Microwave-Assisted Coprecipitation Synthesis of LaCoO3 Nanoparticles and Their Catalytic Activity for Syngas Production by Partial Oxidation of Methane

Introduction

Natural gas is found in many locations around the world (more distributed than oil reserves) and avoids dependence from oil producing countries. However, the low cost of oil coupled with the high cost of natural gas storage and transportation from remote reservoirs hampers its use. At present, numerous efforts have been done investigating on methods to enhance the value of natural gas, either by synthesizing chemicals or fuels or more readily transportable products that nowadays are mainly obtained by crude oil refining. Currently, the only economically available route for the conversion of methane into more valuable chemicals is via synthesis gas. Among the different routes for syngas production from methane (steam reforming, dry reforming, and partial oxidation), partial oxidation presents some advantages: it is a mild exothermic reaction, leading to energy saving, therefore, it offers economic incentives when compared to the current industrial process, based on the steam reforming which is a very endothermic reaction. Moreover, catalytic partial oxidation of methane (CPOM) produces a H₂/CO ratio ~2 (suitable for Fischer–Tropsch or methanol syntheses). The main drawbacks are the formation of hotspots in the catalytic bed (which favors the sintering of the active phase), carbon formation and, in some cases, the need of an oxygen separation plant (York, 2003).

Metallic cobalt supported on basic oxide supports proved to be efficient catalysts for syngas production by CPOM (Wang and Ruckenstein, 2001). Perovskite-type (ABO₃) oxides are excellent precursors for supported metal catalysts because, their reduction leads to finely dispersed metallic particles (B⁰) onto a matrix constituted by a metal oxide (A₂O₃) (Hayakawa et al., 1993). LaCoO₃ is particularly promising as catalyst for reactions such as combustion or total oxidation of VOCs (Alvarez-Galvan et al., 2009) or as a catalyst precursor for syngas production by oxidative reforming of diesel (Navarro et al., 2007; Mota et al., 2012), methane reforming, and/or partial oxidation (Zhu et al., 2004; Toniolo et al., 2012; Brackmann et al., 2014; Roseno et al., 2016). However, conventional preparation routes of perovskite type oxides such as coprecipitation and sol-gel methods results in bulk materials with very low specific surface area (ssa), which limits the surface accessibility of active phases. The use of porous catalysts having a high surface area is highly desired because activity is enhanced when referred to unit mass of catalyst.

The potential of well-ordered mesoporous silica for applications in catalysis was recognized in the early 90s of the twentieth century (Kresge et al., 1992) and it has inspired numerous efforts in synthesis of non-silica-based materials composed of catalytically relevant transition metal oxides. The introduction of internal porosity in oxides, such as perovskites, is of great interest for the fields of catalysis, fuel cells, and sensors. The use of porous oxides in catalysis will increase the conversion rate per mass of catalyst and, additionally, might lead to improved selectivity as compared to the respective bulk materials, due to effects such as site isolation, which may open alternative reaction pathways. Moreover, the creation of an internal and stable porous structure would increase heat and mass diffusion, increasing the catalyst stability, by decreasing deactivation by sintering and carbon deposition.

Therefore, it is very important to stablish of a synthesis method that would lead to an increase in the dispersion of active phases. Different methods to achieve this objective involve the use of different compounds as templates or structure directing agents (ionic and neutral surfactants), in order to introduce porosity (Schuth, 2001; He and Antonelli, 2002; Soler-Illia et al., 2002; Carreon and Guliants, 2005; Taguchi and Schüth, 2005; Pal and Bhaumik, 2013). Some thermally stable binary and mixed transition metal oxides, such as SmFe_1−XAl_XO₃ (Stathopoulos et al., 2001), Pb(Sc_1/2Nb_1/2)O₃ (Tang et al., 2009), LaCoO₃ (Xintong et al., 2016), La-Co-Zr-O mixed oxide (Zou et al., 2006), and LaMnO₃ (Hu et al., 2017) were prepared from metal salts precursors in the presence of ionic molecules such as hexadecyltrimethylammonium bromide (CTAB) as endotemplate. The main requirements of this synthesis procedure are (i) the need of interactions between the template molecule and the material precursors (Coulomb interaction, hydrogen bridges, van der Waals forces, etc.) and (ii) the difference between the density of the precursors and the template cannot be too large. The high redox activity of transition metal oxides often lead to a collapse of the mesophase during the template removal by calcination or to an incomplete elimination of the template. Thus, despite many efforts, an efficient preparation of mesoporous mixed oxides has not been reported in literature, and often, the materials prepared by such route show a collapsed structure and/or no mesoporosity (Schüth, 2003). However, the synthesis of porous perovskites using endotemplates has not been sufficiently explored.

On the other hand, another approach to develop new fast and energy-efficient routes for the synthesis of solids is the microwave-assisted method. Microwave synthesis is generally fast, simpler, and very energy efficient. Microwave interaction with reactants during the synthesis of materials is based on energy transfer from microwaves to the material through resonance or relaxation, which results in rapid heating (Rao et al., 1999). Microwave-assisted hydrothermal syntheses have been successfully used to prepare different materials, such as Ir oxohydroxides for electrochemical oxidation of water (Massué et al., 2017), LaNiO₃ for the electrocatalytic activity toward hydrogen evolution reaction, with a smaller grain size than non microwave-assisted routes (Galal et al., 2011), and also to achieve a uniform deposition of Pt nanoparticles on ceramic monoliths (Zavyalova et al., 2009).

