Synthesis of Li2S-Carbon Cathode Materials via Carbothermic Reduction of Li2SO4

Introduction

Lithium-sulfur (Li-S) batteries have received intensive investigations over the past decade due to its great potential as a high-capacity rechargeable battery technology (Ma et al., 2015; Manthiram et al., 2015; Wild et al., 2015; Fang et al., 2017; Peng et al., 2017; Zheng et al., 2017; Chen et al., 2018). To eliminate the potential safety hazard induced by the Li metal anode, high-capacity non-Li anodes, particularly silicon-based materials, have been sought as the alternative (Yang et al., 2010; Agostini et al., 2014; Cao et al., 2015; Jha et al., 2015; Guo et al., 2017). Utilizing non-Li anodes requires lithium sulfide (Li₂S) cathode materials, which have been produced by a number of methods reported in literature. The most common method is to physically mix Li₂S and carbon materials with high-energy ball milling (Cai et al., 2012; Jeong et al., 2013; Chen et al., 2014; Liu et al., 2015a; Lee et al., 2016; Liang et al., 2016). Li₂S solution in ethanol was used to deposit Li₂S on various carbon structures (Wu et al., 2014a,b,c, 2015, 2016; Wang et al., 2015; Han et al., 2016; Zhou et al., 2016). Other solvent such as anhydrous methyl acetate was also used to disperse Li₂S in carbon (Seh et al., 2014). A number of chemical methods were also reported: Li₂S-C composite could be produced from sulfurization of lithium carbonate with H₂S (Dressel et al., 2016; Hart et al., 2018). Li₂S-C composite was also synthesized via the reaction between lithium polysulfides and the nitrile group in polyacrylonitrile (Guo et al., 2013). A recently reported novel method utilized the thermal reaction between metallic Li and gaseous carbon disulfide (CS₂) to form carbon coated Li₂S in one step (Tan et al., 2017). Another chemical method to produce Li₂S-C composites is to convert lithium sulfate (Li₂SO₄) to Li₂S via carbothermic reduction (Yang et al., 2013; Kohl et al., 2015; Li et al., 2015; Liu et al., 2015b; Wang et al., 2016; Yu et al., 2017; Zhang et al., 2017; Ye et al., 2018). Comparing to all other methods mentioned above, carbothermic reduction of Li₂SO₄ involves neither hazardous gas such as gaseous CS₂ or H₂S, nor air sensitive reactants such as Li₂S or Li metal. Furthermore, Li₂S-C composites can be produced in one-step reaction in carbothermic reduction of Li₂SO₄. In this study, we focus on understanding the effect of reaction temperature on stoichiometric ratio of C/Li₂SO₄ in the carbothermic reduction and the structure-property relationship of the obtained Li₂S-C composites as the cathode materials for Li-S batteries.

Materials and Methods

Temperature Effect on C/Li₂SO₄ Stoichiometric Ratio

All reagents were used after purchase without further purification unless otherwise noted. Ketjen black EC-600JD (KJB, purchased from AkzoNobel) was used as the carbon source in this study. To minimize the effect of the impurity in KJB (mainly oxygen) on the carbothermic reduction of Li₂SO₄, KJB was treated by hydrogen reduction: In a typical experiment, approximately 400 mg KJB was heated under hydrogen/argon (5%/95%) environment at 1,000°C for 3 h. Elemental contents of KJB before and after the hydrogen treatment was analyzed as shown in Table 1.

TABLE 1

Table 1. Elemental analysis of KJB before and after the hydrogen reduction treatment.

Li₂SO₄ and KJB was thoroughly mixed by mechanical ball milling with different weight ratios including 2.0:1, 2.3:1, 2.5:1 and 2.9:1. The mixture was heated in a tube furnace under flowing argon (Ar) environment to form Li₂S-C composite. The temperature of the tube furnace was first raised to 200°C from room temperature at 5°C min⁻¹. The temperature was held at 200°C for 2 h, followed by further increasing to neither 700 or 750°C at 5°C min⁻¹. The temperature was kept at 700 or 750°C for 6 h to complete the carbothermic reduction of Li₂SO₄. Ethanol was used to leach out the Li₂S in the resultant Li₂S-C composite to measure the conversion of Li₂SO₄ and carbon content, from which the C/Li₂SO₄ stoichiometric ratio in the carbothermic reduction can be calculated.

