left">1.53</td>
<td align="left">0.245</td>
<td align="left">678.8</td>
</tr>
<tr>
<td align="left">Hot</td>
<td align="left">5.00</td>
<td align="left">2.08</td>
<td align="left">0.125</td>
<td align="left">659.2</td>
</tr>
<tr>
<td align="left">
<bold>Composite</bold>
</td>
<td align="left">
<bold>4.86</bold>
</td>
<td align="left">
<bold>2.01</bold>
</td>
<td align="left">
<bold>0.142</bold>
</td>
<td align="left">
<bold>661.9</bold>
</td>
</tr>
<tr>
<td rowspan="3" align="left">AT &#x2b; EHM system</td>
<td align="left">Cold</td>
<td align="left">4.28</td>
<td align="left">0.60</td>
<td align="left">0.091</td>
<td align="left">686.5</td>
</tr>
<tr>
<td align="left">Hot</td>
<td align="left">5.43</td>
<td align="left">0.69</td>
<td align="left">0.001</td>
<td align="left">662.7</td>
</tr>
<tr>
<td align="left">
<bold>Composite</bold>
</td>
<td align="left">
<bold>5.27</bold>
</td>
<td align="left">
<bold>0.67</bold>
</td>
<td align="left">
<bold>0.014</bold>
</td>
<td align="left">
<bold>666.0</bold>
</td>
</tr>
</tbody>
</table>
<table-wrap-foot>
<fn>
<p>FTP Composite is the composite value of the cold FTP and hot FTP in the ratio of 1:7 and 6:7 respectively as per regulatory standards.</p>
</fn>
</table-wrap-foot>
</table-wrap>
<p>Engine optimization/calibration was not performed in this study. Therefore, the observed results could be optimized <italic>via</italic> further calibration explorations, such as work to reduce the CO<sub>2</sub> penalty. The production engine used in this work currently switches between different modes based on the primary SCR temperature. In the future, the engine calibration could be modified to also consider the LO-SCR temperature so that the engine can stay in fuel economy mode for a longer duration, helping reduce the fuel penalty. The NO<sub>x</sub>/CO<sub>2</sub> tradeoff could also be improvised by combining additional technology with the engine, such as CDA.</p>
</sec>
<sec id="s5">
<title>Future work</title>
<p>The current work focused on thermal management of the AT system through external heaters. However, in addition to the EHM system, adding CDA to the engine can help reduce the fuel penalty for powering up the heaters because CDA technology reduces the exhaust flow rate of the engine, allowing the AT to stay hotter for a longer duration without cooling down, which in turn helps achieve higher fuel economy. This has been observed with one of the programs in the past with a CDA engine and an E-heater (<xref ref-type="bibr" rid="B18">Scott Sluder et al., 2005</xref>).</p>
<p>Likewise, the fuel penalty observed in some cycles could be alleviated by synergizing CDA and higher EO-NO<sub>x</sub> with engine-AT calibration optimization, largely unexplored in this study.</p>
<p>Future studies could focus on exploring the following, amongst others:</p>
<list list-type="simple">
<list-item>
<p>(i) Impact of the EHM system on deposit mitigation.</p>
</list-item>
<list-item>
<p>ii) More aggressive ammonia storage strategies in sustained low-temperature operations consistently below 200&#xa0;C as the EHM system can form reductants &#x201c;on-demand&#x201d; for improved in-use compliance.</p>
</list-item>
<list-item>
<p>iii) Testing Real Driving Emissions (RDE) cycles for European applications.</p>
</list-item>
<list-item>
<p>iv) Using EHM (or EHM &#x2b; E-Heater) for primary SCR.</p>
</list-item>
<list-item>
<p>v) Synergy with advanced engine technologies such as CDA.</p>
</list-item>
</list>
</sec>
</body>
<back>
<sec sec-type="data-availability" id="s6">
<title>Data availability statement</title>
<p>The original contributions presented in the study are included in the article/Supplementary Material, further inquiries can be directed to the corresponding author.</p>
</sec>
<sec id="s7">
<title>Author contributions</title>
<p>All authors were involved with planning the testing and reviewing the results. All authors contributed discussion to the paper, which was led by PM. All authors contributed to the figures. PM compiled the tables. All authors participated in the revision process.</p>
</sec>
<ack>
<p>The testing at SwRI for the work was funded by Eaton in cooperation with the SwRI team. This material is based on the work supported by the National Science Foundation under Grant no. 1831231. The latter acknowledgment refers solely to EHM&#x2122;/ EHM system&#x2122; development and engineering support from Emissol.</p>
</ack>
<sec sec-type="COI-statement" id="s9">
<title>Conflict of interest</title>
<p>PM, AM, and CS were employed by SwRI. JM was employed by the Eaton Corporation. MM, NP, and SN were employed by Emissol LLC.</p>
<p>The authors declare that this study received funding from the Eaton Corporation and Emissol supplied the EHM<sup>&#x2122;</sup>/EHM System<sup>&#x2122;</sup> components (including its microcontroller) and engineering support for this investigation. Testing and analyses were performed by the SwRI team. Eaton, Emissol and SwRI were involved in planning the testing, reviewing the results, the writing of this article, and the decision to submit it for publication.</p>
</sec>
<sec sec-type="disclaimer" id="s10">
<title>Publisher&#x2019;s note</title>
<p>All claims expressed in this article are solely those of the authors and do not necessarily represent those of their affiliated organizations, or those of the publisher, the editors, and the reviewers. Any product that may be evaluated in this article, or claim that may be made by its manufacturer, is not guaranteed or endorsed by the publisher.</p>
</sec>
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