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EDITORIAL article

Front. Nanotechnol., 24 January 2023
Sec. Nanoelectronics
This article is part of the Research Topic Advanced Characterization Methods for HfO2/ZrO2-based Ferroelectrics View all 5 articles

Editorial: Advanced characterization methods for HfO2/ZrO2-based ferroelectrics

  • 1Nanoelectronic Materials Laboratory (NaMLab) gGmbH, Dresden, Germany
  • 2Interuniversity Microelectronics Center (IMEC), Leuven, Belgium
  • 3School of Electrical, Computer and Energy Engineering, Arizona State University, Tempe, AZ, United States
  • 4Fraunhofer IPMS, Center Nanoelectronic Technologies, Dresden, Germany

Ferroelectric HfO2 and ZrO2-based materials are unconventional ferroelectrics compared to historically dominant perovskite-based ferroelectrics. These differences from conventional perovskite ferroelectrics are distinctly seen in HfO2-ZrO2’s fluorite-based structure that exhibits a rich polymorphism of competing crystal phases, enhanced ferroelectric behavior when scaling film thicknesses down to 10 nm and below, and a one order of magnitude lower relative permittivity and higher coercive field. Both the complex interplay of the fluorite crystal phases, as well as the intrinsic material and/or ferroelectric properties associated with them, have made ferroelectric HfO2-ZrO2-based ferroelectrics simultaneously challenging and interesting to characterize. Due in strong part to the nanoscale thicknesses of these fluorite-based ferroelectric films, the device behavior is an inseparable combination of the ferroelectric film properties (i.e., structure, crystalline orientation, grain size) and the material stack structure that encapsulates it into a two or three terminal device (i.e., interfaces, dielectric layers, electrode materials). Each article comprising this Research Topic on advanced characterization methods for HfO2/ZrO2-based ferroelectric illustrates different ways in which the intrinsic material properties or the ferroelectric film’s interaction with the device stack can be characterized to gain physical insight into this unconventional ferroelectric material system.

Surface energy effects and grain size are often attributed to the predominant stabilization of either the non-polar tetragonal, monoclinic, or the polar orthorhombic phases in polycrystalline HfO2–ZrO2 films. It is generally observed that the polar orthorhombic phase is stabilized somewhere between the non-polar tetragonal and monoclinic phase boundaries, and that these non-polar phases are very sensitive to grain size in both HfO2 and ZrO2. Since the preferred crystal phase-dependence on grain size can be sensitive to stoichiometry (for instance, in Hf1-xZrxO2 or Si-doped HfO2), it can be anticipated that there may be a complex interplay between grain-size engineering and ferroelectric film composition. In “Effect of Al2O3 interlayers on the microstructure and electrical response of ferroelectric doped HfO2 thin films” by Lederer et al., the grain-size and composition dependence of ferroelectric Hf1-xZrxO2 and Si-doped HfO2 is investigated in detail in which 1, 2, and 3 Al2O3 interlayers are used to control grain size while adjusting the stoichiometry of the fluorite-structured ferroelectric films. Using a combination of structural techniques, such as grazing-incidence X-ray diffraction and Kikuchi diffraction, as well as electrical characterization to assess the ferroelectric and electric-field cycling properties, the work strikingly shows how stack engineering can be combined with the rich polymorphism to optimize fluorite-structured films for ferroelectric applications, such as front-of-line integration of Hf1-xZrxO2 due to the improved temperature robustness aided by the Al2O3 interlayers.

Other types of interlayers are often found in ferroelectric-based devices as either an intentional or unintentional consequence of the fabricated device stack, most frequently as dielectric interfacial layers between a ferroelectric-metal or ferroelectric-semiconductor interface. While the high coercive field of HfO2-ZrO2-based ferroelectrics makes it more robust to depolarization fields caused by interfacial dead layers compared to perovskite ferroelectrics, the typical 6–10 nm fluorite ferroelectric film thickness can still lead to large depolarization fields that can impact the ferroelectric behavior. Depolarization effects can lead to poor performance in data retention tests for ferroelectric random access memory (FRAM) capacitors and ferroelectric field effect transistors (FeFETs), and thus pose a considerable reliability challenge. In “Investigating charge trapping in ferroelectric thin films through transient measurements” by Lancaster et al., the loss of remanent polarization as a consequence of interfacial layers of Al2O3 in Hf0.5Zr0.5O2 ferroelectric capacitors is presented to assess the competing effects of depolarization and charge trapping at the ferroelectric-dielectric interface. In particular, the dependence of the polarization loss on pulse-width and delay time with a specially designed variant of the positive-up-negative-down (PUND) was proposed as a new technique to better assess the influence of charge injection on polarization loss.

