Abstract
Due to their single-crystalline structures, comparatively large aspect ratios, tight optical confinement and smooth surfaces, nanowires have increasingly attracted research interests for both fundamental studies and technological applications in on-chip photonic devices. This class of nanostructures typically have cross-sections of 2~200 nm and lengths upwards of several micrometers, allowing for the bridging of the nanoscopic and macroscopic world. In particular, the lasing behaviors can be established from a nanowire resonator with positive feedback via end-facet reflection, making the nanowire a promising candidate in the next generation of optoelectronics. Consequently, versatile nanowire-based devices ranging from nanoscale coherent lasers, optical sensors, waveguides, optical switching, and photonic networks have been proposed and experimentally demonstrated in the past decade. In this article, significant progresses in the nanowire fabrication, lasers, circuits, and devices are reviewed. First, we focus on the achievements of nanowire synthesis and introduce the basics of nanowire optics. Following the cavity configurations and mode categories, then the different light sources consisting of nanowires are presented. Next, we review the recent progress and current status of functional nanowire devices. Finally, we offer our perspective of nanowires regarding their challenges and future opportunities in photonic circuits.
Introduction
Manipulating photons on a micro-/nano-scale has been one of the pivotal topics in photonics. For the past few decades, worldwide efforts have been devoted to explore new optical materials and structures that could confine light into the regime <100 nm or beyond the diffraction limits (Bawendi et al., 1990; Takahara et al., 1997; Barnes et al., 2003; Maier et al., 2003; Katagiri et al., 2004; Silveirinha and Engheta, 2006; Oulton et al., 2008, 2009). The pursuit of downsizing the dimensions of optical nanostructures propels the continuing success of photonic technologies for higher flexibilities, better performances, and higher-density integrations (Luo et al., 2014; Mrejen et al., 2015; Gupta et al., 2018; Gatdula et al., 2019). The intensive research on nanomaterials has led to a rich collection of nanostructures of which the shape, size, and composition can be expediently tuned. Nanostructures with fascinating material and optical properties significantly facilitate the trend of optoelectronic devices to low cost and low power consumption which could have remarkable impact in future photonics. Since the 1990s, an important class of nanostructures with cross-sections of 2–200 nm and lengths upwards of several micrometers have emerged that bridge the nanoscopic and microscopic world (Yazawa et al., 1991). They were initially called “nanowhiskers” and later “nanowires” (Xia et al., 2003). Such one-dimensional (1D) nanowires provide new opportunities and platforms that could downsize currently existing structures into subwavelength scales.
Nanowires are different from other structures such as spherical nanocrystals and quantum dots by their morphology as well as physical features. The two-dimensional light confinement allows electrons, holes, or photons to propagate freely along the third dimension. Due to their large refractive indices and smooth surfaces, the two end-facets of the nanowires could serve as mirrors to recycle the energy and pick out light with specific optical frequencies, naturally establishing the optical cavities and indicating promising applications in nanolasers. Furthermore, the subwavelength-diameter nanowires also enable light propagation with small loss and can enhance light-matter interaction results from the evanescent coupling with surroundings. Although significant progress on the fabrication technologies has been made for achieving nanostructures at a nanometer scale (Zhang et al., 2012; Cheon et al., 2017; Cho et al., 2019; Gao et al., 2020), nanowires synthesized with bottom-up growth still show natural advantages such as being defect-free and single-crystalline (Dasgupta et al., 2014). The unique geometric and material properties of nanowires are therefore quite attractive for achieving integrated light sources and many other applications such as data transmission (Ainsworth et al., 2018), sensing (Ambhorkar et al., 2018), and imaging (Park and Crozier, 2013).
The purpose of this review is to give a general overview of the nanowire fabrication, as well as review the principles of the nanowire waveguides and resonators. Then we present the recent progress on the nanowire lasers categorized by their versatile configurations and emission wavelengths, for instance, Fabry-Perot (F-P) lasers, whispering gallery mode (WGM) lasers, and single-mode lasers. Furthermore, the applications of nanowire laser are briefly discussed. Finally, we offer our perspective of nanowires regarding their challenges and future research directions.
Nanowire Fabrication
Over the past decade, many efforts have been devoted to precisely controlling the nanowire dimensions, crystal structure, composition, and growth pattern at the atomic level. The synthesis and fabrication technologies of semiconductor nanowires developed rapidly and vastly advanced the development of nanowire based optoelectronic devices (Duan et al., 2001; Harter et al., 2018). The first semiconductor nanowire was fabricated by bottom-up chemical growth from silicon using a gold metal catalyst by Wagner et al. at Bell Laboratories in the 1960s (Wagner and Ellis, 1964). This “vapor-liquid-solid” (VLS) mechanism has since been developed and extended by other researchers such as Lieber (Yang and Lieber, 1996; Morales and Lieber, 1998), Yang (Wu and Yang, 2001), and many other groups (Björk et al., 2002). The phase diagram in Figure 1A clearly shows the growth process with the VLS method. Three stages of the basic VLS growth process are included: alloying (I); nucleation (II); growth from nanorods to nanowires (III) (Wu and Yang, 2001), as shown in Figure 1B. Using the VLS growth by introducing a catalytic liquid alloy phase, various semiconductor nanowires with precise control over length, diameter, growth direction, and morphology have been successfully realized (Kuykendall et al., 2004). Typically, nanowire diameter is decided by the sizes of the metal alloy droplets. In this sense, uniform size of the nanowire arrays can be facilely achieved by employing monodispersed metal nanoparticles (Hochbaum et al., 2005). With this strategy, the length of the nanowire can be tuned from micrometer to millimeter. Furthermore, to obtain high-quality nanowire arrays, VLS epitaxy techniques have been utilized to control the orientation during the nanowire growth process (He et al., 2005). For instance, the (0001) plane of the ZnO nanowire and the (110) plane of the sapphire substrate have the good epitaxial interface, leading to the uniquely vertical epitaxial growth of the nanowires from substrate (Figures 1C–H) (Huang et al., 2001). To date, a wide range of inorganic semiconductor nanowires can be synthesized via VLS method, including group IV (Si, Ge) (Morales and Lieber, 1998; Cui et al., 2000; Wu and Yang, 2000; Sivakov et al., 2006; Colli et al., 2007), II-VI and III–V (ZnO, ZnS, CdS, CdSe, GaN, GaSb, GaAs, InP) (Duan and Lieber, 2000a,b; Zhang et al., 2001; Yang et al., 2002; Heo et al., 2004; Hsu and Lu, 2005; Noborisaka et al., 2005; Venugopal et al., 2005; Moore and Wang, 2006; Shtrikman et al., 2009; Zhai et al., 2010; Zhao et al., 2012), and alloy nanowires (CdSSe, ZnCdS, ZnCdSSe) (Duan and Lieber, 2000a; Radovanovic et al., 2005; Johansson et al., 2006; Kuykendall et al., 2007; Mårtensson et al., 2007; Pan et al., 2009a; Gu et al., 2011; Yang et al., 2011).