This work describes an attempt of preparing LaCoO₃ by microwave-assisted hydrothermal synthesis, with the aid of an ionic endotemplate. The synthesis protocol aims to obtain porous materials of higher ssa and thus of enhanced catalytic activity. CTAB is a cationic surfactant, soluble in H₂O, which was introduced to interact with the nitrate salts of the corresponding cations and to improve the homogeneity of the precursors. The physicochemical properties of the materials were investigated by means of N₂ adsorption–desorption isotherms at −196°C, powder X-ray diffraction (XRD), scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), and Raman spectroscopy. The prepared samples were used as catalysts precursors for syngas production by partial oxidation of methane. Correlations of structure–activity were stablished with the aim to understand which parameters are influencing the reactivity.

Materials and Methods

Samples Preparation

In order to prepare 5 g of LaCoO₃, the corresponding stoichiometric amounts of cobalt and lanthanum nitrate precursors were dissolved in 100 ml bidistilled water. In the case of using CTAB as endotemplate [molar ratio CTAB/(Co + La cations)], this is suspended in water and added to the Co and La solution under stirring. The resultant gel is stirred for 30 min at 60°C. NH₄OH or NaOH is added until the pH is 9 or 11 (the color of the suspension can have different tonalities between pink and purple). Then, the hydrothermal treatment is carried out, transferring the gel into a teflon-lined microwaved-assisted autoclave. After 4 h at 200°C, the product is filtered, washed twice with 100 ml of water to remove nitrates, and dried 14 h at 80°C. Finally, the materials were calcined under flowing air, first at 300°C for 2 h and then at 750°C for 4 h (2°C/min), obtaining black samples.

As previously commented, CTAB was used as endotemplate, for crystal growth agent. CTAB is a cationic surfactant, with a hydrophilic head and a hydrophobic organic tail. In the synthesis of the samples, La(NO₃)₃ and Co(NO₃)₂ were combined with NaOH or NH₄OH to generate hydroxide ions. Therefore, ion pairs between the hydroxide and CTA⁺ were formed because of the electrostatic interaction in the alkaline solution. The hydrophilic head of CTAB is adsorbed on the surface of the nuclei of La and Co hydroxides precipitate. When the hydrothermal temperature was increased to 200°C, CTAB micelles were destroyed (Hu et al., 2017). The nomenclature of the samples is composed by the precipitant cation symbol followed by the value of the pH of precipitation and, finally, in the case of using CTAB as endotemplate, the letter “E” as suffix.

Samples Characterization

Specific surface areas were calculated using the BET method from the nitrogen adsorption isotherms recorded at −196°C using a Micromeritics ASAP 2420 automatic instrument. The accuracy of ssa values is below 0.5%. The calculation of the pore size distribution was performed using the desorption branch of the isotherm and the Barrett–Joyner–Halenda model.

The phase identification was performed by XRD analysis using an X’Pert Pro PANalytical equipment. XRD patterns were recorded using a CuKα radiation (λ = 1.5406 Å, 45 kV, 40 mA). The mean crystallite size was then estimated from X-ray line broadening using the Scherrer equation. Width was taken as the full width at half maximum intensity of the most intense and least overlapped peaks of LaCoO₃ (2·θ ~47.5°) for the fresh calcined samples and of Co⁰ and La(OH)₃ (2·θ ~44.2 and 39.5°, respectively) for the catalysts after reaction.

The morphology of the fresh calcined samples was analyzed by SEM (Hitachi S-3000N), instrument with a resolution of 3 nm. The acceleration voltage was 20 kV. The samples were dispersed on aluminum stubs.

X-ray photoelectron spectroscopy measurements were recorded using an Escalab 200 R spectrometer equipped with a hemispherical electron analyzer and an Al Kα (h·ν = 1,486.6 eV) 120 W X-ray source. The area of the peaks was estimated by calculating the integral of each peak after smoothing and subtraction of an S-shaped background and fitting of the experimental curve to a mixture of Lorentzian and Gaussian lines (90G/10L). All binding energies (BE) were referenced to the C 1 s signal at 284.8 eV from carbon contamination of the samples to correct the charging effects. This reference gave BE values within an accuracy of ±0.2 eV. Quantification of the atomic fractions on the sample surface was obtained by integration of the peaks normalized with atomic sensitivity factors.

The amount of adsorbed compounds as well as the decomposition of perovskite samples during pretreatment were determined by thermogravimetric analysis (TGA/SDTA 851e Mettler Toledo), measuring the weight change of the calcined samples during heating at high temperature. Analyses were carried out by raising the sample temperature from room temperature to 950°C at a rate of 20°C/min in a N₂ flow.

Raman spectra were recorded with a Renishaw in via Raman Microscope spectrometer equipped with a laser beam emitting at 532 nm, at 100 mW output power. The photons scattered by the sample were dispersed by a 1,200 lines/mm grating monochromator and simultaneously collected on a CCD camera; the collection optic was set at 50× objective. These measurement conditions gave Raman shift within an accuracy lower of 0.1/cm.

Catalytic Activity Tests Protocol

The catalytic behavior of prepared samples for the partial oxidation of methane to syngas was studied under atmospheric pressure, at 900°C using a quartz fixed bed reactor (external diameter = 6 mm, internal diameter = 4 mm). The catalysts (40 mg) were subjected to a pretreatment under 44.4 mL_N/min (10% H₂–90%N₂) flow, increasing the temperature up to 900°C and maintaining these conditions for 30 min (ramp, 30°C/min). Once the activation stage has finished, the reactants are introduced. The space velocity was 36,600 mL_N/h·g and the feed composition was 40% CH₄, 20% O₂, and 40% N₂ (molar). The reaction stream was analyzed on line by gas chromatography (HP 6890), equipped with a column Carboxen 1010 PLOT (SUPELCO^®) and with a thermal conductivity detector. This system was used to analyze H₂, O₂, N₂, CO, CO₂, and CH₄. Nitrogen was used as an inert standard for quantification. During the activity tests, carbon balances were always close to 100%. All reaction experiments were repeated three times with variation of the conversion and selectivity lower than two units of calculated percentage (average values are reported).

