- 1Department of Physics, Ionic Liquid and Nano Materials Laboratory, Faculty of Engineering and Technology, V. B. S. Purvanchal University, Jaunpur, India
- 2Department of Mechanical Engineering, Faculty of Engineering and Technology, V. B. S. Purvanchal University, Jaunpur, India
- 3Department of Physics, Nanomaterials and Sensor Research Laboratory, Babasaheb Bhimrao Ambedkar University, Lucknow, India
In the current study, a highly efficient and affordable sensor for liquefied petroleum gas (LPG) that operates at ambient temperature was fabricated using a thin film through an easy and low-cost approach. To achieve this objective, MoTe2 was synthesized using a hydrothermal method. The synthesized material was characterized through powder X-ray diffraction (PXRD), Raman spectroscopy, Fourier transform infrared (FTIR) spectroscopy, field-emission scanning electron microscopy (FE-SEM), and energy-dispersive X-ray spectroscopy (EDS). According to the results of PXRD and Raman spectroscopy, a pure phase of layered MoTe2 with a hexagonal structure without any notable impurities was formed. The average crystallite size of the synthesized material is ∼37 nm. Raman spectroscopy and FTIR analysis revealed the presence of Mo–Te vibrational modes. The surface morphology reveals thin, wrinkled sheets with a crumpled topology having flake-like structures. The coexistence of Mo and Te elements was confirmed using the EDS study. The optimized sample was used to prepare the thin film using a spin-coating process. The sensing properties of the MoTe2-based thin film were investigated as a room-ambient sensor for various LPG concentrations below the lower explosive limit of 0.5–2.0 vol%. The best sensor responses were recorded at 2.0 vol% LPG, with a value of 137, and at 0.5 vol% LPG, with a value of 26. Moreover, a rapid response time of 8 s and a recovery time of 22 s were observed at 0.5 vol% of LPG. These rapid dynamics are attributed to the prompt interaction between LPG molecules and pre-adsorbed oxygen species on the film surface, enabling fast adsorption-desorption cycles at active sensing sites. The results highlight the potential of MoTe2 thin films as effective and scalable candidates for ambient LPG detection.
1 Introduction
Unintentional release of flammable gases, such as liquefied petroleum gas (LPG), continues to be a major risk to infrastructure and public safety. Fires, explosions, and fatalities have been reported frequently in residential, commercial, and industrial settings. These incidents, which continue to occur alarmingly frequently despite advancements in safety procedures, are frequently caused by corroded pipelines, faulty fittings, poor maintenance, or user negligence. Because of their low ignition energy, quick diffusion, and accumulation in confined spaces, even minor leaks have the potential to become life-threatening situations if they are not discovered in a timely manner. This reality emphasizes how urgently effective and dependable sensing technologies that can continuously monitor environments and provide early warnings in the event of a gas release are needed.
LPG is an exceptionally flammable gas composed primarily of propane (C3H8) (5%–10%) and butane (C4H10) (70%–80%), along with a small amount of other hydrocarbons (Chaurasiya et al., 2023). It is predominantly used as a source of fuel at domestic and industrial levels. Its high flammability and volatility make it essential to detect leaks promptly to prevent fire hazards and explosions. The lower explosive limit (LEL) of LPG components is ∼2% by volume in air, and regulatory exposure limits set by OSHA and NIOSH mandate early detection at levels well below this threshold (Singh et al., 2021). Gas sensors are a resistive type of sensors that have emerged as a vital tool in LPG detection. These sensors operate using a mechanism where gas adsorption modulates the charge carrier density of the sensing material (n or p type), leading to measurable changes to the resistance, as shown in Table 1. The key performance parameters of any gas sensor are sensitivity, selectivity, response/recovery time, operating temperature, and long-term stability.
So far, a wide variety of materials (viz. metal oxides, carbon nanotubes, graphene, MXene, transition metal dichalcogenides, perovskites, and metal organic frameworks) have been explored for LPG sensing (Gautam et al., 2021; Xu et al., 2017; Island et al., 2017; Dai et al., 2016; Bharati et al., 2024; Tiwari et al., 2022; Tiwari et al., 2024). Metal-oxide semiconductors (SMOs) such as ZnO, TiO2, SnO2, NiO, Fe2O3, and WO3 have been widely studied for their chemical stability, cost effectiveness, ease of fabrication, and high sensitivity. These SMOs have the same working mechanism as that of resistive type of sensors. For example, Choudhary et al. (2021) synthesized α-Fe2O3 and examined their LPG-sensing performance. The fabricated sensor exhibits a response and a recovery time of 52 s and 107 s, respectively, with a sensor response of 87% toward 10 ppm of LPG at 170°C. Shinde et al. (2024) reported the ZnO-based LPG sensor with a sensor response of 367 toward 50 ppm at 350°C, with a rapid response time of 10 s. However, these SMOs often face challenges, such as high operating temperatures, long recovery time, and low selectivity, limiting their use in portable or room-temperature applications.