Figure 1
Nanowire Fundamentals
Mechanisms for nanowire cavity
To establish lasing, three essential factors must be satisfied: (1) gain medium for population inversion; (2) pump source for exciting medium; (3) optical cavity for amplifying light. Usually, nanowire itself can serve as a gain medium. With the excitation of external light sources, population inversion can be achieved. The end-facets of nanowire naturally play the roles of reflection mirrors due to large index differences with its surroundings, satisfying the conditions to form an optical cavity, as shown in Figure 2. The light in the nanowire cavity can be amplified by optical feedback and thus lasing can be obtained when the round-trip gain compensates the total cavity losses,
where Γ is the confinement factor, g is the material gain, αm is the mirror loss, αp is the propagation loss, L is the cavity length, and R1, R2 are the effective reflection coefficients of the two end-facets. Therefore, from Equation (1), the key points for achieving low-threshold lasing are to increase the gain efficiency g or to reduce cavity loss. Furthermore, the estimation of the reflectivity for the guided modes in nanowire is complicated because their diameter is typically smaller than the lasing wavelength that leads to the diffraction effect at the nanowire edges. For a nanowire vertically standing on a substrate (Huang et al., 2001), the ends of reflectivity at the two facets are different (Maslov and Ning, 2004). The reflection coefficient from the top facet grows with the mode confinement as well the frequency. However, the reflection coefficient from the bottom facet does not grow monotonically with mode confinement, which does not match the prediction from the Fresnel formula. The reason is that the optical fields outside of the nanowire experience a jump in the dielectric constant, resulting in larger reflectivity at low frequencies despite the small refractive index contrast between nanowire and substrate.
Figure 2
The research on nanowire lasers increases apace, so rigorous modeling of nanoscale lasers, therefore, becomes increasingly important. The coupled rate equations to describe the carrier density and photon density for a single mode in a semiconductor cavity is an effective approach to analyze the lasing threshold, which can be defined as
where N is the carrier density, S is the photon density, P is the pump intensity, η is the pumping efficiency, τr and τnr are the spontaneous emission and non-radiative lifetime, respectively, τS is the photon lifetime, β is the spontaneous emission factor, N0 is the transparency carrier density, α is the differential gain, ? is the confinement factor and νg is the group velocity. By solving for these coupled rate equations under steady-state conditions, the photon density can be plotted as a function of pump intensity (Oulton et al., 2009). Then the lasing threshold can be more quantitatively defined by fitting the experimental power plot to a calculated plot.
Another key figure of merit for nanowire lasers is the confinement factor Γ. Γ represents the overlap between the resonant mode and gain medium. In this sense, the nanowire size and shape as well as the mode profile are pivotal parameters that determine Γ. For example, a confinement factor of >0.8 can be obtained for the nanowire with a sufficiently large triangular cross section (Seo et al., 2008). For typical semiconductor nanowires formed with wurtzite crystal structures such as GaN, CdS, and ZnO, their geometrical axis coincides with the optical axis of the crystal (also called the -axis) (Maslov and Ning, 2004). The optical gain in wurtzite bulk crystals depends on the polarization of the lasing mode. Therefore, the orientation of the electric field of the mode in nanowire relative to the optical axis of the crystal is essential to determine the modal gain. According to the polarization of optical modes in nanowire, one can introduce the longitudinal gain G∥, transverse gain G⊥, longitudinal confinement factor Γ∥, and transverse confinement factor Γ⊥. The total gain of mode can be written as
Mechanisms for Nanowire Waveguide
The theories about waveguiding and light confinement have been extensively studied in freestanding nanowire in the visible region (Maslov and Ning, 2004; Eaton et al., 2016). The ability of nanowire structure to support multiple modes has been confirmed by solving Maxwell's equations analytically. For a circular-cross-section nanowire, the modes can be analytically solved in cylindrical coordinates with the following eigenvalue equations (Ma et al., 2013):
TE0m modes
TM0m modes
HE and EH modes
where Jν is the Bessel function of the first kind, and Kν is the modified Bessel function of the second kind. , , and are waveguide parameters, n1, n2 are refractive indices of the nanowire and the surrounding medium, a is the radius of the nanowire, , λ is the wavelength of light in vacuum, and β is the propagation constant. By numerically solving Equations (5–7), waveguiding modes supported by the nanowire can be obtained. For reference, Figure 3A gives the evolution of the propagation constant β of the fundamental modes at different nanowire radii (Ma et al., 2013). At higher diameters, several modes with strong confinement are sustained within the nanowire. Though the propagation loss is reduced, the multiple mode regime will spoil the device performance that leads to mode competition. Furthermore, the free-standing nanowire usually exhibits tightly confined electromagnetic fields with a high fraction of evanescent fields, as shown in Figures 3B–E. Interestingly, when the nanowire diameter is small enough, the fundamental transverse mode TE01 and TM01 can be suppressed and single-mode operation is available. Furthermore, the effective index of the survived mode, associated with propagation velocity, is very close to the air, such that the evanescent wave outside the nanowire is considerably large, undoubtedly resulting in a small confinement factor and thus less overlap with the gain medium.
Figure 3
Nanowire Lasers
The large refractive index difference between the semiconductor material and its surrounding dielectric environment enables light confinement in the nanowire. Thus, the two end-facets function well as the reflection mirrors and constitute the optical cavities for light amplification. Benefitting by the capability of emission-wavelength tuning, complementary metal-oxide-semiconductor (CMOS) compatibility, and miniaturization, the semiconductor nanowires have been widely recognized as promising candidates for significant building blocks for the next-generation of integrated photonics. In the past few decades, many types of semiconductor nanowires have been fabricated and thoroughly investigated. Meanwhile, considering the less trap-state density, the single-crystalline nanowire enabled F-P cavities usually exhibit good performance such as low lasing threshold. In this section, we introduce the typical nanowire lasers including photonic lasers, plasmonic lasers, single-mode lasers, and wavelength-tunable lasers.
