Network-Like Platinum Nanosheets Enabled by a Calorific-Effect-Induced-Fusion Strategy for Enhanced Catalytic Hydrogenation Performance

Introduction

Platinum (Pt) plays an indispensable role in industrial production owing to its unique and versatile catalytic capability (Hao et al., 2014). Considering the high cost and rare reserve of Pt (Huang et al., 2012), a key point is to explore Pt-based catalysts with high atom utilization and superior catalytic performance (Gong et al., 2014; Song et al., 2017). Up to now, the commonly adopted strategies include alloying Pt with non-precious metals (such as Fe, Co, Ni, etc.) (Yang et al., 2017; Zeng et al., 2017; Li et al., 2021), modulating the exposed surface crystallography (to get specific facet or high-index facet) (Cao et al., 2017; Wang et al., 2017; Dong et al., 2020) and/or constructing unique morphologies (such as core shell, framework, hollow, etc.) (Ge et al., 2018; Lin et al., 2018; Liu et al., 2021).

Owing to the high surface energy aroused by the size effect, nanoparticles inevitably suffer from surface ripening and agglomeration (Chung et al., 2018), which could lead to the deterioration of catalytic activity (Pasricha et al., 2009). Supporting substrates are often used to improve the dispersibility of the nanocatalysts (Tong et al., 2017). Furthermore, the metal-support interaction might also facilitate the catalytic performance optimization (Jackson et al., 2017; Meng et al., 2017). However, like a coin has two sides, the supported catalysts also have adverse effects. 1) The corrosion of the supporting substrates in the reaction media restrains their application. For example, metallic oxides, a kind of widely used carrier, are unstable in acidic condition. Similarly, carbon-based substrates are found easily corroded during electro-catalysis process (Jiang et al., 2016a). 2) Additional components might deteriorate the catalytic performance owing to the unpredicted metal-support interaction though the catalyst could be stably immobilized on the substrate (Jayakumar et al., 2017). 3) The substrates could increase the diffusion length and thus block the efficient accessing of the reactant to the active sites of the catalyst. 4) The increased total mass or volume with the introduction of supporting substrates may lead to the undesired dispersibility in the reaction media.

One core resolution is to engineer the nanocatalysts into self-supported nanoporous networks (usually called nanofoams or porous frameworks). The porous structure could not only increase the surface area but also improve the resistance to agglomeration. Furthermore, the interconnected network-like structure could accelerate the mass transfer and electron mobility (Xu and Zhang, 2014). The superior catalytic performance endowed by the featuring structure aroused great research interest on the nanofoams (Zhu et al., 2021). Strategies like templating (Li et al., 2013; Tamaki et al., 2015; Jang et al., 2020) and selective dissolution (Liu et al., 2009) have been successfully employed for the construction of Pt nanofoams. The advance up till now mainly focused on the 3D porous Pt structure, such as porous nanospheres (Li et al., 2015; Jiang et al., 2016a; Jiang et al., 2016b), periodic porous structures (Stein et al., 2008; Kim et al., 2013; Xu and Zhang, 2014), etc. Contrastively, 2D porous structures possess more extended surface, superior flexibility, and thinner pore channel, thus meriting more active sites, faster mass/electron transfer rate, better dispersibility, and stability. However, the challenge on fabrication of 2D porous Pt nanostructures greatly restricts the exploration of their applications.

Herein, we report a calorific-effect-induced-fusion strategy to construct network-structured Pt porous nanosheets (denoted as Pt PNSs thereafter). The highly dispersed Pt species catalyzed the combustion of the reduced graphene oxide (rGO) substrate, which served both as energy supplier and sacrificial structure guide reagent for the fusion of Pt cluster into network-structure. The as-prepared Pt PNSs exhibit dramatic hydrogenation catalytic ability towards unsaturated bond such as olefins and nitrobenzene.

Materials and Methods

Chemical Reagents and Materials

Graphite powder was purchased from Alfa Aesar. Potassium permanganate (KMnO₄), potassium persulfate (K₂S₂O₈), and phosphorus pentoxide (P₂O₅) were bought from Sinopharm Chemical Reagent Beijing Co., Ltd. Hydrochloric acid (HCl), sulfuric acid (H₂SO₄), hydrogen peroxide (H₂O₂), ammonium hydroxide (NH₃·H₂O), and alcohol were purchased from Beijing Chemical Reagent Company. Chloroplatinic acid (H₂PtCl₆·6H₂O) was purchased from Shenyang Jinke Chemical Reagent Company. Mesitylene, styrene, and the analogue were bought from Beijing InnoChem Science and Technology Co., Ltd. All materials were used as obtained without any purification.

