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ORIGINAL RESEARCH article

Front. Nutr.

Sec. Nutrition and Food Science Technology

This article is part of the Research TopicNutritional Quality of Postharvest Fruits and VegetablesView all 3 articles

Temperature-regulated defective MIL-100(Fe) for clove essential oil loading as an effective natural preservative for peaches

Provisionally accepted
Naiding  WangNaiding Wang1Jun  ZhangJun Zhang2Rongpeng  LiRongpeng Li2Yanqing  DuanYanqing Duan1Ruizhi  ZhuRuizhi Zhu3Lei  YangLei Yang3Haotian  YangHaotian Yang1Yuandong  LiYuandong Li1Juxing  JiangJuxing Jiang1Yanqun  XuYanqun Xu3*Zhigang  TaiZhigang Tai2*
  • 1Yunnan Tobacco Industrial Hi-tech Material Co., Ltd, Kunming, Yunnan Tobacco Company, Kunming, China
  • 2Kunming University of Science and Technology School of Life Science and Technology, Kunming, China
  • 3R&D Central of China Tobacco Yunnan Industrial Co., Ltd, Kunming, China Tobacco Yunnan Industrial Corporation, Kunming, China

The final, formatted version of the article will be published soon.

The perishability of fruits and vegetables poses significant challenges for their transportation and storage. Clove essential oil (CEO) is a natural preservative, but its high volatility and instability limit its practical application. In this study, a series of novel defective MIL-100(Fe)-x (D-MIL-100(Fe)-x, where x represents the molar ratio relative to iron: 1, 5, 10, or 15) were synthesized using trifluoroacetic acid (TFA) as a modulator and subsequently loaded with CEO to enhance stability and enable sustained release for peach preservation. Among these, D-MIL-100(Fe)-1 exhibited the highest CEO loading capacity of 610.6 mg/g, 1.45 times greater than that of conventional MIL-100(Fe). The composite demonstrated significant sustained-release behavior, releasing 42.3% of CEO over 16 days at 25 °C. D-MIL-100(Fe)-1/CEO showed a preservative effect comparable to that of the refrigerated group, offering enhanced versatility, convenience, and cost-effectiveness. This study provides a novel † Naiding Wang, Jun Zhang, and Rongpeng Li contributed equally to this work and should be considered co-first authors. defective MIL-100(Fe)-x for effective essential oil loading, providing a safe and biocompatible method for preserving fruits and vegetables.

Keywords: antibacterial activity, Clove essential oil, Defective MIL-100(Fe)-x, Peach preservation, sustained release

Received: 27 Nov 2025; Accepted: 23 Jan 2026.

Copyright: © 2026 Wang, Zhang, Li, Duan, Zhu, Yang, Yang, Li, Jiang, Xu and Tai. This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) or licensor are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.

* Correspondence:
Yanqun Xu
Zhigang Tai

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