Abstract
Large amounts of conventional gas resources that originated from terrestrial Lower Jurassic shale were discovered in the Tarim Basin, indicating promising exploration prospects for shale gas resources, whereas limited understandings were obtained on the geological and geochemical characteristics of the Lower Jurassic shale. In this study, based on cores of exploration wells and field outcrops, total organic carbon (TOC) pyrolysis, microscopic composition, organic elements, vitrinite reflectance, x-ray diffraction, and methane isothermal adsorption experiments were carried out on Lower Jurassic shale in the Tarim Basin. The results show that the TOC content of shale is relatively high, but the TOC content of shale in different regions is quite different. Among them, the Kuqa Depression is the highest (more than 3%), the Southwest Tarim Basin is second (more than 1%), and the East Tarim Basin is the lowest. The main types of kerogen in shale are mainly type III and type II2. The thermal evolution maturity of shale in different regions is quite different; the highest Ro of shale in the Southwest Tarim Basin is more than 2.0% and that of shale in the Kuqa depression is higher than 1.5%, both of which have entered the stage of high-over-mature evolution, and the shale in the East Tarim Basin is only in the low maturity–mature stage. The overall content of brittle minerals such as quartz in shale is greater than 40%, which has good fracturing properties. The adsorbed gas content of shale is high, but there is a great difference (0.5–4 m3/t), which is related to the large difference in the abundance of organic matter, thermal maturity, and clay mineral content of shale. Therefore, the Lower Jurassic shale gas in the Tarim Basin has good prospects for exploration. Based on the superposition method of the main controlling geological factors, it is predicted that the favorable areas for shale gas exploration are mainly located in the Keshen and Yinan-Yeyun areas of the Kuqa Depression and the Caohu Sag-Mandong area of the East Tarim Basin. This research not only provides basic data for the evaluation of shale gas resources in our country, but also provides certain guidance for the exploration of Lower Jurassic shale gas in the Tarim Basin.
Introduction
As conventional oil and gas resources are increasingly scarce, the main energy status of oil and gas mainly benefits from the contribution of shale oil and gas (; ); in particular, shale gas provides a realistic possibility for coping with climate change and sustainable development of low-carbon economy (; ). In recent years, with the successful development of shale gas in North America (; ), the related research on shale gas in China has also been carried out rapidly, but mainly concentrated in the lower Paleozoic marine shale in the Sichuan Basin (; ; ; ; ). The Tarim Basin is the largest petroliferous basin in China. Many rounds of oil and gas resource evaluation and oil and gas drilling have confirmed that it has huge conventional oil and gas resources (; ; ; ), which also indicates that it has great shale gas resource potential (; ; ).
The lower Jurassic shale in the Tarim Basin is a set of fine-grained sediments, which are mainly deposited in lacustrine and swamp environments. In the past, it has been studied as the source rock of conventional oil and gas (; ; ; ). In recent years, some scholars have carried out research on Jurassic shale gas in the Tarim Basin, but most of them focus on the reservoir structure (; ) and adsorption characteristics (), or mostly concentrated in some areas of the Tarim Basin (; ), and fail to point out the future shale gas exploration direction from the perspective of the whole basin.
Firstly, based on shale cores obtained from exploration wells and field outcrops, this research has carried out a series of experiments, which included total organic carbon (TOC) pyrolysis, microscopic composition analysis, organic elements, vitrinite reflectivity, x-ray diffraction, and methane isothermal adsorption to analyze the geological and geological characteristics of shale. Then, combined with the division of shale strata in single wells, lateral distribution of cross-well profile, seismic inversion, sedimentary facies, and structure contour data, we analyzed the structural burial depth, TOC content, and Ro plane distribution characteristics of the shale. Finally, using the superposition method of the main controlling geological factors, the exploration prospects and favorable areas of the Lower Jurassic shale gas in the Tarim Basin are predicted. This study not only provides reliable basic data for shale gas resource evaluation in China, but also plays a guiding role in shale gas exploration of Lower Jurassic in the Tarim Basin.