Synthesis of Graphite Oxide

Graphite oxide (GO) was prepared using a modified Hummer's method. Typically, for pre-oxidation treatment, 3.0 g graphite powder was added to 15 ml concentrated H₂SO₄ containing 2.5 g K₂S₂O₈ and 2.5 g P₂O₅. After stirring vigorously under 80°C for 6 h, the pre-oxidized graphite powder was collected and dried overnight. Subsequently, the powder was dispersed into 120 ml concentrated H₂SO₄ in an ice bath for further oxidation. Keeping the temperature no higher than 20°C, 15.0 g KMnO₄ was cautiously added into the suspension. After stirring for about 2 h under 35°C, 250 ml deionized water was dropped in while the temperature was kept below 50°C. After stirring for 2 h, 700 ml deionized water and 20 ml H₂O₂ were then added into the above solution. The yellow precipitate was obtained by centrifugation and washed with 1.5 L of 2 M HCl followed by 1.5 L deionized water. The purified GO was re-dispersed in 500 ml deionized water for later use. The concentration of GO was about 5.0 mg ml⁻¹.

Synthesis of Pt PNPs

Before synthesizing the Pt PNPs, the as-prepared GO was reduced into rGO by NaBH₄. GO solution (1 ml) was dissolved in 20 ml deionized water containing 40.0 mg NaBH₄. The mixture was transferred into 50 ml autoclave and kept at 140°C for 6 h. After cooling down to room temperature, the rGO precipitate was collected by centrifugal separation and with ethanol and deionized water 3 times. Finally, rGO powder was obtained by freeze-drying for later use.

rGO (5.0 mg), 1 ml NH₃·H₂O, and 0.16 mM H₂PtCl₆ were dispersed in 30 ml deionized water. After stirring in 60°C water bath for 1 h, 10 ml of ascorbic acid (Vc) aqueous solution (10 mg ml⁻¹) was injected into the mixture. Then, the above solution was transferred into 90°C oil bath and kept stirring for 24 h. After natural cooling to room temperature, the black precipitate was collected by centrifugation and then washed with ethanol and deionized water 3 times. The as-prepared Pt/rGO product was collected by freeze-drying. After annealing in 5% H₂/Ar at 200°C for 2 h, Pt/rGO hybrids spontaneously burned as soon as it was exposed to air, which produced Pt PNSs.

Catalytic Activity Measurement

Typically, 3.0 mg catalyst and 1.7 mM styrene (or p-chlorostyrene/p-methylstyrene/cyclohexene/nitrobenzene) were added into 5 ml ethanol in a 25 ml flask. Mesitylene (1.4 mM) was added simultaneously serving as internal standard substance. Before measurement, H₂ gas was bubbled for several minutes to remove the dissolved air. With forceful stirring, the hydrogenation reaction of olefins was carried out under room temperature and normal pressure with a H₂ balloon as the H₂ supplier. Liquid samples were analyzed by gas chromatography (GC) equipped with a flame ionization detector and an HP-CP8713 capillary column.

The durability was assessed by using the re-used catalyst to initiate a new cycle. Specifically, as one round of the catalytic reaction was completed, the catalyst was separated from the reaction solution by centrifugation. After washing with ethanol, the recollected catalyst was dispersed into a fresh reaction solution containing the same amount of reactant reagent as the initial round for the next cycle of activity measurement.

Results and Discussion

Calorific effect is one of the essential features of chemical reactions, which has been widely applied in our life such as giving us warmth, providing us energy, etc. It can also be exploited to compensate the energy consumption and thus relax the reaction condition or even enable the thermodynamically impossible reaction to occur by introducing extra reagents into the system according to Hess's law. A typical case is aluminothermy, a process producing great heat by oxidizing finely divided aluminum with oxygen to launch the reduction of metal oxide. Graphene is known as 2D material featuring remarkable flexibility, incredible strength, and excellent conductivity. Easy functionalization and simple removal procedure also make the graphene a novel template. Furthermore, the combustion of graphene is exothermic. It is reasonable to infer that if tiny Pt species were uniformly dispersed onto the graphene substrate, the combustion of the graphene would induce the fusion of the Pt species, and 2D network structures might be formed under the guidance of the graphene. It is not an easy task to uniformly disperse pre-formed Pt nanoparticles onto the substrate with desired density. So we adopted the in situ reduction strategy to load tiny Pt species. That is, Pt (II) ions were firstly uniformly adsorbed onto rGO and the thereafter in situ reduction generated rGO-supported Pt metallic species.

Considering that the rGO preferred to absorb cations, the neutral NH₃ was used to substitute the negative ligand of Cl⁻ in the PtCl₆²⁻ precursor through ligand exchange process. Typically, the mixture containing PtCl₆²⁻ and NH₃ was stirred at 60°C for 1 h. The color of the solution turned from yellow into colorless, a distinct character of the successful ligand exchange. Subsequently, the given amount of rGO and ascorbic acid (Vc) were introduced into the above mixture and aged at 90°C for uniform adsorption of Pt (NH₃)₄²⁺ onto the rGO. The achieved black precipitate was collected and characterized to give the detailed information of the transformation. The atomic ratio of Pt and N was determined as 1:4.2, approaching the theoretical stoichiometry of Pt (NH₃)₄²⁺ (Supplementary Figure S1). Moreover, the Pt 4f_2/7 X-ray photoelectron spectroscopy (XPS) spectrum was dominated by peaks ascribed to Pt²⁺ locating at 73.35 eV (Supplementary Figure S1), confirming that most of the PtCl₆²⁻ ions had transformed into Pt (NH₃)₄²⁺ (Cheng et al., 2020). The weak Pt⁴⁺-related diffractions were believed to originate from the small amount of the remaining PtCl₆²⁻ (Kim et al., 2006). Metallic Pt-related XPS (Supplementary Figure S1) and X-ray diffraction (XRD) (Supplementary Figure S2) indicated no Pt nanoparticles formed at this stage. The high-angle annular dark field-scanning transmission electron microscopy (HAADF-STEM) images (Supplementary Figure S3) show that the Pt (NH₃)₄²⁺ ions were uniformly dispersed on rGO, and no nanoscaled aggregates was identified. The inductively coupled plasma atomic emission spectrometry (ICP-AES) data indicates the loading amount of Pt on rGO reached as high as 26.46 wt%.