Results and Discussion

Characterization of Fresh Calcined Samples

The fresh calcined samples have been analyzed by adsorption–desorption of N₂. Obtained results (BET surface area, external and micropore area, and pore volume) are reported in Table 1. The surface areas of this novel mesostructured LaCoO₃ oxide are higher than those obtained for standard LaCoO₃ samples, prepared by coprecipitation or sol-gel methods (Villoria et al., 2011). The samples prepared using NaOH as precipitant agent show lower ssa than those prepared using NH₄OH, under the same precipitation pH. For the samples prepared with NH₄OH, an increase of the precipitation pH from 9 to 11 produces a small increase in ssa values. Furthermore, external surface area values are somewhat higher when CTAB is incorporated to the precipitation medium. This effect is attributed to the development of a larger mesoporosity (Hellgardt and Chadwick, 1998), as it is observed when pore size distributions are compared (Figure 1).

TABLE 1

Table 1. Textural properties of fresh calcined samples.

FIGURE 1

Figure 1. Pore size distributions of fresh calcined samples (from Barrett–Joyner–Halenda model desorption branch).

Figure 2 shows the nitrogen adsorption–desorption isotherms for the fresh calcined samples. All of them are type IV isotherms, characteristic of mesoporous materials. Except for the sample Na-11-E, all the materials show, to a greater or lesser extent, a H3 hysteresis loop, due to capillary condensation in mesoporous solids containing aggregates of plate-like particles giving rise to slit-shaped pores. H3 type hysteresis loop indicates that the samples contain interparticular pores and have lost the possible inner mesoporosity introduced by CTAB, probably due to the high temperature used during the calcination (Zou et al., 2008). The N₂ adsorption/desorption isotherms of the samples show a sharp capillary condensation step at high relative pressures (P/P₀ ~ 0.9–1.0), indicating a relatively large pore size and wide pore distribution (Zou et al., 2008; Zhao et al., 2010).

FIGURE 2

Figure 2. N₂ adsorption–desorption isotherms at −196°C of fresh calcined samples.

It can be observed that, only for the sample prepared at pH 11 and using ammonium hydroxide as precipitant, an increase in mesoporosity and ssa is generated when CTAB is used as endotemplate (sample NH4–11-E in relation to NH4–11), as it was expected by the endotemplate removal (see Figures 1 and 2).

A very broad pore size distribution in the range of meso and macropores with a relative maximum around 60 nm has been observed for all the materials, except for the sample Na-11-E (Figure 1). A relative maximum around 2–3 nm is also observed for all the samples.

The crystalline composition of the samples after calcination has been determined by XRD. The diffractograms, in Figure 3, show that samples Na-11 and Na-11-E, prepared using NaOH to precipitate cobalt and lanthanum cations, consist only of rhombohedral lanthanum cobaltite (PDF card: 01-084-0848), characterized by the typical doublet around 32.9 and 33.3°. On the contrary, the samples prepared using NH₄OH as precipitant contain, besides of LaCoO₃, some other phases, such as hexagonal La₂O₃ (01-083-1344) and cubic Co₃O₄ (01-076-1802), for those named NH4–9, NH4–9-E, and NH4–11, and hexagonal La(OH)₃ (as well as Co₃O₄ and LaCoO₃) in the case of the sample NH4–11-E. The average domain size of lanthanum cobaltite has been determined using the Scherrer equation (Table 2). The results clearly show that the average domain size of this phase is larger for the samples synthesized using NaOH as precipitant (Na-11 and Na-11-E).

FIGURE 3

Figure 3. X-ray diffractograms of (A) fresh calcined samples and (B) catalysts after reaction (♦: rhombohedral LaCoO₃, ▪: cubic Co₃O₄, •: hexagonal La₂O₃, 5:▴ hexagonal La(OH)₃, ♣: Co⁰).

TABLE 2

Table 2. Average domain size of LaCoO₃ for fresh calcined samples and for catalysts after reaction.

The morphology of the samples (fresh calcined) has been studied by SEM. Micrographs, in Figure 4, revealed some differences depending on the preparation of the sample. In general, the particles have a granular shape, but the size and specific morphology is different. Those samples prepared using NaOH as precipitant (Na-11 and Na-11-E) show an average grain size somewhat higher (around 0.10–0.15 µm) than those prepared using NH₄OH (with an average grain size around 0.03–0.05 µm). The sample Na-11-E shows grains that are bigger, more defined and with a more regular shape than grains in Na-11 sample. In the case of the samples prepared under the same pH (11) but using ammonium hydroxide as precipitant (NH4–11 and NH4–11-E), similarly to samples prepared with NaOH, the use of an endotemplate produces more regularly shaped grains. On the other hand, the sample NH4–9 presents a nanorod-based morphology. Considering the grain size and shape observed by SEM, it can be derived that there is a correlation between these properties and the ssa (Table 1). In essence, a smaller grain size and more intricate morphology are related to a higher surface area. The decrease in the grain size for the samples prepared using NH₄OH was attributed to the combined effect of surfactant CTAB and precipitant ammonium hydroxide. In the samples prepared in this work, it is observed that the surfactant CTAB, which was introduced into the precipitation system to control the aggregation of precipitates, reduces the aggregation tendency of the precipitates due to its micellar effect and steric repulsive effects. Hence, in highly basic media metal hydroxo species, e.g., (Co(OH)₄)²⁻, (La(OH)₄)⁻, interact with the cationic template. In this way, the anionic inorganic species are stabilized with a cationic surfactant (CTA⁺) through electrostatic interaction (Pal and Bhaumik, 2013).

