ORIGINAL RESEARCH article
Sec. Solar Energy
Solution-plasma-induced oxygen vacancy enhances MoOx/Pt electrocatalytic counter electrode for bifacial dye-sensitized solar cells
- Center for Advanced Optoelectronic Functional Materials Research, and Key Lab of UV-Emitting Materials and Technology of Ministry of Education, Northeast Normal University, Changchun, China
Bifacial dye-sensitized solar cells (DSCs), harvesting light from both front and rear sides, are potential high-efficiency photovoltaic devices with broad application environments. The electrocatalytic counter electrodes (CEs) of bifacial DSCs could determine the light-harvesting from the rear side and the charge collection of solar cells through electrocatalytic processes. As a result, high-activity and high-transparency CEs are essential for bifacial DSCs. Recently, novel CEs based on strong metal-support interaction (SMSI) have been proven to improve the catalysis and stability of the metal catalytic sites and induce great efficiency increase of bifacial DSCs. However, the contradiction between the transparency and conductivity of support is still a major challenge for the application of SMSI-based CEs on bifacial DSCs. Herein, we utilized a solution plasma (SP) method to introduce oxygen vacancies into a transparent MoOx support film. These SP-induced oxygen vacancies improved the conductivity of MoOx and the interaction between the metal Pt catalytic sites and support, thereby enhancing the catalytic activity and transparency of MoOx/Pt CEs. Consequently, the bifacial DSCs with MoOx/Pt CEs yielded a high efficiency of 7.56% and 6.41% with the front- and rear-side illumination, respectively. This impressive front-to-rear efficiency ratio of 85% indicates that the SP method has a positive effect in constructing high-performance CEs and other electrocatalytic materials based on the SMSI.
Dye-sensitized solar cells (DSCs) have attracted much attention due to their advantages of simple fabrication, low cost, and multicolor appearances (Chen et al., 2020). Especially, bifacial DSCs can absorb photons from the front and rear sides of the devices, probably leading to an efficiency boost of around ∼35%, compared with conventional DSCs only absorbing photons from the front (Ito et al., 2008; Duan et al., 2014; Tian et al., 2020). Furthermore, they have potential prospects in applications such as indoor and building photovoltaics owing to their installation flexibility. In bifacial DSCs, electrocatalytic counter electrodes (CEs) are the important components to determine the device efficiency because they not only facilitate the reduction reaction of the electrolyte through the electrocatalytic process but also control the light harvest of bifacial DSCs from the rear side (Xu et al., 2020). Consequently, numerous works were explored for the high-activity and high-transparency CEs.
Strong metal-support interaction (SMSI) is a powerful strategy to produce high-performance catalytic materials (Tauster and Fung, 1978; Ge et al., 2021). It boosts the activity of catalytic sites due to electron transfer between the metal and supports and prevents the nanosized metal catalytic sites from sintering. Nowadays, SMSI has generated numerous catalytic materials, including Pt-, Pd-, Au-, Cu-, and Ru-based catalysts (Guo et al., 2018; Yu et al., 2019; Zhang et al., 2019; Han et al., 2020; Wang et al., 2021; Yu et al., 2021). Recently, a novel Pt-Mo2C CE based on SMSI was reported by our group (Wu et al., 2020). It possesses highly dispersed Pt nanoclusters on Mo2C support and successfully achieved a rear-to-front efficiency of ∼75% in bifacial DSCs. However, Mo2C as a support suffered from poor transmittance in the visible range, hindering the further performance improvement of CEs based on the SMSI strategy.
