ORIGINAL RESEARCH article

Front. Environ. Sci., 28 April 2025

Sec. Interdisciplinary Climate Studies

Volume 13 - 2025 | https://doi.org/10.3389/fenvs.2025.1562087

This article is part of the Research TopicInnovations in Climate Resilience, Volume IIView all articles

Machine learning provides reconnaissance-type estimates of carbon dioxide storage resources in oil and gas reservoirs

Emil Attanasi
Emil Attanasi1*Philip FreemanPhilip Freeman1Timothy Coburn
Timothy Coburn2*
  • 1U.S. Geological Survey, Geology, Energy and Minerals Science Center, Reston, VA, United States
  • 2Department of Systems Engineering, Colorado State University, Fort Collins, CO, United States

Oil and gas reservoirs represent suitable containers to sequester carbon dioxide (CO2) in a supercritical state because they are accessible, reservoir properties are known, and they previously contained stored buoyant fluids. However, planners must quantify the relative magnitude of the CO2 storage resource in these reservoirs to formulate a comprehensive strategy for CO2 mitigation. Even reconnaissance-type estimates of CO2 storage resources of known oil and gas reservoirs may require complicated calculations involving 1) estimates of recoverable oil and gas, 2) reservoir properties (depth, temperature, pressure, etc.), and 3) the physical qualities of the retained fluids. We demonstrate the application of machine learning (ML) algorithms to bypass these computations to yield more rapid estimates of CO2 storage resources in reservoirs capable of hosting CO2 in a supercritical state. ML algorithms are computationally efficient because they do not impose the strong assumptions on the data-generating process that standard statistical or engineering procedures require. Further, ML algorithms can capture highly complex, particularly nonlinear, relationships among predictor variables. We demonstrate the application of four different ML algorithms using data from onshore and offshore oil and gas reservoirs in Europe, and show they perform well when predictions are compared to engineering estimates. The proposed methods and models provide an effective and novel way to more rapidly and directly determine the subsurface CO2 storage capacity of oil and gas reservoirs around the world, information that operators, researchers, and policymakers alike require to meet energy transition and decarbonization goals.

1 Introduction

Carbon dioxide (CO2) capture and geologic storage is one of the methods proposed to moderate the growth and even reduce CO2 emissions to the atmosphere. To make meaningful contributions to this goal, potential geologic storage units must be identified, and the CO2 storage resource assessed1 (Bachu et al., 2007). Depleted oil and gas reservoirs2 represent a class of such geologic structures that are already identified and whose storage potential may be appraised using known production and reservoir data. These reservoirs are appealing because data characterizing the reservoir and the contained hydrocarbons have already been collected by the producer and regulatory authority. Moreover, the structural integrity of these reservoirs has already been demonstrated because they have previously stored hydrocarbons.

In this study we develop machine learning (ML) approaches to make reconnaissance-type estimates of the CO2 storage resources of known oil and gas reservoirs. These reconnaissance-type estimates are based on data that characterize the properties of individual oil and gas reservoirs located in a study area. Such data may be published in public or propriety databases. Reconnaissance estimates are particularly important to policymakers and planners because they can provide a comprehensive view of the potentially available resources required for environmental policy and planning decisions. The data-driven nature of ML allows such estimates to be computed more rapidly than those obtained through a workflow of conventional engineering calculations, and it permits nonlinearities in the data to be accommodated directly without complex computation.

The oil and gas reservoir data used here included 9,340 known oil and gas reservoirs located in onshore and offshore western Europe that are currently or were formerly producing (IHS Markit, 2021); now known as S&P Global, retrieved September 2021. The calculation of CO2 storage resources for these reservoirs, even at the reconnaissance level, requires complex computations entailing estimates of recoverable oil and gas, reservoir properties, and the physical properties of the produced oil and gas (see Supplementary Appendix 1). To this end, we applied ML algorithms using reservoir and oil and gas properties to facilitate the calculation of the CO2 storage resources. The algorithms are trained and tested using a screened subset of these data. This paper first provides a short literature review, then describes the reservoir data, and briefly identifies the ML algorithms applied along with their hyperparameters. The predictive performance of the algorithms is then compared and summarized, and final remarks and discussion are provided.