Then, the Pt (NH₃)₄²⁺/rGO hybrids were annealed in H₂/Ar at 200°C for 2 h to reduce the absorbed Pt (NH₃)₄²⁺ into metallic Pt. Interestingly, once exposed to the air, the Pt/rGO would spontaneously burn. The transmission electron microscopy (TEM) observation (Figure 1A) reveals that the overview morphology of the product after combustion highly resembled that of rGO with 2D nanosheet structure of several micrometers in diameter. Closer observation (Figures 1B, C) clearly demonstrates the network-like nanosheet structure feature. The ligaments of the network were made of fused nanoparticles with mean diameter of about 20 nm (Figures 1B, C). The high-resolution TEM (HRTEM) characterizations (Figures 1C1–C3) show that the lattice fringe at different regions along the ligament all agree well with the (111) and (200) facet of face-centered cubic Pt (JCPDS No. 04-0802). Obviously, there were distinct grain boundaries at the junctions of adjacent nanoparticles (Figures 1C1, C3). No rGO could be further identified, indicating the complete oxidation of the rGO by combustion.

FIGURE 1

FIGURE 1. Morphology and structure characterization of the Pt PNSs. (A–C) different-magnified TEM images, (C1–C3) high-resolution TEM images recorded from the different framed regions in (C). The grain boundaries were marked out by white dash line in C1 and C3.

The composition and structure of the as-prepared Pt PNSs were further validated by XRD, XPS, and X-ray absorption near-edge structure (XANES) characterizations. As shown in Figure 2A, there are three diffraction peaks in the XRD pattern located at 39.76, 46.24, and 67.45, respectively, fitting well with fcc-Pt (JCPDS No. 04-0802). The XPS spectrum reveals that the Pt 4f_2/7 binding energy sited at 71.38 eV, coincident well with that of pure Pt nanoparticles (Lai et al., 2019). No Pt (II/Ⅳ)-related peak was detected in both XPS (Figure 2B) and XANES spectroscopy analysis (Figures 2C, D), elaborating complete reduction from Pt (NH₃)₄²⁺ to Pt (Lu et al., 2015; Meng et al., 2017).

FIGURE 2

FIGURE 2. Spectroscopy characterizations of Pt PNSs. (A) XRD pattern, (B) XPS Pt4f spectrum, (C) XANES spectra, and (D) Fourier-transformed-extended X-ray absorption fine structure (FT-EXAFS) curves.

As discussed earlier, H₂ was employed to reduce Pt (NH₃)₄²⁺ into metallic Pt. It is reasonable to conclude that there was also H₂ adsorbed on the surface of the as-formed metallic Pt species, and the adsorbed H₂ might be further activated since Pt is a well-documented hydrogenation and dehydrogenation catalyst (Yan et al., 2017). It is also well known that Pt is a highly efficient catalyst for the H₂-O₂ combination reaction (Michaelides and Hu, 2001). Thus, once the H₂-adsorbed Pt is exposed to the air, the combination reaction would be initiated according to the following equation.

${\mathrm{H}}_2\left(\mathrm{g}\right)+12{\mathrm{O}}_2\left(\mathrm{g}\right)={\mathrm{H}}_2\mathrm{O}\left(\mathrm{g}\right){\mathrm{\Delta }}_{\mathrm{r}}{H}_{\mathrm{m}}^{\theta }=-241.8\mathrm{kJ}\mathrm{mo}{\mathrm{l}}^{-1}(1)$

The burst of the reaction produced great heat, which further triggered the burning of the rGO. The oxidation of rGO is also an intense exothermic reaction (Eq. 2).

$\mathrm{C}\left(\mathrm{s}\right)+{\mathrm{O}}_2\left(\mathrm{g}\right)=\mathrm{C}{\mathrm{O}}_2\left(\mathrm{g}\right){\mathrm{\Delta }}_{\mathrm{r}}{H}_{\mathrm{m}}^{\theta }=-393.5\mathrm{kJ}\mathrm{mo}{\mathrm{l}}^{\mathrm{-1}}(2)$

The released massive heat might induce the fusion of the adjacent Pt tiny species. Under the structural guidance of the rGO, 2D porous network structure was formed. Scheme 1 illustrates the whole process for the formation of the porous network structure.