We notice that transition metal oxides (TMOs) are attractive support for SMSI-based catalysis because the electronic structure of their transition-metal cations facilitates electron transfer between the catalytic sites and TMO support (Tauster, 1987). In addition, their excellent transmittance in the visible range efficiently overcomes the shortage of Mo2C support, whereas it is a challenge that the insufficient conductivity of TMO support may affect the electrocatalytic activity of CEs. Thus, improving the electrical conductivity of TMO becomes essential for developing high-activity and high-transparency TMO-based SMSI CEs. Oxygen vacancies serve as shallow donors in TMO, increasing the carrier concentration, so introducing oxygen vacancies becomes an effective means to improve the conductivity of TMO (Wang et al., 2012). As a result, oxygen vacancies have been introduced into TMO for conductivity improvement through several methods, including liquid exfoliation, plasma etching, chemical reduction, and thermal treatment (Zheng et al., 2017; Yan et al., 2018; Tran et al., 2019; Li et al., 2020; Wang et al., 2020).
Herein, we utilized the solution plasma (SP) method to introduce oxygen vacancies into the MoOx support and further prepared SMIS-based MoOx/Pt CEs for bifacial DSCs. To our best knowledge, this is the first time that the SP method has been presented to design high-performance electrocatalyst electrodes. The SP method could generate numerous highly reactive species including H+, OH−, and O2− species to induce oxygen vacancies in TMO in a simple, eco-friendly, and non-reducing-reagent way (Takai, 2014; Jedsukontorn et al., 2018; Pitchaimuthu et al., 2018). MoOx is used as the support because of the ability to easily introduce oxygen vacancies and its great stability compared with Mo2C. The SP-induced oxygen vacancies boosted the conductivity of MoOx films and enhanced the electron transfer between the MoOx support and Pt catalytic sites. These factors endow MoOx/Pt CEs obtained by the SP method (named MoOx/Pt-SP) with higher electrocatalytic activity than the untreated reference sample. In addition, MoOx/Pt-SP possesses outstanding transparency, which generated only 3.4% of light loss at 550 nm compared with the conductive substrate fluorine-doped tin oxide (FTO). Consequently, the obtained bifacial DSCs with MoOx/Pt-SP CEs produced a power conversion efficiency (PCE) of 7.56% under the front illumination, which is similar to that of 7.65% for DSCs with the generally used Pt electrode.
Preparation of electrocatalytic electrodes
The MoOx thin films were deposited on a well-cleaned FTO substrate by radio frequency magnetron sputtering. All of the samples were deposited for 2 min in an inert atmosphere of argon with a sputtering pressure of 0.8 Pa after being pre-sputtered for 15 min to remove impurities from the target surface. We then subjected the MoOx support to SP treatment in deionized water with a discharge time of 1 min and a voltage of 1.5 kV. The next step is that the treated MoOx support was impregnated in 10 mM/L chloroplatinic acid isopropanol solvent for 1 h at room temperature and then removed and blown dry. Finally, the samples were placed in an annealing furnace and annealed at 450°C for 15 min.
Fabrication of dye-sensitized solar cells
The cleaned FTO was immersed in a TiCl4 aqueous solution (0.04 mol/L) and heated in an oven at 70°C for 30 min. TiO2 paste with a particle size of 30 nm was scraped by the screen-printing method to obtain a film with a thickness of 12–14 μm and then annealed at 500°C for 30 min in a muffle furnace. After the samples were post-treated with a TiCl4 aqueous solution for 20 min and sintered at 500°C, the TiO2 photoanode was immersed in a 0.3 mM N719 ethanol solution and soaked at room temperature for 24 h to complete the dye adsorption and then rinsed three times for 3 s each with ethanol and dried. The DSCs were assembled by sandwiching the sensitized TiO2 photoanode with an electrocatalytic electrode by introducing an electrolyte containing 0.6 M 1,3-dimethylimidazolium iodide, 0.1 M guanidinium thiocyanate, 0.03 M iodine, 50 mM lithium iodide, and 0.5 M 4-tert-butylprine in acetonitrile/valeronitrile (85:15, v/v).
