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REVIEW article

Front. Mater., 03 January 2022
Sec. Structural Materials
https://doi.org/10.3389/fmats.2021.792359

Mechanical Properties and Deformation Mechanisms of Heterostructured High-Entropy and Medium-Entropy Alloys: A Review

  • 1Nano and Heterogeneous Materials Center, School of Materials Science and Engineering, Nanjing University of Science and Technology, Nanjing, China
  • 2Department of Materials Science and Engineering, City University of Hong Kong, Hong Kong, China

Recently, heterostructured (HS) materials, consisting of hard and soft zones with dramatically different strengths, have been developed and received extensive attention because they have been reported to exhibit superior mechanical properties over those predicted by the rule of mixtures. Due to the accumulation of geometrically necessary dislocations during plastic deformation, a back stress is developed in the soft zones to increase the yield strength of HS materials, which also induce forward stress in the hard zones, and a global hetero-deformation induced (HDI) hardening to retain ductility. High-entropy alloys (HEAs) and medium-entropy alloys (MEAs) or multicomponent alloys usually contain three or more principal elements in near-equal atomic ratios and have been widely studied in the world. This review paper first introduces concepts of HS materials and HEAs/MEAs, respectively, and then reviewed emphatically the mechanical properties and deformation mechanisms of HS HEAs/MEAs. Finally, we discuss the prospect for industrial applications of the HS HEAs and MEAs.

Introduction

Heterostructured Materials

Metallic materials with outstanding mechanical properties, especially high strength and ductility, are widely used in many engineering fields such as transportation, spacecraft, and industrial manufacture (Bouaziz et al., 2013; He et al., 2017; Zhao and Jiang, 2018). For example, super strong metallic materials can significantly reduce the weight of transport vehicles, thus improving their energy efficiency (Zhao and Jiang, 2018). Therefore, the development of metallic materials with high strength and ductility is an unremitting research subject for material scientists (Gao et al., 2020). Nowadays, the challenge for the industrial application of metallic materials is that the strength of most metallic materials is limited and needs to be further improved to meet the industrial requirements. Considering the internal mechanism that affects the strength and ductility of metallic materials, the strength of metallic materials depends on the hindrance of dislocation motion, while the ductility depends on the ability of dislocation activity, such as dislocation generation, accumulation, and movement (Hughes et al., 2003; Meyers and Chawla, 2008). Therefore, one of the traditional strengthening strategies for high-strength materials is to produce nanostructured materials by grain refinement through severe plastic deformation, such as equal-channel angular pressing (ECAP) and high-pressure torsion (HPT) (Cao et al., 2018). According to the empirical Hall–Petch relationship and classic Taylor hardening model, the strength of metallic materials monotonically increases with reducing grain size and increasing dislocation density (Taylor, 1934; Hansen, 2004). The introduction of substantial grain boundaries and high density of dislocations is a powerful approach for blocking dislocation movement and thus significantly enhances the strength of metallic materials (He et al., 2017; Jiang et al., 2021a). Moreover, the introduction of precipitates and solute atoms to induce precipitation hardening and solid solution strengthening are also effective means of strengthening (Zhao et al., 2004; Li et al., 2015; Jiang et al., 2021a).

Unfortunately, these traditional methods of introducing obstacles, e.g., grain boundaries, dislocations, precipitation, and solute atoms, to improve strength inevitably limit the multiplication and accumulation of dislocations. According to the Hart’s theory (Hart, 1967) and the Considère criterion (Wei et al., 2004), higher dislocation storage capacity associated with dislocation multiplication and accumulation means higher strain hardening, which can help delay the onset of necking during plastic deformation and prolong ductility. Consequently, the enhancement of strength through the traditional strengthening mechanisms always leads to a degradation of ductility, which is referred to as the strength-ductility trade-off, as shown in Figure 1 (Wang et al., 2002; Ritchie, 2011; Wu et al., 2015; Shahmir et al., 2016). Actually, the strength-ductility trade-off has always been a problem in the materials science community, because good ductility is simultaneously required for high-strength materials to prevent catastrophic failure during service (Wang and Ma, 2004; Ma and Zhu, 2017). Over the centuries, engineers have been forced to choose either strength or ductile of metallic materials, not both as desired (Zhu and Li, 2010).

FIGURE 1
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FIGURE 1. Traditional strength–ductility trade-off relationship in pure (A) Ti and (B) Cu (Wang et al., 2002; Ritchie, 2011; Wu et al., 2015; Shahmir et al., 2016).

Previous efforts to resolve this trade-off problem have been focused on boundary engineering such as coherent twin boundaries (Lu et al., 2004; Lu K. et al., 2009; Gutierrez-Urrutia and Raabe, 2011) and phase boundaries (Byun et al., 2004); the associated strengthening mechanisms are known as twinning-induced plasticity (TWIP) effect (Gutierrez-Urrutia and Raabe, 2011) and transformation-induced plasticity (TRIP) effect (Byun et al., 2004), respectively. TWIP and TRIP effects generate additional boundaries in-situ for dislocation storage and significantly reduce the effective grain size, resulting in secondary strain hardening (Byun et al., 2004; Gutierrez-Urrutia and Raabe, 2011, 2012; Zhu et al., 2012; Su et al., 2019) and enhanced ductility. Moreover, the preexisting twin boundaries can act as both obstacles to dislocation movement and pathways to dislocation slip and cross-slip, simultaneously enhancing the strength and ductility (Ming et al., 2019). However, there are still shortcomings: 1) their strength may reach a limit with reducing boundary spacing to nanometers (Lu L. et al., 2009; Li et al., 2010); 2) both the TWIP and TRIP effects are confined in materials with low stacking-fault energy (SFE) (Grässel et al., 2000; An et al., 2012); and 3) the yield strength is low, and a further increase in yield strength will still lead to a degradation of ductility (Bouaziz et al., 2011).