2 Literature review

Various engineering and volumetric methods have been used in recent years to estimate the geological resource that could be available to store captured carbon (Bradshaw et al., 2006; Bachu, 2008; Pingping et al., 2009; Popova et al., 2012; Goodman, 2012; Heidug, 2013; Gorecki et al., 2015; NETL, 2015; Cantucci et al., 2016; Goodman et al., 2016; Ajayi et al., 2019; Moore, 2022). U.S. Geological Survey (2013), Consoli (2016), Kearns et al. (2017), Sanguinito et al. (2020), Zhang et al. (2022), and others provide estimates of geological CO2 storage capacity on a global or regional scale, and/or for specific depositional or operational settings. Peck et al. (2017), for example, specifically discuss best practices for quantifying CO2 storage resources in the context of enhanced oil recovery (EOR). Argatan et al. (2018) address CO2 storage in depleted oil and gas fields in the Gulf of Mexico, and Haagsma et al. (2020) and Jones et al. (2024) consider storage in Michigan Basin oil and gas reservoirs.

This body of literature suggests that the various estimates of geologic CO2 storage resources are quite uncertain, a situation largely attributable to methodological differences and treatment of the subsurface physics. Kadeethum et al. (2023) note that the various subsurface reservoir environments in which CO2 could be stored are rather heterogeneous in terms of their physical and flow characteristics, and the behavior of these phenomena are often nonlinear and difficult to model, requiring significant time and computational resources. On the other hand, ML provides a way to effectively capture the relationships among subsurface features, including any nonlinear behaviors, without having to specifically rely on the theoretical constructs and assumptions more often associated with engineering approaches.

In layman’s terms, ML is “a method of data analysis that automates analytical model building” or “a branch of artificial intelligence based on the idea that systems can learn from data, identify patterns and make decisions with minimal human intervention” (SAS n. d.; Wilpon et al., 2017). Consequently, the use of ML has been suggested as an alternative, surrogate, or proxy approach with which to address various aspects of carbon capture, utilization, and storage (CCUS) (Dumakor-Dupey and Arya, 2021; Mahoob et al., 2022; Kadeethum et al., 2023). For example, You et al. (2019) use ML to evaluate EOR and CO2 storage resources in the Farnsworth Unit in the Texas Panhandle. Smeenk and Leeuwenburgh (2023) and Ferreira et al. (2024) use deep learning approaches to evaluate CO2 storage resources in depleted gas fields. Bakhshian et al. (2022) use deep learning to assess CO2 storage resources in reservoirs containing residual gas. He et al. (2022) provide an ML workflow for CO2 storage capacity in deep saline reservoirs. Chen et al. (2018), Chen and Pawar (2019), Thanh et al. (2020), and Abdulwarith et al. (2024) use ML to address CO2 EOR and storage capacity in residual oil zones. Moreover, Wen et al. (2023) develop a nested Fourier neural network model trained on detailed reservoir model output data to produce high-resolution CO2 storage resource estimates for site-specific reservoirs. Here, we consider a novel application of ML to formulate reconnaissance-type estimates of CO2 geologic storage resources, with specific reference to western Europe.

3 Data description

Country-wide, regional, or basin-wide high-level or reconnaissance appraisals of the CO2 storage resources of oil and gas reservoirs commonly assume CO2 will replace the produced reservoir fluids in the reservoir’s pore space (Bachu et al., 2007; Goodman et al., 2011; Cantucci et al., 2016; Aminu et al., 2017).3 Because data on the location and appraisal of the CO2 storage resources are critical for long-range planning for deployment of CO2 transport and storage, the approach taken here is to base the CO2 storage resource on an estimate of the reservoir volume of the recoverable hydrocarbons that can be expected to be produced from startup to abandonment. Supplementary Appendix 1 presents details of the multiple steps of the more conventional engineering procedure that uses the individual reservoir properties to estimate the CO2 storage resource for each reservoir.

