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Original Research ARTICLE

Front. Energy Res., 13 February 2018 | https://doi.org/10.3389/fenrg.2018.00002

High Catalytic Efficiency of Lignin Depolymerization over Low Pd-Zeolite Y Loading at Mild Temperature

imageYuling Qin1, imageHongliang Wang1, imageHao Ruan1, imageMaoqi Feng2 and imageBin Yang1*
  • 1Bioproducts, Sciences and Engineering Laboratory, Department of Biological Systems Engineering, Washington State University, Richland, WA, United States
  • 2Chemistry and Chemical Engineering Division, Southwest Research Institute, San Antonio, TX, United States

This article reported a novel low-temperature process for aromatics production through lignin depolymerization catalyzed by 0.1 wt% Pd-zeolite Y catalyst prepared by a facile method. Under the same reactive condition, the as-prepared Pd-zeolite Y catalysts exhibited much higher catalytic efficiency than zeolite Y or commercial Pd/Al2O3–zeolite composites. The selectivity of the Pd-zeolite Y toward lignin depolymerization was also much higher than the other commercial zeolite-based catalysts. With the presence of hydrogen, aromatics were the predominant products with high yields of phenols and dimers (over 99%). The as-obtained aromatics can be promising feedstock for production of fuels or chemicals for various applications. Results revealed that the Pd-zeolite Y catalyst is a highly active catalyst for the cleavage of lignin interlinkages, especially the C–O–C bonds by hydrogenolysis.

Introduction

Catalytic conversion of biomass lignin into value-added chemicals and fuels is a promising route to resolve the energy crisis (Jae et al., 2010; Ragauskas et al., 2014; Kong et al., 2015; Wang et al., 2016). Nevertheless, state-of-the-art lignin utilization technologies still face tremendous challenges, including depolymerization and upgradation, especially the catalytic depolymerization process (Alonso et al., 2010; Xu et al., 2014; Li et al., 2015; Yang et al., 2015). Among various catalysts for lignin depolymerization, zeolites are widely accepted due to their low-cost, high surface area, and outstanding acid sites catalytic performance (Taarning et al., 2011; Ben and Ragauskas, 2012; Wang et al., 2017). External Brønsted acidity in meso-/microporous zeolites was reported to effectively affect the selectivity of de-alkylation and de-etherification reactions in parallel during lignin conversion (Taarning et al., 2011; Singh and Ekhe, 2014; Deepa and Dhepe, 2015). Deepa reported that aromatic monomers were the predominant products using zeolite as solid acid catalysts for lignin depolymerization at 250°C in H2O/CH3OH mixture (Deepa and Dhepe, 2015).

GRAPHICAL ABSTRACT
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Graphical Abstract. High catalytic efficiency of lignin depolymerization over low Pd-zeolite Y loading at mild temperature.

However, challenges remain for catalytic lignin depolymerization by zeolites because the current zeolite-based catalysis requires high temperature (250°C or above), which leads to faster catalyst deactivation by coking and dealumination (Jia et al., 2011). Furthermore, the high temperature for solid acid-catalyzed lignin hydrolysis process possibly results in extensive side products from condensation reactions (Jia et al., 2011; Li et al., 2015). Therefore, the development of low-cost zeolite-based catalysts for lignin conversion at mild temperature will enhance lignin conversion to valuable products.

A group of catalysts with a combination of zeolite and noble metal nanoparticles drew increasing attention due to their excellent catalytic activity in lignin degradation. For example, lignin degradation and/or hydrodeoxygenation reaction were reportedly enhanced by a combination of Pt, Ru, and Pd nanoparticles supported on zeolites (Laskar et al., 2014; Wang et al., 2015). However, the complexity of the preparation of these catalysts hinders their further application.

Combining the outstanding catalytic performance of zeolites and metals, metal-exchanged zeolites potentially have higher activity than non-exchanged zeolites (Hui et al., 2010; Singh et al., 2015). The Pd metal in Pd-zeolites can become reactive sites for the cleavage of lignin bonds due to its high hydrogen-activation ability. Notably, Pd2+ ions exchanged on the zeolite frameworks appeared highly stable against metal agglomeration while maintaining high catalytic activities in hydrogen atmosphere (Choi et al., 2009). It was proposed that the catalytic reactions were carried out by the Pd(0) species, which was generated in situ under the tested reaction conditions. Furthermore, because of the strong metal-catalyst support interaction and pore limitation, the catalysts were reportedly stable in the zeolite pore without agglomeration (Zhang et al., 2014a).