To address these limitations, two-dimensional (2D) materials have gained attention for their high surface-to-volume ratio, tunable electronic properties, and low activation energy for gas adsorption. Graphene, MoS2, and MXenes have been successfully deployed in sensors for gases such as NO2, NH3, and H2, with improved sensitivity and faster kinetics. Nevertheless, in the context of LPG sensing, studies based on 2D materials remain scarce, with most investigations confined to metal oxide or sulfide-based systems. Within the 2D material family, transition metal tellurides (TMTs), particularly MoTe2, have emerged as highly promising but underexplored candidates. MoTe2 exists in both semiconducting 2H and metallic 1T′ phases, offering a unique ability to tailor surface reactivity and charge transport behavior (Zappa, 2017). MoTe2 is a suitable material for gas sensing because the Te atoms are the most favorable site for the adsorption of O2 molecules in MoTe2. This is owing to the longer bond length (3.93 Å) of Te–O compared to the shorter bond length of Mo–O2 (2.71 Å) in MoTe2. This also explains the facile release of gas molecules from the surface of MoTe2 and enhances the rate at which the system returns to its original state (Zhu et al., 2014). Furthermore, MoTe2 shows a narrow energy bandgap (direct type) of approximately 1.5 eV for a single layer and an indirect energy bandgap of approximately 0.83 eV for bulk MoTe2. This is smaller than the bandgaps of other TMDs (Zhou et al., 2015; Octon et al., 2016). Furthermore, the higher charge carrier density in MoTe2 than in other TMDs, like MoSe2 and WSe2, results in increased sensitivity to gas molecules (Su et al., 2019; Varghese et al., 2015). These characteristics make it a suitable candidate for gas-sensing applications, demanding high sensitivity and rapid response, particularly under ambient conditions. For example, Yan et al. (2024) reported room-temperature NO2 gas sensing based on MoS2/MoO3 heterojunctions. The sensor exhibits 18.9 sensor responses at 1 ppm, with a response time and a recovery time of 20 s and 30 s, respectively. Munusami et al. (2022) reported room-temperature LPG and H2 gas-sensing performance of MoS2/graphene. The sensor showed a sensor response of 12.2 at 1,000 ppm LPG, with a response time and a recovery time of 15 s and 22 s, respectively, compared to H2 gas. Kodan et al. (2024) reported MoSe2–WS2 room-temperature NO2 gas-sensing performance. The sensor gives a sensor response of 59.63% to 50 ppb concentration, with a response time and a recovery time of 68.90 and 65.68 s, respectively.
Recent studies have shown that MoTe2-based devices, including field effect transistors (FETs), exhibit strong gas-sensing behavior toward oxidizing and reducing gases (Feng et al., 2017a; Wu et al., 2018a; Wu et al., 2018b). There are also some reports which show that other MoTe2-based devices such as Schottky diodes exhibit even a better response and recovery time (Feng et al., 2017b; Shackery et al., 2018). Density functional theory and first-principles calculations further support MoTe2’s sensitivity to various gas molecules (Liu et al., 2022; Cao et al., 2021; Panigrahi et al., 2019; Szary et al., 2022; Zhu et al., 2020; Feng et al., 2017a; Liu et al., 2021). Recently, Huang et al. (2025) reported layered MoTe2/ZnO heterojunction for a sensitive TEA sensor at room temperature (RT). The sensor displayed a response time and a recovery time of 147 s and 173 s, respectively, with a sensor response of 91.9% at 19°C. Wu et al. (2025) reported a theoretical calculation using the first-principles DFT calculation for developing a ZnO–MoTe2-based gas sensor. The results showed better adsorption and recovery performance for C2H6 than for CO2 and H2. However, a comprehensive study on MoTe2 for LPG detection has yet to be reported.