FIGURE 4

Figure 4. Scanning electron microscopy micrographs of fresh calcined samples.

In order to explain the role of ammonium hydroxide in decreasing the growth of the as-precipitated grains, it is necessary to comment on the formation mechanism of precipitates. The precipitation process is based on a simple reaction between metallic cations and OH⁻ anions to form hydroxide precipitates. Afterward, these initial precipitate particles will grow via a ripening process according to crystal growth theory. Ammonium cations adsorb on the nuclei and inhibit further growth of the particles due to its spatial configuration. ${\text{NH}}_4^{+}$ is more prone to adsorb onto the electronegative surface of the LaCoO₃ particles because it is a stronger Lewis acid than Na⁺. Moreover, the larger size of ammonium cation increases the thickness of the electric layer on the precipitates. Consequently, the mobility of the metal ions on the surface of the particles is remarkably reduced and consequently their growth via Ostwald ripening is restrained (Tang et al., 2009).

These morphological properties obtained by SEM are in good agreement with results obtained by N₂ adsorption–desorption at −196°C, where the prepared solids were found to be conformed by a meso and macroporosity network. The primary lanthanum cobaltite particles are arranged into 30–150 nm agglomerates, generating mesopores of 2–50 nm diameter. These agglomerates coalesce into aggregates, and pores >50 nm are formed in the interstices (Soboleva et al., 2010).

The fresh calcined samples have been analyzed by TGA under N₂ flow and obtained profiles are depicted in Figure 5. The first weight loss region up to 200°C is related to loss of adsorbed water. The second one is due to the decomposition of surface lanthana carbonated hydroxide, which produces carbon dioxide and water, up to 470°C. Then, a third loss, up to 600°C is related to the decomposition of lanthanum hydroxide (Ino et al., 1976), which is evident for the sample NH4–11-E [in accordance to the presence of La(OH)₃, observed by XRD]. Finally, the last loss, between 600 and 830°C, is related to the formation of O₂ by solid state reaction between Co₃O₄ and La₂O₃ to form LaCoO₃ and by the desorption of mobile bulk oxygen associated with a defective perovskite structure (Navarro et al., 2007; Singha et al., 2017).

FIGURE 5

Figure 5. Thermogravimetric analysis profiles of fresh calcined samples.

As reported in literature (Singha et al., 2017), the loss of CTAB is produced between 300 and 600°C, therefore, this compound was removed during the calcination stage (at 750°C), carried out in the last stage of the samples preparation (see Samples Preparation) and, because of this, none of the weight losses are attributed to the removal of this compound.

Activity Tests Results

Conversion of methane with high selectivity to CO and H₂ can be obtained at 900°C over activated samples (under 44.4 mL_N/min flow of 10% H₂–90%N₂ for 30 min). The catalytic behavior evolves differently with time on stream depending on the type of sample (Figure 6). The catalysts NH4–11 and NH4–9 are the most active, selective, and stable for syngas production by CPOM along 6 h of reaction, with methane conversions and syngas selectivities in the thermodynamic equilibrium (York, 2003). They are followed in catalytic efficiency by the catalysts NH4–11-E and NH4–9-E, for which an induction period of around 5 h is observed. This induction period is explained by the progressive reduction of surface cobalt oxide to metallic cobalt under reaction conditions (Navarro et al., 2007).

FIGURE 6

Figure 6. Activity parameters of catalysts for partial oxidation of methane to syngas [900°C, 36,600 mL_N/h·g, 40% CH₄, 20% O₂, and 40% N₂ (molar)]. (A) CH₄ conversion, % (B) CO₂ selectivity, % (C) H₂ yield, and (D) CO yield.

Finally, the less active catalysts are those prepared using sodium hydroxide as precipitant (Na-11-E and Na-11). The catalyst Na-11-E shows a quite stable catalytic behavior in the whole reaction time. On the contrary, the catalytic performance of catalyst Na-11 changes with time on stream and an increase in the selectivity to CO₂ is observed (Figure 6B). This is likely due to the progressive reoxidation of the active metallic Co (Cimino et al., 2005), to cobalt oxide which is active for methane combustion. Indeed, under CPOM reaction conditions, CH₄ conversion progressively decreases from 55 to 35% and CO₂ selectivity increases from 27 to 61% during the first 6 h of reaction.

After 6 h of reaction, CH₄ conversion (Figure 6A) and syngas yield (Figures 6C,D) show the following trend: NH4–9 > NH4–11 > NH4–11-E > NH4–9-E > Na-11-E > Na-11. For the catalysts prepared using ammonium hydroxide as precipitant, the addition of CTAB to the synthesis medium has a detrimental effect on the catalytic performance, which is explained by a collapse of the pores created by endotemplating during the calcination and/or during the activation and reaction stages (Zou et al., 2008).