Li₂S-C Composite Synthesis and Characterization

To improve the areal loading the Li₂S-C composite at the cathode, micron-sized carbon particles were first synthesized with KJB as the precursor following the method reported by Lv et al. (2015). In a typical synthesis of Li₂S-C composite, the micron-sized carbon particles were mixed into 5 mL aqueous solution of Li₂SO₄ with a specific Li₂SO₄/C ratio, followed by dispersion by sonication for 5 min and thorough stir for additional 24 h. One hundred milliliter ethanol was then added into the mixture and stirred for 10 min. The Li₂SO₄-C dispersion in the water/ethanol mixture was dried with rotary evaporator at 90°C. The obtained Li₂SO₄-C mixture was further dried at 80°C under vacuum overnight. To produce the Li₂S-C composite, 0.5 g of Li₂SO₄-C mixture was heated under flowing Ar environment in a tube furnace using the same process as aforementioned.

The Li₂S-C composite was characterized by powder X-Ray diffraction (XRD, PANalytical). Kapton tape was used to seal the XRD sample to prevent Li₂S from reacting with moisture in the ambient environment. Nitrogen adsorption-desorption isotherms of the Li₂S-C composites were measured with a surface area and porosity analyzer (Micromeritics ASAP2020). The surface area was obtained with the Brunauer-Emmett-Teller (BET) method. To avoid Li₂S reacting with environmental moisture, all Li₂S-C composites were transferred into the BET sample tube in the glovebox and sealed with Teflon tape. The microstructure of the Li₂S-C composites was characterized with scanning electron microscopy (SEM) and elemental mapping was obtained by energy-dispersive X-ray spectroscopy (EDX). To perform the SEM characterization, the samples were carefully sealed into a stainless-steel vacuum tube in an Ar-filled glovebox. The sample tube was transferred into the SEM chamber under flowing argon protection using a glove-bag.

Electrode Fabrication, Cell Assembly and Testing

To prepare the electrode, Li₂S-C composite was mixed with carbon black and polyvinylidene difluoride with a weight ratio of 85:5:10 in N-methyl-2-pyrrolidone. The obtained slurry was uniformly pasted on a carbon coated aluminum foil current collector and dried in the Ar-filled glovebox at 135°C for at least 15 h. The dried electrodes were assembled into 2032-type coin cells with Li foil anode (99.9%, Alfa Aesar) and Celgard^® 2500 separator. The electrolyte used in this study was 1 M lithium bis(trifluoromethanesulfonyl)imide solution in a mixture of 1,3-dioxolane, dimethoxyethane and 1-butyl-1-methylpyrrolidinium bis(trifluoromethanesulfonyl)imide (1:1:2 by vol.) with 1.5 wt.% of LiNO₃. The electrolyte to Li₂S ratio (μL/mg) was kept at 7 in all coin cells testing. The average areal loading of Li₂S on the electrode is 2 mg cm⁻². The first charge (activation) was performed at a rate of C/50 (24 mA g⁻¹) to a charge cutoff of 3.8 V vs. Li⁺/Li. The subsequent cycles were performed at C/10, C/5, C/2, and 1C between 2.8 and 1.7 V.

Results and Discussion

Despite the previous reports on synthesizing Li₂S-C composites via carbothermic reduction of Li₂SO₄, the influence of reaction temperature on the stoichiometric ratio between carbon and Li₂SO₄ has not been investigated. As shown in Reaction 1, carbothermic reduction of Li₂SO₄ generally produces both carbon dioxide (CO₂) and carbon monoxide (CO) (Li et al., 2015; Zhang et al., 2017). However, the ratio between CO₂ and CO changes with temperature due to their different stability as the function of temperature (Zhang et al., 2017). Therefore, the carbothermic reduction of Li₂SO₄ can be expressed as Reaction 2, in which the stoichiometric ratio of C/Li₂SO₄, x, is a function of temperature. To synthesize Li₂S-C composite in one-step carbothermic reduction with precise carbon content, it is critical to learn the value of x at different temperature.