The present work addresses this gap by investigating the LPG-sensing behavior of hydrothermally synthesized p-type MoTe2 thin films at room temperature. The sensor exhibits high response, fast response/recovery time, and excellent selectivity toward LPG, demonstrating the potential of MoTe2 as an effective and robust material for next-generation gas sensors for the first time.
2 Experiment
2.1 Materials
Sodium molybdate dihydrate (Na2MoO4·2H2O ≥ 99%), hydrazine hydrate (N2H4.H2O, 98%), absolute ethanol (C2H5OH, 99.8%) and Tellurium metal powder (Te, 99.9% and ∼200 mesh) were purchased from Sisco Research Laboratory (SRL) India. All the chemicals were used as received.
2.2 Hydrothermal synthesis of MoTe2
Two millimole of Na2MoO4.2H2O and four millimole of Te powder were added to 140 mL of deionized (DI) water and stirred for 10 min; after that, 10 mL of N2H4.H2O was added in the above mixture. The resulting mixture was stirred for half an hour. The stirred mixture was transferred into a stainless-steel autoclave having a Teflon-lined sleeve. The autoclave was transferred into an oven at a temperature of 200°C for a reaction time of 48 h. Once the reaction was complete, the autoclave was allowed to cool at room temperature. The obtained sample was rinsed with an abundant amount of DI water and ethanol, and subsequently dried for 12 h at a temperature of 60°C. The synthesis process of hydrothermally synthesized MoTe2 is depicted in Figure 1.
2.3 Thin-film preparation of pristine MoTe2
A photo-resist spin coater was used to prepare the thin film from the synthesized p-type MoTe2 sample on a 2 × 1 cm2 glass substrate. Initially, the glass substrate was cleaned via an ultrasonic cleaner using DI water and ethanol. DI water was used to dissolve the sample for the preparation of the dilute MoTe2 solution. The diluted solution was subjected to sonication. The resulting solution was dropped on the clean glass substrate and placed on a spin coater for 60 s at 3,000 rpm, followed by drying of the coated glass substrate at 50°C for 5 minutes. To obtain the necessary thickness of the thin film, the same procedure was repeated.
2.4 Characterization
The hydrothermally synthesized MoTe2 was characterized using powder X-ray diffraction (PXRD). The PXRD data from the hydrothermally synthesized samples were collected in the range of 20°–70° 2
2.5 LPG-sensing setup
The experimental evaluation of the sensor’s sensing capabilities was conducted by monitoring the fluctuation in electric current during exposure to LPG. A gas chamber constructed from borosilicate glass was designed specifically for detecting LPG gas. The chamber is equipped with inlet and outflow knobs for the purpose of inserting and removing LPG, respectively. The gas chamber consists of a concentration-measuring apparatus, in which the gas chamber was connected to a gas cylinder, along with a mass flow controller that quantified the gas admitted in vol.%. Furthermore, an outlet knob was designed to withdraw unadsorbed LPG. The contacts were made on the prepared thin film using silver paste. The sensing device was connected to a Keithley electrometer (model 6517B) manufactured by Tektronix, Beaverton, Oregon, USA. This electrometer was connected with a sensing device at one terminal and a computer system handling the measurement of electrical data, including current and resistance, at the other terminal, as shown in Figure 2.
3 Results and discussion
3.1 PXRD
PXRD is used to examine the purity of the synthesized phase and crystalline nature of the synthesized sample. The PXRD pattern of the synthesized sample is shown in Figure 3. The diffraction peaks for pristine MoTe2 were observed at 2
Here, λ is the wavelength of X-ray in radians,
3.2 FTIR spectroscopy
FTIR analysis offers important information regarding the functional groups and various types of chemical bonds present in the materials. The FTIR spectrum of synthesized MoTe2 nano-material is used to analyze the vibrational bands of synthesized nano MoTe2 in the frequency range between 4,000 and 500 cm−1. The recorded FTIR spectrum of synthesized nano MoTe2 is depicted in Figure 4. The FTIR spectrum of the synthesized nano MoTe2 material show a vibrational band at 1,632 cm−1. The band assigned to this is attributed to the bending mode of adsorbed water, whereas the wide band at 3,447–3,499 cm−1 is assigned to a O−H stretching mode of liquid or adsorbed water H−O−H (Shinde et al., 2021; Singh et al., 2017). Additionally, the vibrational band observed at 1,084 cm−1 is assigned to the stretching mode of metal oxide (M−Ox) bonds (Abdullah et al., 2023; Shirpay and Mohagheghi, 2020). The vibrational bands observed at a low wave number of 602 cm−1 and a vibrational peak at 735 cm−1 correspond to the vibrational mode of metal-telluride for nano MoTe2 (Abdullah et al., 2023). The vibrational frequency at 1,435 cm−1 is corresponding to Te−O oxidation vibrational modes. The presence of characteristic vibrational modes of synthesized nano MoTe2 validates the effective synthesis of the MoTe2 material.
