CORRECTION article

Front. Chem., 04 August 2022

Sec. Supramolecular Chemistry

Volume 10 - 2022 | https://doi.org/10.3389/fchem.2022.953052

Corrigendum: Rigidity and Flexibility in Rotaxanes and Their Relatives; On Being Stubborn and Easy-Going

  • Department of Chemistry, Indiana University, Bloomington, IN, United States

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In the original article, there were mistakes in some of the figures as published. The corrected figures are below.

In Figure 1F, the cyclodextrin was missing from the repeating unit.

FIGURE 1

In Figures 5D,E, the organic substituents on the lower porphyrin ring were incorrect.

FIGURE 5

In Figure 6, the chelating units on the thread consisted of a 4,7-phenanthroline and two pyridines rather than two 2,2′-bipyridines. In addition, the zinc coordinates to triazole in Figure 6B on both the top and bottom thread, not a pyridine nitrogen. Ar labels were also provided.

FIGURE 6

In Figure 13A, the methyl groups on the exterior pyridines were in the wrong position. The number of methylene carbons was fixed.

FIGURE 13

In Figure 14D, the +2e and –2e were going in the wrong direction. The oxidized tetrathiafulvalene structure had a bridging double bond instead of a single bond.

FIGURE 14

The H2O and DMSO solvent labels were flipped in Figures 15C,D.

FIGURE 15

In the original article there was an error in the section Translating Molecular Designs Into Bulk Materials, page 18, last paragraph. The correct description of Figure 4 is as follows:

“Ke showed that DMSO causes the 3D printed object to smear (Figure 4DFigure 4B), and water recovers the original shape (Figure 4BFigure 4D).”

The authors apologize for these errors and state that this does not change the scientific conclusions of the article in any way. The original article has been updated.

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Publisher’s note

All claims expressed in this article are solely those of the authors and do not necessarily represent those of their affiliated organizations, or those of the publisher, the editors and the reviewers. Any product that may be evaluated in this article, or claim that may be made by its manufacturer, is not guaranteed or endorsed by the publisher.

Summary

Keywords

conformations, flexible, host-guest chemistry, macrocycle, polyrotaxane, pseudorotaxane, rigid, rotaxane

Citation

Fadler RE and Flood AH (2022) Corrigendum: Rigidity and Flexibility in Rotaxanes and Their Relatives; On Being Stubborn and Easy-Going. Front. Chem. 10:953052. doi: 10.3389/fchem.2022.953052

Received

25 May 2022

Accepted

02 June 2022

Published

04 August 2022

Volume

10 - 2022

Edited and reviewed by

Tsuyoshi Minami, The University of Tokyo, Japan

Updates

Copyright

*Correspondence: Amar H. Flood,

This article was submitted to Supramolecular Chemistry, a section of the journal Frontiers in Chemistry

Disclaimer

All claims expressed in this article are solely those of the authors and do not necessarily represent those of their affiliated organizations, or those of the publisher, the editors and the reviewers. Any product that may be evaluated in this article or claim that may be made by its manufacturer is not guaranteed or endorsed by the publisher.

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