$\begin{array}{ll}{Li}_{2}S{O}_4+xC\to {Li}_{2}S+{yCO}_2+zCO& (1)\end{array}$

$\begin{array}{ll}{Li}_{2}S{O}_4+xC\to {Li}_{2}S+{xCO}_{4/x}& (2)\end{array}$

With certain Li₂SO₄/C mass ratio (carbon in excess) and assumption of 100% conversion of Li₂SO₄ to Li₂S, the Li₂S content in the Li₂S-C composite from the carbothermic reduction can be calculated as the function of the stoichiometric ratio of C/Li₂SO₄ as shown in Figure 1. The four solid lines represent four different Li₂SO₄/C mass ratio, 2.0:1, 2.3:1, 2.5:1, and 2.9:1, which all have excess of carbon. Carbothermic experiments were first performed with Li₂SO₄/C mass ratio of 2.0:1, 2.3:1 and 2.5:1 at 700 and 750°C. The reaction at each condition (temperature and Li₂SO₄/C mass ratio) was repeated at least three times to minimize experimental errors. The content of Li₂S in the resultant Li₂S-C composite was measured and the results demonstrated full conversion of Li₂SO₄ to Li₂S in all experiments. Therefore, the stoichiometric ratio of C/Li₂SO₄, x, was calculated at all experimental conditions and the average values were marked on the theoretic curves in Figure 1. It is clear that the stoichiometric ratio of C/Li₂SO₄ is lower at 700°C, indicating less carbon is consumed at lower temperature with higher CO₂ content in the gaseous products. The experimental results can also be linearly fitted to obtain an empirical relationship between Li₂S content in Li₂S-C and the stoichiometric C/Li₂SO₄ ratio at different temperature. The empirical relationship at 700°C is Li₂S wt.% = 175.3 – 54.9x (red dotted line) and the one at 750°C is Li₂S wt.% = 212.0 – 58.6x (blue dotted line).

FIGURE 1

Figure 1. Mass ratio of Li₂S in the Li₂S-C composite as the function of stoichiometry ratio of C/Li₂SO₄ with different Li₂SO₄/C mass ratio at 2.0:1, 2.3:1, 2.5:1, and 2.9:1 at 700 and 750°C.

To study the structure-property relationship of the Li₂S-C composites, we need to select a composite from each reaction temperature with same Li₂S content. One selected Li₂S-C composite is produced at 750°C with Li₂SO₄/C mass ratio of 2.5:1, which contains 72 wt.% of Li₂S. The same Li₂S content was projected on the empirical linear fitting of Li₂S content vs. stoichiometric C/Li₂SO₄ ratio at 700°C, from which the required Li₂SO₄/C mass ratio was calculated to be 2.9:1. The carbothermic reduction of Li₂SO₄ at 700°C with Li₂SO₄/C mass ratio of 2.9:1 yielded Li₂S-C with 71 wt.% Li₂S content, which agreed very well with the prediction.

The two Li₂S-C composites with the same Li₂S content are denoted as Li₂S-C₇₀₀ and Li₂S-C₇₅₀ according to the reaction temperature. The XRD patterns of these two composites in Figure 2A indicate well-crystallized Li₂S formed from the carbothermic reduction of Li₂SO₄. The broad peak around 20° is due to the Kapton tape protecting Li₂S from reacting to the ambient moisture. Based on the full-width at half-maximum of the XRD peaks, Li₂S-C₇₅₀ has smaller crystal grain size than that of Li₂S-C₇₀₀. The BET surface areas of these two Li₂S-C composites from the N₂ adsorption-desorption isotherms (Figure 2B) are very close: 350.8 m² g⁻¹ for Li₂S-C₇₅₀ and 326.8 m² g⁻¹ for Li₂S-C₇₀₀. We believe the higher carbon content in the Li₂SO₄-C mixture at the 750°C reaction alleviated the particle aggregation thus leading to smaller Li₂S particles.