SCHEME 1

SCHEME 1. Schematic illustration of the synthesis process of Pt PNSs.

To verify our speculation, we purged the system with N₂ for another 2 h after the reduction of Pt (NH₃)₄²⁺ to remove the adsorbed H₂ on metallic Pt (the products were denoted as Pt/rGO thereafter). Burning could not occur when exposing the N₂-purged Pt/rGO to air. Thus, it could be confirmed that it was the exothermic effect of the H₂-O₂ combination reaction that sparked the combustion of the rGO. Pt nanoparticles could be easily identified for the N₂-purged Pt/rGO during HAADF-STEM observation (Supplementary Figure S4A), as also demonstrated by the apparent diffractions assigned to fcc-Pt in the corresponding XRD pattern (Supplementary Figure S5A). High-resolution HAADF-STEM image reveal that there also existed large quantities of single atoms and clusters at the blank area of nanoparticles (insert in Supplementary Figure S4B). The coexistence of single atoms/clusters and nanoparticles were confirmed by XPS characterization (Supplementary Figure S5B). The Pt 4f_2/7 XPS spectrum could be deconvoluted into two sets of peaks, one centered at 71.88 eV and another at 73.18 eV. The former one could be assigned to Pt nanoparticles, while the latter one could be ascribed to single Pt atoms or clusters (Lai et al., 2019). It should be pointed that even the signal from Pt nanoparticles also deviated from the binding energy of metallic Pt (0), which might be aroused by the electron interaction among the nanoparticles and single atoms/clusters. It is reasonable to conclude that the Pt single atoms and clusters are highly active, which might be a key factor for the catalysis of the oxidation of the adsorbed H₂ and the rGO combustion.

Pure rGO without introduction of the Pt precursor was also treated under the same condition. As expected, the rGO did not burn as exposed to air after annealing in H₂/Ar at 200°C for 2 h. Even additional intense flame could not trigger the combustion of the rGO (Supplementary Figure S6). Contrastively, the combustion could be initiated for the N₂-purged Pt/rGO (Supplementary Figure S7). The distinctly different phenomena suggested that the Pt species also catalyzed the oxidation of rGO.

The loading amount of Pt was also a key parameter for the successful construction of the porous nanosheets. When the introduced H₂PtCl₆ was of 2 µM, self-ignition could not be observed for the as-prepared Pt/rGO when exposed to air after the H₂ annealing process. And the combustion could only occur within a very small range instead of transferring to the whole sample even with a flame to trigger the oxidation (Supplementary Figure S8). It is easy to accept that the lower loading amount of Pt on rGO would produce lower concentration of active sites. Thus, the rGO oxidation was only limited in the local area of the flame. The spontaneous combustion could not be observed for the as-prepared Pt/rGO until the amount of the added H₂PtCl₆ was raised up to 10 µM. However, the Pt nanoparticles instead of network-like structure dominated the products, and the residual rGO could be easily identified in this case (Supplementary Figure S9), which implied that the loading amount of Pt was still relatively low. Although the active site concentration was high enough to trigger the combustion of rGO, the larger interspecies distance was not sufficient for their interconnection and thus the formation of the network structure. Therefore, a quite high Pt loading is an essential factor for the successful construction of the network-like nanosheet structure.

Inspired by the unique network-like nanosheet structure, we investigated the catalytic performance of the as-prepared Pt PNSs towards the styrene hydrogenation reaction, which is recognized as a model hydrogenation reaction. For comparison, N₂-purged Pt/rGO hybrids and Pt dendritic structure with nanoparticles as building blocks were used as references. Supplementary Figure S10 demonstrated the diameter of the Pt nanoparticle building block was about 20 nm, similar to that of the segments in the Pt PNSs. However, the interconnection among the particle building blocks in the dendritic structures was far insufficient compared with the Pt PNSs. Figure 3A compares the conversions of styrene against reaction time. Pt PNSs presented an excellent hydrogenation performance with the completely conversion from styrene into phenylethane within 1 h. For the N₂-purged Pt/rGO catalysts, although the conversion rate in the initial 15 min was similar to that of Pt PNSs, it suffered a subsequent deterioration. Only ∼88% of the styrene was converted after 1 h. Using Pt nanoparticles as the catalyst, the conversion rate was greatly reduced, and the conversion percent only reached 48% after 1 h under the same reaction conditions. The catalytic results showed that the Pt PNSs exhibited outstanding catalytic hydrogenation activity.

FIGURE 3

FIGURE 3. (A) conversions of styrene hydrogenation as a function of reaction time over the different catalysts at room temperature and (B) recycling data for (blue) Pt PNSs and (pink) Pt nanoparticles.