More recently, a novel concept of heterostructured (HS) materials has attracted increasing attention due to their superior strength-ductility combination (Zhu et al., 2020), as shown in Figure 2. After years of development, there are several types of HS materials, including bimodal grain structures (Wang et al., 2002; Han et al., 2005; Zhao et al., 2008), heterogeneous lamella structures (HLSs) (Wu et al., 2015; Li J. et al., 2019), gradient grain structures (Wu X. et al., 2014; Lu, 2014; Wei et al., 2014; Qin et al., 2019), laminate structures (Qin et al., 2019), dual-phase structures (Li et al., 2016), harmonic structures (Sawangrat et al., 2014), and metal matrix composites (Choudhuri et al., 2018; Liu et al., 2018). What they have in common is that all these HS materials consist of very diverse microstructures: the mixture of hard and soft zones with dramatically different strengths (Wu and Zhu, 2017). The strength difference between the hard and soft zones can be achieved by adjusting the crystal structures (Zhao et al., 2017), defect concentration (Yang M. et al., 2018; Ming et al., 2019), and just the grain size ranging from nanometers to millimeters (Wang et al., 2002). For example, a simple thermomechanical treatment of Cu skillfully avoids the traditional strength–ductility paradox through the bimodal grain structures, in which a small amount of micron-size grains randomly distribute in nanocrystalline (NC) and ultrafine grain (UFG) matrices (Wang et al., 2002).

FIGURE 2
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FIGURE 2. Normalized yield strength versus normalized uniform tensile strain of metallic materials with homogeneous (banana-shaped shaded regions) and heterogeneous (solid circle) microstructures. Image adopted from Ref. Ma and Zhu (2017). with permission from Elsevier.

The key concept for HS materials to increase strength while retaining ductility is to enhance the strain hardening ability and thus in turn delay plastic instability. As shown in Figure 3, HS materials experience a unique deformation process during tension, compared to homogeneous materials. Once loaded, both the hard and soft zones start elastic deformation first (Wu and Zhu, 2017). After the simultaneous elastic deformation stage, the soft zones begin plastic deformation, while the hard zones are still in elastic status. Constraints resulting from the hard zones will be imposed on the soft zones to inhibit its free plastic deformation. Consequently, geometrically necessary dislocations (GNDs) will be generated and pile up against zone interfaces due to mechanical incompatibility of hard and soft zones. The induced GNDs can produce long-range internal stress, i.e., back stress, in soft zones to offset the applied shear stress, making them appear stronger to withstand higher shear stress (Wu and Zhu, 2017; Zhu and Wu, 2019). Meanwhile, the stress concentration caused by dislocation piling up at zone interfaces induces forward stress in hard zones to make hard zones appear weaker (Zhu and Wu, 2019). As evidenced by the increasing works in recent years, the hetero-deformation-induced (HDI) hardening effect (Zhu and Wu, 2019), induced by the interaction between back stresses and forward stresses, exert extra strain hardening in HS materials and thus enhanced the yield strength and ductility (Zhu and Wu, 2019; Liu et al., 2020). With the flow stress further increasing, the hard zones start yielding to accommodate the stress concentration (Zhu and Wu, 2019). Finally, both the hard and soft zones are deforming plastically, while the soft zones bear higher plastic strain, leading to a strain partitioning. However, the continuity of zone boundaries requires the same plastic strain for adjacent soft and hard zones. Thus, strain gradient is necessary near the zone interface to accommodate the strain partitioning (Zhu and Wu, 2019). There is clear evidence that rapid accumulation of GNDs in the hetero-zone boundary-affected regions (HBARs) (Wu and Zhu, 2021) will result in a significant HDI effect at low strain (>4.5%), while dislocation hardening dominates at higher strain levels (Fang et al., 2020).

FIGURE 3
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FIGURE 3. The plastic deformation process of heterogeneous materials during tension. Image adopted from Ref. Wu and Zhu (2017) with permission from Taylor and Francis.

There is no doubt that the HS materials have microstructural requirements for the optimum mechanical properties, such as volume fraction of soft zones, interface spacing, and distribution of hard zones (Ma et al., 2016; Huang et al., 2018; Liu et al., 2020). For instance, thinner interface spacing results in a synergetic improvement of strength and ductility in copper/bronze laminates (Ma et al., 2016). In the vicinity of zone boundaries, the accumulation of GNDs results in a (HBAR) of a few micrometers. The optimum spacing is that the adjacent HBARs begin to overlap to maximize the hardening capacity, after which the strength–ductility trade-off occurred (Huang et al., 2018). Likewise, the volume fractions of the gradient structure have a significant influence on the strength and ductility of gradient structural pure copper (Yang et al., 2015). The optimum gradient structure volume fraction of 0.08–0.1 produces an excellent strength–ductility combination (Yang et al., 2015). Moreover, the strength–ductility combination in HS materials can be optimized by adjusting the volume and density of boundaries between the hard and soft zones to maximize the strain/stress partitioning and strain gradient between the zones (Ma and Zhu, 2017; Wu and Zhu, 2017). For guidance of material design, Zhu et al. have made numerous efforts to systematically study the effectiveness of various HS structural materials (Wu and Zhu, 2017). With regard to the gradient structures, the dynamic migration of interfaces from the coarse-grained core to the nanograined layer makes the successive deformation over the sample and suppresses strain localization (Lu, 2014). However, the limited interface density of gradient structures weakens the density of accumulated dislocation and thus their capability of back-stress work hardening (Wu X. et al., 2014; Lu, 2014). For bimodal structures (Wang et al., 2002; Han et al., 2005; Zhao et al., 2008), the problem that still exists is that the limited interface density cannot effectively maximize the HDI stress strengthening potential. For dual-phase steels with hard zones embedded in the soft matrix, the continuous soft matrix induces high ductility but relatively low yield strength (Calcagnotto et al., 2011; Li et al., 2016). For harmonic structures with soft zones surrounded by hard zones, strength can be further improved by tuning the interface spacing and volume fraction of hard zones (Sawangrat et al., 2014). In contrast, the heterogeneous lamella structures (HLSs) present the best strength–ductility combination (Wu et al., 2015). By asymmetric rolling and partial recrystallization, HLS Ti featured with soft lamellae zones embedded in the hard lamella matrix was architected (Wu et al., 2015). The high constraint of the soft zones by the hard matrix renders high strength, and the strong strain partitioning also renders extraordinary strain hardening and consequent increased ductility (Wu et al., 2015).