In this study, the Pd-zeolite Y catalysts were prepared via both the facile and maneuverable ion-exchange methods for depolymerizing lignin at relatively low temperatures (180–200°C). We studied catalytic activity and selectivity of these catalysts on depolymerization of alkali lignin compare with zeolite alone and commercial Pd/Al2O3–zeolite composite catalysts (with more Pd loading) and Pd-zeolite Y catalyst (with the synergistic effect of palladium and zeolite Y). The mechanism of Pd-zeolite catalysis of lignin conversion was explored. It was found that the high efficiency of surficial Pd atoms and the synergistic effects between Pd and zeolite Y played critical roles in lignin depolymerization and conversion.

Experimental

Preparation of Pd-Zeolite Y

CBV 300 purchased from Zeolyst International was heated in air at 550°C for 5 h. Pd(NO3)2 (Aldrich) was dissolved in diluted aqueous HNO3 (0.01 M) solution. Then 1 g of zeolite (CBV300) was dispersed into 50 mL of water solution by stirring, followed by adding aqueous Pd(NO3)2 solution [containing 5 mg of Pd(NO3)2]. Stirring continued for 30 min. Then 20 mg of NH4NO3 was added, followed by stirring for another 2 h. The mixture was then centrifuged and thoroughly washed with distilled water. The precipitate was dried at room temperature before catalytic reaction tests. Commercial Pd/C (5 wt%) was purchased from Aldrich.

Lignin Depolymerization in a Parr Reactor

For a typical catalytic depolymerization experiment, 30 mL of deionized water was added into a 100 mL Parr reactor as solvent for the reaction, followed by adding 200 mg of lignin and 200 mg of Pd-zeolite catalysts. After sealing the vessel, H2 was used to flush out the air in the reactor at least four times, and then the reactor was pressurized to 3.5 MPa at room temperature. The reactor was heated to reach the reaction temperature (180–200°C) where the reaction time was started. The reaction was conducted for 3 h. Then the vessel was plunged into cold water to cool the reaction system. Ethyl acetate was used to extract products while the 0.5 wt% of toluene (in ethyl acetate) was added as an internal standard. Then a sample was acquired from the organic phase for GC–MS analysis. For GC–MS analysis, the response factor for each product was standardized with the use of efficient carbon number (Scanion and Willis, 1985; Zhang et al., 2014b), which enabled the analysis of compounds without pure standards.

GC–MS Analysis and Structural Analysis of Catalysts

After ethyl acetate extraction, the organic phase was analyzed by GC–MS. 1 µL of sample was injected with 0.6 mL/min of He (carrier gas) into a DB-5 (30 m length × 250 µm I.D. × 0.25 µm film thickness, J&W Scientific) capillary column installed in an Agilent Technologies 7890A GC that was set at splitless mode. The GC oven was set to maintain 45°C for 2 min, then heated to 200°C at the rate of 15°C/min then held at 200°C for another 1 min. After that, the oven was heated up to 300°C at the rate of 10°C/min and held for 5 min. Eluting compounds were determined using a MS (Agilent Technologies 5975C) inter XL EI/CI MSD with a triple axis detector and matched to NIST GC–MS libraries (Wang et al., 2017).

Scanning electron microscopy (SEM) analysis was performed using a field emission SEM instrument (Hitachi S-4800), operating at an accelerating voltage of 10 kV. Transmission electron microscope analysis was performed using an FEI Tecnai G2 S-Twin instrument with a field emission gun operating at 200 kV. Inductively coupled plasma atomic emission spectroscopy (ICP-AES) measurements were performed on a Thermo Jarrell Ash Atom scan Advantage instrument.

Equations

The mass yield of each product and its selectivity from lignin depolymerization were calculated as follows:

Yieldx(wt %)=Mass of toluene92×areax/ECNxarea of toluene/7×MWxMass of lignin,
Selectivityx=YieldxYield of total calculated products×100%,
Toal product yield=n=17Yieldxn.

