Abstract
Neuromorphic computing is a promising paradigm for developing energy-efficient and high-performance artificial intelligence systems. The unique properties of lithium niobate-based (LiNbO3)-based memristors, such as low power consumption, non-volatility, and high-speed switching, make them ideal candidates for synaptic emulation in neuromorphic systems. This study investigates the potential of LiNbO3-based memristors to revolutionize neuromorphic computing by exploring their synaptic behavior and optimizing device parameters, as well as harnessing the potential of LiNbO3-based memristors to create efficient and high-performance neuromorphic computing systems. By realizing efficient and high-speed neural networks, this literature review aims to pave the way for innovative artificial intelligence systems capable of addressing complex real-world challenges. The results obtained from this investigation will be crucial for future researchers and engineers working on designing and implementing LiNbO3-based neuromorphic computing architectures.
Introduction
The quest for energy-efficient and high-performance computing systems has led to exploring novel materials for applications in emerging paradigms, such as neuromorphic computing. Neuromorphic computing (), inspired by the remarkable efficiency of the human brain, has emerged as a promising alternative to traditional computing paradigms for building energy-efficient and high-performance artificial intelligence systems. This field focuses on developing brain-inspired architectures that mimic neural networks’ parallel and distributed processing capabilities. A crucial component of neuromorphic systems is the memristor (Volos et al., 2015), the fundamental building block that emulates synaptic behavior and enables efficient learning and adaptation in neural networks.
Among various materials investigated for memristor technology, LiNbO3-based memristors () have garnered significant attention due to their unique combination of properties. The ferroelectric nature, electro-optic properties, non-volatility, low power consumption, high-speed switching, and the capability for multi-level resistance states collectively position LiNbO3 as a multifaceted material for developing efficient and brain-inspired computing architectures. Accordingly, the exploration of LiNbO3 in neuromorphic computing stems from its potential to mimic synaptic behavior and facilitate energy-efficient computing processes (; Xu et al., 2023).
The ferroelectric nature of LiNbO3
LiNbO3 is a ferroelectric material with multiple invaluable technological applications. Ferroelectricity in lithium niobate crystals can be attributed to face-sharing octahedra aligned along the crystal’s c-axis (Xue and Kitamura, 2003). In neuromorphic computing, a material’s ferroelectric nature becomes particularly intriguing due to its potential to mimic synaptic behavior—a key aspect of artificial neural networks inspired by the human brain (Suna et al., 2022; Wang et al., 2022; Xu et al., 2023). The study of LiNbO3 in neuromorphic computing is relevant in pursuing efficient and brain-like computing architectures. LiNbO3’s ferroelectricity property is crucial for emulating synaptic plasticity, allowing for the adjustment of synaptic weights in response to external stimuli (Wang et al., 2022; X; ; Wang et al., 2023a; ). The reversible polarization of LiNbO3 aligns with the dynamic nature of synapses, providing a foundation for the material’s application in neuromorphic systems. The inherent ferroelectric nature of LiNbO3, characterized by spontaneous polarization (; Yoo et al., 2018), domain structures (), and piezoelectricity (Vakulov et al., 2020; ; ), justifies its multifaceted utility. These articles serve as key references in comprehending the fundamental aspects of LiNbO3’s ferroelectric nature.
The spontaneous electric polarization that LiNbO3 exhibits can be reversed by applying an external electric field (; Stone et al., 2011; Tayi et al., 2012). Besides, LiNbO3 crystallizes in the trigonal structure belonging to the R3c space group (; ; ; ). The crystal structure comprises corner-sharing NbO6 octahedra and Li ions occupying interstitial sites (). The non-centrosymmetric structure also contributes to the material’s ferroelectric properties (). Additionally, LiNbO3 undergoes a ferroelectric phase transition at a high Curie temperature (TC) of between 1,141 and 1,210°C (), where ferroelectric properties, including the spontaneous polarization, disappears (Voskresenskii et al., 2017; ; ). Figure 1 illustrates the crystalline structure of LiNbO3 exhibiting ferroelectric properties with a stoichiometric composition that remains stable for temperatures below the curie temperature. The Curie temperature shifts depending on the chemical composition. The basic net consists of six evenly spaced layers of oxygen per unit length, arranged along the polar axis c.
FIGURE 1
LiNbO3 has advantageous ferroelectric properties over other perovskite materials, making it a prominent candidate for various neuromorphic applications. Its high Tc ensures stability over a wider range of operating conditions than its counterparts, including lead zirconate titanate (PZT) (
FIGURE 2

Schematic phase diagram of the Li2O—Nb2O5 pseudo-binary system near the congruent and stoichiometric composition of LiNbO3 (
The binary phase diagram in Figure 2 shows the wide solid solution range exhibited by LiNbO3. This solution can be stable on lithium composition between 46.5 and 50 mol%. The diffuse peak at around 48.5% Li2O is evident in the liquid–solid curve, beyond which the formation of secondary phases such as LiNb3O8 and Li3NbO4 can occur (
The ferroelectric property makes lithium niobate have significant applications in various fields, including optics, acoustics, and information processing (
Piezoelectric phenomena in LiNbO3
While investigating the piezoelectric nature of LiNbO3, studies have offered a detailed exploration of the material’s response to mechanical stress (
Non-volatility and low power consumption
Although lithium niobate is not typically associated with memory retention in the same way as traditional electronic materials used in computer memory, such as silicon-based technologies, it has been explored for multiple applications, including non-volatile memory and optical memory devices. The non-volatile characteristics of LiNbO3 play a pivotal role in reducing the power requirements for maintaining synaptic weights. One of the defining features that positions LiNbO3 as a frontrunner in neuromorphic computing is its non-volatile nature, which allows for the retention of synaptic weights even when power is removed. Xu et al. (2023) and Wang et al. (2015) discuss how this characteristic allows for the retention of synaptic weights even in the absence of power, mimicking the persistent connectivity of biological synapses. Besides, Wang et al. (2017) show that the ferroelectric property of LiNbO3 enables the retention of synaptic weights even when power is removed. This persistence aligns with the essence of non-volatile memory, mirroring the sustained connectivity observed in biological synapses. The non-volatile aspect is fundamental for the stability and integrity of neural networks.