To further evaluate the intrinsic activity of the catalysts, the initial (in the first 0.5 h) turnover frequency (TOF) values were calculated. The TOF value of Pt PNSs was 158.14 h⁻¹, which was nearly 3 times higher than that of Pt nanoparticles (TOF: 56.53 h⁻¹). In recent years, intensive efforts have been devoted to introducing another transition metal into noble metal catalysts system to modulate the electronic structure by ligand and/or stain effects to optimize the catalytic performance. Our results indicate that the activity of the Pt PNSs is comparable to the reported unsupported bimetallic catalysts (Supplementary Table S1), even superior to some Pt-M bimetal system (M = Fe, Co, Ni, etc.) (Wang et al., 2014; Wang et al., 2015). We believe both the high surface area of the nanosheet structure and the interconnected network feature contribute to the superior activity. The former guaranteed the high concentration of active sites, and the latter accelerated the charge transfer during the catalyzation.

Recycling experiments were carried out to examine the catalytic durability of Pt PNSs and Pt nanoparticles catalysts (Figure 3B). Remarkably, conversion decline could be hardly identified over Pt PNSs after five recycles, whereas for Pt nanoparticles, the conversion decreases from 48% to 40% after five runs. The contrasting results demonstrated that Pt PNSs possessed much higher durability relative to the Pt nanoparticles. It is known that nanostructured materials often suffer from aggregations during the catalytic process, which is a predominant factor leading to the activity decline of nanocatalysts (Cheng et al., 2016). In our case, Pt PNSs could be well dispersed in the solvent by slightly shaking the container, and no precipitate was identified during the entire catalytic reaction process. In contrast, strong ultrasonication was necessary to get a better dispersion of Pt nanoparticles, and it always sedimented rapidly even under continuous stirring. Supplementary Figure S11 shows the clearly contrastive dispersion state of the nanosheets and the nanoparticles after the catalytic reaction. Obviously, the two-dimensional structure impeded the Pt PNSs from aggregations. The good dispersibility and excellent anti-aggregation performance resulted in the excellent durability of the Pt PNSs.

Moreover, we also explored the catalytic hydrogenation performance of the as-prepared Pt PNSs towards other olefins (p-chlorostyrene, p-methylstyrene, and cyclohexene) and nitrobenzene. Figure 4 shows that the hydrogenation of all the four kinds of molecules could be completed within 90 min. Nitrobenzene was converted into aniline, and the hydrogenation of the olefins are on the non-aromatic unsaturated sites. The TOF values at 0.5 h were calculated as 90.47, 184.92, 136.17, and 86.63 h⁻¹ for p-chlorostyrene, p-methylstyrene, cyclohexene, and nitrobenzene, respectively. The competitive data demonstrated the dramatic hydrogenation catalytic ability of Pt PNSs towards unsaturated bond.

FIGURE 4

FIGURE 4. The plots of conversion versus time for the hydrogenation of (A) p-chlorostyrene, (B) p-methylstyrene, (C) cyclohexene, and (D) nitrobenzene over the Pt PNSs catalyst under room temperature and normal pressure with a H₂ balloon as the H₂ supplier.

Conclusion

In summary, self-supported Pt porous nanosheets were successfully achieved by an in situ fusion strategy using rGO as both energy supplier and structure-directing templates. Tiny Pt species were firstly uniformly loaded onto rGO by an ion-adsorption and subsequent in situ H₂ reduction process, which catalyzed the exothermic H₂-O₂ combination reaction as exposed to the air. The generated heat triggered the Pt-catalyzed rGO combustion, which in turn induced the in situ fusion of the Pt species into porous nanosheets under the 2D templating of rGO. The Pt PNSs exhibited great potential as hydrogenation catalyst by presenting outstanding catalytic hydrogenation activities towards nitrobenzene and different olefins such as styrene, p-chlorostyrene, p-methylstyrene, and cyclohexene. The styrene could be completely converted within 60 min under ambient conditions. The TOF value was as high as 158.14 h⁻¹, three times higher than Pt nanoparticles. The satisfying performance was attributed to the enhanced surface area and the interconnected structure, which ensured both rich active sites and accelerated charge transfer rate. Furthermore, the network-like 2D structure gave the catalyst good dispersibility and aggregation resistance, which endowed the Pt PNSs with excellent recyclability.

Data Availability Statement

The raw data supporting the conclusion of this article will be made available by the authors, without undue reservation.

Author Contributions

LG and D-FZ conceived and designed the experiments. T-WC was responsible for the synthesis and catalytic performance test, and D-WP performed the morphology and structure characterizations. J-XK analyzed the experimental data. T-WC prepared the draft, and LG and D-FZ proofread the draft.

Funding

This work was financially supported by the National Natural Science Foundation of China (21771014).

Conflict of Interest

The authors declare that the research was conducted in the absence of any commercial or financial relationships that could be construed as a potential conflict of interest.

Publisher’s Note

All claims expressed in this article are solely those of the authors and do not necessarily represent those of their affiliated organizations or those of the publisher, the editors, and the reviewers. Any product that may be evaluated in this article, or claim that may be made by its manufacturer, is not guaranteed or endorsed by the publisher.

Acknowledgments

The authors acknowledge the staff of the XAS beamlines of the Shanghai Synchrotron Radiation Facility for their support.