Geological Background
The Tarim Basin is located at the western end of the North China-Tarim platform; the north is adjacent to the Tianshan fold belt, and the southwest is bounded by the Kunlun fold belt and is separated from the Qaidam Basin by the Altyn fault to the southeast. The exploration area is about 560,000 km2, which is the largest Mesozoic and Cenozoic inland sedimentary basin in China (). The Tarim Basin includes seven first-level structural units including the Kuqa Depression, Northern Uplift, Northern Depression, Central Uplift, Southwest Depression, Southern Uplift, and Southeast Depression (Figures 1A,B). Since the Sinian, the Tarim Basin has experienced a complete depositional cycle from marine facies, marine-terrestrial transitional facies, to continental facies (), with a thickness of 18,000 m. The Lower Jurassic is dominated by gray-green, gray, and dark purple sandstone and mudstone, and is composed of delta, shallow lake, semi-deep lake, and swamp facies () (Figure 1C).
FIGURE 1
Methods
The sample preparation and test procedures for TOC, pyrolysis, maceral, elemental composition, vitrinite reflectance, x-ray diffraction, and isothermal adsorption were the same with
Results and Discussion
Distribution and Thickness
According to the statistics of the single-well burial depth of the effective shale of the Lower Jurassic in the Tarim Basin, combined with the seismic inversion data, structural morphology and depositional environment of the areas without wells, or lack of well drilling, the burial depth of the Lower Jurassic shale is determined. The burial depth contour map of the Lower Jurassic shale in the Tarim Basin was drawn (Figure 2A). The results show that the Lower Jurassic shale in the Tarim Basin is mainly distributed in the Kuqa Depression, East Tarim, and Southwest Tarim. The maximum buried depth is located in the central area of Baicheng Sag and Yangxia Sag in the Kuqa Depression, reaching more than 7,000 m. The buried depth of the Caohu Sag in the East Tarim Basin is mostly about 5,000 m, and the burial depth gradually goes southeast (the East Tarim Basin) and decreases. The burial depth in the southwestern part of the Tarim Basin is relatively shallow, only some areas near Zepu exceed 5,000 m, and most of the other areas are below 5000 m.
FIGURE 2

(A) Contour map of buried depth of Lower Jurassic shale in the Tarim Basin. (B) Contour map of effective shale thickness of Lower Jurassic in the Tarim Basin.
Based on a comprehensive analysis of single-well shale interval division, lateral distribution of continuous well profiles, seismic inversion data, and sedimentary facies data, the contour map of the cumulative thickness of the Lower Jurassic shale in the Tarim Basin was drawn (Figure 2B). The results show that the Lower Jurassic shale is mainly distributed in the Kuqa Depression, the Southwest Tarim, and the East Tarim. Among them, the shale in the Kuqa Depression and the Southwest Tarim is relatively thick, and the thickness center is located in Yangxia, Kuqa Depression. The maximum thickness of the Kashi sag and Yecheng sag in the southwestern part of the Tarim Basin reaches 200 and 100 m respectively. On the whole, the thickness of the shale gradually decreases from the center of the depression to the surrounding area until it pinches out.
Organic Matter Richness
TOC and hydrocarbon generation potential (PG) are effective indicators for evaluating the organic matter richness of shale (
FIGURE 3

(A) Geochemical profile of Lower Jurassic shale in Kezi-1 well in the Kuqa Depression. (B) Geochemical profile of Lower Jurassic shale in Yixi-1 well in the Kuqa Depression. (C) Geochemical profile of Jurassic in Huayingcan-1 well in the East Tarim area. (D) Geochemical profile of Lower Jurassic shale outcrop in the Southwest Tarim Basin. KZ—Kuzigongsu section, KS—Kangsu section, QM—Qiemogan section, GZ—Gaizi river section, KH—Kushan river section, YG—Yigeziya section, TR—Tierekeqike section, HS—Heshilapu section, MM—Momok section, DW—Duwa section.
Compared with the Kuqa Depression, the organic matter abundance of the Lower Jurassic shale in the Eastern Tarim Basin is generally lower, the TOC is mostly between 0.5% and 2%, and PG is mainly between 0.93 and 3.76 mg/g, but mostly less than 2.0 mg/g. However, the shale of well Huayingcan 1 is rich in organic matter, with TOC content mostly between 0.5% and 4%, and PG between 1.5 and 6 mg/g (Figure 3C). The abundance of organic matter in the Lower Jurassic shale in the southwestern Tarim basin is relatively high.