In Figure 3A left, a LiNbO3 device retention test was conducted as the device was set to RMIN and was measured at regular intervals within 24 h. Data reveals negligible variation in the programed device state when measured at room temperature over that period. Figure 3A right shows the results of a retention test on a LiNbO3 device at different temperatures, considering a programmed intermediate state at approximately 1 mA. The tests were also performed on the LiNbO3 device at temperatures between 20 and 100°C (Wang et al., 2017). Results showed negligible current change as device temperatures are increased. Likewise, Figure 3E illustrates how LiNbO3 device demonstrates outstanding data retention performance over 27.7 h at room temperature. Additionally, Figure 3F shows conductance undergoes only a 0.74% decay process after approximately 16.7 h from programming the device to a high conductance state, as it remains stable without degradation. As a result, Wang et al. (2023c) speculates that the device retention lifetime at room temperature can be up to 10 years.
FIGURE 3

(A) Shows a retention test to prove the non-volatility characteristics of LiNbO3 memristor (Wang et al., 2017). (B) Shows the electroforming process and resulting I–V curve are typical, with a cross-sectional diagram of the memristor showing its structure as Au/LNO/Cr/Pt/Cr. In (C), device endurance is demonstrated over 5 × 105 cycles with a switching window of 80, indicating robust performance. (D) Reveals detailed statistical analysis that the device effectively switches with minimal fluctuations, as evidenced by the Normal distribution function fitting of the low-resistance state (LRS). Just as in (A), (E) reveals that retention testing over a prolonged period of 105 s shows stable behavior. (F) Detailed analysis of LRS retention over the same period indicates minimal conductance decay, with stability maintained for approximately 16.7 h after programming the device to a high-conductance state (LRS) (Wang et al., 2023b).
LiNbO3-based memristors also exhibit low power consumption, addressing the demand for energy-efficient computing systems, as revealed by Zaman et al. (2017), Xu et al. (2023), Wang et al. (2015), and
In the pursuit of prolonged neural network operations (Wang et al., 2023b), shed light on LiNbO3’s role in enabling persistent synaptic connections. The non-volatile property of LiNbO3 ensures that the information encoded in synaptic weights remains intact over extended periods. This feature is particularly crucial for applications requiring continuous learning and adaptation, positioning LiNbO3 as a material with profound implications for the longevity of neuromorphic systems. As this field advances, integrating LiNbO3 into neuromorphic architectures holds promise for creating sustainable, high-performance artificial intelligence systems. Likewise, non-volatile memory is crucial for retaining information even when power is disconnected, offering energy efficiency and data persistence advantages. Sun et al. (2023) explore the implications of LiNbO3’s ferroelectricity in non-volatile memory applications. The study investigates ferroelectric field-effect transistors based on LiNbO3, highlighting its potential for high-density memory storage. This work underlines the relevance of LiNbO3’s ferroelectric nature in advancing data storage technologies. Indeed, LiNbO3-based memristors exhibit low power consumption and efficient memory retention, crucial for extending the operational life of neural network systems, especially in scenarios where energy conservation is imperative.
High-speed switching and synaptic plasticity
High-speed switching and synaptic plasticity support neuromorphic computing systems’ dynamic learning and adaptation processes. Multiple studies collectively reveal the important role of LiNbO3 in enabling high-speed switching and synaptic plasticity within neuromorphic computing. LiNbO3’s high-speed switching capability is critical for emulating synaptic plasticity in neuromorphic systems. For instance, Figure 3B illustrates the typical electroforming process and successive I–V sweeps for the LNO-based devices. Following electroforming, the device exhibits analog switching behavior. According to J. Wang et al. (2023c), Ar+ beam irradiation allows the device to acquire switching characteristics and significantly reduces the operating voltage. Figure 3C shows the endurance property of the LiNbO3 memristor, demonstrating reliable endurance characteristics. More detailed cyclic switching analyses are depicted in Figure 3D in which the cyclic conductance states show that the device effectively switches in every cycle without becoming stuck at any state. Indeed, memristors based on LiNbO3 have demonstrated rapid switching speeds, enabling efficient adaptation to changing neural network conditions (Yakopcic et al., 2017;
Research has also focused on realizing synaptic plasticity in LiNbO3-based memristors. For instance, Wang et al. (2022) and
Multi-level resistance states and weighted synapses
LiNbO3 memristors play a significant role in achieving multi-level resistance states and weighted synapses within neuromorphic computing. LiNbO3-based memristors exhibit multi-level resistance states, enabling the implementation of weighted synapses. This aspect, discussed by (Zaman et al., 2017), is pivotal for the precision and flexibility of synaptic emulation. The ability to represent the strength of connections between artificial neurons with high granularity enhances neuromorphic systems’ computational power and accuracy. LiNbO3-based memristors exhibit multi-level resistance states, providing the opportunity for implementing weighted synapses. This feature is essential for accurately representing the strength of connections between artificial neurons in a neuromorphic system (Zaman et al., 2017; Zaman, 2020). Multi-level resistance states contribute to the precision and versatility of synaptic emulation.