High Entropy Alloy

While alloys of dilute solid solutions are still being researched, there is a continuous surge worldwide in developing alloys of concentrated solid solutions—medium-entropy alloys (MEAs) and high-entropy alloys (HEAs) (Zhang et al., 2014; Gludovatz et al., 2016; Ding et al., 2019). Different from traditional dilute solid solution alloys with only one principal element and some other elements in minor quantity, the MEAs/HEAs are nominally equiatomic or near-equimolar multicomponent alloys typically with three or more principal elements. This concept, first pointed out by Yeh et al. (Yeh et al., 2004) and Cantor et al. (Cantor et al., 2004), results in a paradigm shift in the alloy design concept toward the unexplored center region of the phase diagram and broadens the field of scope on alloy design (Miracle and Senkov, 2017; Sathiyamoorthi and Kim, 2020; Jiang et al., 2021b). MEAs are composed of three or more principal elements with near-equal atomic percentages (Gludovatz et al., 2016), and their configurational entropies are in the range of 1–1.5R (R = 8.314 mol−1∙K−1). HEAs are comprised of five or more principal elements with near-equal atomic percentages (Zhang et al., 2014), and their configurational entropies are larger than 1.5R (Miracle et al., 2014). Due to the high mixing entropy associated with a disordered solution of several elements, both MEAs and HEAs can form stable single-phase solid solutions, in which atoms with different sizes are homogeneously distributed in the ideal situation. However, enthalpic interactions unavoidably change the local chemical order (LCO) in MEAs and HEAs, leading to short-range ordering (SRO) and/or incipient concentration waves. Notwithstanding the uncertainty of LCO, a mixture of atoms of diverse sizes results in severe lattice distortion, presenting frequent short-range resistance to dislocation slip, in this manner to maximize the solid solution strengthening effect in MEAs and HEAs (Yeh et al., 2007; Tsai et al., 2013; Li Q.-J. et al., 2019; Jiang et al., 2021c). Thus, the MEAs/HEAs exhibit remarkable properties and spark a lot of research interests among materials scientists.

After years of research, there are four unique core effects summarized in HEAs, which are relatively unusual in conventional alloys: high entropy effect, sluggish diffusion effect, lattice distortion effect, and cocktail effect (Tsai et al., 2013; Tsai and Yeh, 2014; Song et al., 2017; Li et al., 2021). These effects are closely related to the phase stability, microstructures, and mechanical properties of MEAs/HEAs. Nevertheless, the high entropy effect is still debatable. In some research, the high mixing entropy was confirmed that can stabilize MEA/HEA solution phases rather than intermetallic and complex phases (Yeh et al., 2004; Tsai and Yeh, 2014). Works on CoCrFeNi HEA argue the absence of long-range ordering, indicating the formation of really disordered solid solutions (Lucas et al., 2012). However, both first-principle density functional theory (DFT)-based simulations and direct experimental observation also verify the presence of LCO in MEAs/HEAs (Ding et al., 2018; Li Q.-J. et al., 2019; Chen et al., 2021).

Hitherto, it has been broadly demonstrated that both MEAs and HEAs have extraordinary mechanical properties over a wide temperature range from elevated to cryogenic temperatures (Jo et al., 2017; Yang M. et al., 2019; Gao et al., 2019; Jiang et al., 2021c). For instance, almost all the traditional high-temperature alloys tend to lose both strength and ductility at high temperatures, while equiatomic NbMoTaW and VNbMoTaW refractory HEAs sustain high strength at elevated temperatures more than 1,000°C (Senkov et al., 2011). At room and cryogenic temperatures, researchers attempt to introduce deformation substructures of stacking faults, deformation twins, and hexagonal close-packed (HCP) phase into MEAs/HEAs by tailoring the SFE (Zaddach et al., 2013). As evidenced by first-principle electronic structure calculations, the SFEs of MEAs/HEAs can be tuned by tailoring the atomic proportions of individual components. For example, the SFE of CrMnFeCoNi HEA is determined as approximately 25.5–27.3 mJm−2, and that of Cr26Mn20Fe20Co20Ni14 HEA is as low as 3.5 mJm−2 (Zaddach et al., 2013). These induced deformation substructures contribute to improve the strain hardening ability and leads to high tensile strength and ductility. As exemplified, Li et al. designed a metastable Fe50Mn30Co10Cr10 HEA to induce interface hardening and dynamic transformation induced hardening effects and consequently overcome the traditional strength–ductility trade-off (Li et al., 2016). Moreover, the prototypical Cantor alloy (CoCrFeMnNi) and its variants and subsets such as Cr26Mn20Fe20Co20Ni14 HEA, CoCrFeNi HEA, and CoCrNi MEA are proven to possess remarkable cryogenic properties such as enhanced strength and ductility and superior fracture toughness, which are ascribed to their low SFEs and high propensity for twinning and phase transformation (Zaddach et al., 2013; Gludovatz et al., 2014; Gludovatz et al., 2016). More recently, LCO is confirmed to have significant influence on the SFE, which results in the increase of the SFE with the increase of the LCO (Ding et al., 2018). Furthermore, LCO affects the critical stress for dislocation slip and dislocation storage capacity in the bulk material, thus in turn affecting strain hardening in single phase MEAs/HEAs (Jiang et al., 2021c). The dislocation slip in MEAs/HEAs has to continuously overcome the activation barriers created by LCO. In turn, MEAs/HEAs with LCO may exhibit higher strength.

Unfortunately, the yield strength of MEAs/HEAs is relatively low, especially for those with single-phase face-centered cubic (FCC) structures, which will greatly limit their industrial application prospects. Traditional methods to improve yield strength, such as solid solution strengthening (He et al., 2020), precipitation strengthening (Ming et al., 2017), and grain boundary strengthening (Sathiyamoorthi et al., 2019b), inevitably cause a degradation of ductility. The simple MEAs/HEAs are not exempted from the dilemma of the strength–ductility trade-off. Therefore, based on the novel alloy design concept with multi-principal elements, it is anticipated to achieve superior mechanical properties by further tuning the microstructures of HEAs/MEAs to fabricate HS structures. This review paper introduces the concept of HS MEAs/HEAs and then emphatically overviews the mechanical properties and deformation mechanisms of HS MEAs/HEAs. Finally, we discuss the prospects and industrial applications of the HS MEAs/HEAs.

HS HEAs

Heterogeneous Gradient Structure

A typical gradient structure is featured by a microstructural gradient at a macroscopic scale, which shows gradually increased grain size, increased substructure size, and reduced defect density from the surface layer to the interior layer (Wu X. L. et al., 2014; Yang et al., 2016; Bian et al., 2017; Pan et al., 2021). Due to the existing grain size gradient and/or the defect density gradient, the gradient structures possess prominent mechanical incompatibility, thus in turn leading to a macroscopic strain gradient and complex stress state, which needs to be accommodated by accumulated GNDs. The gradient structural materials usually show superior strength–ductility synergy, which are ascribed to either mechanically driven grain growth of the unstable nanostructured surface layer (Fang et al., 2011) or extra strain hardening caused by the presence of the strain gradient combined with the stress state change for the mechanically stable gradient structure (Wu X. et al., 2014; Wu X. L. et al., 2014; Bian et al., 2017). The intrinsic synergetic strengthening effect induced by the gradient structure is even much higher than the sum of the strength of individual layers, as calculated by the rule of mixtures (Wu X. L. et al., 2014).