3.3 Raman spectroscopy
Raman spectroscopy is a powerful method for investigating vibrational modes, detecting defects, and assessing structural phase purity. A LASER source of 532 nm was used to record the Raman spectrum of the MoTe2 nano-crystalline material. Figure 5 presents the Raman spectrum of MoTe2 recorded between 1,000 and 80 cm−1. MoTe2 exhibits all the Raman active modes in the investigated range. These three prominent modes of vibration correspond to the characteristic vibrational modes of MoTe2. The vibrational mode at 224 cm−1 corresponds to the conspicuous in-plane E12g mode of vibration. The E12g peak signifies the in-plane vibration induced by two tellurium atoms in relation to a molybdenum atom (Grzeszczyk et al., 2016). The existence of this mode of vibration indicates the formation of the layered MoTe2 structure. The vibrational mode at 175 cm−1 corresponds to the out-of-plane A1g mode. The in-plane E1g mode is observed at 118 cm−1. The presence of the weaker A1g mode also confirms few numbers of layers in the synthesized MoTe2. All the observed vibrational modes of Raman corresponding to E12g, A1g, and E1g modes are in good agreement with the 2H phase of MoTe2. The absence of additional bands that typically arise in the monoclinic 1T′ phase—characterized by complex multiple structures due to the reduced symmetry—confirms that the synthesized sample is structurally consistent with the semiconducting 2H phase. These vibrational characteristics are in strong agreement with previously reported Raman profiles for hexagonal 2H–MoTe2. This result is consistent with the PXRD analysis, confirming the formation of the pure 2H–MoTe2 phase (Zhou et al., 2015; Guo et al., 2015; Lv et al., 2017).
3.4 FE-SEM
The morphology and structure of the MoTe2 material were analyzed using FE-SEM. Figure 6a, b depicts the FE-SEM micro-images of MoTe2 synthesized using the hydrothermal technique. Figure 6a shows a disordered and highly textured surface with prominent flake-like and platelet structures. These flakes appear randomly oriented and aggregated into loosely packed clusters, suggesting a layered morphology. The lateral dimensions of the flakes range from ∼200 to 800 nm, with thicknesses consistent with few-layered to multilayered structures. Additionally, several elongated features are observed, which may indicate anisotropic growth behavior, possibly driven by the directional energy minimization along specific crystallographic planes during hydrothermal synthesis. Figure 6b shows thin, wrinkled sheets with a crumpled topology, consistent with exfoliated or few-layered 2D layers. These morphological features are indicative of weak van der Waals interactions between the layers, facilitating delamination and restacking. Notably, numerous ultrafine nanoparticles can be observed uniformly distributed on or near the MoTe2 flakes. These particles are attributed to a nucleation center. This morphology is consistent with the crystallographic features identified in PXRD analysis. The diffraction peaks observed at 2θ values of 38.38°, 43.47°, 52.07°, 63.83° and 66.02° correspond to the (006), (105), (110), (203) and (116) planes of hexagonal 2H–MoTe2, respectively, confirming the formation of a layered structure. Raman observations also complemented these findings by revealing a few-layer configuration, which aligns with the thin-sheet morphology observed in the SEM. Together, the SEM, PXRD, and Raman results confirm that the synthesized MoTe2 possesses a layered, few-sheet architecture, with high crystallinity and pure 2H symmetry, which is ideal for applications requiring efficient surface interaction and charge transport.
Furthermore, the EDS analysis, as shown in Figure 7a, was conducted to determine the composition of the elements present in the synthesized MoTe2 nano-material. The results confirm that the material primarily consists of two elements: molybdenum (Mo) and tellurium (Te). Figures 7b–d display the elemental distribution and color mapping of MoTe2, revealing a uniform dispersion of Mo and Te throughout the sample. It is also worth noting that the color mapping indicates a Te-rich pattern, which aligns with the PXRD observation and is attributed to the presence of weaker Te rings (Bhat and Nagaraja, 2019).