Figure 4A shows experimental findings concerning the stability challenges influencing the non-volatile LiNbO3 circuit element at room temperature. The plot in Figure 4A illustrates a steady rise in resistance levels and the stability of the state for voltage pulses at 0.1, 0.4, and 0.7 V. Stable resistance states between the high and low resistance states of the Ti/LiNbO3/Pt MIM structure were successfully attained for the three distinct pulse voltages. Besides, Figure 4B confirms the LiNbO3 memristor’s high reliability across multiple conductance levels (16 distinguishable states) for weight updating in artificial neural networks (Wang et al., 2023b).
FIGURE 4

(A) Multiple resistance levels along the sub-threshold region within a 7.5 um2 memristor device at room temperature (Zaman et al., 2017). (B) Retention performance of 4-bit distinguishable intermediate states of a LiNbO3 memristor (Wang et al., 2023a).
Zaman (2020) and
Zaman et al. (2020) provide experimental evidence supporting the feasibility of achieving weighted synapses with LiNbO3-based memristors. Experimental studies also reveal how LiNbO3’s inherent properties, when harnessed through advanced fabrication techniques, enable the reliable and reproducible creation of memristors with multiple resistance states (Wang et al., 2017; Zaman et al., 2019). These experimental validations reinforce the theoretical foundation for LiNbO3 as a material for implementing weighted synapses. Besides, Wang et al. (2017) explore the role of weighted synapses in enabling dynamic adaptation within neuromorphic systems. Their research demonstrates how the precise adjustment of synaptic weights, facilitated by LiNbO3’s multi-level resistance states, contributes to the efficient emulation of cognitive functions such as pattern recognition and deep learning capabilities. This dynamic adaptation is a hallmark of intelligent systems inspired by biological neural networks.
Expanding on the scalability (
Electro-optic and nonlinear optical properties
LiNbO3’s electro-optic and nonlinear optical properties add a layer of versatility to its utility in neuromorphic computing. Studies have extensively explored these properties, highlighting how LiNbO3 facilitates various nonlinear optical processes, including frequency conversion and generation of new wavelengths through processes like second harmonic generation.
Foundational works by Weigand et al. (2021),
Volatile properties of LiNbO3 memristors
Dynamic memristors based on LiNbO3 exhibit unique volatile properties, primarily attributed to its nonlinear I-V (current-voltage) characteristics. As shown in Figure 5, LiNbO3 device exhibits bi-directional switching between a HRS and a LRS when the voltage surpasses specific threshold values of either polarity. Once the voltage intensity decreases below a certain hold value, spontaneous transition from LRS to HRS occurs, indicating the device’s volatile memristive behavior. Besides, its I-V characteristics display nonlinearity, regardless of varying sizes, signifying volatile switching across all lithium niobate devices. Despite size differences, all devices switch to LRS at approximately 2 V. Additionally, Figure 5F illustrates the dependency of LRS and HRS currents on device size, where HRS current escalates with device size while LRS current remains relatively constant. This suggests a filamentary nature in volatile switching. The I-V curves in Figure 5F for a specific device size under positive voltage sweepings with different stop voltages reveal an increase in LRS current with higher stop voltages, indicating thicker conducting filament formation under stronger voltages. The nonlinearity in the I-V curve enables the memristor to have short-term memory, a characteristic that sets it apart from traditional resistive switching devices (Zhao et al., 2023).
FIGURE 5

(A) shows the schematic structure of the Pt/LiNbO3/Au memristor, while (B) illustrates the typical I-V characteristics of the lithium niobate memristor. (C) displays the results of a fifty-cycle endurance test conducted on the lithium niobate memristor. (D) presents the I-V characteristics of five lithium niobate memristors of varying sizes. (E) shows the currents flowing through five lithium niobate memristors of different sizes in both their low resistance states and high resistance states. (F) exhibits the I-V characteristics obtained by altering the stop voltage during the sweeping process (Zhao et al., 2023).
The volatile property stems from the material’s ability to undergo reversible changes in resistance, enabling swift information storage and retrieval within short time frames (
Compatibility with advanced fabrication techniques
The seamless integration of novel materials into neuromorphic devices necessitates compatibility with advanced fabrication techniques. LiNbO3 aligns with this requirement, enabling precise manufacturing processes and contributing to developing high-performance neuromorphic devices. Advancements in fabrication techniques have facilitated the integration of LiNbO3 into memristor arrays. The compatibility of LiNbO3 with various fabrication methods, such as chemical vapor deposition and sputtering (
Besides, integrating electro-optic devices on lithium-niobate-on-insulator (LNOI) holds promise for enhancing the functionality and performance of memristors in neuromorphic systems. LNOI has an edge over indium phosphorus, silicon, silicon nitride, and silicon oxide materials due to multiple features such as intrinsic electro-optical effects, which makes LNOI’s optical switching speed faster with lower power consumption than its counterparts that depend on thermal-optical effects to attain the modulation of optical phase (
Studies have demonstrated the compatibility of LiNbO3 with advanced fabrication techniques. This adaptability positions LiNbO3 as a versatile material that can be seamlessly integrated into the rapidly evolving landscape of neuromorphic device manufacturing, presenting a potential for developing precise, scalable, and multifunctional artificial intelligence systems. The intricate interplay between advanced fabrication methods and the unique characteristics of LiNbO3 memristor devices opens avenues for tailoring neuromorphic devices with unprecedented precision, paving the way for their seamless integration into the rapidly evolving landscape of artificial intelligence and cognitive computing.