Solution plasma process
SP was performed as described in detail elsewhere. The sample was placed into a reactor containing 80 ml of deionized water. A tungsten rod and a tungsten tube were used as electrodes. The sample was placed below the inter-electrode gap. Also, the distance between the sample and the two tungsten electrodes was approximately 10 mm. N2 was introduced into the reactor through the hollow tungsten electrode. Plasma was generated by a bipolar-DC pulsed power supply (Kurita, Japan). The pulse width and frequency were 2.0 μs and 20 kHz, respectively. The temperature of the solution, which was 10°C, was controlled by a water chiller.
Results and discussion
As shown in Figure 1, the MoOx film (Supplementary Figure S1) was deposited on a clean conductive glass FTO by radio frequency magnetron sputtering (RFMS) and then was treated via the SP process. This SP process in the aqueous solution could generate numerous highly reactive species, including H+, OH−, and O2− species, due to the ready dissociation of water (Pitchaimuthu et al., 2018). According to the research of our groups, we deem that the H+ species rapidly diffuses into the plasma/liquid interface bombarding the surface of TiO2, which causes removal of the oxygen atoms and generates oxygen vacancies since the mass of the H+ species is less than that of the OH−and O2− species (Yu et al., 2020). Therefore, we consider that MoOx, which has a similar electronic structure to TiO2, can also generate oxygen vacancies through the bombardment of H+ species. Then, the SP-treated MoOx support was impregnated in the isopropanol solution of chloroplatinic acid for loading the platinum (Pt) nanoclusters. Finally, an electrocatalytic electrode (denoted as MoOx-Pt-SP) was prepared by thermal annealing in an inert atmosphere (N2) at 450°C. In contrast, the reference sample (named as MoOx-Pt) was also prepared by impregnating the MoOx support without SP treatment into the chloroplatinic acid isopropanol solvent and then annealing at 450°C.
First, we investigated the influence of SP treatment on the oxygen vacancies of MoOx films by X-ray photoelectron spectroscopy (XPS) and electron spin resonance (ESR). Three peaks of each sample were exhibited clearly in the O1s core-level spectra shown in Figure 2A: the main component peak was deemed as lattice oxygen (Mo-O) located at 530.81 eV; another peak located at 532.44 eV, that is attributed to oxygen in hydroxyl groups (−OH); the last peak at 533.15 eV corresponds to physically adsorbed water (H2O) (Sendova-Vassileva et al., 2016). The peak area is related to the content of elements. The lattice oxygen peak area of MoOx is reduced through SP treatment, indicating that SP can generate oxygen vacancies. Figure 2B shows the Mo3d core-level spectra of MoOx and MoOx-SP. The Mo3d core-level spectra of MoOx is composed of two peaks which are attributed to 3d3/2 and 3d5/2. Also, Mo3d5/2 of MoOx at 232.75 eV can be assigned to Mo6+ species. For the MoOx-SP sample, Mo3d5/2 shifted to a lower binding energy at 232.50 eV, resulting from the electron transfer from the oxygen vacancy to the Mo. Meanwhile, the electron transfer means an increase in electron density and a weaker binding effect of Mo-O (Luo et al., 2016; Li et al., 2021). Moreover, Figure 2C shows that both samples have signals at the oxygen vacancy characteristic spectral line (g = 2.007) by ESR (Ohno, 1986; Poppl and Volkel, 1989; Nakamura et al., 2000). For MoOx-SP, the intensity of the oxygen vacancy signal increases, manifesting that there are more oxygen vacancies in MoOx-SP. This is the same as the results of O1s XPS in Figure 2A. All the aforementioned information indicates that SP is an effective approach to introducing oxygen vacancies.