FIGURE 2

Figure 2. (A) XRD patterns and (B) N₂ adsorption-desorption isotherms of the Li₂S-C composites synthesized at different temperature.

SEM was used to characterize the microstructure of the Li₂S-C composites. Figure 3a shows the structure of the Li₂SO₄/C mixture before carbothermic reduction for Li₂S-C₇₅₀. Li₂SO₄ exhibited typical monoclinic crystal structure as hexagonal plate with crystal size around 10 μm. Interestingly, the carbothermic reduction of Li₂SO₄ yielded spherical Li₂S particles dispersed in carbon matrix as displayed in the SEM image in Figure 3b and the EDX elemental mapping in Figures 3c,d. The SEM characterization of the Li₂S-C₇₀₀ demonstrated very similar microstructure with Li₂S-C₇₅₀ as displayed in Figures 3f–i. The particle size of Li₂S was measured by ImageJ software and the average particle size was analyzed by Gaussian distribution over 700 particles. As the particle size distribution shown in Figures 3e,j, the Li₂S particle size in Li₂S-C₇₅₀ was smaller than that in Li₂S-C₇₀₀: The average Li₂S particle size was 4.4 μm in Li₂S-C₇₅₀ and 6.4 μm in Li₂S-C₇₀₀.

FIGURE 3

Figure 3. (a) SEM image of Li₂SO₄-C mixture with Li₂SO₄/C mass ratio of 2.5:1, (b) SEM image, (c,d) EDX elemental mapping, and (e) Li₂S size distribution of Li₂S-C₇₅₀; (f) SEM image of Li₂SO₄-C mixture with Li₂SO₄/C mass ratio of 2.9:1, (g) SEM image, (h,i) EDX elemental mapping and (j) Li₂S size distribution of Li₂S-C₇₀₀.

Figures 4A,B show the CV cycles of Li₂S-C₇₅₀ and Li₂S-C₇₀₀ electrodes. The Li₂S-C₇₅₀ electrode demonstrated slightly lower delithiation potential than Li₂S-C₇₀₀ in the first cycle (3.5 vs. 3.6 V for the cathodic peak, respectively). This observation is consistent with the first galvanostatic delithiation (charge) curves of these two composites shown in Figures 4C,D. Li₂S-C₇₅₀ clearly demonstrated a lower activation potential at approximately 3.2 V vs. Li⁺/Li in the first two third of the charge process. On the contrary, Li₂S-C₇₀₀ showed much higher activation potential at 3.5 V vs. Li⁺/Li, which led to a lower first charge capacity. We speculate that the lower delithiation overpotential of Li₂S-C₇₅₀ is attributed to its structural advantage, mainly smaller Li₂S particle size. Previous studies also reported that larger Li₂S particle size could result to higher activation potential in the first charge process (Yang et al., 2012; Kohl et al., 2015; Liu et al., 2015a; Wang et al., 2016; Ye et al., 2018). In addition to the effect from particle size, activation potential of Li₂S can also be affected by surface impurities such as Li₂SO₄, Li₂CO₃, and Li₂O (Jung and Kang, 2016; Vizintin et al., 2017). The better microstructure of Li₂S-C₇₅₀ is also evidenced by the lower charge-discharge potential hysteresis (Figures 4C,D), better cycle stability and rate capability shown in Figures 4E,F. The average initial discharge capacity of Li₂S-C₇₅₀ is 600 mAh g⁻¹ (average of 3 electrodes), and 400 mAh g⁻¹ capacity was retained after 200 cycles at C/5. The specific capacity of Li₂S-C₇₅₀ at C/2 only slightly decreased from C/10 and C/5, indicating good rate capability. On the other hand, Li₂S-C₇₀₀ suffered from not only lower specific capacity at C/10, but also inferior rate capability as indicated by the low capacity at C/5, C/2, and 1C. It is clear that particle size of Li₂S is the critical parameter for rate performance of the Li₂S-C composites. It is also worth noting that the initial specific capacity of Li₂S-C₇₀₀ started with slight increase during cycling at C/10, which can be attributed to its inferior activation process due to larger Li₂S particle size.