Conclusion
The significance of lithium niobate memristors in neuromorphic computing and its potential impact on artificial intelligence applications cannot be ignored. The literature reviewed reveals the unique properties of LiNbO3 that make it an excellent candidate for neuromorphic computing. Its unique set of electro-optic and nonlinear optical properties, non-volatile nature, low power consumption, high-speed switching, multi-level resistance states, I-V volatile properties, and compatibility with advanced fabrication techniques position LiNbO3 as a versatile material for efficient and high-performance memristor-based neuromorphic systems. As the field advances, integrating LiNbO3 into neuromorphic architectures holds immense promise for realizing dynamic, responsive, and efficient artificial intelligence systems.
Statements
Author contributions
CK: Resources, Writing–original draft, Writing–review and editing. YL: Resources, Supervision, Writing–review and editing, Conceptualization.
Funding
The author(s) declare that no financial support was received for the research, authorship, and/or publication of this article.
Acknowledgments
The authors would like to thank postgraduate students and academics at Liaoning Technical University, especially Polycarp Shizawaliyi Yakoi, who assisted during the article’s editing process. The authors wish to thank the editor and reviewers for their valuable time in reviewing the manuscript.
Conflict of interest
The authors declare that the research was conducted in the absence of any commercial or financial relationships that could be construed as a potential conflict of interest.
Publisher’s note
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References
1
Abdul-HusseinW. A.AlmusaweA. J. (2023). Structural, electronic, linear, and nonlinear optical properties of undoped and Mo (I, II)-doped LiNbO3 crystal. Tech. Romanian J. Appl. Sci. Technol.13, 88–101. 10.47577/technium.v13i.9623
2
BacheM.WiseF. W. (2010). Type-I cascaded quadratic soliton compression in lithium niobate: compressing femtosecond pulses from high-power fiber lasers. Phys. Rev. A - Atomic, Mol. Opt. Phys.81 (5), 053815. 10.1103/PhysRevA.81.053815
3
BirnieD. P. (1990). The spontaneous polarization as evidence for lithium disordering in LiNbO 3. J. Mater. Res.5 (9), 1933–1939. 10.1557/JMR.1990.1933
4
BoesA.CorcoranB.ChangL.BowersJ.MitchellA. (2018). Status and potential of lithium niobate on insulator (LNOI) for photonic integrated circuits. Laser Photonics Rev.12 (4). 10.1002/lpor.201700256
5
BornandV.HuetI.PapetP. (2003). LiNbO3 thin films deposited on Si substrates: a morphological development study. Mater. Chem. Phys.77 (2), 571–577. 10.1016/S0254-0584(02)00107-4
6
CabukS. (2012). The nonlinear optical susceptibility and electro-optic tensor of ferroelectrics: first-principle study. Central Eur. J. Phys.10 (1), 239–252. 10.2478/s11534-011-0079-3
7
ChaudharyP.LuH.LipatovA.AhmadiZ.McConvilleJ. P. V.SokolovA.et al (2020). Low-voltage domain-wall LiNbO3Memristors. Nano Lett.20 (8), 5873–5878. 10.1021/acs.nanolett.0c01836
8
ChenF.AmekuraH.JiaY. (2020). Photonic structures based on thin films produced by ion beams. Berlin, Germany: Springer, 45–60. 10.1007/978-981-15-4607-5_3
9
ChenG.LinH.-L.NgJ. D.DannerA. J. (2021a). Integrated electro-optic modulator in Z-cut lithium niobate thin film with vertical structure. IEEE Photonics Technol. Lett.33 (23), 1285–1288. 10.1109/LPT.2021.3114993
10
ChenK.ZhuY.LiuZ.XueD. (2021b). State of the art in crystallization of linbo3 and their applications. Molecules26 (22), 7044. 10.3390/molecules26227044
11
ChlupZ.DrdlíkD.HadrabaH.ŠevečekO.ŠiškaF.ErhartJ.et al (2023). Temperature effect on elastic and fracture behaviour of lead-free piezoceramic BaTiO3. J. Eur. Ceram. Soc.43 (4), 1509–1522. 10.1016/j.jeurceramsoc.2022.11.030
12
ChuaL. (1971). Memristor-The missing circuit element. IEEE Trans. Circuit Theory18 (5), 507–519. 10.1109/TCT.1971.1083337
13
DecJ.KleemannW.BoldyrevaK.ItohM. (2005). Unique features of strontium titanate. Ferroelectrics314 (1), 7–18. 10.1080/00150190590926003
14
DongaleT. D.MohiteS. V.BagadeA. A.KamatR. K.RajpureK. Y. (2017). Bio-mimicking the synaptic weights, analog memory, and forgetting effect using spray deposited WO 3 memristor device. Microelectron. Eng.183–184, 12–18. 10.1016/j.mee.2017.10.003
15
DuH.TangF.LiuD.ZhuD.ZhouW.QuS. (2007). The microstructure and ferroelectric properties of (K0.5Na0.5)NbO3–LiNbO3 lead-free piezoelectric ceramics. Mater. Sci. Eng. B136 (2–3), 165–169. 10.1016/j.mseb.2006.09.031
16
EdonV.RèmiensD.SaadaS. (2009). Structural, electrical and piezoelectric properties of LiNbO3 thin films for surface acoustic wave resonators applications. Appl. Surf. Sci.256 (5), 1455–1460. 10.1016/j.apsusc.2009.09.002
17
EidM. M. A.RashedA. N. Z.AmiriI. S. (2020). Fast speed switching response and high modulation signal processing bandwidth through LiNbO3electro-optic modulators. J. Opt. Commun.0. 10.1515/joc-2020-0012
18
GateaH. A.NajiI. S. (2020). The effect of Ba/Sr ratio on the Curie temperature for ferroelectric barium strontium titanate ceramics. J. Adv. Dielectr.10 (05), 2050021. 10.1142/S2010135X20500216