As of 2021, IHS Markit (2021) identified 9,340 oil and gas reservoirs located in western Europe. A reservoir was classified as oil if the natural gas to oil ratio, in terms of thousands of cubic feet (MCF) to barrels of oil (bbl), was less than 20 to 1 (Charpentier and Klett, 2005). Otherwise, it was classified as a non-associated gas reservoir (hereafter just called gas reservoir). Applying this criterion resulted in 3,943 oil reservoirs and 5,397 gas reservoirs. Total recoverable oil in the reservoirs is estimated to be 97.6 billion barrels and the total recoverable non-associated gas in the reservoirs is estimated to be 584 trillion cubic feet of gas (IHS Markit, 2021).

We first arrayed oil and gas reservoirs separately by the estimated subsurface volume of their contained hydrocarbons in order to screen by subsurface size. The largest 1,017 oil reservoirs by subsurface volume accounted for 95 percent of the cumulative subsurface oil reservoir volume, and similarly, the largest 1,619 gas reservoirs accounted for 95 percent of the cumulative gas reservoir volume. We further screened the oil and gas reservoirs using reservoir pressure and temperature data to identify reservoirs that could theoretically sustain injected CO2 in its supercritical phase. That screening left 950 oil and 1,278 gas reservoirs. These 950 oil reservoirs accounted for 85.6 BBO of recoverable (producible) oil and the 1,278 gas reservoirs accounted for 509.1 TCF of producible gas.

A fundamental assumption of the procedure for computing the reconnaissance level estimates of CO2 storage is that the volume of supercritical CO2 that can be safely stored is equivalent to the reservoir volume of pore space vacated by the producible hydrocarbons. These estimates do not account for the injected CO2 that might also be incidentally stored in formation water or in the residual oil and gas left in the reservoir after commercial production ceases. Alternatively, at a reconnaissance level, there is no way to determine which reservoirs might have been subject to subsidence after production, thus reducing the actual CO2 storage resource.

We assumed that CO2 is injected and stored in its supercritical state. Figure 1 shows how the density of supercritical CO2 varies with pressures at various levels of constant temperature. For the pressure and temperature range in the figure, the supercritical CO2 density increases as pressure increases and temperature declines.

Figure 1
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Figure 1. Density of supercritical carbon dioxide (CO2) as a function of pressure at various temperatures. C is degrees Celsius, and F is degrees Fahrenheit. Calculations using the predictive model by Ouyang (2011) are based on the National Institutes Standards and Technology (NIST, 2024) data from Span and Wagner (1999).

The locations of individual reservoirs are proprietary to IHS Markit (2021), but cell maps show the sum total CO2 storage resource of reservoirs within each 25-km square grid cell. Figure 2 is a map that shows the geographical distribution of the 950 oil reservoirs and Figure 3 shows the map of the 1,278 gas reservoirs used in this study. The total estimated CO2 storage resource for the 950 screened oil reservoirs amounted to 17.7 metric gigatons (GT), and similarly, the 1,278 CO2 storage resources for the gas reservoirs amounted to 40.3 GT.

Figure 2
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Figure 2. Estimated CO2 storage resources in mass of megatons (Mt) for oil reservoirs in western Europe. Estimates of CO2 storage resource are calculated from the estimates of volumes of recoverable oil from IHS Markit (2021). Cells of dimension 25 km by 25 km show the combined CO2 storage resource of all individual oil reservoirs within the cell.

Figure 3
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Figure 3. Estimated CO2 storage resources in mass of megatons (Mt) for gas reservoirs in western Europe. Estimates of CO2 storage resource are calculated from the estimates of volumes of recoverable gas from IHS Markit (2021). Cells of dimension 25 km by 25 km show the combined CO2 storage resource of all individual gas reservoirs within the cell.