Results and Discussion

Transmission electron microscopy (TEM) image in Figure 1A shows that Pd-precursor dispersed very well on the surface of zeolite Y, which could enhance lignin degradation because the macromolecular lignin depolymerization reacts on the surface of the zeolite. In this study, the commercial zeolite Y, Zeolyst CBV 300, was used as a support for Pd after thermal treatment. Clearly, Pd-precursor nanoparticles with small particle size were evenly dispersed on the zeolite, while the smaller particle size led to higher atom efficiency. As seen in Figure 1B, after the H2 treatment at 200°C, Pd2+ was successfully reduced into Pd(0) in situ while no obvious aggregation of Pd was found. Furthermore, the high-resolution transmission electron microscopy image of the as-obtained Pd(0) is shown in Figure 1B inset. The d-spacing of the nanoparticle is ~2.25 Å, which corresponds to the (111) of fcc Pd, indicating the existence of Pd(0). On the other hand, the ICP-AES results showed that the loading of Pd in Pd-zeolite was 0.1 wt%. Due to the very low Pd loading in this catalyst, it is difficult to use the X-ray diffraction spectroscopy or X-ray photoelectron spectroscopy to prove the existence of Pd in Pd-zeolite. Therefore, the energy dispersive spectrometer (from the inset scanning electron microscope image) was further employed for the characterization of Pd. As shown in Figure 2, Pd was found from the energy dispersive spectrometer results even if its loading was low. Although the loading of Pd was quite low, it significantly improved lignin depolymerization as proved in the following lignin conversion process.

FIGURE 1
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Figure 1. Transmission electron microscopy images of Pd-zeolite Y before (A) and after (B) H2 treatment under 200°C. Inset in panel (B): high-resolution transmission electron microscopy image of Pd nanoparticle on zeolite Y.

FIGURE 2
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Figure 2. Energy dispersive spectrometer result on the surface of Pd-zeolite Y after H2 treatment under 200°C (inset: scanning electron microscopy image of Pd-zeolite Y).

The GC–MS results of the products derived from catalytic lignin conversion are concentrated in 18–28 min interval (Figure 3). In Deepa’s report (Deepa and Dhepe, 2015), lignin conversion generated wide range of products from 10 to 25 min. However, in this work, only seven products were detected by GC–MS, indicating much higher selectivity of this catalyst. Furthermore, as shown in Figure 4, phenols and substituted phenols, including guaiacols, phenol, and dimers, were the major products from lignin depolymerization on Pd-zeolite, indicating the high efficiency of the catalysts toward the cleavage of Cβ–O–C and dehydroxylation on branched alkanes. In addition, no aromatic saturated products (i.e., cyclohexane and its derivatives) were observed, implying low catalytic activity of Pd-zeolite Y toward hydrogenation of aromatics. This results indicated that Pd-zeolite Y can be efficiently employed to selectively produce aromatics with wide applications in the production of useful chemicals from lignin.

FIGURE 3
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Figure 3. GC–MS spectrum of the products from lignin depolymerization on Pd-zeolite Y at 200°C.

FIGURE 4
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Figure 4. GC–MS analysis of the products from lignin depolymerization on the three catalysts: (a) Pd-zeolite, (b) zeolite, and (c) Pd2+ [Pd(NO3)2 solution] catalysts (reaction conditions: 200°C, 3.5 MPa H2, 3 h).

Furthermore, Pd-zeolite Y showed much higher activity than both zeolite Y and Pd when they were applied separately, suggesting strong synergistic effects of Pd and zeolite Y on lignin depolymerization. Under the same reaction conditions, as shown in Figure 4, zeolite Y exhibited much lower catalytic activity than Pd-zeolite Y toward lignin degradation, while for Pd2+, almost no lignin depolymerization products were detected. From Table 1, for the major products (P2, P3, and P7), Pd-zeolite Y led to at least four times higher of product yields (P2, P3, and P7) than commercial zeolite, indicating that the addition of Pd significantly improved lignin depolymerization. Specially, P6 was only found in lignin depolymerization over Pd-zeolite but not over commercial zeolite.

TABLE 1
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Table 1. The major products from lignin conversion.