The Tarim Basin is relatively high. However, due to the lack of core samples, this research analyzed several shale samples from field profiles in this area (Figure 3D), and most of their TOC content is greater than 1%, the maximum is over 5%, and the maximum PG can reach 2.5 mg/g. However, the TOC of shale samples from different field profiles is different. The lowest TOC of the Lower Jurassic shale in the Kushanhe section is 1.3%, and the TOC of the shale in the Mogan section and the Heshirap section can exceed 5%.
Based on the analysis of core and field outcrop test data, combined with the TOC data predicted by logging data, the TOC contour plane distribution of the Lower Jurassic shale in the Tarim Basin is carried out. The results show that the TOC of the Lower Jurassic shale in the Tarim Basin is generally higher. Among them, the TOC of the shale in the Baicheng Sag–Yangxia Sag of the Kuqa Depression exceeds 3%. The TOC of the shale in the East Tarim area is more than 1%, and the high value is mainly located in the Caohu Sag-Mandong area and Yingjisu Sag area. The TOC of some shale in the Southwest Tarim Basin is greater than 1.5% (Figure 4).
FIGURE 4

Contour map of TOC of Lower Jurassic in the Tarim Basin.
Organic Matter Type
Generally, the maceral content of organic matter, H/C-O/C chart, and HI-Tmax chart can be used to evaluate the organic matter type of shale (
FIGURE 5

(A) Triangles of kerogen macerals of Lower Jurassic shale in the Tarim Basin (according to the modification of Xiao Zhongyao, 2003; Zhao Mengjun, 2001). (B) Fan’s diagram of element composition of Lower Jurassic kerogen in the Kuqa Depression. (C) Organic matter types of Lower Jurassic shale in the Southwestern Tarim Basin.
Thermal Maturity
Vitrinite reflectance (Ro) is an effective indicator for evaluating the thermal maturity of shale (
FIGURE 6

Variation of Ro with depth of Jurassic shale in well Yixi 1 and well Yinan 2 in the Kuqa Depression.
Based on the analysis of core and field outcrop test data, the relationship between Ro and burial depth of shale in different regions has been established, and combined with the tectonic burial depth of the Lower Jurassic shale in the Tarim Basin, the Ro plane distribution of lower Jurassic shale in the Tarim Basin was carried out. The results show that the thermal evolution maturity of organic matter in the Lower Jurassic shale is relatively high in the Baicheng Sag in the Kuqa Depression, and Kashgar Sag and Yecheng Sag in the Southwest Tarim Basin, with a Ro of more than 2%, which is at a high-over-mature stage. Among them, the maximum buried depth of the Jurassic in the center of Baicheng Depression exceeds 7,000 m, and its Ro is predicted to be as high as 2.2%–2.5%. In contrast, the thermal evolution degree of the East Tarim Basin is relatively low due to the relatively shallow buried depth, and Ro is mostly less than 1% (Figure 7).
FIGURE 7

Contour map of Ro of Lower Jurassic in the Tarim Basin.
Hydrocarbon Generation History
The Tarim Basin has been in a subsidence state since the Mesozoic. However, the subsidence rate and geothermal gradient of the Lower Jurassic strata are different in different structural units (
Since the Mesozoic, the Kuqa Depression has experienced the Yanshan Movement and the Himalayan Movement (
FIGURE 8

(A) Burial history of Jurassic shale in Yinan 2 well, Kuqa Depression. (B) Burial history of Mesozoic shale in Kuzigongsu section, Southwest Tarim Basin. (C) Burial history of Mesozoic shale in Cao7 well, Northeastern Tarim Basin. (D) Burial history of Mesozoic shale in the Southeastern Tarim Basin.
The Southwest Tarim has been in an extensional environment for a long time since the Mesozoic (
Ro = 0.7% until the end of the Paleogene. In the middle and late Neogene, the Lower Jurassic shale reached a high maturity stage (Ro = 1.2%). Since the Pleistocene, the thermal evolution of the Lower Jurassic shale has ceased due to the uplift and denudation of the formation due to structural uplift (Figure 8B). In fact, due to differences in the burial evolution of shale in different areas of the Southwest Tarim, the current thermal evolution of shale in different areas is different. Among them, the Kuzi Gongsu section and Yigeziya section have entered the mature stage, while the Kangsu section, Yangye section, and Duwa section shale are still in the immature–low mature stage.