Supplementary Material

The Supplementary Material for this article can be found online at: https://www.frontiersin.org/articles/10.3389/fchem.2021.818900/full#supplementary-material

References

Cao, Z., Chen, Q., Zhang, J., Li, H., Jiang, Y., Shen, S., et al. (2017). Platinum-nickel alloy Excavated Nano-Multipods with Hexagonal Close-Packed Structure and superior Activity towards Hydrogen Evolution Reaction. Nat. Commun. 8, 15131. doi:10.1038/ncomms15131

PubMed Abstract | CrossRef Full Text | Google Scholar

Cheng, N., Stambula, S., Wang, D., Banis, M. N., Liu, J., Riese, A., et al. (2016). Platinum Single-Atom and Cluster Catalysis of the Hydrogen Evolution Reaction. Nat. Commun. 7, 13638. doi:10.1038/ncomms13638

PubMed Abstract | CrossRef Full Text | Google Scholar

Cheng, Q., Hu, C., Wang, G., Zou, Z., Yang, H., and Dai, L. (2020). Carbon-defect-driven Electroless Deposition of Pt Atomic Clusters for Highly Efficient Hydrogen Evolution. J. Am. Chem. Soc. 142, 5594–5601. doi:10.1021/jacs.9b11524

PubMed Abstract | CrossRef Full Text | Google Scholar

Chung, D. Y., Yoo, J. M., and Sung, Y.-E. (2018). Highly Durable and Active Pt-Based Nanoscale Design for Fuel-Cell Oxygen-Reduction Electrocatalysts. Adv. Mater. 30, 1704123. doi:10.1002/adma.201704123

PubMed Abstract | CrossRef Full Text | Google Scholar

Dong, J.-C., Su, M., Briega-Martos, V., Li, L., Le, J.-B., Radjenovic, P., et al. (2020). Direct In Situ Raman Spectroscopic Evidence of Oxygen Reduction Reaction Intermediates at High-index Pt(hkl) Surfaces. J. Am. Chem. Soc. 142, 715–719. doi:10.1021/jacs.9b12803

PubMed Abstract | CrossRef Full Text | Google Scholar

Ge, C., Wu, R., Chong, Y., Fang, G., Jiang, X., Pan, Y., et al. (2018). Synthesis of Pt Hollow Nanodendrites with Enhanced Peroxidase-like Activity against Bacterial Infections: Implication for Wound Healing. Adv. Funct. Mater. 28, 1801484. doi:10.1002/adfm.201801484

CrossRef Full Text | Google Scholar

Gong, M., Fu, G., Chen, Y., Tang, Y., and Lu, T. (2014). Autocatalysis and Selective Oxidative Etching Induced Synthesis of Platinum-Copper Bimetallic alloy Nanodendrites Electrocatalysts. ACS Appl. Mater. Inter. 6, 7301–7308. doi:10.1021/am500656j

PubMed Abstract | CrossRef Full Text | Google Scholar

Hao, Y., Yang, Y., Hong, L., Yuan, J., Niu, L., and Gui, Y. (2014). Facile Preparation of Ultralong Dendritic PtIrTe Nanotubes and Their High Electrocatalytic Activity on Methanol Oxidation. ACS Appl. Mater. Inter. 6, 21986–21994. doi:10.1021/am5047747

CrossRef Full Text | Google Scholar

Huang, X., Li, Y., Li, Y., Zhou, H., Duan, X., and Huang, Y. (2012). Synthesis of PtPd Bimetal Nanocrystals with Controllable Shape, Composition, and Their Tunable Catalytic Properties. Nano Lett. 12, 4265–4270. doi:10.1021/nl301931m

PubMed Abstract | CrossRef Full Text | Google Scholar

Jackson, C., Smith, G. T., Inwood, D. W., Leach, A. S., Whalley, P. S., Callisti, M., et al. (2017). Electronic Metal-Support Interaction Enhanced Oxygen Reduction Activity and Stability of boron Carbide Supported Platinum. Nat. Commun. 8, 15802. doi:10.1038/ncomms15802

PubMed Abstract | CrossRef Full Text | Google Scholar

Jang, S. W., Dutta, S., Kumar, A., Hong, Y.-R., Kang, H., Lee, S., et al. (2020). Holey Pt Nanosheets on NiFe-Hydroxide Laminates: Synergistically Enhanced Electrocatalytic 2D Interface toward Hydrogen Evolution Reaction. Acs Nano 14, 10578–10588. doi:10.1021/acsnano.0c04628

PubMed Abstract | CrossRef Full Text | Google Scholar

Jayakumar, S., Modak, A., Guo, M., Li, H., Hu, X., and Yang, Q. (2017). Ultrasmall Platinum Stabilized on Triphenylphosphine-Modified Silica for Chemoselective Hydrogenation. Chem. Eur. J. 23, 7791–7797. doi:10.1002/chem.201700980

PubMed Abstract | CrossRef Full Text | Google Scholar

Jiang, B., Li, C., Malgras, V., Imura, M., Tominaka, S., and Yamauchi, Y. (2016a). Mesoporous Pt Nanospheres with Designed Pore Surface as Highly Active Electrocatalyst. Chem. Sci. 7, 1575–1581. doi:10.1039/c5sc03779d