Zeolites have been widely used as solid acid catalysts for lignin depolymerization. In this work, in situ generated Pd can be used as a new catalytic site for C–O–C bond cleavage in hydrogen atmosphere. With the addition of Pd as-prepared catalyst exhibited much higher activity than zeolite Y with sole H+-sites for lignin depolymerization, probably due to the accessorial depolymerization caused by Pd induced hydrogenolysis reaction. However, without the acidic support of zeolite Y, Pd alone showed negligible catalytic activity on lignin depolymerization. It indicated that zeolite Y dramatically improved the hydrogenolysis activity of Pd. Similar synergetic effects of acids and noble metals on lignin depolymerization were reported in previous studies (Laskar et al., 2014; Zhang et al., 2014a; Wang et al., 2015). Except for OH and –OCH3 bonds, no other O-content functional groups was found on the side chains of the products. It suggested that Pd-zeolite facilely removed “O” from the side chains of lignin through deoxygenation.

Based on the products in this work, potential reaction pathways to generate phenols and guaiacols are summarized in Figure 5. It was reported that the dehydration of Cα hydroxyl group in the side chains of lignin occurred first and formed a double carbon bond prior to β-O-4 bond cleavage (Jia et al., 2010). However, in this work, the cleavage of β-O-4 bond can occur first because of the high hydrogen transferring ability of Pd, which is similar to the reaction path previously reported using Pt-based and Ni-based catalysts (Zakzeski and Weckhuysen, 2011; Song et al., 2012). For the next step, three routes can react in parallel. One route is to generate guaiacol (P1, Figure 5) through removing the hydroxyl-containing side chains. The second route is the formation of a double bond through dehydration reaction of Cα, which can further generate P3 (Figure 5) by hydrogenation. The methoxy group linked on the benzene ring can be activated by the adjacent hydroxyl group and converted into hydroxyl through demethylation and further generate phenol structure P2 (Figure 5) (Peters et al., 2015). On the other hand, dehydroxylation may also happen on the Cγ position to generate P5 and P4 through further dehydration and hydrogenation reaction successively (Li et al., 2015). For product 6, biphenyl structure may be generated by coupling reaction between two aromatics (Hong et al., 2010).

FIGURE 5
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Figure 5. Proposed reaction pathways for the formation of the major products from cleavage of the β-O-4 lignin.

Besides the catalysts as mentioned in the previous mechanism, hydrogen also plays a pivotal role in lignin depolymerization. From previous reports, lignin depolymerization in aqueous phase through hydrolysis by a solid acid catalyst is the dominant route (Taarning et al., 2011; Deepa and Dhepe, 2014). However, after Pd was loaded, results showed that hydrogenolysis was the principal route for bonds cleavage in hydrogen atmosphere at 200°C. To further verify the significant role of hydrogen in this depolymerization process, lignin conversion without hydrogen was performed. As shown in Figure 6, under the same temperature and catalyst conditions, almost no product was detected in the N2 atmosphere. It is plausible that due to the existence of Pd, the hydrogen-activation ability was significantly increased, thus further promoted lignin conversion. While in the N2 atmosphere, Pd-zeolite Y showed very low hydrolysis activity at the relatively low temperature. On the other hand, the product selectivity was also different on Pd-zeolite from that on zeolite because of the different hydrogen reactive ability. For example, about 18% P6 (Table 2) was obtained from Pd-zeolite while almost no obvious P6 peak could be found in zeolite Y catalysis because Pd showed high activity toward coupling reactions to form biphenyls.

FIGURE 6
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Figure 6. GC–MS spectrum of the products from lignin depolymerization on Pd-zeolite under the N2 atmosphere.

TABLE 2
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Table 2. Percentage of lignin aromatic inter-unit linkages and the selectivity of the major products via Pd-zeolite Y catalysis.

Furthermore, compositions of lignin inter-unit linkages obtained from NMR analysis and the major product selectivity are shown in Table 2. The alkali lignin used in this study was prepared and analyzed as reported in our previous work (Wang et al., 2015). Results suggested that the major products were divided into two categories: ~82% phenols and ~18% biphenyls. More than half (56.8%) of the phenols were guaiacols, indicating the high preeminent selectivity of Pd-zeolite toward lignin degradation. The catalytic performance of Pd-zeolite Y and zeolite Y alone toward lignin degradation at even lower temperature (180°C, initial H2 pressure 3.5 MPa) was studied. As shown in Figure 7, similar products selectivity was obtained on Pd-zeolite Y as compared with the reaction under 200°C, and the products P1–P7 were clearly observed. Pd-zeolite Y still exhibited much better catalytic performance than zeolite at 180°C. Results indicated that lignin was depolymerized at the temperature as low as 180°C.