Both oil and gas reservoirs exhibit a right skewed size distribution in terms of recoverable hydrocarbon resources and estimated volumes of CO2 storage resources. There are many small reservoirs which together account for a small fraction of the total resource in contrast to relatively few large reservoirs that account for most of the resource. Figures 4A,B show the frequency volume distribution of the screened oil and gas reservoirs, respectively, and Figures 5A,B show the frequency volume distributions of the estimated CO2 storage resource of the screened oil and gas reservoirs. In these figures, the horizontal axes providing the size classes are delineated in log base two in order to more clearly depict the wide range of sizes. In Figures 4A,B the largest five percent of the oil reservoirs (47) contain nearly half of the oil, and similarly, the largest 5 percent of the gas reservoirs (64) contain 55 percent of the non-associated gas. Further, in Figures 5A,B the largest five percent of oil and gas reservoirs account for 53 percent and 55 percent of the estimated CO2 storage resource, respectively.

Figure 4
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Figure 4. Distributions of reservoir sizes and respective cumulative percentages of recoverable resource volume: (A), recoverable oil in millions of barrels in oil reservoirs, and (B), recoverable gas in billions of cubic feet in gas reservoirs where the minimum size oil or gas reservoir is estimated to have the equivalent of 1 megaton (Mt) CO2 storage resource. Note: The reservoir class size doubles on the x-axis.

Figure 5
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Figure 5. Distributions of CO2 storage resource and cumulative percentage of total CO2 storage resource volume: (A), individual oil reservoir size and (B) individual gas reservoir size (minimum reservoir CO2 storage resource is 1 megaton, Mt). The size class doubles on the x-axis.

4 Methodology

Oil and gas reservoirs were modeled separately because they use different measures for quality of the hydrocarbons, i.e., API gravity for oil and specific gravity for gas. Three observations of CO2 storage resources beyond five standard deviations from the mean for the gas reservoirs were eliminated as extreme outliers, as well as one observation with an invalid gas specific gravity value. The final data sets represented 950 oil reservoirs and 1,274 gas reservoirs. Each reservoir dataset was then randomly divided into a training set containing 70 percent of the respective observations and a test set containing the remaining 30 percent. The predictor variables used for the CO2 storage resource for oil reservoirs were reservoir temperature, reservoir pressure, API gravity, estimated oil recovery and estimated natural gas recovery. Predictor variables used for the CO2 storage resource in gas reservoirs included reservoir temperature, reservoir pressure, specific gravity of the gas, and the estimate of the volume of recoverable gas from the reservoir.

Descriptive statistics of the predictor variables and CO2 storage resource estimates are presented in Table 1, 2. The table shows the means and standard deviations, as well as the coefficients of variation (ratio of standard deviation to the mean) associated with each predictor variable in the training and test sets associated with the oil and gas reservoirs, respectively. Supplementary Appendix 2 provides box plots of the predictors and the CO2 storage values for the oil and natural gas reservoirs (Supplementary Appendix 2; Figure 1), as well as tables of bivariate correlations (Supplementary Appendix 2; Tables 1, 2). The box plots for both the oil and gas reservoirs show observations concentrated in the smaller sizes of recoverable oil and gas, and for CO2 storage resource. The bivariate correlation matrix shows the recoverable oil and gas having the strongest predictor correlations with the storage values of CO2.

Table 1
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Table 1. Means, standard deviations, medians and coefficients of variation of predictor variables in the training and test sets of oil reservoirs [psia, pounds per square inch absolute; MMBO, million barrels oil; BCF, billion cubic feet; Mt, megatons or million metric tons; stddev, standard deviation; CV, coefficient of variation].

Table 2
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Table 2. Means, standard deviations, medians and coefficients of variation of predictor variables in the training and test sets of gas reservoirs. [psia, pounds per square inch absolute; BCF, billion cubic feet; BCF, billion cubic feet; Mt, megatons or million metric tons; stddev, standard deviation; CV, coefficient of variation].

Four different machine learning algorithms were applied to the data to construct predictive models. The algorithms and their respective hyperparameters, along with the procedures applied to the data are described in the following section. Each algorithm was trained on the same training dataset and the evaluation of predictive performance used the same test dataset.