The common methods for producing gradient materials include surface mechanical grinding treatment (SMGT) (Li et al., 2008), surface mechanical rolling treatment (SMRT) (Chen et al., 2020), surface mechanical attrition treatment (SMAT) (Yang et al., 2016), and rotationally accelerated shot peening (RASP) (Hasan et al., 2019; Liang et al., 2020). However, these surface treatment techniques produce only thin nanostructured surface layers with a depth of a few hundred micrometers (∼200 μm) along the thickness direction of materials. In contrast, torsion, especially the HPT process, can produce larger-scale gradient structures along the diameter of the samples (Cao et al., 2011; Cao et al., 2014).

RASP was used to prepare gradient structural CoCrFeNiMn HEA (Hasan et al., 2019). Along the thickness direction, there exist gradient microstructures (Figure 4), such as gradients in twin and dislocation densities, and hierarchical nanotwin, which contribute to the strain hardening capability and mechanical properties (Hasan et al., 2019). Compared to the coarse grain (CG), the CoCrFeNiMn HEA with gradient structures (RASP1) shows enhanced strength (418 MPa) and ductility (45%) (Figure 4) (Hasan et al., 2019). However, an appropriate gradient structure profile is essential for the effective improvement of mechanical properties. Simultaneously enhanced strength and ductility can be realized in a gradient structure with an undeformed core sandwiched between two thin deformed surface layers (RASP1), while the fully deformed gradient structure profile (RASP3) will double the yield strength but sacrifice ductility (Hasan et al., 2019). This is due to the higher strain gradient in the gradient samples with the thin gradient structure profile, thus in turn promoting the generation and accumulation of GNDs to enhance the yield strength and strain hardening.

FIGURE 4
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FIGURE 4. (A) Gradient microstructures of CG, RASP1, and RASP3 samples along depths from the surface. (B) Engineering stress–strain curves for CG, RASP1, and RASP3 samples. Insets are the 3D surface topography for RASP1 and RASP3 after tensile deformation. Image adopted from Ref. Hasan et al. (2019) with permission from Elsevier.

Gradient structures produced by SMRT are closely related to the processing passes, in which the depth of the surface gradient layer increases with increasing SMRT passes. For the (Fe40Mn40Co10Cr10)96.7C3.3 HEA with a gradient structure, enhanced strength (from 429 to 765 MPa) together with considerable ductility (20.5%) is achieved, due to the high HDI hardening (Chen et al., 2020). The gradient structure containing dislocations and twins produces multiaxial stress state and strain gradient under tensile deformation, which contributes to the accumulation of GNDs, leading to the improvement of strength higher than the prediction of the rule of mixture.

Cyclic dynamic torsion (CDT) processing was used to obtain a gradient microstructural Al0.1CoCrFeNi HEA (Chen et al., 2019a; Chen et al., 2019b). Along the radial direction, grain size gradually decreases from CG (∼130 μm) at the center to fine grain (FG, ∼8 μm) at the surface layer, as shown in Figure 5. Moreover, numerous deformation structures, such as deformation twins, dislocations, and microbands, form due to the torsional strain. The gradient structure results in a gradient distribution of hardness, which decreases from 3.4 GPa in surface layers to 2.6 GPa at the center (Chen et al., 2019a). A combination of high yield strength (850 MPa) and ductility (19%) indicates the important role of gradient microstructures (Chen et al., 2019b). More recently, Pan et al. designed a novel gradient nanoscaled dislocation–cell structures in Al0.1CoCrFeNi HEA, which lead to enhanced strength (539 MPa) and little sacrificed ductility (42.6%) (Pan et al., 2021). Numerous low-angle dislocation cells provide nucleation sites for the formation of stacking faults and deformation twins, thereby contributing to extra strengthening, work hardening, and ductility (Pan et al., 2021).

FIGURE 5
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FIGURE 5. A schematic diagram of the gradient microstructural Al0.1CoCrFeNi HEA after DT processing, showing coarse grain area, intermediate area, and the fine grain area along the radial direction (Chen et al., 2019b; Mao et al., 2021).

Asymmetric rolling (ASR) followed by annealing is a novel strategy for producing CoCrFeMnNi HEA with gradient microstructures (Han et al., 2018). Different from the homogeneous structures achieved by symmetric rolling and annealing treatment, ASR and subsequent annealing processing produce a gradient structure. The surface layers contain UFGs (∼500 nm), while the center consists of FGs (∼2 μm) (Han et al., 2018). The combined effects of fine-grain strengthening and HDI hardening induced by the gradient microstructure give rise to a superior combination of strength (930 MPa) and ductility (42%).

During the tensile deformation of gradient structures, elastic–plastic deformation occurs immediately after the initial elastic deformation between the center CG regions and the gradient surface layer, thus in turn resulting in an elastic–plastic interface. As the deformation continues, the grains in the inner gradient layer gradually reach the yielding state and begin to deform plastically, leading to the dynamic movement of the elastic–plastic interface toward the surface. Due to the mechanical incompatibility between the center CG regions and the gradient surface layer, they significantly constrain each other during tensile deformation (Yang et al., 2015; Li et al., 2017). The CG core is subjected to tensile stresses laterally, while the gradient surface layer is subjected to compressive stresses along the gradient direction. These biaxial stress states can effectively activate more slip systems and improve the dislocation activities. Moreover, the mutual constraint between the central CG region and the gradient layer during the plastic deformation results in strain gradients near the interfaces to sustain the strain continuity, causing the generation and accumulation of GNDs at the interface. Some surface treatment processes, e.g., SMAT and SMRT, will also introduce the compressive stress, developing multiaxial stress states (Moering et al., 2016). The combined effect of the piling-up of GNDs and multiaxial stress states results in the superior strength–ductility combination in gradient structural materials (Table 1).

TABLE 1
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TABLE 1. List of the processing steps (P), yield strength (YS), ultimate tensile strength (UTS), and uniform elongation (UE) of MEAs/HEAs reported with gradient structure. AN—annealing; EP-USR—electropulsing-assisted ultrasonic surface rolling; SP—shot peening.