At the reaction temperature, the ratio H₂/CO in the thermodynamic equilibrium is 2. For the most active catalysts for CPOM to syngas, those prepared using ammonium hydroxide as precipitant, the ratios H₂/CO after 6 h of reaction are between 1.53 (NH4–9-E) and 1.70 (NH4–9), somewhat lower than the thermodynamic value. This is due to the coexistence of other parallel reaction pathways that are favored at such high reaction temperatures, such as the Reverse Water Gas Shift reaction (RWGS, CO₂ + H₂ ⇆ CO + H₂O) and Reverse Boudouard reaction (CO₂ + C ⇆ 2CO). The latter reaction enhances the formation of CO, while RWGS reaction favors CO formation and hinders H₂ production (Ozdemir et al., 2010). Both reactions therefore would decrease the H₂/CO ratio.

Characterization of Catalysts After Reaction

The structural composition of the catalysts after reaction has been analyzed by XRD. The diffraction profiles are shown in Figure 3. The only crystalline phases found in all the samples are Co⁰ (PDF card 00-015-0806) and La(OH)₃ (PDF card 00-036-1481). The formation of these new crystalline phases are the result of the reduction of LaCoO₃/Co₃O₄ and other phases found in the calcined catalysts precursors both during the catalyst activation and the reaction stage. Hydroxylation of lanthanum oxide by water is responsible for the formation of La(OH)₃. The average domain size of metallic cobalt and lanthanum hydroxide, as determined by the Scherrer equation, are shown in Table 2. The mean size of Co⁰ crystallites varies between 22 and 37 nm, for Na-11-E catalyst and for NH4–9-E, respectively. In the case of La(OH)₃, the average crystallite size changes between 14 nm (for Na-11-E) and 16 nm (for NH4–9). The introduction of CTAB decreased the average crystallite size of La(OH)₃. These results indicate that there is not any clear correlation between the average crystallite size of lanthanum cobaltite in fresh calcined samples and the mean crystallite sizes of crystalline phases existing in catalysts [Co⁰ and La(OH)₃].

The surface composition of catalysts after reaction has been determined by XPS. Obtained BE corresponding to Co2p3/2, La3d5/2, O1s, and C1s levels and Co/(Co + La) ratios are reported in Table 3. X-ray photoelectron spectra for Co2p and La3d core levels are shown in Figure 7 for the catalyst NH4–11-E, by way of example. The absence of a satellite peak in the Co2p spectra indicates that cobalt phase is as Co³⁺. The C1s spectra show two components, one at 284.8 eV due to adventitious carbon contamination and another around 289.6 eV due to carbonates. Indeed, the presence of carbonate at the surface of lanthanum oxide is usual, due to the basic character of lanthana that favors the adsorption of CO₂ and formation of very stable surface carbonates (Villoria et al., 2011; Brackmann et al., 2014). For quantitative calculations only this last contribution has been considered.

TABLE 3

Table 3. Binding energies of La3d5/2, Co2p3/2, O1s, and C1s core levels and Co/La, Co/(Co + La), ${\text{CO}}_{\text{3}}^{\text{2}-}$/La surface ratios for catalysts after reaction.

FIGURE 7

Figure 7. Co2p and La3d X-ray photoelectron spectroscopy spectra of spent NH4–11-E catalyst after catalytic partial oxidation of methane reaction.

In all samples, the La 3d level was characterized by a double peak for each spin–orbit component, attributed either to energy loss phenomena (“shake-up” satellites) induced by intense O 2p–La 4f charge events or to the existence of a mixing of electronic configurations (Villoria et al., 2011). The La 3d core level of catalysts after reaction showed a main component of the La 3d5/2 core level at BE of 834.9–835.1 eV, characteristic of La³⁺ in La(OH)₃ environment (Natile et al., 2007).

Surface Co/La ratios calculated from XPS data (Table 3) are substantially for the studied samples. Obtained Co/La values are lower than the nominal (1.0) for LaCoO₃ for all the samples. This is likely due to the segregation of La³⁺ ions on the surface, forming lanthanum carbonates and hydroxides. Regarding the Co/(Co + La) ratio, slightly higher values were found for those samples prepared using sodium hydroxide as precipitant (Na-11-E and Na-11).

The characterization of carbon deposits over the spent catalysts was carried out by Raman spectroscopy. For each catalyst, at least three Raman spectra were registered in different areas to ensure that chemical composition is homogeneous. All the Raman spectra exhibited two bands indicative of two types of carbon deposited on the catalysts: the G (graphitic) peak around 1,580/cm and the D (disordered) peak around 1,350/cm that could be attributed to the formation of carbon nanoparticles, amorphous carbon, or defective filamentous carbon. For all the spent catalysts, the intensity of the G band is higher than the intensity of the D band. In CPOM to syngas, carbon deposition is mainly produced by two different reactions: methane decomposition [CH₄ ⇆ C_(s) + 2H₂; ΔH⁰ = 75 kJ/mol] and Boudouard reaction [2CO ⇆ C_(s) + CO₂; ΔH⁰ = −172 kJ/mol]. However, only methane decomposition occurs at temperatures higher than 820°C (Wang et al., 1996; Ozdemir et al., 2010). Thus, under our experimental conditions we attribute carbon deposition solely to methane decomposition.