The subsidence rate of the Lower Jurassic shale in the northeast Tarim Basin is much lower than that of the Kuqa Depression and the Southwest Tarim Basin. Because there are many depressions, elevations, and slopes in the northeast of the Tarim Basin, and the subsidence amplitudes in different regions are different, the thermal evolution history of shale in different regions is also different. Taking the Korla nose-shaped bulge-Kongque River slope area as an example, the Lower Jurassic shale was in a state of continuous subsidence during the Early-Middle Jurassic. At this time, the geothermal gradient was 2.3°C/100 m, and then in the Late Jurassic (Yanshan Late period) experienced a large uplift and continued subsidence after the Cretaceous. Since the Neogene, the Lower Jurassic shale has been buried rapidly and deeply, with a maximum subsidence rate of 146 m/Ma, and a geothermal gradient to 1.9°C/100 m. It was not until the mid-Neogene that the Lower Jurassic shale entered the low maturity–mature stage (Figure 8C).
Compared with the Kuqa Depression and the Southwest and the Northeast Tarim Basin, the Lower Jurassic shale subsidence in the Southeast Tarim Basin is the smallest, and most of the areas are still less than 3000 m. The subsidence rate is also relatively slow, the Jurassic-Cretaceous subsidence rate is about 10 m/Ma, the Paleogene subsidence rate increased to 20 m/Ma, and the Neogene-Quaternary subsidence rate further increased to 30 m/Ma. However, due to the relatively small burial depth and low geothermal gradient, most areas in the southeast of Tajikistan are still in the immature stage, and only the deeply buried Lower Jurassic shale entered the low maturity–mature stage at the end of the Paleogene (Figure 8D).
Mineralogy
Shale not only has the ability to generate gas, but also serves as an effective reservoir for natural gas. The mineral composition of shale determines its fracturing effect in the later development process. The higher the content of brittle minerals, the better the fracturing effect, which is more conducive to the development and utilization of shale gas (
FIGURE 9

Mineral composition of Lower Jurassic shale in the Tarim Basin.
On the whole, the mineral composition of shale in the study area is dominated by brittle minerals such as quartz and clay minerals, among which the content of brittle minerals is more than 40%, which is conducive to the later fracturing development. The content of clay minerals is more than 40%, which is conducive to the adsorption and accumulation of shale gas. Compared with the Barnett shale in the United States (
Gas Sorption Capacity
In addition to the free state of natural gas in shale in larger pores or fissures, the natural gas is also adsorbed on the surface of clay mineral particles and organic matter in a large amount (
Among them, V is the measured adsorption capacity, m3/t; VL is the Langmuir volume, which is the maximum adsorption capacity, m3/t; P is the experimental pressure, MPa; and PL is the Langmuir pressure, which is the pressure when the adsorption capacity is half of VL.
The adsorption isotherms of different shale samples differ greatly in shape, but they are all single-molecule adsorption types; that is, the adsorption amount in the first half of the stage increases rapidly with the increase of pressure, and then the range of change becomes smaller, and the adsorption tends to be saturated. This adsorption characteristic reflects the pore structure of shale in the study area dominated by micropores and microcracks; that is, there is a large free internal surface area for adsorption in the pores or microfractures at the initial stage of the test. As the pressure increases, methane rapidly adsorbs on the surface of mineral particles and organic matter. As the adsorption progresses, the surface area of the pores not occupied by methane molecules decreases rapidly, resulting in a decrease in the adsorption increment and the curve tends to be horizontal. Specifically, the maximum adsorption capacity of shale in the study area is mainly between 0.5 and 4 m3/t, and there are some shale samples larger than 4 m3/t (Figure 10), which have high gas content. The maximum adsorbed gas volume of different shale is quite different, which is related to factors such as the abundance of organic matter, the thermal evolution maturity of organic matter and the content of clay minerals of the shale (
FIGURE 10

Distribution characteristics of isothermal adsorption capacity of Lower Jurassic shale in the Tarim Basin.