It has been substantiated that there exist optimal gradient thickness condition and microstructures within the gradient layer to optimize the strain hardening capacity and mechanical properties. Hasan et al. (Hasan et al., 2019) used different RASP parameters to produce a series of gradient structural CoCrFeNiMn HEAs with different gradient structural profiles. This accordingly results in different mechanical properties. Among the gradient structural CoCrFeNiMn HEAs, samples subjected to more severe deformation exhibit an obvious fine-grained layer, while those subjected to mild deformation only exhibit TBs, high-angle grain boundaries, and low-angle grain boundaries distributed along the gradient direction (Hasan et al., 2019). The former shows the dramatic improvement of yield strength but scarified ductility, while the latter shows the simultaneously enhanced strength and ductility (Figure 4). This is attributed to the optimal gradient structures of a sandwich structure with a CG core and a thin layer of gradient structure on each side of the surface, improving mechanical properties due to the hierarchical twin structures in the gradient structural layers and the prominent strain gradient induced during the subsequent tensile deformation (Hasan et al., 2019). Besides, the surface treatment processes and the geometry of the tensile samples will lead to the difference in stress state and thus in turn influence the mechanical properties of the materials with gradient structures (Moering et al., 2016). For example, the SMAT and RASP processes can produce rod and flat samples, respectively. For the former, the ductile core is fully confined by the hard-outer surface and subjected to complex stress states, while for the latter, the ductile core is not confined in the lateral surface and subjected to biaxial stress states (Hasan et al., 2019; Chen et al., 2020).

Heterogeneous Grain Structure

“Smaller is stronger” means that grain refinement from CG to nano-grain (NG) results in extreme improvement in strength for conventional materials. However, low ductility has always been a problem for NG materials. Scientists are always looking for materials that have both the strength of NG and the ductility of CG. Recently, a heterogeneous material with bimodal and/or multimodal grain structures is a novel material design strategy to unite the advantages of both CG materials and NG materials, which present high strain hardening rate and superior strength and ductility combination (Wang et al., 2002).

Inspired by this concept, many strategies are explored to produce bimodal structural materials (Table 2). Both bimodal Fe30Co30Ni30Ti10 MEA and Fe25Co25Ni25Al7.5Cu17.5 HEA produced by mechanical alloying and following spark plasma sintering exhibit high compressive strength (>1.7 GPa) and enhanced plasticity, as compared to their CG counterparts (Fu et al., 2016; Fu et al., 2018). The combined effect of local temperature gradient in SPS processing and sluggish diffusion effect of MEAs/HEAs results in the inhomogeneous grain size, where the Fe30Co30Ni30Ti10 MEA consists of CGs (>1 μm) and NGs and the Fe25Co25Ni25Al7.5Cu17.5 HEA is comprised of NGs and UFGs (>200 nm) (Olevsky and Froyen, 2009; Tsai et al., 2013). HPT followed by annealing processing successfully produces bimodal microstructures in CoCrNi MEA (Sathiyamoorthi et al., 2019b; Schuh et al., 2019). Annealing parameters such as temperature and time play an important role in the ratio of bimodal grains and thus in turn influence the mechanical properties. For the CoCrNi MEA annealed at 500°C/100 h, the mixture of NG and FG structures gains the ultra-high strength (1,500 MPa) and decent ductility (10%) combination (Schuh et al., 2019). By contrast, Sathiyamoorthi et al. (Sathiyamoorthi et al., 2019b) doubled the ductility (24%) of CoCrNi MEA with comparable strength (1,580 MPa) via HPT and followed annealing processing (600°C/1 h). Bimodal grain structures comprised of UFGs and FGs are responsible for the superior strength–ductility synergy. This observation indicates that the bimodal grain structure with UFGs and FGs seems to be better than that with NGs and FGs.

TABLE 2
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TABLE 2. List of the heterogeneous structures (H) and mechanical properties of MEAs/HEAs reported with heterogeneous grain structure. “-” represents the compressive test.

More strikingly, material design strategies for fabricating three-level heterogeneous grain structures, characterized by mixture of NGs, UFGs, and FGs, are successfully controlled (Table 2). Through partial recrystallization, Yang et al. (Yang M. et al., 2018) produced a HS CoCrNi MEA with a large span of grain size from NG to FG, imparting gigapascal yield strength (1,150 MPa) and high ductility (22%). Similarly, the CoCrFeNiAl0.1 HEA with multiscale grains was produced by cold-rolling and intermediate temperature annealing, which is featured by three types of grains consisting of stretched grains (∼20 μm), deformed grains (1–20 μm), and recrystallized grains (0.2–5 μm) (Wu S. W. et al., 2019). The thermomechanical treatments induced a difference in grain sizes, and dislocation density leads to a superior combination of yield strength (711 MPa) ductility (30.3%) (Wu S. W. et al., 2019).

According to the “smaller is stronger,” NGs and/or UFGs in either bimodal or multimodal MEAs/HEAs serve as hard zones, while CGs serve as soft zones. Such HS materials present extra strain hardening ability, attributing to the generation and accumulation of GNDs to accommodate the strain gradient at zone interface (Wang et al., 2002). Moreover, partitioning of stress and strain comes into being at the zone interface, inducing a high stress concentration upon plastic deformation. Such stress concentration will achieve the critical resolved shear stress (CRSS) for twinning and generate twinned NGs, which in turn results in greater inhomogeneity (Yang M. et al., 2018). Significant HDI hardening effects together with the TWIP effects result in the superior strength–ductility synergy.

HLS

The HLS is featured by the soft micro-grained lamellae embedded in the hard UFG/NG lamella matrix (Figure 6). This material design strategies can also effectively unite the advantages of both CG materials and nanostructured materials to achieve excellent mechanical properties. Wu et al. (Wu et al., 2015) produced an HLS Ti, which presents an unprecedented property combination: as strong as UFG metals and as ductile as CG metals (Wu et al., 2015). HDI stress results in the unusual high strength, while HDI hardening and dislocation hardening lead to the high ductility (Wu et al., 2015).

FIGURE 6
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FIGURE 6. Schematics of the lamella structure with elongated soft coarse-grained domains embedded in an ultrafine-grained matrix. Image adopted from Ref. Wu and Zhu (2017) with permission from Taylor and Francis.