FIGURE 4

Figure 4. CV curves of (A) Li₂S-C₇₅₀ and (B) Li₂S-C₇₀₀; the 1st, 2nd, 10th, and 50th cycles of charge-discharge of (C) Li₂S-C₇₅₀ and (D) Li₂S-C₇₀₀ at C/5; the cycle stability at C/10, C/5, C/2, and 1C of (E) Li₂S-C₇₅₀ and (F) Li₂S-C₇₀₀.

Conclusion

In summary, the synthetic route of Li₂S-C from carbothermic reduction of Li₂SO₄ was investigated in this study. Particularly the relationship between reaction temperature and stoichiometric ratio of C/Li₂SO₄ in the carbothermic reduction was obtained for the first time. Through investigations on microstructures and electrochemical properties, we speculated that smaller Li₂S particle size dispersed in carbon matrix is the key parameter to improve the electrochemical performance. Methods to further reduce particle size of Li₂S via carbothermic reduction of Li₂SO₄ will be investigated in future studies.

Data Availability

All datasets generated for this study are included in the manuscript and/or the supplementary files.

Author Contributions

JS performed the majority of the experiments. JZ performed SEM and EDX. YZ and ZY synthesized the micron-sized carbon particles used in Li₂S-C synthesis. NH and JG designed the experiments. All authors co-wrote the manuscript.

Conflict of Interest Statement

The authors declare that the research was conducted in the absence of any commercial or financial relationships that could be construed as a potential conflict of interest.

Acknowledgments

We acknowledge the National Science Foundation for financial support under grant no. CBET-1604908.

References

Agostini, M., Hassoun, J., Liu, J., Jeong, M., Nara, H., Momma, T., et al. (2014). A lithium-ion sulfur battery based on a carbon-coated lithium-sulfide cathode and an electrodeposited silicon-based anode. ACS Appl. Mater. Interfaces 6, 10924–10928. doi: 10.1021/am4057166

PubMed Abstract | CrossRef Full Text | Google Scholar

Cai, K., Song, M., Cairns, E., and Zhang, Y. (2012). Nanostructured Li₂S-C composites as cathode material for high-energy lithium/sulfur batteries. Nano Lett. 12, 6474–6479. doi: 10.1021/nl303965a

CrossRef Full Text | Google Scholar

Cao, R., Xu, W., Lv, D., Xiao, J., and Zhang, J. (2015). Anodes for rechargeable lithium-sulfur batteries. Adv. Energy Mater. 5:1402273. doi: 10.1002/aenm.201402273

CrossRef Full Text | Google Scholar

Chen, L., Guo, X., Lu, W., Chen, M., Li, Q., Xue, H., et al. (2018). Manganese monoxide-based materials for advanced batteries. Coordination Chem. Rev. 368, 13–34. doi: 10.1016/j.ccr.2018.04.015

CrossRef Full Text | Google Scholar

Chen, L., Liu, Y., Ashuri, M., Liu, C., and Shaw, L. L. (2014). Li₂S encapsulated by nitrogen-doped carbon for lithium sulfur batteries. J. Mater. Chem. A 2:18026. doi: 10.1039/C4TA04103H

CrossRef Full Text | Google Scholar

Dressel, B. C., Jha, H., Eberle, A., Gasteiger, A. H., and Fassler, F. T. (2016). Electrochemical performance of lithium-sulfur batteries based on a sulfur cathode obtained by H₂S gas treatment of a lithium salt. J. Power Sources 307, 844–848. doi: 10.1016/j.jpowsour.2015.12.140

CrossRef Full Text | Google Scholar

Fang, R., Zhao, S., Sun, Z., Wang, D. W., Cheng, H. M., et al. (2017). More reliable lithium-sulfur batteries: status, solutions and prospects. Adv. Mater. 29:1606823. doi: 10.1002/adma.201606823