The microstructure of the MoOx and MoOx-SP deposited on the silicon wafer is exhibited in Figures 3A,B. Corresponding height profiles in Figure 3C shows that the thickness of the two films is similar, around 3 nm, which indicates that the SP has no impact on the film thickness. To shed light on the role of oxygen vacancies, the electrical conductivity of samples was characterized. We tested the electrochemical impedance spectrum (EIS) of two samples shown in Figure 3D, and the corresponding charge transfer resistance is listed in Table 1. The test structure used is mainly a symmetrical cell structure in the form of CE//electrolyte//CE. EIS results show that the charge transfer resistance (Rct) of MoOx-SP is lower (1.20 × 104 Ω cm−2) than that of MoOx (2.25 × 104 Ω cm−2), which may be attributed to the increase of interfacial oxygen vacancy active sites and electrical conductivity owing to the introduction of oxygen vacancies. As shown in Figures 3E,F, conducting atomic force microscopy (C-AFM) demonstrates that the average current of the MoOx-SP thin film is 0.5300 nA (Table 1), which is two orders of magnitude higher than that of the MoOx thin film (0.0065 nA) with the same bias voltage. We can discover that the bulk resistance of the MoOx-SP thin film is lower than that of the MoOx thin film, considering the nearly identical thickness of the two films. The bulk resistance of MoOx-SP decreased, suggesting that oxygen vacancies contributed to the improvement of electrical conductivity. We suggest that the oxygen vacancies likely act as shallow donors to increase the carrier concentration, thereby enhancing the electrical conductivity.
FIGURE 3. AFM surface morphologies of (A) the MoOx and (B) MoOx-SP thin film. The corresponding height profiles (C) of the MoOx and MoOx-SP thin film in two regions shown in (A) (g1) and (B) (g2). Nyquist plots (D) of the MoOx and MoOx-SP thin film. C-AFM images of (E) the MoOx and (F) MoOx-SP thin film.
According to the previous literature about SMSI, oxygen vacancies were favorable for enhancing the SMSI (Farmer and Campbell, 2010; Jang et al., 2016; Liu et al., 2019) because metal cations in the supports are reduced by the nearby oxygen vacancies, triggering the charge transfer between the reduced metal cation and the catalytic sites. Consequently, we investigated the effect of oxygen vacancies. The Pt4f core-level spectra were deconvoluted into two pairs of doublets in Figure 4A, which can be assigned to Pt0 and Pt2+ species. The more intense doublet is attributed to Pt0. Comparing the binding energies of Pt04f7/2 peak, we could observe that the peak position for MoOx-Pt-SP (71.30 eV) has a slight shift to higher binding energy in contrast to that of MoOx-Pt (71.15 eV) treated without the SP. It is proved that MoOx-Pt-SP with more oxygen vacancies has a reduction in the electron density of platinum sites, which leads to the formation of an electron-rich region between Pt-Mo and substantial changes in the metal–support interaction (Lin et al., 2017). The positive role of oxygen vacancies in SMSI can be verified by Pt4f XPS, which has the potential to enhance the catalytic activity of the electrocatalyst.
FIGURE 4. Pt4f XPS spectra (A) of MoOx-Pt and MoOx-Pt-SP. Nyquist plots (B) and Tafel polarization curves (C) of MoOx-Pt and MoOx-Pt-SP electrocatalytic electrodes. Transmittance spectra (D) of FTO, MoOx-Pt, MoOx-Pt-SP, and HT-Pt electrocatalytic electrodes.
In order to characterize the catalytic performance of the samples, EIS was carried out. The test structure used is mainly a symmetrical cell structure in the form of CE//electrolyte//CE. The consequence of EIS can be fitted by Z-View software combined with the equivalent circuit diagram shown in Figure 4B. The equivalent circuit diagram incorporates the series resistance (Rs), which chiefly comprises sheet resistance at the contact point, external wire, and electrode; the interfacial charge transfer resistance (Rct) at the CE/electrolyte interface; the diffusion impedance (Zw) of the redox couple in the electrolyte; and the interfacial double-layer chemical capacitance (CPE). The EIS is shown in Figure 4B, and its data are summarized in Table 2 after fitting. A slight difference is present in the Rs of MoOx-Pt and MoOx-Pt-SP CEs (were 17.02 Ω cm−2 and 18.00 Ω cm−2, respectively), which may be caused by different contact points and external wire connections during the test. The Rct of MoOx-Pt-SP CEs is 1.80 Ω cm−2, which is 4.20 Ω cm−2 lower than that of MoOx-Pt CEs (Rct = 6.00 Ω cm−2). This illustrates that the charge transfer at the interface between the electrocatalytic electrode and electrolyte is easier in MoOx-Pt-SP.