Favorable Exploration Areas
Based on the shale plane distribution, geochemical characteristics, and gas-bearing data, this research adopts the superposition method of main controlling geological factors to predict the prospective and favorable areas for the Lower Jurassic shale gas exploration in the Tarim Basin. The main geological factors include thickness, Ro, TOC, and top structure of Lower Jurassic shale. The evaluation parameter system of the prospective area and the favorable area are shown in Tables 1, 2, respectively. The results show that the Lower Jurassic shale gas prospective area of the Tarim Basin is distributed in the Kuqa Depression, the East Tarim, and the Kashi Sag–Yecheng Sag in the Southwest Tarim. The favorable areas are mainly distributed in the Keshen and Yinan-Yeyun areas in the Kuqa Depression and the Caohu Sag-Mandong area in the East Tarim (Figure 11).
TABLE 1
| Mainly parameter | Variation range |
|---|---|
| TOC(%) | Average not less than 0.5% |
| Ro (%) | Not less than 0.5% |
| Burial depth | 100–4,500 m |
| Surface condition | Plains, hills, mountains, deserts, plateaus, etc. |
| Preservation condition | Development and distribution of regional shale |
Reference standard for optimization of favorable areas of continental and transitional shale gas.
TABLE 2
| Mainly parameter | Variation range |
|---|---|
| Lower limit of shale area | The smallest area of the target area may be found in it, and it may be distributed in the stable area or the reformed area. According to many factors, the lower shale area is 200–500 km2 |
| Shale thickness | The thickness of a single layer is not less than 10 m, or the ratio of mudstone thickness to stratum thickness is greater than 60. Single layer thickness is greater than 5 m and continuous is not less than 30 m |
| TOC (%) | 1.5%–2%, average not less than 2% |
| Ro (%) | Type I kerogen not less than 1.2%; Type II not less than 0.7%; Type III not less than 0.5% |
| Burial depth | 300–4,500 m |
| Surface condition | The terrain height difference is small, such as plains, hills, deserts, etc. |
| Total air content | Not less than 0.5 m3/t |
| Preservation condition | Middle |
Reference standard for optimization of favorable areas of continental and transitional shale gas.
FIGURE 11

Prediction plan of shale gas prospect and favorable area of Lower Jurassic in the Tarim Basin.
The shale in the Keshen favorable area in the Kuqa Depression is mainly composed of shallow-semi deep lacustrine facies. The cumulative thickness of shale with a single-layer thickness greater than 10 m is 30–100 m, and the burial depth is mainly between 3,000 and 4000 m. In mainly gray-black mudstone intercalated with argillaceous siltstone, TOC is between 2.0% and 2.5%, organic matter type is mainly type III, and the degree of thermal evolution of organic matter is low maturity–mature, with Ro between 1.25% and 1.5%. The cumulative thickness of the shale in the Yinan-Yeyun favorable area is 50–200 m, the buried depth is mainly between 3,000 and 4500 m, the TOC is between 1.5% and 3.0%, the organic matter is mainly type III, the degree of thermal evolution of the organic matter is low maturity–mature, and Ro is mostly between 0.75% and 1%. The free shale gas content is between 0.174 and 0.743 m3/t, the adsorbed shale gas content is between 0.905 and 0.956 m3/t, the total gas content is between 1.079 and 1.699 m3/t, and the gas content is low.
The shale in the Caohu Sag-Mandong favorable area in East Tarim is mainly composed of shallow lake facies and floodplain facies deposits. The cumulative thickness of shale with a single-layer thickness greater than 10 m is 30–50 m, and the buried depth is mainly between 3,000 and 4000 m. In mainly carbonaceous mudstone and silty mudstone, TOC is between 1.5% and 2.5%, organic matter type is mainly type III, and the degree of thermal evolution of organic matter is low maturity–mature, with Ro mostly between 0.5% and 1.0%. The free shale gas content ranges from 0.703 to 1.654 m3/t, the adsorbed shale gas content ranges from 0.792 to 0.986 m3/t, and the total gas content ranges from 1.495 to 2.640 m3/t. The gas content is relatively high.
The shale in the Kashgar Sag–Yecheng Sag prospective area in Southwest Tarim is mainly fluvial-marsh deposits. The cumulative thickness of shale with a single-layer thickness of more than 10 m is 30–100 m, and the burial depth is mainly between 2,000 and 4,000 m and the TOC is between 0.5% and 1.5%. Due to the low abundance of organic matter in shale, there is no favorable area for shale gas exploration in the Southwest Tarim.