Fabry-Perot Lasers
Photonic Lasers
In 2001, Huang et al. reported the first nanowire cavity and laser from multiple ZnO nanowires synthesized by VLS approach (Huang et al., 2001). Under the excitation of He-Cd laser (325 nm), clear near-band-gap edge emission at 377 nm has been observed, as shown in Figure 4A. By conducting the power strength-dependent pumping with the fourth harmonic of Nd: yttrium-aluminum-garnet laser (266 nm, 3 ns pulse width) at room temperature, the stimulated emission has been explored and confirmed. The lasing action in these ZnO nanowires was clearly observed without any fabricated reflection mirrors (see insert in Figure 4A) by steadily increasing the pump power, explicitly proving the formation of F-P cavity and positive feedback. Above the threshold, sharp peaks with linewidth <0.3 nm emerged in the emission spectra. The demonstration of these ZnO nanowire lasers paves the way to realize lasers in nanoscale and leads to a considerable focus of the research on nanowire geometry. Shortly after, ZnO nanolasers with external quantum efficiency (QE) as high as 60% and internal QE of 85% were reported (Zhang et al., 2005). Two- and three-photon absorption with threshold of 100 mJ cm−2 were also investigated in ZnO nanowires (Zhang et al., 2006). In 2009, Zhang et al. further reduced the threshold to 160 μJ cm−2 from two-photon absorption of ZnO nanowires (Zhang et al., 2009). Following these pioneering works, II-VI semiconductors became the focus of investigation. The CdS nanowire lasing properties under different temperatures were then reported by Lieber et al. at Harvard University (Figure 4B) (Duan et al., 2003). In 2004, Ding et al. reported the first ZnS nanowire lasers (Ding et al., 2004). Moreover, the III-V compounds with emission wavelength spanning from ultraviolet (UV) to near Infrared (IR) such as GaAs (Figure 4C) (Saxena et al., 2013), GaN (Figure 4D) (Johnson et al., 2002; Zhang et al., 2014b), InGasAs/GaAs (Chen et al., 2011), GaAs/GaAsP (Johnson et al., 2001), GaSb (Figure 4E) (Chin et al., 2006), and InGaN/GaN (Wu et al., 2011) have been successfully demonstrated.
Figure 4
In addition to traditional II-VI and III-V semiconductors, a new class of materials with chemical formula ABX3 (metal halide perovskite) have been developed in the past few years. A can be referred to as methylammonium (CH3NH3 or MA), formamidinium (CH(NH2)2 or FA), cesium (Cs), B to lead (Pb), tin (Sn), and X to halide (chloride (Cl), bromide (Br), iodide (I)). Such type of material exhibits outstanding features including high absorption coefficients, low defect densities, long carrier diffusion lengths, direct bandgap (Green et al., 2014; Sum and Mathews, 2014; Stranks and Snaith, 2015; Brenner et al., 2016; Correa-Baena et al., 2017; Ha et al., 2017; Huang et al., 2017; Zhang et al., 2017). The excellent optical and material properties of the perovskite material have attracted tremendous research interests ranging from lasers (Sutherland et al., 2014; Zhang et al., 2014a), solar cells (Kim et al., 2012; Yang et al., 2015; Anaraki et al., 2016; Bi et al., 2016), optoelectronics (Tan et al., 2014; Jaramillo-Quintero et al., 2015; Saidaminov et al., 2015), and sensing (Zhu et al., 2018; Rahimi et al., 2019). In 2015, Zhu et al. reported the perovskite nanolasers with ultralow lasing threshold in high-quality perovskite nanowires (Zhu et al., 2015). They chemically synthesized the single-crystal perovskite nanowires via a two-step solution processed surface-initiated growth approach. A single peak has been observed with the excitation of the femtosecond laser (Figure 4F). The “S-like” light-light curve confirmed the formation of lasing behavior. The lowest measured lasing threshold of the perovskite nanowire laser is as small as 220 nJ cm−2, which is far lower than other perovskite nanostructures (Deschler et al., 2014; Zhang et al., 2014a). Due to the high crystal quality enabled smooth surface, the full width at half maxima (FWHM) of the lasing peak is quite narrow (~0.22 nm) and later reduced to 0.08 nm (Wang et al., 2017).
Plasmonic lasers
The fast development of nanowire nanolasers has significantly advanced the research on nanowire photonics. Nowadays, device miniaturization in fundamental sciences and industrial applications is a long-term and continuous pursuit. Though the semiconductor nanowires could confine light in a wavelength scale, the demonstrated nanowire nanolasers are still constrained by the diffraction limit and their dimensions are larger than the half of the optical wavelength in free space. In the past decade, a new type of nanolasers, based on semiconductor nanowires and metal substrates, have attracted widespread attention for achieving deep sub-wavelength coherent light sources since their first creation in 2009 (Oulton et al., 2009). The generated surface plasmonics at the dielectric-metal interface strongly couple with the waveguide modes within the semiconductor nanowires, which were named as “hybrid surface plasmonic modes” (HSPMs). The HSPMs transfer the light to electron oscillations and propagate along the surface of the metal substrate but are simultaneously guided by the nanowire waveguide effect. As a result, the physical dimension of the optical devices can be compressed to the nanometer scale. Furthermore, the photon-plasmon interaction immensely enhances the local field in such structures, enabling the realization of plasmonic nanolasers with high power, low consumption, and fast response. In this section, we introduce and review in detail the plasmonic nanolasers including hybrid surface plasmonic lasers, photonic-plasmonic integrated lasers, and wavelength-tunable plasmonic lasers.
Hybrid surface plasmonic lasers
In 2008, Oulton et al. presented the concept of a hybrid plasmonic waveguide in which a nanowire and metal substrate is separated by a thin dielectric film with a low refractive index (Oulton et al., 2008). The continuity of the displacement field of normal to substrate endows the extreme light confinement within the thin insulator layer and ultrasmall mode volume. Mode area from λ2/40-λ2/400 has been achieved in this plasmonic waveguide. They theoretically and numerically demonstrated that the hybrid surface plasmonic modes simultaneously come from strong light localization of surface plasmonic mode and low propagation loss of photonic mode. In 2009, the same group experimentally demonstrated the plasmonic lasers from a CdS nanowire, separated from a silver surface by a nanometer-thick MgF2 insulating gap (Figure 5A) (Oulton et al., 2009). The plasmonic device was optically pumped with a femtosecond pulsed laser (405 nm, 100 fs) below 10 K. With the increasing of the pump fluence, clear transition from spontaneous emission to lasing from the dominant I2 CdS exciton line at 489 nm has been observed (Thomas and Hopfield, 1962). By integrating the lasing intensities, an “S-like” curve can be obtained which matches well with the rate equation (inset of Figure 5B) and confirms the lasing action. The measured free spectral range (FSR) of the lasing modes exhibited a linear relationship with the reciprocal of the nanowire length, definitely notarizing the existence of F-P resonant modes (inset of Figure 5B). Above the threshold, bright blue spots could be seen due to the scattering at the nanowire end-facets (left inset of Figure 5B). Notably, due to the high intrinsic metal ohmic losses and radiation leakage, the proposed plasmonic lasers still need higher power to be excited compared with their photonic counterpart. However, the realization of plasmonic nanolasers from nanowire represents a significant step toward integrating devices with high-density and small footprints. After the first demonstration of hybrid surface plasmonic lasing from nanowires, the research on this type of nanolaser has since expanded rapidly and vastly boosted the development of lasers from physics to cavity design.