FIGURE 7
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Figure 7. GC–MS spectrum of the products from lignin depolymerization on Pd-zeolite Y and zeolite at 180°C.

Lignin depolymerization on the state-of-the-art commercial Pd/Al2O3–zeolite composites catalysts with equal amount of Pd and zeolite was tested to compare with the catalytic performance of Pd-zeolite Y. As shown in Figure 8, 4 mg of Pd/Al2O3 (0.2 mg Pd) with 200 mg of zeolite displayed much lower catalytic activity than Pd-zeolite. Generation of P1–P7 products remained similar even with 10 times Pd/Al2O3 loading, which proves the high Pd atom efficiency of the Pd-zeolite Y catalyst developed in this study. From the abovementioned TEM images (Figure 1), it is observed that the particle size of the Pd is quite small, corresponding to the “atom economy” catalysis. The high catalytic activity of Pd-zeolite Y can be attributed to the high efficiency of surficial Pd atoms and the synergistic effects between Pd and zeolite Y.

FIGURE 8
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Figure 8. GC–MS spectrum of the products from lignin depolymerization on Pd-zeolite (a) and commercial Pd/Al2O3–zeolite composites catalysts [(b) 40 mg of Pd/Al2O3 + 200 mg of zeolite and (c) 4 mg of Pd/Al2O3 + 200 mg of zeolite] at 200°C.

Conclusion

Herein, we demonstrated that the Pd-zeolite Y catalysts prepared via the facile method were effective catalysts to depolymerize lignin to phenols and phenol derivatives at 99% yield. Due to the synergistic effects, Pd-zeolite led to much higher total yield of products than non-metalized zeolite or Pd2+ did when applied separately. In addition to catalysts, hydrogen was proved to have a critical role in lignin depolymerization. Although the as-prepared Pd-zeolite Y exhibited excellent catalytic performance toward the cleavage of ether bonds, its dehydroxylation and demethoxylation (on benzene) performance needs further improvement. Taking the advantage of the synergy effect of palladium and zeolite Y, the Pd-zeolite Y catalyst in this study could be more cost effective and efficient than many other previously reported catalysts for conversion of lignin to value-added chemicals and fuels.

Author Contributions

YQ, HR, HW, MF, and BY conceptualized the work, designed experiment, analyzed data, and wrote the manuscript. YQ and HR conducted the experiment. All the authors have approved the manuscript and agreed with submission to Frontiers in Energy Research.

Conflict of Interest Statement

The authors declare that the research was conducted in the absence of any commercial or financial relationships that could be construed as a potential conflict of interest.

Acknowledgments

Part of this work was conducted at the William R. Wiley Environmental Molecular Sciences Laboratory (EMSL), a national scientific user facility located at the Pacific Northwest National Laboratory (PNNL) and sponsored by the Department of Energy’s Office of Biological and Environmental Research (BER). The authors also thank Dr. Zheming Wang and Ms. Marie S. Swita for insightful discussions.

Funding

This work was supported by the Seattle-based Joint Center for Aerospace Technology Innovation (JACTI), Sun Grant-U.S. Department of Transportation (DOT) Award # T0013GA-Task 8, and U.S. Department of Energy DOE EERE Awards (DE-EE0007104 and DE-EE0006112) with the Bioproducts, Science and Engineering Laboratory, Department of Biological Systems Engineering at Washington State University.

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Keywords: lignin conversion, biomass, Pd, zeolite, phenols, aromatics, high efficiency and selectivity

Citation: Qin Y, Wang H, Ruan H, Feng M and Yang B (2018) High Catalytic Efficiency of Lignin Depolymerization over Low Pd-Zeolite Y Loading at Mild Temperature. Front. Energy Res. 6:2. doi: 10.3389/fenrg.2018.00002

Received: 27 October 2017; Accepted: 24 January 2018;
Published: 13 February 2018

Edited by:

Arthur Jonas Ragauskas, University of Tennessee, Knoxville, United States

Reviewed by:

Selhan Karagoz, Karabük University, Turkey
Ao Xia, Chongqing University, China

Copyright: © 2018 Qin, Wang, Ruan, Feng and Yang. This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.

*Correspondence: Bin Yang, bin.yang@wsu.edu