PubMed Abstract | CrossRef Full Text | Google Scholar

Guo, J., Yang, Z., Yu, Y., Abruña, H. D., and Archer, L. A. (2013). Lithium-sulfur battery cathode enabled by lithium-nitrile interaction. J. Am. Chem. Soc. 135, 763–767. doi: 10.1021/ja309435f

PubMed Abstract | CrossRef Full Text | Google Scholar

Guo, X., Zheng, S., Zhang, G., Xiao, X., Li, X., Xu, Y., et al. (2017). Nanostructured graphene-based materials for flexible energy storage. Energy Storage Mater. 9, 150–169. doi: 10.1016/j.ensm.2017.07.006

CrossRef Full Text | Google Scholar

Han, F., Yue, J., Fan, X., Gao, T., Luo, C., Ma, Z., et al. (2016). High-performance all-solid-state lithium-sulfur battery enabled by a mixed-conductive Li₂S nanocomposite. Nano Lett. 16, 4521–4527. doi: 10.1021/acs.nanolett.6b01754

PubMed Abstract | CrossRef Full Text | Google Scholar

Hart, N., Shi, J., Zhang, J., Fu, C., and Guo, J. (2018). Lithium sulfide-carbon composites via aerosol spray pyrolysis as cathode materials for lithium-sulfur batteries. Front. Chem. 6:674. doi: 10.3389/fchem.2018.00476

PubMed Abstract | CrossRef Full Text | Google Scholar

Jeong, S., Bresser, D., Buchholz, D., Winter, M., and Passerini, S. (2013). Carbon coated lithium sulfide particles for lithium battery cathodes. J. Power Sources 235, 220–225. doi: 10.1016/j.jpowsour.2013.01.084

CrossRef Full Text | Google Scholar

Jha, H., Buchberger, I., Cui, X., Meini, S., and Gasteiger, H. A. (2015). Li-S batteries with Li₂S cathodes and Si/C anodes. J. Electrochem. Soc. 162, A1829–A1835. doi: 10.1149/2.0681509jes

CrossRef Full Text | Google Scholar

Jung, Y., and Kang, B. (2016). Understanding abnormal potential behaviors at the 1st charge in Li₂S cathode material for rechargeable Li-S batteries. Phys. Chem. Chem. Phys. 18:21500. doi: 10.1039/C6CP03146C

PubMed Abstract | CrossRef Full Text | Google Scholar

Kohl, M., Bruckner, J., Bauer, I., Althues, H., and Kaskel, S. (2015). Synthesis of highly electrochemically active Li₂S nanoparticles for lithium–sulfur-batteries. J. Mater. Chem. A 3, 16307–16312. doi: 10.1039/C5TA04504E

CrossRef Full Text | Google Scholar

Lee, S., Lee, Y. J., and Sun, Y. (2016). Nanostructured lithium sulfide materials for lithium-sulfur batteries. J. Power Sources 323, 174–188. doi: 10.1016/j.jpowsour.2016.05.037

CrossRef Full Text | Google Scholar

Li, Z., Zhang, S., Zhang, C., Ueno, K., Yasuda, T., Tatara, R., et al. (2015). One-pot pyrolysis of lithium sulfate and graphene nanoplatelet aggregates: in situ formed Li₂S/graphene composite for lithium-sulfur batteries. Nanoscale 7, 14385–14392. doi: 10.1039/C5NR03201F

CrossRef Full Text | Google Scholar

Liang, S., Liang, C., Xia, Y., Xu, H., Huang, H., Tao, X., et al. (2016). Facile synthesis of porous Li₂S@C composites as cathode materials for lithium-sulfur batteries. J. Power Sources 306, 200–207. doi: 10.1016/j.jpowsour.2015.12.030

CrossRef Full Text | Google Scholar

Liu, J., Nara, H., Yokoshima, T., Momma, T., and Osaka, T. (2015a). Li₂S cathode modified with polyvinylpyrrolidone and mechanical milling with carbon. J. Power Sources 273, 1136–1141. doi: 10.1016/j.jpowsour.2014.09.179

CrossRef Full Text | Google Scholar

Liu, J., Nara, H., Yokoshima, T., Momma, T., and Osaka, T. (2015b). Micro-scale Li₂S-C composite preparation from Li₂SO₄ for cathode of lithium ion battery. Electrochim. Acta 183, 70–77. doi: 10.1016/j.electacta.2015.07.116