Figure 5
At the initial stage for implementing plasmonic nanowire lasers, cryogenic operation is widely utilized in the process of measuring plasmonic nanowire lasers to promote the optical gain and prevent device damages (Oulton et al., 2009; Nezhad et al., 2010; Ma et al., 2011), which is still one of the obstacles and truly limits their practical applications. In 2014, Zhang et al. reported the UV plasmonic laser devices with low-loss from triangular GaN nanowires (Zhang et al., 2014b). In this work, several strategies have been executed to reduce the lasing threshold of plasmonic lasers. First, aluminum (Al) film was chosen to be the substrate and plasmonic medium to impair the ohmic loss instead of silver substrate with high loss at UV region (Huang et al., 2001). Second, they used nanowires with triangular cross-sections to construct a fully planar semiconductor-insulator-metal interface (Figure 5C). The large contact interface between the nanowire and the nether insulator-metal ensures a sufficient photonic-plasmonic modal overlap, providing an effective channel for exciton-plasmon coupling. Last, the planar nanowire-dielectric interface suffers smaller scattering loss compared with previous works (Oulton et al., 2009; Lu et al., 2012). By adopting these improvements, a threshold of 3.5 MW cm−2 (Figure 5D, inset) has been obtained which is three orders of magnitude lower than that of the previously reported room temperature plasmonic nanolasers (Ma et al., 2011). Furthermore, Chou et al. designed a plasmonic nanolaser without additional insulator layers in 2016 (Chou et al., 2016). The average lasing threshold of the presented structure was around 20 MW cm−2, which was four-times lower than that of structures with insulator layers. The lower lasing threshold was ascribed to the relatively strong mode confinement at the Al-ZnO interface.
Usually, the as-introduced nanolasers are optically excited by femtosecond pulsed lasers which prevents the practical application of such devices. To overcome this limit, using electric injection is an alternative route to achieve amplified light emission from plasmonic lasers. However, the large ohmic losses and joule heating of electrical injection tremendously weaken the effective gain and consequently induce the increasing of operation threshold. The threshold of the demonstrated electrically driven plasmonic lasers were almost one order of magnitude larger than their photonic counterpart. Furthermore, the high injection currents may change the emission spectra and also affect the stability and reliability of plasmonic lasers (Zhang Y. et al., 2019). The first electrically driven plasmonic laser was demonstrated by Hill et al. in 2009 (Zhou et al., 2013). Super-linear emission with a line width of ~0.5 nm was observed by employing electric injection above 104 A cm−2. Unfortunately, the proposed devices can only be operated under a cryogenic environment due to poor heat dissipation. To reduce the lasing threshold and realize room-temperature lasing for plasmonic nanolasers, Ding et al. improved the fabrication process to minimize imperfections of plasmonic devices (Ding et al., 2013). After conducting several strategies, they successfully realized the lasing of plasmonic structures at room-temperature. In 2019, Yang et al. designed and experimentally demonstrated an electrically driven UV plasmonic nanowire laser at room-temperature, realized in a p-GaN/MgO/ZnO/MgO/Ag structure, as shown in Figure 5E (Yang X. et al., 2019). The high optical gain coefficient, large exciton binding energy, large oscillator strength, and material stability of ZnO was selected to ensure the performance of the device under high current injection and beneficial for a faster radiative lifetime (Djurišić et al., 2010; Sidiropoulos et al., 2014; Chou et al., 2015) due to its facile coupling with surface plasmon polaritons (SPPs). In this configuration, the electrons were injected into ZnO layer from Ag layer through MgO gap layer, while holes were injected from p-GaN layer by tunneling effect. The MgO layers between ZnO active region and p-GaN layer was introduced to block electrons from entering into the p-GaN and enhance the emission from ZnO. As a result, an extremely low threshold of 70.2 A cm−2 was achieved at room temperature and the output power reached 30 μW when the injection current was 40 mA. Figure 5F summarized the relationship between injection current density and emission spectra of the device collected from the lateral direction of the cavity. At an injection current density of 66.3 A cm−2, a broad spontaneous emission peak was observed. Sharp lasing peaks with FWHM of 1.2 nm emerged when the injection current was improved to 70.9 A cm−2. Given a higher injection current (74.8 A cm−2), multiple modes with higher intensities were excited which corresponds to an effective index of 3.65, clearly suggesting the lasing action from the device.
Photonic-plasmonic integrated structures
SPPs represent one of the most promising candidates to break diffraction limits imposed by conventional photonic structures. Though the subwavelength–scale mode volume makes it possible to build optical devices with high-density and better performance, the large metal loss hinders the possibility to channel information across the entire plasmonic waveguides. Hence, the optical routing by integrating metal and dielectric nanowires is a significant issue to be addressed. Furthermore, the excitation of SPPs faces a severe challenge due to the momentum mismatch between SSPs and photons. In 2009, Yan et al. proposed a simple approach to couple dielectric mode in SnO2 nanoribbon with SPPs in silver nanowires (see Figure 6a) (Yan et al., 2009). A silver nanowire was placed on the top of a SnO2 nanoribbon waveguide that bridges two SiO2 substrates, as the SEM image shown in Figures 6c,d. The photoluminescence (PL) was excited by a UV laser with a focused spot on the lower right of the SnO2 nanoribbon. The photons propagating in the SnO2 waveguide were scattered at the metal-dielectric contact point that provides wave vectors in a broad range and compensates the momentum mismatch of photons and SPPs. Then the excited SPPs traveled along the silver nanowire and emitted into free space at the end of the wire, as shown in Figure 6b. It is noted that the SPP propagation loss was related to the frequency. The high frequency suffers larger loss than the low frequency, so the frequency distribution of the SSPs was expected to red shift which accounts for the red spot on the upper right end of the silver nanowire (Figure 6b). Furthermore, the dielectric-metal-dielectric coupling device was designed (see Figures 6d–f). Two SnO2 nanoribbons bridged by a silver nanowire were placed on the substrate. When the bent nanoribbon was excited, the guided light propagated along the nanoribbon. As expected, the light was scattered and then coupled into silver wire at the left SnO2-Ag joint point. The excited SPPs consequently propagate to the straight ribbon without any excitation, distinctly confirming the coupling between SPPs and photons. For comparison, the case of without silver nanowire was also conducted and no signals were detected from the straight ribbon. This work proves the possibility of incorporating metal nanowire in photonic circuits and can be extended to other dielectrics such as Si, SiO2, and GaN.
