REVIEW article

Front. Phys.

Sec. Optics and Photonics

Volume 13 - 2025 | doi: 10.3389/fphy.2025.1615872

This article is part of the Research TopicAcquisition and Application of Multimodal Sensing Information, Volume IIIView all articles

Gas Detection Technology for Thermal Runaway of Lithium-ion Batteries

Provisionally accepted
Yihua  QianYihua QianYaohong  ZhaoYaohong Zhao*Zhi  LiZhi LiQing  WangQing WangYifeng  ZhaoYifeng Zhao
  • Electric Power Research Institute of Guangdong Power Grid Co., Ltd, Guangzhou, China

The final, formatted version of the article will be published soon.

This paper presents a comprehensive review of gas detection and early warning technologies for lithium-ion battery thermal runaway a critical safety concern in modern energy storage and electric vehicle applications. With the increasing push for higher battery energy densities, thermal runaway has emerged as a severe risk characterized by rapid self-heating, complex exothermic reactions, and the evolution of flammable gases that can lead to explosions and fires. The review begins by detailing the underlying physicochemical mechanisms of thermal runaway and the subsequent gas generation processes, emphasizing the early evolution of gas signals as a promising indicator for imminent failure. A wide range of detection techniques are critically evaluated, including gas chromatography, Fouriertransform infrared spectroscopy, Raman spectroscopy, differential electrochemical mass spectrometry, metal oxide semiconductor sensors, and non-dispersive infrared technology-each offering unique advantages and facing distinct challenges in practical applications. Special attention is given to the emerging role of optical fiber-based sensors (e.g., Fabry-Perot interferometers, fiber Bragg gratings, and fluorescence-based sensors), which provide notable benefits such as immunity to electromagnetic interference, flexible integration, and high sensitivity for key gases (CO₂, H₂, and CH₄). The paper concludes by discussing the limitations of current approaches and proposes future directions to achieve integrated, cost-effective, and robust battery safety monitoring systems.

Keywords: Gas detection, lithium-ion battery, Thermal runaway, optical fiber, spectroscopy

Received: 22 Apr 2025; Accepted: 22 May 2025.

Copyright: © 2025 Qian, Zhao, Li, Wang and Zhao. This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) or licensor are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.

* Correspondence: Yaohong Zhao, Electric Power Research Institute of Guangdong Power Grid Co., Ltd, Guangzhou, China

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