CrossRef Full Text | Google Scholar

Lv, D., Zheng, J., Li, Q., Xie, X., Ferrara, S., Nie, Z., et al. (2015). High energy density lithium–sulfur batteries: challenges of thick sulfur cathodes. Adv. Energy Mater. 5:1402290. doi: 10.1002/aenm.201402290

CrossRef Full Text | Google Scholar

Ma, L., Hendrickson, K. E., Wei, S., and Archer, L. A. (2015). Nanomaterials: science and applications in the lithium-sulfur battery. Nano Today 10, 315–338. doi: 10.1016/j.nantod.2015.04.011

CrossRef Full Text | Google Scholar

Manthiram, A., Chung, S. H., and Zu, C. (2015). Lithium-sulfur batteries: progress and prospects. Adv. Mater. 27, 1980–2006. doi: 10.1002/adma.201405115

PubMed Abstract | CrossRef Full Text | Google Scholar

Peng, H., Huang, J., Cheng, X., and Zhang, Q. (2017). Review on high-loading and high-energy lithium-sulfur batteries. Adv. Energy Mater. 7:1700260. doi: 10.1002/aenm.201700260

CrossRef Full Text | Google Scholar

Seh, Z. W., Wang, H., Hsu, P., Zhang, Q., Li, W., Zheng, G., et al. (2014). Facile synthesis of Li₂S-polypyrrole composite structures for high-performance Li₂S cathodes. Energy Environ. Sci. 7, 672–676. doi: 10.1039/c3ee43395a

CrossRef Full Text | Google Scholar

Tan, G., Xu, R., Xing, Z., Yuan, Y., Lu, J., Wen, J., et al. (2017). Burning lithium in CS₂ for high-performing compact Li₂S-graphene nanocapsules for Li-S batteries. Nat. Energy. 2:17090. doi: 10.1038/nenergy.2017.90

CrossRef Full Text | Google Scholar

Vizintin, A., Chabanne, L., Tchernychova, E., Arcon, I., Stievano, L., Aquilanti, G., et al. (2017). The mechanism of Li₂S activation in lithium-sulfur batteries: can we avoid the polysulfide formation? J. Power Sources 344, 208–217. doi: 10.1016/j.jpowsour.2017.01.112

CrossRef Full Text | Google Scholar

Wang, C., Wang, X., Yang, Y., Kushima, A., Chen, J., Huang, Y., et al. (2015). Slurryless Li₂S/reduced graphene oxide cathode paper for high-performance lithium sulfur battery. Nano Lett. 15, 1796–1802. doi: 10.1021/acs.nanolett.5b00112

PubMed Abstract | CrossRef Full Text | Google Scholar

Wang, D., Xie, D., Yang, T., Zhang, Y., Wang, X., Xia, X., et al. (2016). Conversion from Li₂SO₄ to Li₂S@C on carbon paper matrix: a novel integrated cathode for lithium-sulfur batteries. J. Power Sources 331, 475–480. doi: 10.1016/j.jpowsour.2016.09.033

CrossRef Full Text | Google Scholar

Wild, M., O'Neill, L., Zhang, T., Purkayastha, R., Minton, G., Marinescu, M., et al. (2015). Lithium sulfur batteries, a mechanistic review. Energy Environ. Sci. 8:3477. doi: 10.1039/C5EE01388G

CrossRef Full Text | Google Scholar

Wu, F., Kim, H., Magasinski, A., Lee, J., Lin, H., and Yushin, G. (2014a). Harnessing steric separation of freshly nucleated Li₂S nanoparticles for bottom-up assembly of high-performance cathodes for lithium-sulfur and lithium-ion batteries. Adv. Energy Mater. 4:1400196. doi: 10.1002/aenm.201400196

CrossRef Full Text | Google Scholar

Wu, F., Lee, J., Magasinski, A., Kim, H., and Yushin, G. (2014b). Solution-based processing of graphene-Li₂S composite cathodes for lithium-ion and lithium-sulfur batteries. Part. Part. Syst. Charact. 31, 639–644. doi: 10.1002/ppsc.201300358