Figure 6
For hybrid plasmonic structures, one of the disadvantages is the mixture property of plasmonic and photonic components, making it difficult to extract a pure plasmonic mode from the generated mode (Hill et al., 2007; Noginov et al., 2009; Oulton et al., 2009; De Leon and Berini, 2010; Gather et al., 2010; Ma et al., 2011; Lu et al., 2012; Liu N. et al., 2013). In 2013, Wu et al. attempted to solve this issue by designing a new cavity scheme (Wu et al., 2013). As shown in Figures 6g,h, a bent CdSe nanowire was placed on the substrate and then a curved silver nanowire was coupled to this CdSe nanowire with a small point. When the semiconductor CdSe nanowire was optically pumped, the longitudinal photonic modes could be excited and then propagated along the CdSe nanowire. Consequently, the guiding modes from CdSe nanowire effectively excited the SPP waves in the silver nanowire. Importantly, this configuration accomplished the spatial separation between plasmonic and photonic components at the emission output ports. When the waveguide modes within the CdSe nanowire were excited, these guided modes were reflected at the end-facets of both CdSe and silver nanowires which satisfies the condition of optical cavity. To investigate the lasing behaviors of the combined structure, a 532 nm pulsed laser (5 ns pulse width, 2 kHz repetition rate) was employed to pump the CdSe nanowire by focusing the laser spot on the left segment of the nanowire (Figure 6h). The typical emission spectra from the right end of the silver nanowire were plotted in Figure 6j. Clear light output was observed from the right end-facet of the silver nanowire (see Figure 6l), distinctly indicating the strong photon-plasmon coupling. Multiple lasing modes centered around 723 nm were obtained from both the CdSe and silver nanowires, as shown in Figures 6j,k. The average FSR of the CdSe-Ag hybrid cavity was estimated to be 1.5 nm which matches well with the theoretical calculation by FSR ≈ (λ, LCdSe, ng, CdSe, are the lasing wavelength, length, and group index of CdSe nanowire; LAg, ng, Ag are the length and group index of silver nanowire, respectively), verifying that the lasing originates from the hybridization of CdSe and silver nanowires. It is worth noting that the above equation about FSR only holds true for the materials with low dispersion. In addition, almost the same threshold of 60 μJ cm−2 for the CdSe and silver nanowires was observed (see inset in Figure 6l). When the pump fluence was further increased to 97 μJ cm−2, an extra peak around 745 nm was measured that coincides with the lasing peak of the bare CdSe nanowire (gray line in Figure 6k), suggesting the coexistence of the hybrid cavity mode and single CdSe nanowire mode. Notably, the mode around 745 nm was absent in the emission spectra of the silver nanowire, confirming that the output of silver nanowire stems from the hybrid cavity. Moreover, the lasing threshold of single CdSe nanowire was about 90 μJ cm−2 due to the absence of silver nanowire with higher reflection coefficients end-facets. Therefore, the low threshold and different emission spectra of the combined structure became the solid evidences to prove the lasing behavior of the proposed hybrid cavity. To further verify the property of the output from silver nanowire, the polarization-dependent lasing emissions were conducted, as shown in Figure 6m. A polarization ratio of 92% was obtained by comparing the lasing intensities perpendicular to the nanowire axis and parallel polarization, manifesting the feature of the plasmonic mode (Oulton et al., 2009).
Multicolor plasmonic lasers
Nowadays, lasers have been widely used for applications including illumination, information, and display (Sirbuly et al., 2005; Neumann et al., 2011; Yang et al., 2011; Dang et al., 2012; Zhang et al., 2015), steadily increasing the need for lasers with high performance and multifunction. Multicolor laser is one of the essential targets to be achieved and significant progress has been made in this area. In 2012, Ma et al. have demonstrated a room-temperature CdS plasmonic laser with multicolor emissions (Ma et al., 2012). The CdS nanobelt was crosswise integrated onto five silver strips with width of 1 μm and thickness of 250 nm separated by a MgF2 layer (5 nm). Six In/Au electrodes were fabricated to introduce controllable electrical modulation, as shown in Figure 7A. Five plasmonic cavities have been constructed at the overlap areas of silver and CdS, which were marked as 1–5 in Figure 7A. The cavity sizes were determined by the width of the areas from 1 to 5. The hybrid plasmonic mode could be generated in the overlap area of Ag/MgF2/CdS when the device was optically pumped. Clear lasing peaks spanning from 491.2 to 502.7 nm were observed and the wavelengths were decided by the width of the CdS nanobelt (see Figure 7B). Moreover, the authors also provided a solution to tailor the wavelength by applying electric field (4 V). A wavelength shift of ~0.3 nm has been achieved by electric field enhanced density of excited carriers. In this configuration, more than 70% of its radiation could be directed in the embedded semiconductor nanobelt. Such hybrid photonic-plasmonic circuit offers the platform to realize devices with multifunction such as multicolored plasmonic lasers, electrical modulation, and efficient waveguide collection, indicating a significant step toward on-chip integrated optoelectronic circuitry.
Figure 7
In addition to the multicolored plasmonic lasers by tuning cavity size, another strategy to achieve all-color plasmonic nanolasers has been proposed by Lu et al. (2014), as shown in Figure 8A. The indium gallium nitride (InxGa1−xN, 0 ≤ x ≤ 1) compound semiconductor alloy system has been utilized to realize plasmonic lasers from blue (474 nm) to red (627 nm). The direct band gap of such material can be tuned by different indium contents in the nanorods. By multiple drop casting, they fabricated the InxGa1−xN/Al2O3/Ag plasmonic nanolasers with different emission colors. As confirmed by Figure 8B, single-mode lasing emissions in the full visible region (blue, cyan, green, yellow, orange, and red) have been observed. The Airy disk diffraction patterns in the optical images in Figure 8B clearly prove the subwavelength scale of the physical sizes of these devices. The numerical calculation revealed the strong light confinement in the Al2O3 insulator layer (see Figure 8C). To demonstrate the potential application in display, three diluted suspension solutions of nanorods with different indium contents were sequentially applied to deposit RGB nanorods within close proximity of each other, as shown in Figure 8D. From the SEM image shown in Figure 8E, the nanorod length and diameter were determined to be ~200 and ~50, unambiguously verifying the subwavelength footprint of the device. Optical microscopy images and the emission spectra (see lower panel in Figure 8E) indicates that the frequency pulling effect (Stockman, 2010; Lu et al., 2012) has occurred from spontaneous (642 nm) emission to lasing (627 nm). In addition, lasing with ultralow thresholds have been achieved by optimizing the composing materials in InxGa1−xN/Al2O3/Ag configuration. These results open up a route to a wide range of potential applications in ultrafast information processing, nanoscopy, nanolithography, biomedicine, and sensing.