For fabricating the HLSs, some approaches are typically employed, such as powder metallurgy with different size particles and asymmetrical rolling followed by annealing to obtain recrystallization with laminar distribution (Wu et al., 2015; Huang et al., 2017). Zhang et al. (Zhang et al., 2018; Zhang et al., 2019) successfully produced two kinds of MEAs with HLSs through thermomechanical processing (rolling and annealing). After cold rolling, numerous deformed structures, such as deformation bands, shear bands, and microbands, are formed, which depends on the original grain size (Zhang et al., 2019). After subsequent annealing, these deformed structures evolve into different annealing structures, forming HLSs. Partial recrystallization occurs to form recrystallized grains with sizes between 3 and 7 μm in the shear bands due to the high dislocation density (Zhang et al., 2019), while some UFGs with sizes less than 1 μm form in the large deformation bands (Zhang et al., 2019). The difference in the fraction of precipitates between the large deformation bands and shear bands has great influence on the behavior of recrystallization and grain growth. With increasing annealing time, the recrystallization and grain growth in large deformation bands occur, while these behaviors are much slower in shear bands due to the much more precipitate-induced Zener pinning effect (Zhang et al., 2018; Zhang et al., 2019). Thus, the rolling and subsequent annealing process results in the nonuniform grain size and the formation of the HLSs comprising of a UFG-FG lamella structure or FG-CG lamella structure (Zhang et al., 2019). The HS structure leads to a good combination of strength and ductility compared to simple FG and CG samples (Zhang et al., 2018).

The key advantage of materials with HLSs is the enhanced strain hardening ability (Wu et al., 2015; Wu and Zhu, 2017), which can prevent the early onset of necking (Hart, 1967). Due to the distribution of soft and hard lamella structures, corresponding to the CG and UFG grains, lots of GNDs are introduced to accommodate the strain gradients in order to avoid the formation of voids during the loading process. UFG lamellae with higher yield strength surround and constrain the soft CG lamellae, leading to the accumulation and block of dislocations in the CGs. Thus, yielding occurs in CG lamellae first due to the higher resolved shear stress from dislocation pile-ups at the CG/UFG interface (Eshelby et al., 1951). Pile-ups of GNDs will also induce the long-range back stress, which resists the movement of dislocations in the CG lamellae and thus enhance strain hardening (Wu et al., 2015). With further increase in tensile load, the UFG lamellae begin plastic deformation, and hence the overall strength is enhanced by the HDI stress. The MEAs/HEAs with HLSs present remarkable mechanical properties, as shown in Table 3.

TABLE 3
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TABLE 3. List of the heterogeneous structures and mechanical properties of MEAs/HEAs reported with HLSs.

Heterogeneous Phase Structure

Eutectic structure

The approach of introducing two phases has been successfully used in MEAs/HEAs such as eutectic HEAs (Lu et al., 2014; Gao et al., 2017). Generally, the eutectic HEAs consist of alternate layers of soft FCC and hard B2 phases (Baker et al., 2016; Wang et al., 2016; Jin et al., 2018b; a; Jin et al., 2019; Wu Q. et al., 2019; Dong et al., 2020), which possess a dramatic difference in strength and hardness. Like conventional dual-phase steel, the eutectic HEAs are typical HS materials that present a superior combination of strength and ductility, as shown in Table 4.

TABLE 4
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TABLE 4. A collection of reported HEAs with completely eutectic microstructure.

Among the numerous eutectic HEAs, AlCoCrFeNi2.1 is the most widely investigated. Through different thermomechanical treatments, such as warm-rolling, cryo-rolling, cold-rolling, and subsequent annealing process, the heterogeneous microstructures of the AlCoCrFeNi2.1 eutectic HEA can be further tuned to achieve superior mechanical properties, as shown in Figure 7 (Bhattacharjee et al., 2018; Shukla et al., 2018; Reddy et al., 2019; Shi et al., 2019). Warm-rolled (750°C) AlCoCrFeNi2.1 eutectic HEA presents a heterogeneous microstructure characterized by the mixture of the retained lamellar region of B2 and FCC with B2 phases inside the FCC lamellar and non-lamellar regions consisting of disordered FCC, precipitated B2, and Cr-rich sigma phases (Reddy et al., 2019). The heterogeneous microstructures produced by cold-rolling and cryo-rolling and subsequent annealing are quite different. Through cold-rolling and following annealing, the AlCoCrFeNi2.1 eutectic HEA consists of hard and soft lamellae with recrystallized grains and substantial B2 precipitates (Shukla et al., 2018; Shi et al., 2019). The cryo-rolling and subsequent annealing result in an HLS comprising of fine alternative FCC and B2 lamellar structures and coarse non-lamellar regions (Bhattacharjee et al., 2018). The fine FCC and B2 lamellae are filled with recrystallized UFGs (∼200–250 nm) and low-angle grain boundaries, respectively, while the coarse non-lamellar regions are featured by ultrafine FCC (∼200–250 nm), coarse recrystallized FCC grains, and coarse uncrystallized B2 phase (∼2.5 μm) (Bhattacharjee et al., 2018). However, the Cr-rich sigma phases observed in the warm-rolled (750°C) AlCoCrFeNi2.1 eutectic HEA were not observed in the HEA processed by cold-rolling and cryo-rolling.

FIGURE 7
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FIGURE 7. Eutectic lamellate structures in AlCoCrFeNi2.1 HEA by thermomechanical treatments. (A) Cryo-rolling and annealing (Bhattacharjee et al., 2018), (B) cold-rolling and annealing (Shi et al., 2019). Image adopted with permission under the terms of Creative Common License.

Despite of the difference in thermomechanical treatments, all these remarkable HS AlCoCrFeNi2.1 eutectic HEAs with high lamella density obtain an outstanding strength–ductility combination with gigapascal yield strength and ductility of over 15% (Table 5). This is attributed to the constraint effect originated from the lamellae. Upon plastic deformation, the hard B2 lamellae and the intergranular B2 precipitates provide rigid deformation constraint to FCC lamellae, resulting in generation and accumulation of GNDs at the lamellar interface and at the FCC-B2 interphase. This in turn makes the soft FCC lamellae stronger and improves the overall yield strength of AlCoCrFeNi2.1 eutectic HEAs. Further plastic deformation results in the synergistic deformation of both hard and soft lamellae, with soft FCC lamellae bearing a higher strain, leading to the more substantial HDI hardening effect. Moreover, the aligned lamellar structure and ductile FCC matrix can delay crack propagation and coalescence, thereby delaying the onset of global necking (Shi et al., 2019; Shi et al., 2021).

TABLE 5
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TABLE 5. List of the processing steps (P), eutectic structure (S) and mechanical properties of reported eutectic HEAs. AC–—as cast, WR—warm rolling, CR—cold rolling, CryoR—cryo rolling, AN—annealing, A—aging.