19
GruberM.KonetschnikR.PopovM.SpitalerJ.SupancicP.KienerD.et al (2018). Atomistic origins of the differences in anisotropic fracture behaviour of LiTaO3 and LiNbO3 single crystals. Acta Mater.150, 373–380. 10.1016/j.actamat.2018.03.020
20
HouS.ChenP.ShahM.BriggsI.XingW.LiuZ.et al (2023). Programmable optical filter in thin-film lithium niobate with simultaneous tunability of extinction ratio and wavelength. ACS Photonics10 (11), 3896–3900. 10.1021/acsphotonics.3c00574
21
HuH.RickenR.SohlerW. (2009). Lithium niobate photonic wires. Opt. Express17 (26), 24261. 10.1364/OE.17.024261
22
HuH.YangJ.GuiL.SohlerW. (2012). Lithium niobate-on-insulator (LNOI): status and perspectives. Proc. SPIE - Int. Soc. Opt. Eng.84311. 10.1117/12.922401
23
HuX.HouX.ZhangY.ChaiX.LianJ.WangC.et al (2021). Size-controlled polarization retention and wall current in lithium niobate single-crystal memories. ACS Appl. Mater. Interfaces13 (14), 16641–16649. 10.1021/acsami.0c22969
24
HuangS.LuoW.PanX.ZhaoJ.QiaoS.ShuaiY.et al (2021). Resistive switching effects of crystal-ion-slicing fabricated LiNbO 3 single crystalline thin film on flexible polyimide substrate. Adv. Electron. Mater.7 (9). 10.1002/aelm.202100301
25
HwangH. J.NagaiT.OhjiT.SandoM.ToriyamaM.NiiharaK. (1998). Curie temperature anomaly in lead zirconate titanate/silver composites. J. Am. Ceram. Soc.81 (3), 709–712. 10.1111/j.1151-2916.1998.tb02394.x
26
InbarI.CohenR. E. (1997). Origin of ferroelectricity in LiNbO3 and LiTaO3. Ferroelectrics194 (1–4), 83–95. 10.1080/00150199708016084
27
IoachimA.ToacsanM. I.BanciuM. G.NedelcuL.DutuA.AntoheS.et al (2007). Transitions of barium strontium titanate ferroelectric ceramics for different strontium content. Thin Solid Films515 (16), 6289–6293. 10.1016/j.tsf.2006.11.097
28
IvanI. A.AgnusJ.LambertP. (2012). PMN–PT (lead magnesium niobate–lead titanate) piezoelectric material micromachining by excimer laser ablation and dry etching (DRIE). Sensors Actuators A Phys.177, 37–47. 10.1016/j.sna.2011.09.015
29
JiaY.WangL.ChenF. (2021). Ion-cut lithium niobate on insulator technology: recent advances and perspectives. Appl. Phys. Rev.8 (1). 10.1063/5.0037771
30
JinH.LiuF. M.XuP.XiaJ. L.ZhongM. L.YuanY.et al (2014). On-Chip generation and manipulation of entangled photons based on reconfigurable lithium-niobate waveguide circuits. Phys. Rev. Lett.113 (10), 103601. 10.1103/PhysRevLett.113.103601
31
KangB.RheeB. K.JooG. T. (2006). Variation of electro-optic coefficients in MgO-doped LiNbO3 single crystals. Mater. Lett.60 (17–18), 2306–2308. 10.1016/j.matlet.2005.12.144
32
KislyukA. M.IlinaT. S.KubasovI. V.KiselevD. A.TemirovA. A.TurutinA. V.et al (2022). Degradation of the electrical conductivity of charged domain walls in reduced lithium niobate crystals. Mod. Electron. Mater.8 (1), 15–22. 10.3897/j.moem.8.1.85251
33
LefortL.PuechK.ButterworthS. D.SvirkoY. P.HannaD. C. (1999). Generation of femtosecond pulses from order-of-magnitude pulse compression in a synchronously pumped optical parametric oscillator based on periodically poled lithium niobate. Opt. Lett.24 (1), 28. 10.1364/ol.24.000028
34
LengB.ZhangY.TsaiD. P.XiaoS. (2024). Meta-device: advanced manufacturing. Light Adv. Manuf.5 (1), 1. 10.37188/lam.2024.005
35
LewisR. W. C.AllsoppD. W. E.ShieldsP.ŠatkaA.YuS.TopolovV. Y.et al (2012). Nano-imprinting of highly ordered nano-pillars of lithium niobate (LiNbO 3). Ferroelectrics429 (1), 62–68. 10.1080/00150193.2012.676955
36
LiL.ZhaoJ.GuiZ. (2004). The thermal sensitivity and dielectric properties of SrTiO3-based ceramics. Ceram. Int.30 (7), 1073–1078. 10.1016/j.ceramint.2003.12.027
37
LiangX.ChenX.YangX.NiJ. (2021). The fabrication of LiNbO 3 memristors for electronic synapses using oxygen annealing. Nanotechnology32 (2), 025706. 10.1088/1361-6528/abb1eb
38
LinJ.BoF.ChengY.XuJ. (2020). Advances in on-chip photonic devices based on lithium niobate on insulator. Photonics Res.8 (12), 1910. 10.1364/PRJ.395305
39
LinS.XiongC.MaD.LiH.LongS.WangB. (2018). Persistent luminescence found in Mg 2+ and Pr 3+ co-doped LiNbO 3 single crystal. J. Mater. Chem. C6 (37), 10067–10072. 10.1039/C8TC03783C
40
LinZ.LinY.LiH.XuM.HeM.KeW.et al (2022). High-performance polarization management devices based on thin-film lithium niobate. Light Sci. Appl.11 (1), 93. 10.1038/s41377-022-00779-8
41
LiuS.ZhengY.FangZ.YeX.ChengY.ChenX. (2019). Effective four-wave mixing in the lithium niobate on insulator microdisk by cascading quadratic processes. Opt. Lett.44 (6), 1456. 10.1364/OL.44.001456
42
MarkovićD.MizrahiA.QuerliozD.GrollierJ. (2020). Physics for neuromorphic computing. Nat. Rev. Phys.2 (9), 499–510. 10.1038/s42254-020-0208-2
43
McConvilleJ. P. V.LuH.WangB.TanY.CochardC.ConroyM.et al (2020). Ferroelectric domain wall memristor. Adv. Funct. Mater.30 (28), 2000109. 10.1002/adfm.202000109
44
MengX. Y.WangZ. Z.ZhuY.ChenC. T. (2007). Mechanism of the electro-optic effect in the perovskite-type ferroelectric KNbO3 and LiNbO3. J. Appl. Phys.101 (10). 10.1063/1.2734534
45
MinakataM. (2001). Recent Progress of 40 GHz high-speed LiNbO3 optical modulator. http://spiedl.org/terms.