While the ferroelectric-dielectric interface plays an important role in conventional CMOS-based FeFET behavior and reliability, there is interest in making FeFETs out of semiconducting oxide channels that may be suited for neuromorphic computing applications. The electrostatic control of the semiconducting oxide channel and the corresponding high and low resistance states are performance metrics of note for the construction of this class of artificial synapse. In “Physical modeling of HZO-based ferroelectric field-effect transistors with a WOx channel” by Wen et al., simulations are presented that illustrate the potential for using ferroelectric HfO2-ZrO2 with a WOx semiconducting channel to achieve artificial synaptic devices for neural networks. While scaling the ferroelectric film thickness and semiconducting oxide layer thickness were found to enhance the margin between the on and off resistance, a double-gated structure was found to enhance the on/off resistance ratio by a factor of 13 compared to back-gated structures. Thus, the results provide an interesting framework that can help guide the characterization of synaptic-based devices utilizing ferroelectric HfO2-ZrO2 and WOx.

The last article in the Research Topic “Simulation of XRD, Raman and IR spectrum for phase identification in doped HfO2 and ZrO2” by Kersch et al., performed ab initio simulations of the phases in HfO2 and ZrO2 with resulting X-ray diffraction, Raman, and infrared patterns. Since most experimentally reported HfO2-ZrO2-based ferroelectric films are polycrystalline and often contain more than one phase, the accurate quantification of the presence of each crystal phase is important to understand the resulting device behavior. However, phase quantification using X-ray diffraction only is extremely difficult in HfO2 and ZrO2 polycrystalline films due to the close similarity in the tetragonal and orthorhombic diffraction patterns. The reported Raman and infrared spectroscopy for crystal structures in HfO2 and ZrO2 can thus provide important reference patterns that experimentalists can use to more accurately quantify the phase composition in fluorite ferroelectric films.

The articles on grain-size engineering, interfacial effects involving charge trapping and depolarization, conducting oxide transistors with ferroelectric gates, and the ab initio simulations of the XRD, Raman, and infrared signatures of the crystalline phases capture a small cross-section of the fascinating complexity of ferroelectric HfO2 and ZrO2. This Research Topic on advanced characterization methods for HfO2/ZrO2-based ferroelectrics provides important insights into the material and device-level behavior for these unconventional ferroelectric materials.

Author contributions

All authors listed have made a substantial, direct, and intellectual contribution to the work and approved it for publication.

Conflict of interest

The authors declare that the research was conducted in the absence of any commercial or financial relationships that could be construed as a potential conflict of interest.

Publisher’s note

All claims expressed in this article are solely those of the authors and do not necessarily represent those of their affiliated organizations, or those of the publisher, the editors and the reviewers. Any product that may be evaluated in this article, or claim that may be made by its manufacturer, is not guaranteed or endorsed by the publisher.

Keywords: ferroelectrics, HfO2, ZrO2, device characterisation, material characterisation

Citation: Lomenzo PD, Celano U, Kämpfe T and McMitchell SRC (2023) Editorial: Advanced characterization methods for HfO2/ZrO2-based ferroelectrics. Front. Nanotechnol. 5:1114267. doi: 10.3389/fnano.2023.1114267

Received: 02 December 2022; Accepted: 09 January 2023;
Published: 24 January 2023.

Edited and reviewed by:

Rajamani Nagarajan, University of Delhi, India

Copyright © 2023 Lomenzo, Celano, Kämpfe and McMitchell. This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.

*Correspondence: Patrick D. Lomenzo, Patrick.Lomenzo@namlab.com

Disclaimer: All claims expressed in this article are solely those of the authors and do not necessarily represent those of their affiliated organizations, or those of the publisher, the editors and the reviewers. Any product that may be evaluated in this article or claim that may be made by its manufacturer is not guaranteed or endorsed by the publisher.