Figure 7. EDS spectra of synthesized MoTe2. (a) Elemental mapping of Mo (b), elemental mapping of Te (c), and elemental mapping of MoTe2 (d).
4 LPG-sensing performance of the MoTe2-sensing film
The LPG-sensing capabilities are assessed by investigating the change in electrical resistance of the prepared MoTe2 thin-film sensor at 0.5–2.0 volume % of LPG concentration at an ambient temperature. Figure 8 illustrates the response and recovery properties of the MoTe2-sensing film after exposure to a range of concentrations from 0.5 to 2.0 vol%, below the LEL value. First, the value of sensor’s current is set fixed at a constant value in air, and then, the static resistance was observed in air. This is taken as Ra. Second, the thin film was exposed through LPG, and the change in resistance (Rg) was recorded. To check the all-inclusive sensor’s parameters, such as response and recovery time, selectivity, and sensitivity, relevant tests were conducted. Figure 8 shows the response of the sensor at various concentrations of LPG. A strong correlation between the detection capabilities of the sensor and the gas concentration is shown by the fact that as the LPG concentration increases from 0.5 to 2.0 vol%., it is interesting to observe that the resistance of the sensing element increases with the LPG concentration. The sensor response of the prepared thin-film sensor is determined by the ratio of the measured resistance (when exposed to the target gas) to the resistance in the air. The response of the thin-film sensor at different concentrations of LPG was determined using Equation 2 (Verma et al., 2022; Singh et al., 2021) and presented in Figure 9a.
where Rg is the resistance after LPG exposure and Ra is the resistance in the air. Figure 9a shows that the sensor response at a low concentration of LPG (0.5 vol%) is 26. In contrast, the largest sensor response was determined as 137 at 2.0 vol% LPG concentration. It is demonstrated that with the increase in the concentration of LPG, the sensor response increases linearly (Figure 9a), indicating that a smaller amount of the gas interacts with a smaller portion of the sensing film surface. However, when the LPG concentration increases, the area covered by the gas also increases proportionately; therefore, an increased surface contact is established between the LPG and the thin-film sensor, consequently increasing the sensor response. The sensitivity of the LPG sensor is defined as the ratio of the change in the resistance to the change in the concentration (Verma et al., 2022).

Figure 9. (a) LPG volume % vs. response of sensor of the MoTe2 thin-film sensor. (b) LPG concentration-dependence time of response and time of recovery. (c) Sensing response curve at 0.5 volume % LPG. (d) Reproducibility for 1.5 volume % LPG.
To find out the value of the sensitivity of the thin-film sensor, a linear regression analysis was carried out. The value of sensitivity is obtained from the slope of linear fitting of LPG vol% vs. sensor response. The evaluated value of sensitivity was 77 sensor response per vol%. Moreover, the R2 factor value was 0.97, indicating that even the device operates well below the LEL. This sensitivity value and R2 generally describe the reliability of the LPG sensor.
The fabricated MoTe2 thin film has a faster response and recovery time for low-concentration gas than for high-concentration LPG. The determination of response and recovery time is derived using the characteristic graph (Figure 8). The response and recovery curves of the sensing film at different LPG concentrations are depicted in Figure 9b. The time of response of the sensing films was determined by measuring how long it takes for their resistance to change by 90% after exposure to LPG. Similarly, the time of recovery of the sensing films was determined by measuring how long it takes for their resistance to change by 90% and return to its initial value after the removal of the LPG. The characteristic curve of the sensor response for 0.5 vol% of LPG is presented in Figure 9c. An excellent sensor response and a recovery time of 8 and 22 s, respectively, were achieved for 0.5 vol% LPG. Table 2 shows the sensor response and time of response and recovery at different concentrations of LPG.
Repeatability is an essential sensor parameter that refers to the ability to consistently produce the similar result over a specific time interval for similar measurements. The recurrence graph for 1.5 vol% LPG using the MoTe2 sensor film is shown in Figure 9d, which displays four consecutive cycles. Here, we found that the reported sensor yielded a result of 99.40%, with an error of only 0.6%. This is possibly due to the presence of moisture, which reduces the absorption capacity (Hu et al., 2012).