46
MorozovA. Y.AbgaryanK. K.ReviznikovD. L. (2022). Interval model of a memristor crossbar network. Phys. Status Solidi (b)259 (11). 10.1002/pssb.202200150
47
NakajimaM.InoueK.TanakaK.KuniyoshiY.HashimotoT.NakajimaK. (2022). Physical deep learning with biologically plausible training method. https://arxiv.org/abs/2204.13991.
48
NarayanareddyB. (2008). “Growth and physical properties of LiNbO3, CsLiB6O10 and CsH(C4H4O5)H2O,” in Nonlinear optical crystals. (Bengaluru, India: Indian Institute of Science).
49
NicoC.MonteiroT.GraçaM. P. F. (2016). Niobium oxides and niobates physical properties: review and prospects. Prog. Mater. Sci.80, 1–37. 10.1016/j.pmatsci.2016.02.001
50
OngL.-H.OsmanJ.TilleyD. R. (2001). Landau theory of second-order phase transitions in ferroelectric films. Phys. Rev. B63 (14), 144109. 10.1103/PhysRevB.63.144109
51
PalatnikovM.MakarovaO.KadetovaA.SidorovN.TeplyakovaN.BiryukovaI.et al (2023). Structure, optical properties and physicochemical features of LiNbO3:Mg,B crystals grown in a single technological cycle: an optical material for converting laser radiation. Materials16 (13), 4541. 10.3390/ma16134541
52
PanB.HuJ.HuangY.SongL.WangJ.ChenP.et al (2021). Demonstration of high-speed thin-film lithium-niobate-on-insulator optical modulators at the 2-µm wavelength. Opt. Express29 (12), 17710. 10.1364/OE.416908
53
PanX.ShuaiY.WuC.ZhangL.GuoH.ChengH.et al (2019). Ar+ ions irradiation induced memristive behavior and neuromorphic computing in monolithic LiNbO3 thin films. Appl. Surf. Sci.484, 751–758. 10.1016/j.apsusc.2019.04.114
54
PoberajG.HuH.SohlerW.GünterP. (2012). Lithium niobate on insulator (LNOI) for micro-photonic devices. Laser Photonics Rev.6 (4), 488–503. 10.1002/lpor.201100035
55
QiY.LiY. (2020). Integrated lithium niobate photonics. Nanophotonics9 (6), 1287–1320. 10.1515/nanoph-2020-0013
56
RabeK. M.AhnC.TrisconeJ.-M. (2007). Physics of ferroelectrics: a modern perspective. Berlin, Germany: Springer.
57
RiveraA.GarciaG.OlivaresJ.CrespilloM. L.Agulló-LópezF. (2011). Elastic (stress–strain) halo associated with ion-induced nano-tracks in lithium niobate: role of crystal anisotropy. J. Phys. D Appl. Phys.44 (47), 475301. 10.1088/0022-3727/44/47/475301
58
RoshchupkinD. V.IrzhakD. V.AntipovV. V. (2009). Study of LiNbO3 and LiTaO3 ferroelectric domain structures using high-resolution x-ray diffraction under application of external electric field. J. Appl. Phys.105 (2). 10.1063/1.3066481
59
SakayoriK.MatsuiY.AbeH.NakamuraE.KenmokuM.HaraT.et al (1995). Curie temperature of BaTiO 3. Jpn. J. Appl. Phys.34 (9S), 5443. 10.1143/JJAP.34.5443
60
SalehS.KoldehofeB. (2022). On memristors for enabling energy efficient and enhanced cognitive network functions. IEEE Access10, 129279–129312. 10.1109/ACCESS.2022.3226447
61
Sánchez-DenaO.Fierro-RuizC. D.Villalobos-MendozaS. D.FloresD. M. C.Elizalde-GalindoJ. T.FaríasR. (2020). Lithium niobate single crystals and powders reviewed—Part I. Crystals10 (11), 973. 10.3390/cryst10110973
62
SangX.YuC.IslamM. K.LuN. (2006). Generation of photon pairs in highly nonlinear photonic crystal fibres for quantum information processing. J. Optoelectron. Adv. Mater.8 (5).