TABLE 2. Summary of Rs and Rct fitted from EIS and Tafel polarization curves of MoOx-Pt and MoOx-Pt-SP CEs.
Apart from the EIS, the Tafel polarization curve test is another main means to characterize the catalytic activity of the electrode, and its test structure is consistent with that of the EIS. Theoretically, the Tafel polarization curve can be divided into three zones: the polarization zone, the Tafel zone, and the diffusion zone. The left branch with negative voltage corresponds to the reduction reaction of I3−, which is the focus area, and the right branch with positive voltage corresponds to the oxidation reaction of I−. The exchange current density (J0) and the limiting diffusion current density (Jlim) can be obtained from the Tafel polarization curve. J0 is directly related to Rct by the formula: J0 = RT/nFRct, where R is the gas constant, n (n = 2) is the number of electrons involved in the reduction of I3− at the electrode, T is thermodynamic temperature, and F is Faraday constant. Figure 4C shows the polarization curves of the two samples. It is obvious that MoOx-Pt-SP CEs have higher anode or cathode branches, so their J0 is larger and they have higher electrocatalytic activity. Rct calculated from J0 of the Tafel polarization curves is shown in Table 2 and shows that MoOx-Pt-SP CEs have higher electrocatalytic activity. Consequently, EIS and Tafel polarization curves have the same results, implying that the MoOx-Pt-SP CEs have higher electrocatalytic activity. The reason may be ascribed to the improvement of the electrocatalytic electrode conductivity caused by the increase of oxygen vacancies. Furthermore, the enhanced SMSI performance caused by oxygen vacancies further dispersed the Pt particles, thereby increasing the active area of the catalyst. This may be another reason for the better electrocatalytic effect of the MoOx-Pt-SP electrode.
The optical transmittance of the electrocatalytic electrode impacts the efficiency of the rear side illumination for bifacial DSCs. But Pt CEs (HT-Pt), which were fabricated using the spinning coating method followed by a high-temperature pyrolysis process, have usually been disappointing in transmittance. So, we utilized SMSI to achieve the electrocatalytic electrode with high transmittance. The transmittance of MoOx-Pt, MoOx-Pt-SP, HT-Pt CEs, and conductive glass FTO is explored by UV–Vis spectroscopy (Figure 4D). The MoOx-Pt and MoOx-Pt-SP CEs show a good optical transmittance of 76.6% at 550 nm, which is only a 3.4% reduction compared to that of the FTO substrate. In contrast, the transmittance of the HT-Pt electrode is 61.7% at 550 nm, which is probably due to light absorption and scattering caused by excessive loading and agglomeration of the Pt (Supplementary Figure S2). The good optical transmittance of MoOx-Pt and MoOx-Pt-SP CEs could be ascribed to the good dispersion of the Pt caused by the SMSI character. Although the transmittance of the MoOx-Pt-SP and MoOx-Pt CEs is similar in the visible range, the EIS and Tafel polarization curve tests show superior electrocatalytic performance of MoOx-Pt-SP CEs. Such a transparent electrocatalytic electrode guarantees the realization of bifacial DSCs.