Taking into consideration the catalytic results obtained here, it can be concluded that the precipitant agent has a major influence over the catalytic behavior of LaCoO₃-derived catalysts for hydrogen production by partial oxidation of methane. The higher activity and selectivity obtained for the catalysts prepared using NH₄OH as precipitating agent (in comparison to NaOH) is explained by the way the cation $\left({\text{NH}}_4^{+}\right)$ surrounds the precipitate. According to literature (Tang et al., 2009), the spatial configuration of ammonium cation decreases the grain size, which is observed at micrometer level by SEM, producing aggregates of smaller size and higher ssa and porosity. The precipitating agent also has an influence over lanthanum cobaltite crystalline domain, which is smaller for those samples precipitated with ammonium hydroxide. A semi quantitative way to represent the amount of cobalt atoms per gram of catalyst exposed at the catalyst surface, is the use of the parameter: surface atomic ratio Co/(Co + La) (XPS) multiplied by the ssa (BET). A higher yield to syngas by CPOM has been found for those catalysts with a higher surface exposure of cobalt atoms per unit of mass of catalyst (see Figure 8). The large values obtained for catalysts NH4–11 and NH4–11-E in contrast to Na-11 and Na-11-E indicates that the precipitating agent plays a key role on the active phase dispersion, directing the porosity and the grain size of lanthanum cobaltite.

FIGURE 8

Figure 8. Correlation between A_BET·[Co/(Co + La)] and yield to syngas by catalytic partial oxidation of methane (CPOM) for the catalysts derived from LaCoO₃ precursors.

Conclusion

In summary, a series of LaCoO₃ perovskites were prepared by microwave-assisted hydrothermal coprecipitation and some of them resulted in efficient catalysts for syngas production by CPOM. The XRD results confirmed the formation of the rhombohedral perovskite phase of LaCoO₃ for all the samples, and this was the only phase for the samples prepared using sodium hydroxide as precipitant. Textural data show that microwave-assisted hydrothermal coprecipitation leads to samples with relatively high ssa and porosity. The best catalytic performance was found for catalysts prepared using ammonium hydroxide as precipitant and without adding CTAB as endotemplate. The use of sodium hydroxide as precipitant lead to the formation of larger LaCoO₃ crystalline domains and grains. This leads to lower ssa, therefore decreasing the dispersion of the active phase in the catalyst. The use of ammonium hydroxide as precipitant hinders the growth of the crystal grains due to the spatial configuration of ${\text{NH}}_4^{+}$ cations. In this way, an increase in the porosity and in the surface active area per unit mass of catalyst is achieved.

Author Contributions

AT and CA-G elaborated the samples synthesis protocol, MS-S supervised the samples preparation, CA-G carried out the preparation of the samples, Raman spectroscopy measurements, and SEM analyses and the analysis-discussion of characterization data. HF carried out the catalytic activity tests. JF carried out the XPS analyses and their discussion. All authors contributed to discussion and interpretation of experimental data.

Conflict of Interest Statement

The authors declare that the research was conducted in the absence of any commercial or financial relationships that could be construed as a potential conflict of interest.

Acknowledgments

CA-G acknowledges the scientific and technical assistance of Dr. Trunschke and all her group members during her stay at AC-FHI (Department of Inorganic Chemistry, Fritz Haber Institut, Berlin). The authors gratefully acknowledge Concepción Diaz Guerri for XRD analyses, Rosa Folgado Martínez for N₂ adsorption–desorption isotherms, and Dr. Miguel A. Peña for TGA analyses.

Funding

The synthesis of LaCoO₃ samples by microwave-assisted coprecpitation was carried out at the Inorganic Chemistry Department of Fritz Haber Institute, Max-Planck Society (AC-FHI) (Berlin) under the project “Development of a novel route to create internal porosity in perovskites using endotemplates which would have potential applications in catalysis, fuel cell technology and sensors field” (PA1002660) supported by a Grant of CSIC/DFG (German Research Foundation) through the program “Programa de Movilidad, Ayudas a Investigadores del CSIC para realización de estancias en centros de investigación extranjeros.” This work was also supported by CSIC (Spain) through the grant 201680I045.

References

Alvarez-Galvan, M. C., de la Peña O’Shea, V. A., Arzamendi, G., Pawelec, B., Gandía, L. M., and Fierro, J. L. G. (2009). Methyl ethyl ketone combustion over La-transition metal (Cr, Co, Ni, Mn) perovskites. Appl. Catal. B. Environ. 92, 445–453. doi: 10.1016/j.apcatb.2009.09.006

CrossRef Full Text | Google Scholar

Brackmann, R., Perez, C. A., and Schmal, M. (2014). LaCoO₃ perovskite on ceramic monoliths – pre and post reaction analyzes of the partial oxidation of methane. Int. J. Hydrogen Energy 39, 13991–14007. doi:10.1016/j.ijhydene.2014.07.027

CrossRef Full Text | Google Scholar

Carreon, M., and Guliants, V. (2005). Ordered meso- and macroporous binary and mixed metal oxides. Eur. J. Inorg. Chem. 2005, 27–43. doi:10.1002/ejic.200500137

CrossRef Full Text | Google Scholar

Cimino, S., Landi, G., Lisi, L., and Russo, G. (2005). Development of a dual functional structured catalyst for partial oxidation of methane to syngas. Catal. Today 105, 718–723. doi:10.1016/j.cattod.2005.06.058

CrossRef Full Text | Google Scholar

Galal, A., Atta, N., and Ali, S. (2011). Optimization of the synthesis conditions for LaNiO3 catalyst by microwave assisted citrate method for hydrogen production. Appl. Catal. A. Gen. 409, 202–208. doi:10.1016/j.apcata.2011.10.005

CrossRef Full Text | Google Scholar

Hayakawa, T., Andersen, A., Shimizu, M., Suzuki, K., and Takehira, K. (1993). Partial oxidation of methane to synthesis gas over some titanates based perovskite oxides. Catal. Lett. 22, 307–317. doi:10.1007/BF00807238