4.1 Machine learning

4.1.1 Algorithms

Random Forest (RF) (Breiman, 2001), Gradient Boosting Trees (GBT) (Friedman, 2002), Extreme Boosting (XGBoost) (Chen and Guestrin, 2016), and deep neural network (DNN) (James et al., 2021) were used along with the values of the above-mentioned reservoir/resource predictor variables to directly model their relationship with the CO2 storage resource estimates computed with the procedure outlined in Supplementary Appendix 1. The three tree-based algorithms, RF, GBT, and XGBoost, are related to the classification and regression tree (CART) algorithms of Breiman et al. (1984). Except for XGBoost, the computational routines are available from H2O.ai’s open-source platform (H2O.ai, 2022). The XGBoost algorithm is published in R format (Chen et al., 2019). The DNN algorithm used here is also provided in the H2O platform, and it automatically standardizes the data prior to model calibration and then transforms the predictions back to the original metric (Candel and LeDell, 2023).

The tree-based approaches model non-linear relationships by partitioning the data space into progressively smaller groups so that data observations become more homogeneous within each partition. Individual trees are assembled by recursive partitioning that maximizes the local partition homogeneity with the tree structure being interpretable as a series of decision rules. The trees are assembled using the training data and predictive performance is evaluated by applying the trained model (algorithm) to the test dataset.

The RF algorithm generates an ensemble (or forest) of individual trees by applying bootstrap sampling to the training data and the predictors when forming individual trees. These sampling procedures are used to induce a degree of independence among individual trees. For regression analysis the predicted value of the target variable (in the present case, a reservoir’s estimated CO2 storage resource) is the average of the predicted values computed from all the individual trees in the forest (Breiman, 2001).

Individual trees are constructed sequentially by the GBT (Friedman, 2002) and XGBoost (Chen and Guestrin, 2016) algorithms rather than generating a forest of trees at the outset. The training data are used to construct a tree initially, but for the next iteration another tree is trained using the computed errors (residuals) associated with the predictions of the previous iteration. The “tree ensemble” is the sequence of fitted trees represented by the iterations, and target variable predictions are computed recursively using the constructed sequence of trees. Both the GBT and XGBoost algorithms entail bootstrap sampling of some fraction of each stage’s residuals/training observations to fit successive trees and avoid overfitting. The XGBoost algorithm also samples the predictors at each iteration to build the next tree to further improve the robustness of predictions.

Hastie et al. (2009) describe single-layer artificial neural networks where predictor variable values are mapped using an activation to a single hidden layer composed of neurons (or activations). The hidden layer neurons, in turn, are mapped to a single-variable output layer by activation functions (Figure 6A).4 These functions determine whether a neuron should be activated by computing the weighted function of input values (from the adjacent layer) and adding a bias term. The effect is to introduce non-linearity into the neuron output (James et al., 2021). Generally, any number of variables might be represented in both input and output layers.

Figure 6
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Figure 6. Illustration comparing schematics of (A) neural network and (B) deep neural network, DNN. Figure modified from Xing and Du (2019).

A DNN network commonly has multiple hidden layers between the input and output layers. A schematic of a DNN having four hidden layers (layers of neurons between the input layer and the output layer) with each layer having four neurons is presented in Figure 6B. The network links represent unknown parameters (weights) that the network algorithm fits with the training data. Model predictions or outputs are calculated by forward propagation computations and the backward pass fits the neural network’s unknown parameter weights (James et al., 2021). The architecture of the model, along with the specification of the activation functions, regularization parameters that include the dropout rate,5 and the linear and quadratic penalty parameters, determines how well the DNN model fits the training data and how accurately it can predict the target variable values for the test data. (James et al., 2021).

