ORIGINAL RESEARCH article
A Note on the Exact Green Function for a Quantum System Decorated by Two or More Impurities
- 1Departamento de Física Teórica, Facultad de Ciencias, Universidad de Valladolid, Valladolid, Spain
- 2Physics Department, Clarkson University, Potsdam, NY, United States
The exact Green function is constructed for a quantum system, with known Green function, which is decorated by two delta function impurities. It is shown that when two such impurities coincide they behave as a single singular potential with combined amplitude. The results are extended to N impurities and higher dimensions.
The one dimensional harmonic oscillator or square well, for example, for which the energy -dependent Green function is known, have been taken for many years as solvable models for semi-conductor quantum wells . Frequently delta function potentials are placed at various points to simulate defects or impurities. In the case of a single impurity potential, V(x) = λδ(x−a), the Green function for the composite system is known to be 
In this note a corresponding formula is derived for the case V(x) = λδ(x−a)+μδ(x−b) On the basis of the analogy of the algebraic structure the result is extended to N-impurities and for a standard interpretation of the Dirac delta function, to higher dimension.
We first note that the same argument can be used for the time dependent-, as well as the energy-dependent Green functions, so we shall omit the third argument and write simply G(x, x′).
Beginning with the Dyson equation, noting that G0(x, y) = G0(y, x)
where the integration extends over the system domain, one has the set of equations
The linear Equations (4) and (5) are easily solved for G(a, x′) and G(b, x′):
By inserting (6) and (7) into (3) we obtain the desired expression
By setting μ to 0 (9) reduces to (1), proving this expression as well. The most salient feature of (9) is the denominator D whose zeros form the exact spectrum of the composite system. For example, when a and b coincide, D reduces to 1−(λ+μ)G(a, a) and (9) reduces to (1) with λ replaced by the amplitude λ+μ. I.e., the two impurities combine to form one with combined amplitude. This generalizes the result of Fasssari and Rinaldi , for two identical defects symmetrically placed with respect to the center of a harmonic oscillator. An expression similar to (9) has been derived recently by Horing (private communication) for the case of a quantum dot in a magnetic field.
Two further points can be made. Nothing in the derivation of (9) restricts it to the line. If we accept the standard definition , then (9), and its consequences, are valid for d-dimensional quantum systems. This has been proven function-theoretically for the three dimensional quantum dot with two symmetrically placed identical impurities by Albeverio et al. .
A second observation is that D is simply the Cramer determinant for the pair of simultaneous linear Equations (4) and (5). In the case of impurity potential
there will be N such equations and the determinant is easily evaluated. The general result is
If a quantum system having Green function G0(x, y) is decorated with N delta function impurities λjδ(x−aj), j = 1, 2, ⋯N, then the new energy levels are the roots of
where Alm = δlm−λlG0(al, am).
which reduces to the N = 1 and N = 2 cases appropriately and shows that any two coinciding impurities coalesce as indicated above.
Note that if all the λs and a's coincide then
Equation (11) might offer a new approach to Kronig-Penney-type systems for periodic or random unit cells.
Finally, it should be pointed out that the work in this note is paralleled in the theory of quantum graphs introduced by Linus Pauling about 1930 to describe electrons in molecules which has developed into a sophisticated and important branch of quantum physics . For relations of this discipline to the present work see the papers by Andrade et al.  and Andrade and Severini .
The author confirms being the sole contributor of this work and has approved it for publication.
Conflict of Interest Statement
The author declares that the research was conducted in the absence of any commercial or financial relationships that could be construed as a potential conflict of interest.
The author thanks Prof. S. Fassari and Prof. L. M. Nieto for helpful comments and acknowledges the financial support of MINECO (Project MTM2014-57129-C2-1-P) and Junta de Castilla y Leon (VA057U16). The author thanks a referee for pointing out the relevance to quantum graphs.
2. Glasser ML, Nieto LM. The energy level structures of a variety of one-dimensional confining potentials and the effects of a local singular perturbation. Can J Phys. (2015) 93:1–9. doi: 10.1139/cjp-2015-0356
3. Fassari S, Rinaldi F. On the spectrum of the Schroedinger Hamiltonian of the one-dimensional harmonic oscillator perturbed by two identical attractive point interactions. Rep Math Phys. (2012) 69: 353–70.
4. Albeverio S, Fassari S, Rinaldi F. Spectral properties of a symmetric three-dimensional quantum dot with a pair of identical attractive impurities symmetrically situated around the origin. Nanosyst Phys Chem Math. (2016) 7: 268–89. doi: 10.17586/22208054201672268289
Keywords: quantum green function, delta function potential, contact interaction, Schroedinger equation, quantum graph
Pacs: 02.30Gp, 02.30Hq, 03.65Db
Citation: Glasser ML (2019) A Note on the Exact Green Function for a Quantum System Decorated by Two or More Impurities. Front. Phys. 7:7. doi: 10.3389/fphy.2019.00007
Received: 01 October 2018; Accepted: 11 January 2019;
Published: 29 January 2019.
Edited by:Luiz A. Manzoni, Concordia College, United States
Reviewed by:Fabio Rinaldi, Universitá degli Studi Guglielmo Marconi, Italy
Fabiano Andrade, Universidade Estadual de Ponta Grossa, Brazil
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*Correspondence: M. L. Glasser, email@example.com