CrossRef Full Text | Google Scholar

He, X., and Antonelli, D. (2002). Recent advances in synthesis and applications of transition metal containing mesoporous molecular sieves. Angew. Chem. Int. Ed. Engl. 41, 214–229. doi:10.1002/1521-3773(20020118)41:2<214::AID-ANIE214>3.0.CO;2-D

PubMed Abstract | CrossRef Full Text | Google Scholar

Hellgardt, K., and Chadwick, D. (1998). Effect of pH of precipitation on the preparation of high surface area aluminas from nitrate solutions. Ind. Eng. Chem. Res. 37, 405–411. doi:10.1021/ie970591a

CrossRef Full Text | Google Scholar

Hu, J., Liu, Q., Shi, L., Shi, Z., and Huang, H. (2017). Silver decorated LaMnO₃ nanorod/graphene composite electrocatalysts as reversible metal-air battery electrodes. Appl. Surf. Sci. 402, 61–69. doi:10.1016/j.apsusc.2017.01.060

CrossRef Full Text | Google Scholar

Ino, E., Shimizu, K., and Yamate, T. (1976). Studies on thermal decomposition process of lanthanum hydroxide. J. Soc. Mater. Sci. Jpn. 25, 1165–1168. doi:10.2472/jsms.25.1165

CrossRef Full Text | Google Scholar

Kresge, C. T., Leonowicz, M. E., Roth, W. J., Vartuli, J. C., and Beck, J. S. (1992). Ordered mesoporous molecular sieves synthesized by a liquid-crystal template mechanism. Nature 359, 710–712. doi:10.1038/359710a0

CrossRef Full Text | Google Scholar

Massué, C., Huang, X., Tarasov, A., Ranjan, C., Cap, S., and Schlögl, R. (2017). Microwave-assisted synthesis of stable and highly active Ir oxohydroxides for electrochemical oxidation of water. ChemSusChem 10, 1958–1968. doi:10.1002/cssc.201601864

PubMed Abstract | CrossRef Full Text | Google Scholar

Mota, N., Alvarez Galván, M. C., Navarro, R. M., Al Zahrani, S. M., Goguet, A., Daly, H., et al. (2012). Insights on the role of Ru substitution in the properties of LaCoO₃-based oxides as catalysts precursors for the oxidative reforming of diesel fuel. Appl. Catal. B. Environ. 113, 271–280. doi:10.1016/j.apcatb.2011.11.047

CrossRef Full Text | Google Scholar

Natile, M., Ugel, E., Maccato, C., and Glisenti, A. (2007). LaCoO₃: effect of synthesis conditions on properties and reactivity. Appl. Catal. B. Environ. 72, 351–362. doi:10.1016/j.apcatb.2006.11.011

CrossRef Full Text | Google Scholar

Navarro, R. M., Alvarez-Galvan, M. C., Villoria, J. A., Gonzalez-Jimenez, I. D., Rosa, F., and Fierro, J. L. G. (2007). Effect of Ru on LaCoO₃ perovskite-derived catalyst properties tested in oxidative reforming of diesel. Appl. Catal. B. Environ. 73, 247–258. doi:10.1016/j.apcatb.2006.12.013

CrossRef Full Text | Google Scholar

Ozdemir, H., Özdemir, H., Faruk Öksüzömer, M. A., and Ali Gürkaynak, M. (2010). Preparation and characterization of Ni based catalysts for the catalytic partial oxidation of methane: effect of support basicity on H₂/CO ratio and carbon deposition. Int. J. Hydrogen Energy 35, 12147–12160. doi:10.1016/j.ijhydene.2010.08.091

CrossRef Full Text | Google Scholar

Pal, N., and Bhaumik, A. (2013). Soft templating strategies for the synthesis of mesoporous materials: inorganic, organic–inorganic hybrid and purely organic solids. Adv. Colloid Interface Sci. 189, 21–41. doi:10.1016/j.cis.2012.12.002

CrossRef Full Text | Google Scholar

Rao, K. J., Vaidhyanathan, B., Ganguli, M., and Ramakrishnan, P. A. (1999). Synthesis of inorganic solids using microwaves. Chem. Mater. 11, 882–895. doi:10.1021/cm9803859

CrossRef Full Text | Google Scholar

Roseno, K. T. C., Brackmann, R., da Silva, M. A., and Schmal, M. (2016). Investigation of LaCoO₃, LaFeO₃ and LaCo_0.5Fe_0.5O₃ perovskites as catalyst precursors for syngas production by partial oxidation of methane. Int. J. Hydrogen Energy 41, 18178–18192. doi:10.1016/j.ijhydene.2016.07.207

CrossRef Full Text | Google Scholar

Schuth, F. (2001). Non-siliceous mesostructured and mesoporous materialsâ. Chem. Mater. 13, 3184–3195. doi:10.1021/cm011030j

CrossRef Full Text | Google Scholar

Schüth, F. (2003). Endo- and exotemplating to create high-surface-area inorganic materials. Angew. Chem. Int. Ed. Engl. 42, 3604–3622. doi:10.1002/anie.200300593

PubMed Abstract | CrossRef Full Text | Google Scholar

Singha, R., Shukla, A., Yadav, A., Sivakumar Konathala, L. N., and Bal, R. (2017). Effect of metal-support interaction on activity and stability of Ni-CeO₂ catalyst for partial oxidation of methane. Appl. Catal. B. Environ. 202, 473–488. doi:10.1016/j.apcatb.2016.09.060