4.1.2 Hyperparameters

Table 3 identifies each algorithm’s hyperparameters and shows the parameter values used to train and test the models. For tree-based algorithms, hyperparameters place restrictions on the stochastic components, complexity, and size of the constructed trees. For DNN algorithms, hyperparameters restrict the size and the architecture of the neural network. The training dataset is used to calibrate the predictive model. The purpose of optimizing tuning hyperparameters is to minimize a measure of the expected error for new data (separate from the training dataset) when predicting the value of the target variable, which in the present case is the estimate of the reservoir’s CO2 storage resource. For all the algorithms evaluated here, we applied to the training data an estimate of the generalization error (e.g., the average root mean square error) obtained using a five-fold cross validation6 approach. We generated the models’ hyperparameters using an exhaustive grid search over a range of possible hyperparameter values (Halder, 2023). Table 3 in Supplementary Appendix 2 shows the range searched. Following the search, some adjustments were made to avoid overfitting the trained model.

Table 3
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Table 3. Hyperparameter values specified for each model for oil reservoirs and for gas reservoirs.

5 Predictive performance

Table 4 shows three measures of predictive performance. The first measure is the mean absolute error, the second is the root mean square error, and the third is the fraction of the variation in each dataset’s target variable (predicted CO2 storage resource) explained by the model. The mean absolute error is the average absolute difference between the predicted values and the actual target value, irrespective of direction. The root mean square error is the square root of the average of the squared differences between predicted values and actual target values, thus giving higher weight to large errors encountered in predicting extreme values. The variation explained is computed as one would compute the coefficient of determination (or R2) commonly associated with regression analysis. The evaluation of predictive performance focusses on how well the trained models predict the target variable for the common test dataset.

Table 4
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Table 4. Predictive performance of four algorithms: Random Forest (RF), Gradient Boosting Trees (GBT), Extreme Boosting (XGBoost), and Deep Neural Network (DNN) [Mt, megatons or million metric tons].

For three of the 4 ML algorithms, the predictive performance of the models associated with the gas reservoir CO2 storage resources is superior to the corresponding models used to predict the CO2 storage resource of oil reservoirs (see Table 3). Of the gas reservoir prediction models, the DNN model explained the target variable’s variation (R2) the best while having the lowest root mean square error. For the gas reservoir models, the tree-based algorithms were able to explain at least 90 percent of the target variable’s variation for the test data. For the oil reservoirs, the DNN algorithm had superior predictive performance in terms of mean absolute error, root mean square error and explained variation statistics. The greater complexity of the DNN algorithm may account for its superior predictive performance for both oil and gas reservoirs7.

Figures 7A,B show the predicted versus calculated (see Supplementary Appendix 1) CO2 storage resources assigned to the test data oil reservoirs and gas reservoirs, respectively. The solid lines show cumulative storage resource growth across storage size classes, and the bars show storage volume attributed to each size class. The bar charts suggest that oil reservoir storage predictions at the size classes smaller than 16 million barrels substantially overestimate CO2 storage values; and although the larger size classes are underestimated, the cumulative curve shows substantial displacement. The natural gas reservoir storage predictions substantially underestimate the calculated storage values in size classes greater than 32 Mt to 128 Mt, as well as for gas reservoirs with storage resource greater than 256 Mt. The graphs suggest why the root mean square errors associated with the test data are large even though the explained variation is relatively high.

Figure 7
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Figure 7. Predicted versus the calculated (see Supplementary Appendix 1) CO2 storage resources assigned to: (A), the 285 oil reservoirs of the test data set, and (B), the 383 gas reservoirs of the test data set. Solid line shows cumulative resource growth across storage size classes and bars shows storage volume attributed to each size class. Test data predictions used the deep neural network (DNN) models (see Table 2) trained with the training data sets for oil and gas reservoirs, respectively. The size class doubles on the x-axis. Box plots of the distributions of predictor variables and CO2 storage variables used in the machine learning (ML) models for: (A), oil reservoirs, and (B), natural gas reservoirs, respectively (psia, pounds per square inch absolute; MMBO, million barrels oil; BCF, billion cubic feet; Mt, megatons or million metric tons.).

