Comparative SEM/EDS Analysis of Gunshot Residues from NonToxic and Traditional Ammunitions Employed by Dubai Police

Asma Askar^1,2Roudha A Alblooshi¹Hamda A Alobeidli¹Rashed H Alremeithi¹ILTAF SHAH^2*

• ¹General Department of Forensic Science and Criminology, Dubai Police GHQ, Dubai, United Arab Emirates
• ²Department of Chemistry, College of Science, UAE University, Al Ain, United Arab Emirates

Analysis and identification of gunshot residue (GSR) are considered critical forensic evidence in shooting incident investigations. This study comparatively analyzed gunshot residues from Fiocchi non-toxic ammunition (NTA), ADCOM, and NATO ammunitions, all commonly utilized by Dubai Police, using Scanning Electron Microscopy coupled with Energy Dispersive X-ray Spectroscopy (SEM/EDS) following the American Society for Testing and Materials (ASTM) E1588-20 standards. The elemental compositions of ammunition components, including cartridge cases, bullets, gunpowder, and primers, were thoroughly characterized. Primer residues revealed significant elemental differences, with Fiocchi NTA ammunition unexpectedly containing detectable lead particles, although at lower levels compared to ADCOM and NATO ammunition. Across all ammunition types, GSR particles predominantly measured below 3 µm, effectively differentiating them from common environmental contaminants. GSR particle deposition was consistently higher on shooters' dominant right hands due to firearm mechanics and hand dominance. Particle counts generally decreased over time post-discharge but were influenced significantly by shooter activities rather than elapsed time alone. Notably, limitations within the ASTM E1588-20 classification scheme resulted in no identifiable Heavy-Metal-Free (HMF) GSR particles for Fiocchi NTA, emphasizing the need for updated and expanded classification criteria. Future research is recommended to enhance forensic methods and classification frameworks to accommodate evolving ammunition formulations.