63
SaraviS.PertschT.SetzpfandtF. (2021). Lithium niobate on insulator: an emerging platform for integrated quantum photonics. Adv. Opt. Mater.9 (22). 10.1002/adom.202100789
64
StoneG.KnorrB.GopalanV.DierolfV. (2011). Frequency shift of Raman modes due to an applied electric field and domain inversion in LiNbO. Phys. Rev. B84 (13), 134303. 10.1103/PhysRevB.84.134303
65
SuharaT. (2009). Generation of quantum-entangled twin photons by waveguide nonlinear‐optic devices. Laser and Photonics Rev.3 (4), 370–393. 10.1002/lpor.200810054
66
SumetsM. (2018). “Thin films of lithium niobate: potential applications, synthesis methods, structure and properties,” in Lithium niobate-based heterostructures (Bristol, United Kingdom: IOP Publishing). 10.1088/978-0-7503-1729-0ch1
67
SunD.ZhangY.WangD.SongW.LiuX.PangJ.et al (2020). Microstructure and domain engineering of lithium niobate crystal films for integrated photonic applications. Light Sci. Appl.9 (1), 197. 10.1038/s41377-020-00434-0
68
SunJ.JiangA.-Q.SharmaP. (2023). Ferroelectric domain wall memory and logic. ACS Appl. Electron. Mater.5 (9), 4692–4703. 10.1021/acsaelm.3c00928
69
SunaA.BaxterO. E.McConvilleJ. P. V.KumarA.McQuaidR. G. P.GreggJ. M. (2022). Conducting ferroelectric domain walls emulating aspects of neurological behavior. Appl. Phys. Lett.121 (22). 10.1063/5.0124390
70
TayiA. S.ShveydA. K.SueA. C. H.SzarkoJ. M.RolczynskiB. S.CaoD.et al (2012). Room-temperature ferroelectricity in supramolecular networks of charge-transfer complexes. Nature488 (7412), 485–489. 10.1038/nature11395
71
TongL.PengZ.LinR.LiZ.WangY.HuangX.et al (2021). 2D materials–based homogeneous transistor-memory architecture for neuromorphic hardware. Science373 (6561), 1353–1358. 10.1126/science.abg3161
72
UchinoK. (2017). Advanced piezoelectric materials: science and technology. Sawston, United Kingdom: Woodhead Publishing. 10.1016/C2015-0-01989-X
73
VakulovZ.GeldashA.KhakhulinD.Il’inaM. V.Il’inO. I.KliminV. S.et al (2020). Piezoelectric energy harvester based on LiNbO3 thin films. Materials13 (18), 3984. 10.3390/ma13183984
74
VolosC. K.KyprianidisI. M.StouboulosI. N.Tlelo-CuautleE.VaidyanathanS. (2015). Memristor: a new concept in synchronization of coupled neuromorphic circuits. J. Eng. Sci. Technol. Rev.8 (2), 157–173. 10.25103/jestr.082.21
75
VoskresenskiiV. M.StarodubO. R.SidorovN. V.PalatnikovM. N. (2017). Investigation of the cluster formation in lithium niobate crystals by computer modeling method. Crystallogr. Rep.62 (2), 205–209. 10.1134/S1063774517020316
76
WangJ.PanX.LuoW.ShuaiY.XieQ.XuJ.et al (2023a). Memristive synapse based on single-crystalline LiNbO 3 thin film with bioinspired microstructure for experience-based dynamic image mask generation. Adv. Electron. Mater.9 (3). 10.1002/aelm.202201064
77
WangJ.PanX.WangQ.LuoW.ShuaiY.XieQ.et al (2022). Reliable resistive switching and synaptic plasticity in Ar+-irradiated single-crystalline LiNbO3 memristor. Appl. Surf. Sci.596, 153653. 10.1016/j.apsusc.2022.153653
78
WangJ.PanX.ZhaoZ.XieY.LuoW.XieQ.et al (2023b). An infrared near-sensor reservoir computing system based on large-dynamic-space memristor with tens of thousands of states for dynamic gesture perception. Adv. Sci.11, e2307359. 10.1002/advs.202307359
79
WangJ.ZengH.XieY.ZhaoZ.PanX.LuoW.et al (2023c). Analog ion-slicing LiNbO 3 memristor based on hopping transport for neuromorphic computing. Adv. Intell. Syst.5 (10). 10.1002/aisy.202300155
80
WangS.WangW.YakopcicC.ShinE.KimR. S.SubramanyamG.et al (2015). “Lithium based memristive device,” in 2015 National Aerospace and Electronics Conference (NAECON), Dayton, OH, USA, June, 2015, 333–335. 10.1109/NAECON.2015.7443092
81
WangS.WangW.YakopcicC.ShinE.SubramanyamG.TahaT. M. (2017). Experimental study of LiNbO3 memristors for use in neuromorphic computing. Microelectron. Eng.168, 37–40. 10.1016/j.mee.2016.10.007
82
WeiD.WangC.WangH.HuX.WeiD.FangX.et al (2018). Experimental demonstration of a three-dimensional lithium niobate nonlinear photonic crystal. Nat. Photonics12 (10), 596–600. 10.1038/s41566-018-0240-2
83
WeigandH.Vogler-NeulingV. V.EscaléM. R.PohlD.RichterF. U.KarvounisA.et al (2021). Enhanced electro-optic modulation in resonant metasurfaces of lithium niobate. ACS Photonics8 (10), 3004–3009. 10.1021/acsphotonics.1c00935
84
WeisR. S.GaylordT. K. (1985). Lithium niobate: summary of physical properties and crystal structure. Appl. Phys. A Solids Surfaces37 (4), 191–203. 10.1007/BF00614817
85
WeissA.FrydendahlC.Bar-DavidJ.ZektzerR.EdreiE.EngelbergJ.et al (2022). Tunable metasurface using thin-film lithium niobate in the telecom regime. ACS Photonics9 (2), 605–612. 10.1021/acsphotonics.1c01582