Examination of the importance of the predictors may prove helpful in explaining the difference in predictive performance of both the oil and gas reservoir models. Table 5 shows the ordered relative importance (percent explanation) of the predictive variables for the RF, GBT, XGBoost, and DNN models. The leading predictors of CO2 storage resources for oil reservoirs are the estimated recoverable oil and recoverable gas for all tree models, but not for DNN. Similarly, the tree-based models have the leading predictor of CO2 storage resources as recoverable gas reservoirs8. The importance of the predictor variables seems to be equalized for the DNN model. Perhaps because of the complexity of the DNN algorithm that was applied, the algorithm may have detected the added influence that reservoir temperature and pressure have on the supercritical CO2 density. For the gas reservoirs, the tree-based models show the same predictor importance ordering; recoverable gas is first, and reservoir temperature is second. Again, the gas reservoir DNN model seems to detect the separate importance that reservoir temperature and pressure have on the density of supercritical CO2.

Table 5
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Table 5. Ordered relative importance (percent explanation) of predictor variables for Random Forest (RF), Gradient Boosting Trees (GBT), Extreme Boosting (XGBoost), and Deep Neural Network (DNN) algorithms for predicted reservoir CO2 storage resource.

6 Summary and extensions

Conventional reconnaissance-type estimates of CO2 storage resources of known oil and gas reservoirs require complicated engineering calculations involving 1) estimates of recoverable oil and gas, 2) reservoir properties (depth, temperature, pressure, etc.), and 3) the physical properties of the fluids. In lieu of the engineering calculations, this study examines the predictive performance of 4 ML algorithms to by-pass these computations to yield more rapid estimates of CO2 storage resources using the same inputs. We demonstrate this capability for oil and gas reservoirs located in western Europe. The predictive performance of the DNN algorithm was superior to those of the RF, GBT, and XGBoost algorithms as measured by the root mean square errors, explained variation of the target variable, and mean absolute error statistics. The root mean square error estimates for all models (in Table 4) appear somewhat high relative to the mean CO2 resource estimates shown in Table 1, 2. This is likely induced by the skewed size-frequency distributions of the oil and gas reservoirs and their estimates of CO2 storage resources. Future analysis may focus on ways to partition the data to reduce these errors in predicting extreme values. In particular, there may be value in developing separate models for onshore and offshore reservoirs due to differences in physical characteristics, dispositional environments, and related operational and management factors.

Whereas reconnaissance estimates of CO2 storage resources may be useful to answer broad planning questions they are not sufficiently sophisticated for site specific evaluation (Wen et al., 2023). Such evaluations involve much more detailed spatial data to be used for reservoir modeling (Erten et al., 2023). Future studies could lead to the potential combining of geostatistical approaches to ML. Da Silva (2020) provides a comparative analysis of ML and geostatistics for mineral resource estimation.

The ML methods and models developed and presented here may be important to the energy transition and the climate change debate because they provide a more rapid and direct path for a reconnaissance assessment of subsurface carbon storage resources. The work presented here represents an effective means for operators, researchers, and policymakers alike to rapidly and accurately quantify the potential storage resource.

Data availability statement

The data analyzed in this study is subject to the following licenses/restrictions: Part of the data are available for purchase from IHS Markit (now part of S&P Global). Part is available from the National Institute of Standards. Requests to access these datasets should be directed to https://energyportal.ci.spglobal.com/home and https://webbook.nist.gov/chemistry/fluid.

Author contributions

EA: Conceptualization, Data curation, Formal Analysis, Investigation, Methodology, Project administration, Resources, Software, Supervision, Validation, Writing – original draft, Writing – review and editing. PF: Data curation, Resources, Software, Visualization, Writing – review and editing, Funding acquisition. TC: Methodology, Supervision, Writing – review and editing.

Funding

The author(s) declare that financial support was received for the research and/or publication of this article. For Attanasi and Freeman, this work was funded by the U.S. Geological Survey’s Energy Resources Program. Research and preparation of paper were done as part of official duties assigned by the U.S. Geological Survey, United States Government. Coburn was supported by the Department of Systems Engineering, Colorado State University.