Selectivity is a sensor’s ability to differentiate the gas of interest from other analyte gases. High selectivity indicates a stronger response of the sensor to the target gas than to other analyte gases. In this study, variety of gases are used to evaluate the MoTe2-sensing film’s selectivity using methanol (CH3OH), LPG, ethanol (C2H5OH), acetone (CH3COCH3), and carbon dioxide (CO2) for 0.5 vol% at room temperature, as illustrated in Figure 10a. The sensor responses to methanol, LPG, ethanol, acetone, and CO2 are recorded as 12, 26, 10, 5, and 3, respectively. Additionally, the coefficient of selectivity (K) of all gases used in this study is evaluated from Equation 4:

Figure 10. (a) Selectivity of the MoTe2 sensor for different target gases at 0.5 vol%. (b) Effect of humidity on LPG sensing.
where S.RLPG and S.RGas represent the sensor response for LPG and other gases, respectively. The thin film exhibited a selectivity coefficient of 2.16 for methanol, 2.6 for ethanol, 5.2 for acetone, and 8.6 for CO2. A higher K-value indicates greater selectivity in LPG detection than in the detection of other gases used in this study. For example, a K-value of 2.16 for methanol describes that the response of the sensor toward LPG is 2.16 times greater than that of methanol. These results indicate that the MoTe2-sensing film exhibits the highest selectivity coefficient toward LPG of all other analyte gases. The performance of the fabricated thin-film sensor based on the synthesized MoTe2 nanomaterial is compared with the recently investigated materials for LPG gas detection, as shown in Table 3. This table clearly demonstrates that the material (MoTe2) used in this study exhibits a rapid response time (8 s) and excellent recovery time (22 s) at room temperature compared to other materials for LPG sensing. It is interesting to note that the present investigation is carried out at room temperature, whereas others are reported at higher temperature. Furthermore, it is also clear from Table 3 that the present work has a much better response time (8 s) than the other materials reported at room temperature for the detection of LPG. Therefore, the MoTe2 nanomaterial is competitive and superior to many of the reported materials that often require elevated operating temperatures or exhibit slower dynamics. This demonstrates the potential of MoTe2 as a promising material for future development of low-power, high-performance gas sensors operating at room temperature.
The influence of humidity on the sensing performance of MoTe2 thin films has also examined in the presence of 0.5 vol% LPG. The humidity within the chamber increases to 30%–100% using a humidifier with a K2SO4-saturated solution, as shown in Figure 10b. In the lower humidity range (30%–45%), the sensor exhibits a strong response, whereas in the mid-range (50%–65%), only minor fluctuations are detected; at elevated humidity levels (70%–90%), the sensor response reduces because at higher humidity, physisorption is saturated, and contact between the sensing film and LPG molecules is weaker, resulting in a reduced sensing performance. The MoTe2 thin film is very appropriate for the mid-humidity spectrum.
5 Gas-sensing mechanism
The mechanism of the gas sensing of the MoTe2 sensor shows fluctuation of the charge carrier on thin film surface upon encountering LPG. Thin film surfaces have adsorbed ambient oxygen via charge transfer. Both the molecular (O2−) and atomic oxygen (O− and O2−) species are ionized as surface oxygen. The existence of negative oxygen species is essential for LPG absorption as it has an affinity for O2−, which enhances receptor activation. The processes governing oxygen absorption on thin-film surfaces are presented in Equations 5–7:
In a LPG-containing environment, LPG adsorbed on the thin film’s surface interacts through pre-ionized oxygen species and forms hydrogen bonds with the surface molecules and produces changes in electrical resistance. The interaction of LPG and the adsorbed oxygen species is described using chemical reactions outlined in Equations 8 and 9, which illustrate the possible mechanisms underlying the LPG-sensing response. When LPG interacts with chemisorbed oxygen species, a dehydration process occurs, resulting in an unstable intermediate complex (CnH2n:O) and release of CO2 and H2O. The probable reactions are as follows:
Here, n is equal to 3 and 4.
On the surface of the thin film, as the concentration of LPG increases, the interaction between LPG and chemisorbed oxygen species also increases. Increased LPG content leads to higher interaction between LPG and chemisorbed oxygen species, resulting in the release of electrons (Equations 8, 9). These electrons then recombine with holes in the p-type material, leading to a reduction in hole concentration. This reduction in majority carriers increases the resistance of the MoTe2 film. The released electron creates a diffusion pathway by reducing the space charge region, facilitating better interaction between gas molecules and the sensor film, which enhances the sensor’s performance.