Precipitation structure

As utilized in traditional materials, precipitations can be introduced in the grain interior to enhance the accumulation of dislocations when they intersect or bypass precipitations. This will result in strain hardening and consequently higher ductility. Moreover, the precipitations will impede the slip of dislocations and increase the stress required for dislocation movement. Thus, precipitation strengthening is an important strategy for improving the yield strength of MEAs/HEAs. This approach has been reported by several groups with the addition of Al, Cu, and Mo alloying elements to produce multiphase structures. Various kinds of precipitations, such as σ, μ, B2, BCC, and L12 phases, have been compounded in MEAs/HEAs to achieve superior mechanical properties (Table 6). It should be noted that, in order for this approach to be effective, the concentration of the alloying elements and the thermomechanical processing need to be optimized (Shahmir et al., 2016).

TABLE 6
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TABLE 6. List of the strengthening phase (P) and mechanical properties of MEAs/HEAs reported with multiphase hierarchical microstructure.

A multiphase hierarchical microstructure in Al0.3CoCrNi MEA was achieved by cold-rolling and annealing (Sathiyamoorthi et al., 2019c). After annealing, the multiphase hierarchical microstructure features non-recrystallized regions, partial recrystallized regions with fine (3 ± 2 μm) and coarse (14 ± 3 μm) grains, and hierarchical distribution of σ phase (100–500 nm) and B2 precipitates (300–400 nm). This Al0.3CoCrNi MEA with a multiphase hierarchical microstructure presents an excellent combination of high yield strength (1 GPa), high tensile strength (1.2 GPa), and high ductility (∼28%). Similarly, the CoCrFeNiMo0.3 HEA strengthened by σ and μ particles presents a yield strength of 816 MPa and a ductility of ∼19% (Liu et al., 2016). By using different thermomechanical processings, Choudhuri et al. fabricated a three-phase microstructure consisting of FG FCC, ordered B2, and σ phase in Al0.3CoCrFeNi HEA (Choudhuri et al., 2019). Strikingly, the Al0.3CoCrFeNi HEA with a three-phase microstructure shows a fourfold increase in yield strength and more significant work hardening ability compared to that with only the FCC microstructure.

The thermomechanical processing-induced precipitations have significant effects on the mechanical properties of MEAs/HEAs. First, the precipitations promote the formation of heterogeneous grain structures. The difference in dislocation density and interface energy induced by plastic deformation results in heterogeneous nucleation and distribution of precipitation (Gwalani et al., 2018; Sathiyamoorthi et al., 2019c). Meanwhile, the heterogeneous precipitations can delay the recrystallization process and facilitate partial recrystallization with formation of fine and coarse recrystallized grains (Sathiyamoorthi et al., 2019c; He et al., 2020). Second, precipitations offer an important strengthening effect. Both the experiments by transmission electron microscopy and molecular dynamic simulations have demonstrated that the ordered B2 and σ phases will raise the local stress levels to facilitate deformation twinning (Choudhuri et al., 2019). Furthermore, direct observation by EBSD shows the heterogeneous distribution of strain induced by the heterogeneous microstructures, with higher strain accumulation in uncrystallized regions and FGs (Sathiyamoorthi et al., 2019c). The outstanding mechanical properties of MEAs/HEAs with multiphase hierarchical microstructure are attributed to the combined effect of hierarchical constraints to the deformation of the major phase. The combination of strengthening from HDI stress induced by heterogeneous structures and effective stress induced by nano-precipitates results in high strength, while the GNDs and twins lead to a remarkable strain hardening rate and thus high ductility.

Dynamic phase transformation

It has been documented that the deformation mechanisms in FCC materials perform as a function of SFE, which can be summarized as the following: 1) SFEs for dislocation slip are higher than 60 mJm−2; 2) SFEs for twinning are in the range of 20–60 mJm−2; and 3) SFEs for transformation from the FCC to HCP phases are lower than 20 mJm−2 (Remy and Pineau, 1977; Saeed-Akbari et al., 2012). The low SFE promotes the dissociation of unit dislocation into partial dislocations and suppresses the unit dislocation slip. Furthermore, the low SFE reduces the CRSS for phase transformation, and hence it enhances the TRIP effects, leading to dynamically accumulating dislocations and hardening of alloys during deformation. Therefore, MEAs/HEAs with extremely low SFE usually experience dynamic phase transformation from FCC to HCP and achieve simultaneously enhanced strength and ductility.

Utilizing this concept, metastable dual-phase Fe80-xMnxCo10Cr10 (at%) HEAs were developed, which overcome the traditional strength–ductility trade-off (Li et al., 2016). By tuning the Mn content, the authors realized the transition of dominating deformation mechanisms from dislocation slip to the TWIP effect in metastable HEAs, due to the lower Mn content-induced reduction of SFE. Finally, the Fe50Mn30Co10Cr10 HEA is composed of the dual-phase microstructure with ∼28% HCP phase and ∼72% FCC phase (Li et al., 2016). Upon plastic deformation, sustaining phase transformation from the FCC to HCP phases is realized through the formation of stacking faults on alternative slip planes. The phase transformation-induced high-phase boundary density creates additional obstacles for dislocation slip, thereby contributing to higher strain hardening in the dual-phase Fe50Mn30Co10Cr10 HEA than in the single-phase HEAs (Li et al., 2016). In conclusion, the increased interface density and the massive solid solution strengthening result in greatly improved strength, while at the same time the dislocation plasticity and transformation-induced hardening lead to enhanced ductility. The synergic deformation of the two phases leads to a highly beneficial dynamic strain–stress partitioning effect, and thus the combined increase in strength and ductility (Li et al., 2016).

Similarly, Su et al. developed an HS interstitial carbon-doped HEA (Fe49.5Mn30Co10Cr10C0.5 (at%), which exhibits excellent mechanical properties (Su et al., 2019). Through a thermomechanical process (cold-rolling and annealing at 600°C), the authors can fine-tune the microstructures of the HEAs to form a trimodal grain structures featured by fine recrystallized grains (<1 µm) related to shear bands, medium-sized grain (1–6 µm) recrystallized from the retained FCC phase, and large non-recrystallized grains from the reverted FCC phase (Figure 8) (Su et al., 2019). The tri-modal grain structure shows superior combination of yield strength and ductility compared to the fully recrystallized coarse and FGs. Nano-twins and grain refinement account for the improvement in yield strength, and multistage work hardening associated with the TWIP and TRIP effects accounts for the enhanced ductility (Su et al., 2019).

FIGURE 8
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FIGURE 8. A schematic diagram of producing Fe49.5Mn30Co10Cr10C0.5 with bimodal and trimodal microstructures (Su et al., 2019).