86
WitmerJ. D.ValeryJ. A.Arrangoiz-ArriolaP.SarabalisC. J.HillJ. T.Safavi-NaeiniA. H. (2017). High-Q photonic resonators and electro-optic coupling using silicon-on-lithium-niobate. Sci. Rep.7, 46313. 10.1038/srep46313
87
WolfR. A.Trolier-McKinstryS. (2004). Temperature dependence of the piezoelectric response in lead zirconate titanate films. J. Appl. Phys.95 (3), 1397–1406. 10.1063/1.1636530
88
WuJ.HuangY.LuC.DingT.ZhengY.ChenX. (2020). Tunable linear polarization-state generator of single photons on a lithium niobate chip. Phys. Rev. Appl.13 (6), 064068. 10.1103/PhysRevApplied.13.064068
89
XuM.ChenX.GuoY.WangY.QiuD.DuX.et al (2023). Reconfigurable neuromorphic computing: materials, devices, and integration. Adv. Mater.35 (51), e2301063. 10.1002/adma.202301063
90
XuS.RenZ.DongB.ZhouJ.LiuW.LeeC. (2022). Mid-infrared silicon-on-lithium-niobate electro-optic modulators toward integrated spectroscopic sensing systems. Adv. Opt. Mater.11 (4). 10.1002/adom.202202228
91
XueD.KitamuraK. (2003). Crystal structure and ferroelectricity of lithium niobate crystals. Ferroelectrics297, 19–27. 10.1080/713642470
92
YakopcicC.WangS.WangW.ShinE.SubramanyamG.TahaT. M. (2017). “Methods for high resolution programming in lithuim niobate memristors for neuromorphic hardware,” in 2017 International Joint Conference on Neural Networks (IJCNN), Anchorage, AK, USA, May, 2017, 1704–1708. 10.1109/IJCNN.2017.7966056
93
YooT. S.LeeS. A.RohC.KangS.SeolD.GuanX.et al (2018). Ferroelectric polarization rotation in order-disorder-type LiNbO 3 thin films. ACS Appl. Mater. Interfaces10 (48), 41471–41478. 10.1021/acsami.8b12900
94
YuM.BartonD.IIIChengR.ReimerC.KharelP.HeL.et al (2022). Integrated femtosecond pulse generator on thin-film lithium niobate. Nature612 (7939), 252–258. 10.1038/s41586-022-05345-1
95
YuanS.HuC.PanA.DingY.WangX.QuZ.et al (2021). Photonic devices based on thin-film lithium niobate on insulator. J. Semicond.42 (4), 041304. 10.1088/1674-4926/42/4/041304
96
ZamanA. (2020). Modeling and experimental characterization of memristor devices for neuromorphic computing. Dayton, OH, United States: University of Dayton.
97
ZamanA.SubramanyamG.ShinE.YakopcicC.TahaT. M.IslamA. E.et al (2020). Experimental verification of current conduction mechanism for a lithium niobate based memristor. ECS J. Solid State Sci. Technol.9 (10), 103003. 10.1149/2162-8777/abc3ce
98
ZamanA.WangW.SubramanyamG. (2017). “Modeling of memristor device and analysis of stability issues,” in 2017 IEEE National Aerospace and Electronics Conference (NAECON), Dayton, OH, USA, June, 2017, 263–266. 10.1109/NAECON.2017.8268782
99
ZamanA.YakopcicC.WangS.ShinE.WangW.TahaT. M.et al (2019). “Analysis of lithium niobate memristor devices for neuromorphic programability,” in 2019 IEEE National Aerospace and Electronics Conference (NAECON), Dayton, OH, USA, July, 2019, 41–45. 10.1109/NAECON46414.2019.9058020
100
ZengX.AshiharaS.ChenX.ShimuraT.KurodaK. (2008). Two-color pulse compression in aperiodically-poled lithium niobate. Opt. Commun.281 (17), 4499–4503. 10.1016/j.optcom.2008.04.080
101
ZhangJ.XuB.WangY.-S.QinZ.KeS.-H. (2019). First-principles investigation of the ferroelectric, piezoelectric and nonlinear optical properties of LiNbO3-type ZnTiO3. Sci. Rep.9 (1), 17632. 10.1038/s41598-019-53986-6
102
ZhaoJ.MaC.RüsingM.MookherjeaS. (2020). High quality entangled photon pair generation in periodically poled thin-film lithium niobate waveguides. Phys. Rev. Lett.124 (16), 163603. 10.1103/PhysRevLett.124.163603
103
ZhaoY.DuanW.WangC.XiaoS.LiY.LiY.et al (2023). LiNbO3 dynamic memristors for reservoir computing. Front. Neurosci.17, 1177118. 10.3389/fnins.2023.1177118
104
ZhengY.ChenX. (2021). Nonlinear wave mixing in lithium niobate thin film. Adv. Phys. X6 (1). 10.1080/23746149.2021.1889402
Summary
Keywords
neuromorphic computing, LiNbO3-based memristors, synaptic behavior, nonlinear optical properties, artificial intelligence, advanced fabrication techniques, synaptic plasticity
Citation
Kibebe CG and Liu Y (2024) LiNbO3-based memristors for neuromorphic computing applications: a review. Front. Electron. Mater. 4:1350447. doi: 10.3389/femat.2024.1350447
Received
05 December 2023
Accepted
29 February 2024
Published
11 March 2024
Volume
4 - 2024
Edited by
Carlos M. Costa, University of Minho, Portugal
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© 2024 Kibebe and Liu.
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*Correspondence: Yue Liu, liuyue@lntu.edu.cn
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