As the LPG concentration increases, the interaction between LPG and chemisorbed oxygen species also increases. As elaborated in Equations 8, 9, the release of electrons increases the height and width of the barrier potential. At saturation, resistance remains constant, and the decrease in resistance upon LPG removal is due to the recovery of surface-adsorbed oxygen species, which re-establish the charge transfer equilibrium and restore hole-rich conditions in the p-type MoTe2 material. The mechanism is schematically depicted in Figure 11. In this study, the MoTe2 thin film serves as an efficient room-temperature LPG sensor capable of detecting trace amounts of LPG with rapid response and fast recovery while exhibiting remarkably high sensor responsivity and sensitivity.
6 Conclusion
In conclusion, a simple and easy hydrothermal method was used for successful synthesis of the MoTe2 nano-materials. The PXRD analysis confirmed the existence of the MoTe2 hexagonal phase, with an average crystallite size of 37.14 nm and percentage crystallinity of 95%. Microstructural, morphological, and elemental analyses of the synthesized MoTe2 revealed thin, wrinkled sheets with a crumpled topology and flake-like structures, along with the presence of Mo and Te elements. Finally, the MoTe2 thin-film sensor was fabricated and tested for room-temperature LPG detection from LPG concentration of 0.5–2.0 vol%. The fabricated sensor demonstrated excellent sensing capabilities with very quick time of response as 8 s and fast time of recovery as 22 s at 0.5 vol% of LPG. The sensitivity of the sensor was found to be 77 sensor responses per concentration. The linear concentration dependence of the sensor’s response was found for LPG, with a maximum value of 137 at 2.0 vol% of LPG. The repeatability test was carried out for 1.5 vol% LPG using the MoTe2 thin film, in which four consecutive cycles were performed, and the fabricated sensor showed a repeatability of 99.40% with an error of 0.6%. The fabricated sensing film shows excellent selectivity toward LPG measurements with various analyte gases, such as methanol, LPG, ethanol, acetone, and CO2, at a concentration of 0.5 vol% and at room temperature. The sensor responses to methanol, LPG, ethanol, acetone, and CO2 were found to be 12, 26, 10, 5, and 3, respectively. These results indicate that the MoTe2-sensing film exhibits the highest sensitivity to LPG of all other gases. As the findings provide shorter response times and greater LPG sensitivity, this cost-effective synthesized MoTe2 with elongated nano-needle and sheet-like structures shows excellent performance in LPG detection. These features establish MoTe2 as a promising candidate for the next generation of low-power, miniaturized gas sensors, with potential extension to other volatile organic compounds, smart home safety systems, and industrial leak detection networks, and it has the potential to boost the sensing market.
Data availability statement
The original contributions presented in the study are included in the article/Supplementary Material; further inquiries can be directed to the corresponding author.
Author contributions
AS: Investigation, Methodology, Writing – original draft, Formal Analysis, Visualization. AK: Visualization, Investigation, Formal analysis, Writing – review and editing. NC: Writing – review and editing, Visualization, Resources, Validation. AR: Resources, Data curation, Validation, Writing – review and editing. MG: Resources, Data curation, Writing – review and editing, Validation. BY: Resources, Validation, Writing – review and editing. MS: Resources, Formal Analysis, Project administration, Funding acquisition, Methodology, Supervision, Conceptualization, Writing – review and editing.
Funding
The author(s) declare that no financial support was received for the research and/or publication of this article.
Conflict of interest
The authors declare that the research was conducted in the absence of any commercial or financial relationships that could be construed as a potential conflict of interest.
Generative AI statement
The author(s) declare that no Generative AI was used in the creation of this manuscript.
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Keywords: LPG sensor, thin films, hydrothermal method, transition metal dichalcogenides, sensor performance
Citation: Singh A, Kumar A, Chaurasiya N, Rani A, Gupta M, Yadav BC and Singh MP (2025) Highly sensitive and fast-responsive room-temperature LPG sensor based on hydrothermally synthesized MoTe2. Front. Nanotechnol. 7:1623625. doi: 10.3389/fnano.2025.1623625
Received: 06 May 2025; Accepted: 17 July 2025;
Published: 29 August 2025.
Edited by:
Chella Santhosh, K L University, IndiaReviewed by:
Yilin Sun, Beijing Institute of Technology, ChinaS. R. Srither, Southern University of Science and Technology, China
Copyright © 2025 Singh, Kumar, Chaurasiya, Rani, Gupta, Yadav and Singh. This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.
*Correspondence: Manish Pratap Singh, ZHJtYW51OTlAZ21haWwuY29t