The transformation nucleus of FCC usually occurs in the SF–SF intersections, which has been revealed in the FCC/BCC transformation in Co25Ni25Fe25Al7.5Cu17.5 HEA by molecular dynamic simulation (Li et al., 2018). In addition, the nano-HCP laths may form in the presence of nano-twins, leading to the formation of nano-twin–HCP composite lamellae. The nanocomposite of the dual-phase mixture offers an optimal balance of strain and stress benefits and decreases the possibility of damage nucleation due to their elastic compliance. Without the adjustment to the deformation via twinning and/or dislocation slip, the deformation attributed solely to the single HCP phase transformation is prone to produce damage to the tensile specimen, thereby leading to a premature fracture even though the TRIP effect is contributed to a high strain hardening effect. When compared with the hardening effect from TBs, the HCP lamellar structure would be an effective barrier for dislocation slip since the transmission of edge-component dislocations into the HCP phase would require the activation of either <c> or < c + a> dislocation with a component along (0001) (Miao et al., 2017; Lu et al., 2018). The <c> or < c + a> dislocation typically exhibits extremely high CRSS in HCP materials.

Heterogeneous Structure by Additive Manufacturing

The additive manufacturing technique, including selective laser melting and direct laser deposition, can also produce bulk heterogeneous structures in HEAs/MEAs, without any post-processing (e.g., homogenization, severe plastic deformation, and annealing). The additive manufacturing technique possesses unique forming mode (e.g., melt pool connection, layer-by-layer deposition, high cooling rate, and nonequilibrium solidification). Thus, the produced heterogeneous structures are usually featured by melt pools, columnar grains, cellular dislocation structures, twinning, solute heterogeneity, and precipitation (Zhu et al., 2018; Park et al., 2019; Kim et al., 2020; Luo et al., 2020; Wang et al., 2020).

In the single-phase CoCrFeMnNi HEA produced by selective laser melting, the three-dimensional dislocation network structures are observed (Zhu et al., 2018). Such unique dislocation networks generate by the substantial interaction between dislocation slip bands and cellular dislocation walls and show no misorientation with the matrix. These cellular dislocation structures can efficiently accommodate and trap dislocations to bring about remarkably dislocation hardening, thereby resulting in an outstanding combination of high strength (609 MPa) and excellent ductility (34%) (Zhu et al., 2018).

Luo et al. fabricate a dual-phase AlCrCuFeNix (x = 2.0, 2.5, 2.75, 3.0) HEA with BCC and FCC structures using selective laser melting (Luo et al., 2020). The AlCrCuFeNix HEA exhibits an excellent combination of strength (957 MPa) and ductility (14.3%), which is attributed to the heterogeneous microstructures and distinct deformation mechanisms in FCC and BCC phases (Luo et al., 2020). The deformation of FCC phases is carried by planar dislocation slip and stacking faults, while high densities of Cr-rich nano-precipitates promote the formation of deformation twins and stacking faults in BCC phases. Moreover, the strain-induced phase transition from BCC to FCC contributes to the strain hardening and ductility.

However, there remains a paucity of studies on the nature and the inherent formation mechanisms of the heterogeneous structures in additively manufactured materials. Much more effort is required to understand the influence of processing parameters to design HEAs/MEAs with superior mechanical properties.

Summary and future issues

This review paper introduces HS and HEA concepts and emphatically reviews the microstructure, mechanical properties, and deformation mechanisms of HS MEAs/HEAs. The HS design can enhance strain hardening capacity and delay plastic instability, effectively evading the paradox between strength and ductility observed in metallic materials with conventional strengthening strategies. The introduction of HS into MEAs/HEAs helps to achieve a superior strength–ductility synergy, as shown in Figure 9. The HS MEAs/HEAs should be comprised of different microstructures characterized by large strength difference, which induces stress and strain partitioning upon tensile deformation and thus leads to GND pile-up and HDI-stress effects.

FIGURE 9
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FIGURE 9. Yield strength versus uniform elongation of MEAs/HEAs with homogeneous structures (below banana-shaped region) and various heterostructures. (GS, HGS, HLS, ES, and PS are gradient structure, heterogeneous grain structure, heterogeneous lamella structure, eutectic structure, and precipitation structure, respectively).

From the previous reported mechanical properties of MEAs/HEAs with heterostructure, the field is still in its incipient stage and the great potential in next-generation structural and functional applications spanning diverse fields remains to be explored, such as transportation, energy sustainability (nuclear reactors and hydrogen storage), aerospace applications, and biomedical applications. Meanwhile, the shortcomings in the field of high-entropy alloy research must be faced up to, which is the transition from laboratory explorations to practical engineering applications. For example, strength and ductility are the concern for laboratory investigations whereas a complex application environment must be considered for practical applications. In this sense, more application-driven and building-up of benchmarking for commercial application is also a crucial step in exploring MEAs/HEAs. Most importantly, the expense could by and large be a decisive issue for utilizations of MEAs/HEAs, which requires careful contemplations.

Author Contributions

WJ wrote the first draft of the manuscript. YTZ and YHZ reviewed and edited the manuscript. All authors contributed to the article and agreed to the submitted version of the manuscript.

Funding

The authors acknowledge financial support from the National Key R and D Program of China (Grant No. 2017YFA0204403), the National Natural Science Foundation of China (Grant No. 51971112 and 51225102), the Fundamental Research Funds for the Central Universities (Grant No. 30919011405), and the Hong Kong Research Grants Council (GRF 11214121).

Conflict of Interest

The authors declare that the research was conducted in the absence of any commercial or financial relationships that could be construed as a potential conflict of interest.

Publisher’s Note

All claims expressed in this article are solely those of the authors and do not necessarily represent those of their affiliated organizations, or those of the publisher, the editors and the reviewers. Any product that may be evaluated in this article, or claim that may be made by its manufacturer, is not guaranteed or endorsed by the publisher.

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Keywords: high-entropy alloy, heterostructured material, microstructure, mechanical property, strength, ductility

Citation: Jiang W, Zhu Y and Zhao Y (2022) Mechanical Properties and Deformation Mechanisms of Heterostructured High-Entropy and Medium-Entropy Alloys: A Review. Front. Mater. 8:792359. doi: 10.3389/fmats.2021.792359

Received: 10 October 2021; Accepted: 12 November 2021;
Published: 03 January 2022.

Edited by:

John L. Provis, The University of Sheffield, United Kingdom

Reviewed by:

Zhiming Li, Central South University, China
Bo Song, Southwest University, China

Copyright © 2022 Jiang, Zhu and Zhao. This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.

*Correspondence: Yonghao Zhao, yhzhao@njust.edu.cn

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