Acknowledgments

Authors gratefully acknowledge reviews of the manuscript by Marc Buursink, Peter Warwick, and Clinton Scott, all of the U.S. Geological Survey. Any use of trade, firm, or product names is for descriptive purposes only and does not imply endorsement by the U.S. Government. Although this information product, for the most part, is in the public domain, it also may contain copyrighted materials as noted in the text. Permission to reproduce copyrighted items must be secured from the copyright owner.

Conflict of interest

The authors declare that the research was conducted in the absence of any commercial or financial relationships that could be construed as a potential conflict of interest.

Generative AI statement

The author(s) declare that no Generative AI was used in the creation of this manuscript.

Publisher’s note

All claims expressed in this article are solely those of the authors and do not necessarily represent those of their affiliated organizations, or those of the publisher, the editors and the reviewers. Any product that may be evaluated in this article, or claim that may be made by its manufacturer, is not guaranteed or endorsed by the publisher.

Supplementary material

The Supplementary Material for this article can be found online at: https://www.frontiersin.org/articles/10.3389/fenvs.2025.1562087/full#supplementary-material

Footnotes

1This study uses the term CO2 storage resource to denote pore space in the reservoir occupied by recoverable oil and gas that could be utilized to store CO2.This terminology is consistent with Society of Petroleum Engineers (2017) accepted definitions

2The U.S. Energy Information Administration (2000) defines conventional oil and gas reservoirs as underground formations containing an individual and separate pool (natural accumulation) of producible oil and/or gas that is confined by impermeable rock or water barriers and is characterized by a single natural pressure system

3Zhao et al. (2014) point out that injected CO2 may also be retained in the formation water or the residual crude oil, or that it may be mineralogically retained in the reservoir rock formation. Furthermore, if extraction of the formation water is economic, the CO2 storage resource can be expanded

4An activation in a neural network is a mathematical function that collects and classifies information according to a specific architecture (number of layers, number of neurons).

5The dropout rate randomly disengages certain nodes in a layer according to the stated dropout probability imposed during training

6In cross-validation, the training set is divided into multiple folds, with one of the folds designated as a validation set, and the model is trained on the remaining folds. This process is repeated multiple times, and each time a different fold is used as the validation set. The performance measures from each of the validation folds are averaged to estimate the model’s predictive performance when new data are applied

7The cross-validation performance statistics for the DNN oil and gas models are presented in Supplementary Appendix 2, Table 4.

8For the tree-based H2O models (i.e., RF and GBT), variable importances are calculated from gains in the squared error loss function over all trees. XGBoost uses a gradient in conjunction with a Hessian (Chen and Guestrin, 2016) formulation. According to Candel and LeDell (2023), the H2O DNN algorithms use the method developed by Gedeon (1997) based on weight connecting neurons in the first two hidden layers.

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Keywords: machine learning, carbon dioxide storage resources, carbon dioxide sequestration, oil and gas reservoirs, supercritical carbon dioxide

Citation: Attanasi E, Freeman P and Coburn T (2025) Machine learning provides reconnaissance-type estimates of carbon dioxide storage resources in oil and gas reservoirs. Front. Environ. Sci. 13:1562087. doi: 10.3389/fenvs.2025.1562087

Received: 16 January 2025; Accepted: 11 April 2025;
Published: 28 April 2025.

Edited by:

Jill A. Engel-Cox, University of Colorado Denver, United States

Reviewed by:

Mohammad H. Elkady, Texas A and M University, United States
Mostafa Saghafi, Shahrood University of Technology, Iran
Derek Vikara, National Energy Technology Laboratory (DOE), United States

Copyright © 2025 Attanasi, Freeman and Coburn. This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.

*Correspondence: Emil Attanasi, YXR0YW5hc2lAdXNncy5nb3Y=; Timothy Coburn, dGltLmNvYnVybkBjb2xvc3RhdGUuZWR1

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