Figure 8
Single-mode lasers
Single-mode lasing is highly desirable for applications in sensing, optical communications, spectroscopy, and interferometry. Semiconductor nanowire lasers featured with optical gain usually exhibit multiple lasing modes because of the relatively long cavity length. Reducing nanowire length to expand the FSR means that only one longitudinal mode exists in the gain window of the nanowire (Li et al., 2012). However, the shortened cavity length would increase the lasing thresholds of the nanowire lasers due to the reduction of round-trip gain. In 2013, Gao et al. developed a strategy to realize mode selection by cleaving a GaN nanowire at a determined point (Gao et al., 2013). As shown in Figure 9A, a GaN nanowire on a Si substrate was cleaved by focused ion beam (FIB) milling. To prevent the degradation of the luminescent properties of the nanowires, a metallic layer was fabricated before ion beam milling. This technique provides the precise control of the cavity length and intercavity gap. The intentionally created gap is around 40 nm, ensuring the intercavity coupling between two disconnected nanowires. In addition, the well-cleaved end-facets also contribute to the low scattering loss of the optical cavities. When the two nanowires (with lengths of 3.86 and 5.14 μm, respectively) were individually pumped, multiple F-P lasing modes have been observed (Figure 9B, green and red lines). Interestingly, when both of the two nanowires were excited, single-mode lasing was generated from the coupled nanowire cavity (blue line in Figure 9B). This study provides an effective way to improve the emission quality by increasing the optical gain in a tailored geometry. In 2016, Wang et al. demonstrated another mode selection mechanism to realize a single-mode laser (Wang et al., 2016). A single-crystalline perovskite nanowire was transferred onto a perovskite microplate by micro-manipulation via a home-made fiber probe (Figure 9E). Due to the identical refractive index of the nanowire and microplate, the quality (Q) factors of the F-P modes were spoiled. Then the natural F-P modes along the longitudinal direction of the nanowire could be significantly suppressed, because of the strong leakage to the perovskite microplate (Gu et al., 2015). Consequently, only the mode in the transverse plane of the nanowire survives and could lase. As demonstrated in Figure 9E, single-mode lasing was obtained when the sample was optically excited by a femtosecond pulsed laser. The local bright emission spot instead of two emission spots of F-P lasers has been clearly captured by optical microscopy (inset in Figure 9E).
Figure 9
Shortly after, Zhang et al. reported another strategy to enable dual-color single-mode lasing, as schematically illustrated in Figure 9C (Zhang C. et al., 2017). An axially coupled nanowire cavity was constructed by two nanowires self-assembled from distinct organic materials. With the assistance of a micromanipulator, these two resonators were integrated to achieve a significant mode selection effect. Lasing actions with multiple peaks at different wavelengths could be readily observed from a single nanowire cavity, as shown in the top and middle panels of Figure 9D. After axially aligning the two nanowires, each nanowire served as a spectral filter to select the mode in the coupled cavity and the single-mode emission could be expected. The nanowire on the left side was solely excited and modulated by the nanowire on the right side. Single-mode lasing (458 nm) was clearly established at this time, as shown in the top panel in Figure 9D. When the nanowire on the right side was pumped, the roles of two nanowires reversed and contributed to the single-mode lasing at 554.8 nm. Moreover, this mutual mode selection effect in the axially coupled heterogeneous nanowire cavities would enable the output of the dual-wavelength single-mode laser when the two coupled nanowires were simultaneously optically excited (see the bottom panel in Figure 9D). The proposed mechanism not only allows for achieving multicolor single-mode lasing but also permits the controllable outcoupling of the modulated lasers at nanoscale, providing new ideas for the construction of photonic elements with desired functionalities.
Based on the similar mode selection mechanism, Zhao et al. demonstrated switchable single-mode microlasers from perovskite nanowire in 2018 (Zhao et al., 2018). A vapor-responsive organic microdisk tangentially coupled with a perovskite nanowire. The nanowire serves as both gain medium and F-P cavity, while the coupled organic microdisk functions as a spectral filter to the lasing modes of the perovskite. As a result, single-mode lasing could be achieved in such a combined nanowire-microdisk system, as illustrated in Figure 10a. The single nanowire shows broad PL spectrum without the coupled microdisk. However, the PL spectrum was clearly modulated and dips were observed when the microdisk tangentially coupled with the nanowire. Therefore, some lasing modes of the nanowire would be suppressed by the spectra dips at the same wavelengths formed via microdisk modulation, leading a single-mode lasing, as shown in Figure 10b. In addition, the microdisk shows inherent sensitivity to acetone gas and exhibits changes of effective radius with the acetone concentration. In this sense, the transmittance spectra of the microdisk could be varied when the gas was introduced. Consequently, the survived mode of the nanowire could be switched by tuning the gas concentration, confirming the potential application of the sensing function.
Figure 10
In addition to the above mechanisms to achieve single-mode lasing, Bao et al. proposed a mode selection scheme using a Mach-Zehnder interferometer (MZI) structure (Bao et al., 2020), as shown in Figure 10c. A CdS nanowire is used as gain medium and is evanescently coupled with an Ω-shaped silicon nitride (SiN) to form the hybrid MZI structure, as the SEM image shown in Figure 10d. The bent areas of the SiN waveguide ensure the high coupling efficiency (Chen et al., 2017). When both sides of the nanowire were fully coupled with the SiN waveguide, the established MZI structure selects only one dominant lasing mode by suppressing all other modes of the CdS nanowire. Under optical pumping, bright green light emissions have been observed from the two end-facets of nanowire and two grating couplers (see Figure 10e). Moreover, a clear single-mode feature was proved by the measured spectra, as shown in Figure 10f. The maximum value of the side-mode suppression ratio (13 dB) could be reached at the pumping density of 5.2 kW cm−2. The “S-like” curve in Figure 10g confirms the lasing action of the on-chip nanowire laser. Compared with previously reported nanowire lasers, this work achieves much higher efficiency and can be operated in the single-mode regime with a small footprint and high flexibility. Furthermore, such an on-chip integration scheme can be extended to other semiconductor nanowire materials and readily realize integrated laser from UV to near IR regions.