We fabricated DSCs using HT-Pt, MoOx-Pt-SP, and MoOx-Pt CEs. Also, the current density−voltage (J−V) curves of DSCs, which were measured under AM 1.5 g 100 mW cm−2 from the front (F) and rear (R) sides, are shown in Figure 5. Specific photovoltaic data, including short-circuit current density (Jsc), open circuit voltage (Voc), fill factor (FF), and PCE, are summarized in Table 3. The DSCs with MoOx-Pt CEs produced a PCE of 6.97% under the front illumination. Also, the front-illuminated PCE of the DSCs with MoOx-Pt-SP CEs is 7.56% (Jsc = 15.21 mA cm−2, Voc = 0.70 V, FF = 0.71), which is close to 7.65% for that of conventional Pt CEs. The high catalytic activity of the MoOx-Pt-SP electrocatalytic electrode was further demonstrated. The rear-illuminated PCE of the MoOx-Pt-SP cell can reach 6.41% (Jsc = 12.71 mA cm−2, Voc = 0.69 V, FF = 0.73), which remains at 85% of the front-side PCE. In comparison, the rear-side efficiency of the Pt cell just retained 71% of the front-illuminated efficiency. The retention rate of the MoOx-Pt-SP cell is 20% higher than that of the Pt cell. This is attributed to the high transmittance of MoOx-Pt-SP CEs. So far, we prepared high catalytic activity electrocatalytic electrodes with good transparency.
FIGURE 5. J–V curves of DSCs with HT-Pt (A), MoOx-Pt-SP (B), and MoOx-Pt (C) CEs measured under AM 1.5G 100 mW cm−2 from the front (F) and rear (R) sides.
In conclusion, this work reveals that the SP is an effective method for introducing oxygen vacancies and improving the catalytic performance of SMSI-based MoOx/Pt CEs for bifacial DSCs. The SP-induced oxygen vacancies enhanced the electrical conductivity of MoOx support and the interaction between Pt and MoOx. Consequently, MoOx/Pt-SP CEs have superior electrocatalytic activity than the untreated reference CEs. The front-illuminated efficiency of the MoOx-Pt-SP cell (7.56%) is comparable with that of the Pt cell (7.65%). But the rear-illuminated efficiency of the MoOx-Pt-SP cell reached 6.41%, thus achieving a high rear-to-front efficiency ratio of 85% in contrast with that of 71% for the Pt cell. This suggests the great potential of MoOx-Pt-SP CEs in high-performance bifacial DSCs. In addition, our work proved the importance of oxygen vacancies in enhancing the activity of TMO-based SMSI electrocatalysts and suggested an efficient SP strategy that could be applied to various electrocatalysis systems.
Data availability statement
The original contributions presented in the study are included in the article/Supplementary Material; further inquiries can be directed to the corresponding authors.
All authors listed have made a substantial, direct, and intellectual contribution to the work and approved it for publication.
The work was supported by the National Natural Science Foundation of China (62074031 and 51872044), funding from Jilin Province (JJKH20211295KJ), the 111 project (B13013), and the Fundamental Research Funds for the Central Universities (2412019FZ036).
Conflict of interest
The authors declare that the research was conducted in the absence of any commercial or financial relationships that could be construed as a potential conflict of interest.
All claims expressed in this article are solely those of the authors and do not necessarily represent those of their affiliated organizations, or those of the publisher, the editors, and the reviewers. Any product that may be evaluated in this article, or claim that may be made by its manufacturer, is not guaranteed or endorsed by the publisher.
The Supplementary Material for this article can be found online at: https://www.frontiersin.org/articles/10.3389/fenrg.2022.924515/full#supplementary-material
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Keywords: dye-sensitized solar cells, electrocatalytic activity, counter electrode, oxygen vacancy, solution plasma process
Citation: Li Y, Wang Y, Lin J, Shi Y, Zhu K, Xing Y, Li X, Jia Y and Zhang X (2022) Solution-plasma-induced oxygen vacancy enhances MoOx/Pt electrocatalytic counter electrode for bifacial dye-sensitized solar cells. Front. Energy Res. 10:924515. doi: 10.3389/fenrg.2022.924515
Received: 20 April 2022; Accepted: 06 July 2022;
Published: 08 August 2022.
Edited by:Takaya Kubo, The University of Tokyo, Japan
Reviewed by:Masashi Ikegami, Toin University of Yokohama, Japan
Takeru Bessho, The University of Tokyo, Japan
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