CrossRef Full Text | Google Scholar

Wu, F., Lee, J. T., Fan, F., Nitta, N., Kim, H., Zhu, J., et al. (2015). A hierarchical particle-shell architecture for long-term cycle stability of Li₂S cathodes. Adv. Mater. 27, 5579–5586. doi: 10.1002/adma.201502289

PubMed Abstract | CrossRef Full Text | Google Scholar

Wu, F., Lee, J. T., Zhao, E., Zhang, B., and Yushin, G. (2016). Graphene-Li₂S-carbon nanocomposite for lithium-sulfur batteries. ACS Nano 10, 1333–1340. doi: 10.1021/acsnano.5b06716

PubMed Abstract | CrossRef Full Text | Google Scholar

Wu, F., Magasinski, A., and Yushin, G. (2014c). Nanoporous Li₂S and MWCNT-linked Li₂S powder cathodes for lithium-sulfur and lithium-ion battery chemistries. J. Mater. Chem. A 2, 6064–6070. doi: 10.1039/C3TA14161F

CrossRef Full Text | Google Scholar

Yang, Y., McDowell, M. T., Jackson, A., Cha, J. J., Hong, S. S., and Cui, Y. (2010). New nanostructured Li₂S/silicon rechargeable battery with high specific energy. Nano Lett. 10, 1486–1491. doi: 10.1021/nl100504q

PubMed Abstract | CrossRef Full Text | Google Scholar

Yang, Y., Zheng, G., Misra, S., Nelson, J., Toney, M. F., and Cui, Y. (2012). High-capacity micrometer-sized Li₂S particles as cathode materials for advanced rechargeable lithium-ion batteries. J. Am. Chem. Soc. 134, 15387–15394. doi: 10.1021/ja3052206

PubMed Abstract | CrossRef Full Text | Google Scholar

Yang, Z., Guo, J., Das, K. S., Yu, Y., Zhou, Z., Abruna, D. H., et al. (2013). In situ synthesis of lithium sulfide-carbon composites as cathode materials for rechargeable lithium batteries. J. Mater. Chem. A 1, 1433–1440. doi: 10.1039/C2TA00779G

CrossRef Full Text | Google Scholar

Ye, F., Noh, H., Lee, J., Lee, H., and Kim, H. (2018). Li₂S/carbon nanocomposite strips from a low-temperature conversion of Li₂SO₄ as high-performance lithium-sulfur cathodes. J. Mater. Chem. A 6, 6617–6624. doi: 10.1039/C8TA00515J

CrossRef Full Text | Google Scholar

Yu, M., Wang, Z., Wang, Y., Dong, Y., and Qiu, J. (2017). Freestanding flexible Li₂S paper electrode with high mass and capacity loading for high-energy Li-S batteries. Adv. Energy Mater. 7:1700018. doi: 10.1002/aenm.201700018

CrossRef Full Text | Google Scholar

Zhang, J., Shi, Y., Ding, Y., Peng, L., Zhang, W., and Yu, G. (2017). A conductive molecular framework derived Li₂S/N, P-codoped carbon cathode for advanced lithium-sulfur batteries. Adv. Energy Mater. 7:1602876. doi: 10.1002/aenm.201602876

CrossRef Full Text | Google Scholar

Zheng, S., Li, X., Yan, B., Hu, Q., Xu, Y., Xiao, X., et al. (2017). Transition-metal (Fe, Co, Ni) based metal-organic frameworks for electrochemical energy storage. Adv. Energy Mater. 7:1602733. doi: 10.1002/aenm.201602733

CrossRef Full Text | Google Scholar

Zhou, G., Paek, E., Hwang, G. S., and Manthiram, A. (2016). High-performance lithium-sulfur batteries with a self-supported, 3D Li₂S-doped graphene aerogel cathodes. Adv. Energy Mater. 6:1501355. doi: 10.1002/aenm.201501355

CrossRef Full Text | Google Scholar