Wavelength-Tunable Lasers
The nanoscale size of nanowire offers the opportunity to realize devices with ultrasmall footprints and mode volumes. However, such properties aggrandize the difficulty to modify the optical properties such as wavelength of the nanowire. A number of approaches have been proposed to achieve wavelength tunability by modifying the dielectric environment via excitation intensity (Johnson et al., 2003), cavity size (Li et al., 2013), or substrate properties (Liu X. et al., 2013). In addition, tailoring the material composition and bandgap is another route to modify the emission color. In the past two decades, an expanse of semiconductor nanowire lasers with tunable wavelength have been demonstrated, for instance, ZnxCdS1−x (Liu et al., 2005), CdxSSe1−x (Pan et al., 2005, 2006, 2009b; Liu et al., 2007; Zapien et al., 2007), InxGa1−xN (Kuykendall et al., 2007), and metal halide perovskite (Xing et al., 2015; Zhu et al., 2015). In 2013, Liu et al. reported a novel design by engineering the material composition and cavity shape to realize lasing with a wide tuning range (Liu et al., 2013). On one hand, the composition along the CdSe alloy nanowire axis was purposely engineered through nanoscale manipulation. The sulfur composition x of CdSxSe1−x can be tuned continuously from 1 to 0, enabling a wide and continuous tuning range from green to red. On the other hand, one end of the nanowire was looped to create two weakly coupled optical cavities, as shown in Figures 11A,B. Thus, the absorption of the short wavelength in the narrow-gap section can be decreased, resulting in the lasing actions of two cavities simultaneously. Two excitation beams with different intensities were employed to separately pump the CdSe-rich straight part and CdS-rich loop, as shown in Figure 11B. By adjusting the intensities of two beams, the output color at the junction area (red box in Figure 11B) can be tuned as green, yellow-green, yellow, and orange, as the optical images shown from B1 to B4 in Figure 11B. The corresponding lasing spectra (C1-C4 in Figure 11C) of B1-B4 uncovers that the essence of tunable color originates the mixture of orange and green light with different weights by varying the pumping power difference of two beams. Additionally, the obtained colors from the nanowire laser match well with the CIE1931 color space and any color on the dashed line (Figure 11D) is available by precisely controlling the intensity ratio of two excitation beams.
Figure 11
Different from engineering the axial composition of alloy nanowire, Li et al. demonstrated a wide-wavelength tunable laser from a single nanowire based on absorption-emission-absorption (AEA) (Li et al., 2013). As shown in Figure 11E, a single 150-μm-long, 402-nm-diameter CdSe nanowire was excited at different positions along the axis direction (as marked by A-E in Figure 11E). Then the PL were collected from the right end of the nanowire, as the dashed box shown in Figure 11E. Because the self-absorption of the higher energy photons and re-emission of low energy photons are related to the propagation distance, clear PL red-shifts from 714 to 740 nm (see the spectra plotted in Figure 11F) have been observed by changing the distance between pumping point and collection point from 5 to 130 μm. Such a scheme provides a flexible way to tailor lasing wavelength and is promising in applications ranging from communication to detection (Hinkley and Kelley, 1971; Chu et al., 2009). In the same year, Liu et al. demonstrated a wavelength tunable laser based on the notion of the Burstein-Moss (BM) effect (Liu X. et al., 2013). Under strong optical pumping, the Fermi energy level in the conduction band may arise due to the state-filling close to the bottom of the conduction band, consequently leading to the blue shift of the optical gap (Burstein, 1954), as illustrated in Figures 12A–C. The strength of the BM shift is proportional to , where ne is the electron carrier concentration in the conduction band which is proportional to the pump fluence and inversely proportional to the nanowire diameter. In this sense, the wavelength of nanowires could be manipulated by varying the pumping intensity or the nanowire size (Sun et al., 2013). As demonstrated in Figure 12D, Liu et al. fabricated the hybrid plasmonic devices with different thicknesses of the insulator layer (5, 10, 20, 100 nm). To avoid the influence of nanowire size, a series of CdS nanowires with approximately the same length (i.e., ~10 ± 0.5 μm) and diameter (i.e., ~220 ± 10 nm) were selected. When decreasing the SiO2 insulator gap from 100 to 5 nm, the local carrier concentrations could be dramatically enhanced and this subsequently improved the BM effect. Thus, given an excitation above the lasing threshold (8 μJ cm−2), a considerable tuning range of >20 nm has been observed, as illustrated in Figure 12E. Notably, the lasing modes were confirmed to be photonic rather than plasmonic. They collected the polarization-dependent emission spectra, as summarized in Figure 12F. It is seen that the emission polarization for an insulator gap of 5 nm was perpendicular to the axis of the nanowire, which matches well with the characterization of transverse electric mode, i.e., photonic mode (Oulton et al., 2009). The strong energy transfer from SPPs to CdS excitons highly enhances the BM effect and provides a valid way to manipulate the light-mater interactions at nanoscale.
Figure 12
WGM Lasers
Compared with WGMs, the nanowire F-P cavity shows a relatively low Q-factor, because the low reflectivity from the end facets of the semiconductor nanowire create a giant light leakage into the free space and a high lasing threshold. Due to the flexibility of manipulating the nanowire into on-demand shapes and tailoring nanowire into a closed loop, nanowires have been an excellent platform to obtain WGMs and have also attracted tremendous attentions in the recent years. Usually, a circular optical cavity can be formed by connecting the two ends of the nanowire. The evanescent coupling between two ends ensures sufficient energy exchange (Law et al., 2004; Gu et al., 2015) and positive feedback. As shown in Figures 13a–c, a ring structure was constructed by overlapping the two ends of the GaN nanowire with the micromanipulator (Pauzauskie et al., 2006). The periodic mode peaks have been observed from this ring cavity (Figure 13d) and the measured mode spacings match well with calculated value by , clearly confirming the formation of WGMs in this structure. In 2009, the similar WGMs lasing from CdS nanowire has also been reported by Ma et al. (2009). Furthermore, they constructed a ring-F-P coupled structure to guide the output and modulate the WGMs of the ring cavity. Later, Ma et al. demonstrated a pigtail structure with high collection efficiency by coupling a tapered nanofiber (Pigtailed, 2010). In 2011, a single-nanowire single-mode laser was demonstrated by Xiao et al. (2011) By folding the CdS nanowire into loops (Figures 13e–j), mode selection is realized by the Vernier effect of the coupled cavities and a single-mode emission of around 738 nm was obtained. The ∞-shaped cavities enlarged the FSR to 3 nm and suppressed the lasing modes of the two individual cavities. Thus, only one dominant mode was selected within the lasing range. As confirmed in Figures 13k–m, the lasing spectra varied with the change of the cavity shapes. Multiple modes with FSR of ~0.75 nm can be observed for the case in Figure 13h, corresponding to the calculated value by FSR, where L = 75 μm is the nanowire length and ng ≈ 4.8 is the group index of the CdSe nanowire. Once the loop mirrors have been established, single mode lasing with a side mode suppression ration of up to 20 dB was achieved, as the spectra plotted in Figure 13m.
