AUTHOR=Wu Chen Lester R. , Stigter Tibor Y. , Craig Simon G. TITLE=Assessing the Quantity and Quality Controls of the Freshwater Lens on a Semi-Arid Coral-Limestone Island in Sri Lanka JOURNAL=Frontiers in Water VOLUME=Volume 4 - 2022 YEAR=2022 URL=https://www.frontiersin.org/journals/water/articles/10.3389/frwa.2022.832227 DOI=10.3389/frwa.2022.832227 ISSN=2624-9375 ABSTRACT=

Uncertainties in the contamination and salinization mechanisms of the freshwater lens (FWL) in the semi-arid coral-limestone aquifer of Delft Island, Sri Lanka threatens its water security. The processes governing the quality and distribution of the FWL were therefore investigated through recharge assessment and hydrochemical analysis. Potential groundwater recharge zones based on land classification and geology were first identified. A rootzone water balance model was then built, which revealed the spatiotemporal variability of potential groundwater recharge occurring rapidly during the wet season (October to January) and most abundantly on pasture land underlain by yellow and brown sand. Recharge also varied largely between dry and wet years. Where the water table was shallow, intense rainfall in wet years was seen to result in surface flooding. Geochemical modeling using PHREEQC combined with diagrams (Piper and Stiff) and scatter plots, including stable water isotopes, revealed the meteoric origin of groundwater with salinization mainly caused by seawater mixing and slight evaporation. Findings also suggest that salinization is driven by the island's low-lying nature (maximum elevation of 6 m above sea level), the low hydraulic heads (maximum of 3.7 m above sea level), the shallow depth of the marine water, the presence of lagoons in the center which are inferred to be in hydraulic continuity with the ocean, and to some extent by unregulated abstraction of groundwater through shallow hand-dug wells. We hypothesize about infiltration and percolation of saline water through the root zone during storm inundations near the coast, supported by the combined occurrence of high values of partial CO2 pressure, alkalinity and salinity in groundwater samples. Cation exchange showed indications of salinization of wells mostly in low lying areas (minimum Na/Cl value of 0.66), and freshening in areas near the coast with high potential groundwater recharge (maximum Na/Cl value of 1.04). Elevated nitrate concentrations (maximum of 2.55 mmol/L NO3-) in groundwater samples were observed. This suggests that anthropogenic contamination is further threatening the already scarce resource as well as coastal ecosystems that may be groundwater dependent.