Based on the above analysis, the Lower Jurassic shale gas in the Tarim Basin has good prospects for exploration, and the Caohu Sag-Mandong area in the East Tarim is the most advantageous.
Conclusion
1) The Lower Jurassic shale in the Tarim Basin is mainly distributed in the Kuqa Depression, East Tarim Basin, and Southwest Tarim Basin. The deposition thickness center is located in the Yangxia Sag of the Kuqa Depression and the Kashi Sag and Yecheng Sag of the Southwest Tarim Basin. The maximum thickness is respectively 200 and 100 m. The TOC of the Lower Jurassic shale is higher overall, of which the TOC of the shale in the Baicheng Sag–Yangxia Sag in the Kuqa Depression exceeds 3%; the TOC of the shale in the East Tarim Basin area is more than 1%. The high values are mainly located in the Caohu Sag-Mandong area and Yingjisu Sag; some shale in the Southwest Tarim Basin have TOC greater than 1.5%. Organic matter is mainly type Ⅲ kerogen, followed by type Ⅱ2 kerogen, and type Ⅱ1 and type Ⅰ kerogen are basically underdeveloped. The thermal evolution maturity of organic matter is relatively high in the Baicheng Sag of the Kuqa Depression, and Kashgar and Yecheng Sag of the Southwest Tarim Basin, of which Ro is more than 2%, and it is in the high-over-mature evolution stage. The thermal degree of evolution is relatively low due to the relatively shallow buried depth, and Ro is mostly less than 1%. The mineral composition of shale is dominated by brittle minerals such as quartz and clay minerals. The content of brittle minerals is more than 40%, which is conducive to the later fracturing development; the content of clay minerals is more than 40%, which is conducive to the adsorption and accumulation of shale gas. The maximum adsorbed gas volume of shale is mainly between 0.5 and 4 m3/t, and shale larger than 4 m3/t also exists with high gas content.
2) The Lower Jurassic shale gas prospective area of the Tarim Basin is distributed in the Kuqa Depression, the East Tarim Basin, and the Kashi Sag–Yecheng Sag in the Southwest Tarim Basin. The favorable areas are mainly distributed in the Keshen and Yinan-Yeyun region of the Kuqa Depression and the Caohu Sag-Mandong region of the East Tarim Basin.
Statements
Data availability statement
The original contributions presented in the study are included in the article/Supplementary Material, further inquiries can be directed to the corresponding authors.
Author contributions
QW: Study design, Research, Data analysis, and Writing—original draft. HT: Data curation, Methodology, Formal analysis, Writing—original draft, and Writing—review and editing. ZG: Idea refinement and Manuscript revision. GC: Data curation, Investigation, and Formal analysis. ZL: Writing—review and editing. QL: Writing—review and editing.
Funding
This study was financially supported by Science and Technology Research Project of PetroChina Company Limited, Research on Water-control and EGR Technology for Deep or Ultra-deep Gas Reservoir Development (2021DJ1005).
Conflict of interest
The authors are employed by Research Institute of Petroleum Exploration and Development, PetroChina.
Publisher’s note
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Summary
Keywords
terrestrial shale gas, geological characteristic, geochemical characteristic, favorable exploration area, lower Jurassic shale, Tarim Basin
Citation
Wang Q, Tang H, Guo Z, Cheng G, Lv Z and Liu Q (2022) Geological and Geochemical Characteristics of the Terrestrial Lower Jurassic Shale in Tarim Basin and its Favorable Exploration Areas. Front. Earth Sci. 10:839427. doi: 10.3389/feart.2022.839427
Received
20 December 2021
Accepted
14 February 2022
Published
17 May 2022
Volume
10 - 2022
Edited by
Dongdong Liu, China University of Petroleum, Beijing, China
Reviewed by
Yingchun Guo, Chinese Academy of Geologi-cal Sciences (CAGS), China
Xiaowei Zheng Zheng, Aarhus University, Denmark
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Copyright
© 2022 Wang, Tang, Guo, Cheng, Lv and Liu.
This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.
*Correspondence: Qifeng Wang, wqf2020@petrochina.com.cn; Haifa Tang, haiftang@petrochina.com.cn
This article was submitted to Economic Geology, a section of the journal Frontiers in Earth Science
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