Figure 13
In addition to tailoring the nanowire into circular shapes, another strategy of transferring semiconductor nanowire onto circular cavity has been developed. In 2012, Wang et al. proposed a hybrid structure consisting of a single CdSe nanowire and a silica microdisk cavity (Wang et al., 2012), as shown in Figures 14a–c. Such a combined system simultaneously possesses the large gain of nanowire and high-Q of the microdisk. A Q-factor higher than 105 at 1.5 μm was achieved, enabling a low threshold on-chip lasing at room temperature. The SEM image of the hybrid structure in Figure 14b shows that the nanowire lay on edge of the microdisk which assured the large overlap between the gain in nanowire and the WGMs in microdisk. When the hybrid cavity was optically pumped, the WGMs with the highest Q-factor lased first under excitation density of 110 μJ cm−2, as shown in Figure 14e. Given a higher pumping power, multiple lasing peaks with FSR of ≈8.9 nm and linewidth of ≈0.18 nm have been observed. Clear light scattering can be seen at the two end-facets of the nanowire and the rim of the microdisk (Figure 14d). Figures 14f–h show the spectra evolution of the emitted light from the microdisk-nanowire system.
Figure 14
Applications
Up to now, the nanowires have been thoroughly investigated for their materials, structures, and physics, boosting the rapid development of nanowire-based devices. Also, the significant progress in synthesis methods and fabrication techniques offers a valued opportunity to manipulate light at nanometer scale, which significantly promotes the research on nanowire applications including (but not limited to) photonic networks (Sirbuly et al., 2005; Guo et al., 2009; Gu et al., 2016), sensing (Meng et al., 2011), optical switching (Zhang N. et al., 2019), and display (Yang et al., 2011). The length, flexibility, and strength of semiconductor nanowires make them easier than other nanostructures to build novel and versatile photonic circuitry. As confirmed in Figure 15A, Sirbuly et al. explored the possible application of SnO2 in optical routing and networks (Sirbuly et al., 2005). A rectangular grid (46 μm long and ≈ 25 μm wide) was constructed by four nanoribbons. Seven output channels (marked as 1–7 in Figure 15A) could be monitored when the long input channel was directly excited. Different intensity distribution of 1 >> 6 > 4 ≈ 7 > 3 > 5 > 2 has been obtained after considering the trajectory of the incoming light and the intensity of scattering at the four ribbon-ribbon junctions (as shown in Figure 15B). In 2008, Gu et al. reported the highly versatile nanosensors using polymer single nanowires (Gu et al., 2008). As shown in Figure 15C, the subwavelength diameter of the nanowire provides adequate evanescent coupling between the nanowire and the surrounding medium. When the environment humidity changed, the corresponding refractive index difference between the nanowire and environment varied, which modified the leakage, consequently modifying the transmission spectra of the nanowire. The small footprint, fast response, and high sensitivity of the demonstrated nanosensors open up vast opportunities for fast detection in physical, chemical, and biological applications. Recently, Yang et al. reported an ultracompact microspectrometer based on a single compositionally engineered nanowire (Yang Z. et al., 2019), as shown in Figure 15D. The CdSxSe1−x nanowires with a continuous gradient of bandgaps spanning from 1.74 to 2.42 eV have been synthesized and transferred onto Si/SiO2 substrate. The unknown incident light F(λ) can be reconstructed by solving the a system of linear equations after measuring the generated photocurrent data. The demonstrated ultracompact functional device offers a significant step forward for the customized design of ultraminiaturized systems.
Figure 15
Outlook
Research conducted over the past 20 years has contributed greatly to the flourishment of semiconductor nanowires, including physics, synthesis, and applications. In particular, great progress has been made by expanding the range of available materials and cavity structures, achieving greater control over the alloy composition and lasing mode, and reducing lasing thresholds. However, many fundamental issues and questions still remain. (1) The light collection efficiency of the nanowire lasers should be improved to a higher level. Though the end-facet reflections of nanowire are sufficient to form an optical cavity that satisfies energy recycling, the considerable scattering into free space at the facet-air interfaces is a critical leaky channel which causes a huge waste of emissions. (2) Further study is needed to improve the Q-factor of the nanowire cavity. It is worth mentioning that most works to improve the Q-factor or reduce the lasing threshold of nanowires are demonstrated by ameliorating structural and material properties. Cavity design using other concepts such as avoided resonance crossing (Song and Cao, 2010) can be a possible approach to acquire mode with a high Q factor in arrayed nanowire. (3) More must be done on electric injection of semiconductor nanowire lasers to achieve commercial applications. Electrical injection is almost a necessity for all semiconductor laser applications, especially for integrated photonics. The rapid development of nanowire technologies has provided numerous exciting opportunities for electronic and photonic applications. One of the utmost important goals for developing nanowire is to construct ultracompact, small footprint devices. (4) Significant efforts are still required to fabricate and operate nanowire lasers with high reproducibility and stability, especially on the level of individual nanowires. Overall, considering such remarkable progress in nanowire photonics, there is plenty of room in either nanowire integrated circuitry or individual nanowire devices. Challenges and opportunities coexist in the future research on semiconductor nanowires.
Statements
Author contributions
ZG, SX, and QS discussed the results and wrote the paper. All authors contributed to the article and approved the submitted version.
Funding
This work was supported by the Postdoctoral Science Foundation (2017M621274) and the National Natural Science Foundation of China (61905113).
Conflict of interest
The authors declare that the research was conducted in the absence of any commercial or financial relationships that could be construed as a potential conflict of interest.
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Summary
Keywords
nanowire, lasers, cavity, photonic circuits, waveguides
Citation
Gu Z, Song Q and Xiao S (2021) Nanowire Waveguides and Lasers: Advances and Opportunities in Photonic Circuits. Front. Chem. 8:613504. doi: 10.3389/fchem.2020.613504
Received
02 October 2020
Accepted
03 December 2020
Published
08 January 2021
Volume
8 - 2020
Edited by
Anatoly P. Pushkarev, ITMO University, Russia
Reviewed by
Patrick Parkinson, The University of Manchester, United Kingdom; Qing Yang, Zhejiang University, China
Updates
Copyright
© 2021 Gu, Song and Xiao.
This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.
*Correspondence: Qinghai Song qinghai.song@hit.edu.cnShumin Xiao shumin.xiao@hit.edu.cn
This article was submitted to Nanoscience, a section of the journal Frontiers in Chemistry
Disclaimer
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