PubMed Abstract | CrossRef Full Text | Google Scholar

Jiang, B., Li, C., Tang, J., Takei, T., Kim, J. H., Ide, Y., et al. (2016b). Tunable-sized Polymeric Micelles and Their Assembly for the Preparation of Large Mesoporous Platinum Nanoparticles. Angew. Chem. Int. Ed. 55, 10037–10041. doi:10.1002/anie.201603967

PubMed Abstract | CrossRef Full Text | Google Scholar

Kim, O.-H., Cho, Y.-H., Kang, S. H., Park, H.-Y., Kim, M., Lim, J. W., et al. (2013). Ordered Macroporous Platinum Electrode and Enhanced Mass Transfer in Fuel Cells Using Inverse Opal Structure. Nat. Commun. 4, 2473. doi:10.1038/ncomms3473

PubMed Abstract | CrossRef Full Text | Google Scholar

Kim, Y.-T., Uruga, T., and Mitani, T. (2006). Formation of Single Pt Atoms on Thiolated Carbon Nanotubes Using a Moderate and Large-Scale Chemical Approach. Adv. Mater. 18, 2634–2638. doi:10.1002/adma.200502019

CrossRef Full Text | Google Scholar

Lai, W. H., Zhang, B. W., Hu, Z., Qu, X. M., Jiang, Y. X., Wang, Y. X., et al. (2019). The Quasi‐Pt‐Allotrope Catalyst: Hollow PtCo@single‐Atom Pt 1 on Nitrogen‐Doped Carbon toward Superior Oxygen Reduction. Adv. Funct. Mater. 29, 1807340. doi:10.1002/adfm.201807340

CrossRef Full Text | Google Scholar

Li, C., Chen, X., Zhang, L., Yan, S., Sharma, A., Zhao, B., et al. (2021). Synthesis of Core@Shell Cu‐Ni@Pt‐Cu Nano‐Octahedra and Their Improved MOR Activity. Angew. Chem. Int. Ed. 60, 7675–7680. doi:10.1002/anie.202014144

CrossRef Full Text | Google Scholar

Li, Q., Xu, P., Zhang, B., Wu, G., Zhao, H., Fu, E., et al. (2013). Self-supported Pt Nanoclusters via Galvanic Replacement from Cu2O Nanocubes as Efficient Electrocatalysts. Nanoscale 5, 7397–7402. doi:10.1039/c3nr02243a

PubMed Abstract | CrossRef Full Text | Google Scholar

Li, Y., Bastakoti, B. P., Malgras, V., Li, C., Tang, J., Kim, J. H., et al. (2015). Polymeric Micelle Assembly for the Smart Synthesis of Mesoporous Platinum Nanospheres with Tunable Pore Sizes. Angew. Chem. Int. Ed. 54, 11073–11077. doi:10.1002/anie.201505232

CrossRef Full Text | Google Scholar

Lin, F., Wang, K., Tang, Y., Lai, J., Lou, M., Huang, M., et al. (2018). Enhanced Bifunctional Fuel Cell Catalysis via Pd/PtCu Core/shell Nanoplates. Chem. Commun. 54, 1315–1318. doi:10.1039/c7cc08346g

PubMed Abstract | CrossRef Full Text | Google Scholar

Liu, G., Zhou, W., Ji, Y., Chen, B., Fu, G., Yun, Q., et al. (2021). Hydrogen-intercalation-induced Lattice Expansion of Pd@Pt Core-Shell Nanoparticles for Highly Efficient Electrocatalytic Alcohol Oxidation. J. Am. Chem. Soc. 143, 11262–11270. doi:10.1021/jacs.1c05856

CrossRef Full Text | Google Scholar

Liu, L., Pippel, E., Scholz, R., and Gösele, U. (2009). Nanoporous Pt−Co Alloy Nanowires: Fabrication, Characterization, and Electrocatalytic Properties. Nano Lett. 9, 4352–4358. doi:10.1021/nl902619q

PubMed Abstract | CrossRef Full Text | Google Scholar

Lu, P., Qiao, B., Lu, N., Hyun, D. C., Wang, J., Kim, M. J., et al. (2015). Photochemical Deposition of Highly Dispersed Pt Nanoparticles on Porous CeO2Nanofibers for the Water-Gas Shift Reaction. Adv. Funct. Mater. 25, 4153–4162. doi:10.1002/adfm.201501392

CrossRef Full Text | Google Scholar

Meng, C., Ling, T., Ma, T. Y., Wang, H., Hu, Z., Zhou, Y., et al. (2017). Atomically and Electronically Coupled Pt and CoO Hybrid Nanocatalysts for Enhanced Electrocatalytic Performance. Adv. Mater. 29, 1604607. doi:10.1002/adma.201604607

PubMed Abstract | CrossRef Full Text | Google Scholar

Michaelides, A., and Hu, P. (2001). Catalytic Water Formation on Platinum: A First-Principles Study. J. Am. Chem. Soc. 123, 4235–4242. doi:10.1021/ja003576x

