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Recent Advances in Volcanic Gas Science

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Front. Earth Sci. | doi: 10.3389/feart.2019.00065

The PiSpec: a low-cost, 3D-printed spectrometer for measuring volcanic SO2 emission rates

 Thomas C. Wilkes1*,  Tom D. Pering1,  Andrew J. McGonigle1, 2, Jon R. Willmott1,  Robert G. Bryant1,  Alan L. Smalley1, Forrest M. Mims III3,  Alfio V. Parisi4 and Rebecca A. England1
  • 1Department of Geography, University of Sheffield, United Kingdom
  • 2School of Geosciences, University of Sydney, Australia
  • 3Geronimo Creek Observatory, United States
  • 4Faculty of Health, Engineering and Sciences, University of Southern Queensland, Australia

The PiSpec is a new, custom-designed, 3D-printed spectrometer based on smartphone sensor technology. This unit has ≈ 1 nm spectral resolution and a spectral range in the ultraviolet of ≈ 280-340 nm, and is specifically configured for the remote sensing of SO2 using Differential Optical Absorption Spectroscopy (DOAS). Here we report on the first field deployment of the PiSpec on a volcano, to demonstrate the proof of concept of the device’s functionality in this application area. The study was performed on Masaya Volcano, Nicaragua, which is one of the largest emitters of SO2 on the planet, during a period of elevated activity, where a lava lake was present in the crater. Both scans and traverses were performed, with resulting emission rates ranging from 3.2 - 45.6 kg s-1 across two measurement days; these values are commensurate with those reported elsewhere in the literature during this activity phase (Aiuppa et al., 2018; Stix et al., 2018). Furthermore, we tested the PiSpec’s thermal stability, finding a wavelength shift of 0.046 nm/˚C between 2.5 - 45 ˚C, which is very similar to that of some commercial spectrometers. Given the low build cost of these units (≈ 500 USD for a one-off build, with prospects for further price reduction with volume manufacture), we suggest these units hold considerable potential for volcano monitoring operations in resource limited environments.

Keywords: UV spectroscopy, DOAS, Sulphur dioxide, Volcanic emissions, Masaya volcano, Raspberry Pi, 3D printing, Smartphone sensor

Received: 14 Sep 2018; Accepted: 14 Mar 2019.

Edited by:

John Stix, McGill University, Canada

Reviewed by:

J. Maarten De Moor, OVSICORI-UNA
Ryunosuke KAZAHAYA, Geological Survey of Japan (AIST), Japan  

Copyright: © 2019 Wilkes, Pering, McGonigle, Willmott, Bryant, Smalley, Mims III, Parisi and England. This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.

* Correspondence: Mr. Thomas C. Wilkes, Department of Geography, University of Sheffield, Sheffield, S10 2TN, United Kingdom, tcwilkes1@sheffield.ac.uk