CrossRef Full Text | Google Scholar

Soboleva, T., Zhao, X., Malek, K., Xie, Z., Navessin, T., and Holdcroft, S. (2010). On the micro-, meso-, and macroporous structures of polymer electrolyte membrane fuel cell catalyst layers. ACS Appl. Mater. Interfaces 2, 375–384. doi:10.1021/am900600y

PubMed Abstract | CrossRef Full Text | Google Scholar

Soler-Illia, G., Sanchez, C., Lebeau, B., and Patarin, J. (2002). Chemical strategies to design textured materials: from microporous and mesoporous oxides to nanonetworks and hierarchical structures. Chem. Rev. 102, 4093–4138. doi:10.1021/cr0200062

CrossRef Full Text | Google Scholar

Stathopoulos, V., Belessi, V., and Ladavos, A. (2001). Samarium based high surface area perovskite type oxides SmFe1-xAlxO3 (X=0.00, 0.50, 0.95). Part I, synthesis and characterization of materials. React. Kinet. Catal. Lett. 72, 43–48. doi:10.1023/A:1010524312637

CrossRef Full Text | Google Scholar

Taguchi, A., and Schüth, F. (2005). Ordered mesoporous materials in catalysis. Microporous Mesoporous Mater. 77, 1–45. doi:10.1016/j.micromeso.2004.06.030

CrossRef Full Text | Google Scholar

Tang, J.-L., Zhu, M.-K., Chen, C., Hou, Y.-D., Wang, H., and Yan, H. (2009). Perovskite Pb(Sc_1/2Nb_1/2)O₃ nanopowders synthesized by surfactant-modulated precipitation. J. Nanopart. Res. 11, 355–363. doi:10.1007/s11051-008-9393-0

CrossRef Full Text | Google Scholar

Toniolo, F., Magalhães, R. N. S. H., Perez, C. A. C., and Schmal, M. (2012). Structural investigation of LaCoO₃ and LaCoCuO₃ perovskite-type oxides and the effect of Cu on coke deposition in the partial oxidation of methane. Appl. Catal. B. Environ. 117, 156–166. doi:10.1016/j.apcatb.2012.01.009

CrossRef Full Text | Google Scholar

Villoria, J. A., Alvarez Galvan, M. C., Al Zahrani, S. M., Palmisano, P., Specchia, S., Specchia, V., et al. (2011). Oxidative reforming of diesel fuel over LaCoO₃ perovskite derived catalysts: influence of perovskite synthesis method on catalyst properties and performance. Appl. Catal. B Environ. 105, 276–288. doi:10.1016/j.apcatb.2011.04.010

CrossRef Full Text | Google Scholar

Wang, H. Y., and Ruckenstein, E. (2001). Partial oxidation of methane to synthesis gas over alkaline earth metal oxide supported cobalt catalysts. J. Catal. 199, 309–317. doi:10.1006/jcat.2001.3190

CrossRef Full Text | Google Scholar

Wang, S., Lu, G. Q., and Millar, G. (1996). Carbon dioxide reforming of methane to produce synthesis gas over metal-supported catalysts: state of the art. Energy Fuels 10, 896–904. doi:10.1021/ef950227t

CrossRef Full Text | Google Scholar

Xintong, P., Yang, G., Yuting, Z., Bingbing, Xu, and Fei, Qi. (2016). LaCoO₃ perovskite oxide activation of peroxymonosulfate for aqueous 2-phenyl-5-sulfobenzimidazole degradation: effect of synthetic method and the reaction mechanism. Chem. Eng. J. 304, 897–907. doi:10.1016/j.cej.2016.07.027

CrossRef Full Text | Google Scholar

York, A. P. E. (2003). Brief overview of the partial oxidation of methane to synthesis gas. Top. Catal. 22, 345–358. doi:10.1023/A:1023552709642

CrossRef Full Text | Google Scholar

Zavyalova, U., Girgsdies, F., Korup, O., Horn, R., and Schlögl, R. (2009). Microwave-assisted self-propagating combustion synthesis for uniform deposition of metal nanoparticles on ceramic monoliths. J. Phys. Chem.C. 113, 17493–17501. doi:10.1021/jp905692g

CrossRef Full Text | Google Scholar

Zhao, C., Wang, W., Yu, Z., Zhang, H., Wang, A., and Yang, Y. (2010). Nano-CaCO₃ as template for preparation of disordered large mesoporous carbon with hierarchical porosities. J. Mater. Chem. 20, 976–980. doi:10.1039/B911913B

CrossRef Full Text | Google Scholar

Zhu, J., Rahuman, M. S. M. M., van Ommen, J. G., and Lefferts, L. (2004). Dual catalyst bed concept for catalytic partial oxidation of methane to synthesis gas. Appl. Catal. A. Gen. 259, 95–100. doi:10.1016/j.apcata.2003.09.022

CrossRef Full Text | Google Scholar

Zou, Z.-Q., Meng, M., Luo, J.-Y., Zha, Y.-Q., Xie, Y.-N., Hu, T.-D., et al. (2006). A novel mesoporous oxidation catalyst La-Co-Zr-O prepared by using nonionic and cationic surfactants as co-templates. J. Mol. Catal. A. Chem. 249, 240–245. doi:10.1016/j.molcata.2006.01.010

CrossRef Full Text | Google Scholar

Zou, Z.-Q., Meng, M., Zha, Y.-Q., and Liu, Y. (2008). Dual templates assisted preparation and characterization of highly thermostable multicomponent mesoporous material La–Ce–Co–Zr–O used for low-temperature CO oxidation. J. Sci. Mater. 43, 1958–1965. doi:10.1007/s10853-008-2460-1

CrossRef Full Text | Google Scholar