CrossRef Full Text | Google Scholar

Pasricha, R., Bala, T., Biradar, A. V., Umbarkar, S., and Sastry, M. (2009). Synthesis of Catalytically Active Porous Platinum Nanoparticles by Transmetallation Reaction and Proposition of the Mechanism. Small 5, 1467–1473. doi:10.1002/smll.200801863

PubMed Abstract | CrossRef Full Text | Google Scholar

Song, S., Liu, X., Li, J., Pan, J., Wang, F., Xing, Y., et al. (2017). Confining the Nucleation of Pt to In Situ Form (Pt-Enriched Cage)@CeO2 Core@Shell Nanostructure as Excellent Catalysts for Hydrogenation Reactions. Adv. Mater. 29, 1700495. doi:10.1002/adma.201700495

PubMed Abstract | CrossRef Full Text | Google Scholar

Stein, A., Li, F., and Denny, N. R. (2008). Morphological Control in Colloidal crystal Templating of Inverse Opals, Hierarchical Structures, and Shaped Particles. Chem. Mater. 20, 649–666. doi:10.1021/cm702107n

CrossRef Full Text | Google Scholar

Tamaki, T., Kuroki, H., Ogura, S., Fuchigami, T., Kitamoto, Y., and Yamaguchi, T. (2015). Connected Nanoparticle Catalysts Possessing a Porous, Hollow Capsule Structure as Carbon-free Electrocatalysts for Oxygen Reduction in Polymer Electrolyte Fuel Cells. Energy Environ. Sci. 8, 3545–3549. doi:10.1039/c5ee02450a

CrossRef Full Text | Google Scholar

Tong, X., Zhang, J., Zhang, G., Wei, Q., Chenitz, R., Claverie, J. P., et al. (2017). Ultrathin Carbon-Coated Pt/Carbon Nanotubes: A Highly Durable Electrocatalyst for Oxygen Reduction. Chem. Mater. 29, 9579–9587. doi:10.1021/acs.chemmater.7b04221

CrossRef Full Text | Google Scholar

Wang, C., Lin, C., Zhang, L., Quan, Z., Sun, K., Zhao, B., et al. (2014). Pt3Co Concave Nanocubes: Synthesis, Formation Understanding, and Enhanced Catalytic Activity toward Hydrogenation of Styrene. Chem. Eur. J. 20, 1753–1759. doi:10.1002/chem.201301724

PubMed Abstract | CrossRef Full Text | Google Scholar

Wang, C., Lin, C., Zhao, B., Zhang, L., Kumbhar, A., Fan, G., et al. (2015). High-Indexed Pt3Fe Nanocatalysts and Their Enhanced Catalytic Performance in Dual Organic Reactions. Chemnanomat 1, 331–337. doi:10.1002/cnma.201500048

CrossRef Full Text | Google Scholar

Wang, C., Zhang, L., Yang, H., Pan, J., Liu, J., Dotse, C., et al. (2017). High-Indexed Pt3Ni Alloy Tetrahexahedral Nanoframes Evolved through Preferential CO Etching. Nano Lett. 17, 2204–2210. doi:10.1021/acs.nanolett.6b04731

PubMed Abstract | CrossRef Full Text | Google Scholar

Xu, Y., and Zhang, B. (2014). Recent Advances in Porous Pt-Based Nanostructures: Synthesis and Electrochemical Applications. Chem. Soc. Rev. 43, 2439–2450. doi:10.1039/c3cs60351b

PubMed Abstract | CrossRef Full Text | Google Scholar

Yan, H., Lin, Y., Wu, H., Zhang, W., Sun, Z., Cheng, H., et al. (2017). Bottom-up Precise Synthesis of Stable Platinum Dimers on Graphene. Nat. Commun. 8, 1070. doi:10.1038/s41467-017-01259-z

PubMed Abstract | CrossRef Full Text | Google Scholar

Yang, P., Yuan, X., Hu, H., Liu, Y., Zheng, H., Yang, D., et al. (2017). Solvothermal Synthesis of Alloyed PtNi Colloidal Nanocrystal Clusters (CNCs) with Enhanced Catalytic Activity for Methanol Oxidation. Adv. Funct. Mater. 28, 1704774. doi:10.1002/adfm.201704774

CrossRef Full Text | Google Scholar

Zeng, Y., Shao, Z., Zhang, H., Wang, Z., Hong, S., Yu, H., et al. (2017). Nanostructured Ultrathin Catalyst Layer Based on Open-Walled PtCo Bimetallic Nanotube Arrays for Proton Exchange Membrane Fuel Cells. Nano Energy 34, 344–355. doi:10.1016/j.nanoen.2017.02.038

CrossRef Full Text | Google Scholar

Zhu, J., Xu, L., Lyu, Z., Xie, M., Chen, R., Jin, W., et al. (2021). Janus Nanocages of Platinum‐Group Metals and Their Use as Effective Dual‐Electrocatalysts. Angew. Chem. Int. Ed. 60, 10384–10392. doi:10.1002/anie.202102275

CrossRef Full Text | Google Scholar