In the original article, there were mistakes in Table 1 as published. Table 1 aimed to compare all glum values at specific wavelengths of four LnIII tris(β-diketonates) (LnIII: EuIII and TbIII) upon intermolecular chirality transfer from CABu, CTA, Glu (D- and L-), Ara (D- and L-), and α-pinene for clarity and readability. However, although the glum values described in the main text are correct, most data in the three right-side columns of Table 1 are incorrectly displayed. Also, in Table 1 caption, D-/L-glucose pentameyhyl esters should be D-/L-glucose pentamethyl esters. The corrected Table 1 with corrected numerical values in the three right-side columns and corrected caption appears below.
Table 1
| LnIII tris(β- diketonates) | CABu glum/10−2 (nm) | CTA glum/10−2 (nm) | Glu glum/10−2 (nm) | Ara glum/10−2 (nm) | α-pinene glum/10−2 (nm) | |||
|---|---|---|---|---|---|---|---|---|
| D- | L- | D- | L- | (1R) | (1S) | |||
| Eu(fod)3 | +6.71 (593)a −0.59 (613)b | +4.63 (593)a −0.40 (613)b | +1.05 (594)a −0.19 (612)b | −0.81 (596)a +0.08 (613)b | +0.19 (593)a −0.02 (607)b | −0.30 (591)a +0.06 (611)b | −0.49 (593)f +0.05 (613)f | +0.41 (593)f −0.04 (613)f |
| Eu(dpm)3 | n.d. g | n.d. g | n.d. g | n.d. g | n.d. g | n.d. g | n.d. g | n.d. g |
| Tb(fod)3 | −0.29 (490)c +0.78 (540)d −0.18 (552)e | −0.10 (490)c +0.35 (542)d −0.07 (553)e | n.d. g | n.d. g | n.d. g | n.d. g | n.d. g | n.d. g |
| Tb(dpm)3 | −0.53 (491)c +0.37 (537)d −0.59 (547)e | −0.44 (489)c – +0.80 (547)e | n.d. g | n.d. g | n.d. g | n.d. g | n.dg (~490) +0.44d (537) −0.13e (547) | n.dg (~490) −0.49d (537) +0.34e (548) |
CPL characteristics (dissymmetry ratio, glum in 10−2 at specific wavelength) of EuIII and TbIII coordinated with three β-diketonates as achiral ligands embedded in two polysaccharide alkyl esters (CABu and CTA), D-/L-glucose pentamethyl esters (D-/L-Glu), and D-/L-Arabinose tetramethyl esters (D-/L-Ara).
All numerical values in bracket mean wavelength extremum for CPL signals.
EuIII5F1 (593 nm),
EuIII5F2 (613 nm),
TbIII5F6 (490 nm),
TbIII5F5 (I) (540 nm),
TbIII5F5 (II) (552 nm),
Data were taken from literature (Jalilah et al., 2018).
Not characterized or no data.
Also, there was an error in Introduction. The sentence starting with “Particularly, chirogenesis in metal coordination chemistry by the chirality transfer has long been one of the central subjects in inorganic chemistry 1 (Mason and Norman, 1965…)” should read as follows: “Particularly, chirogenesis in metal coordination chemistry by the chirality transfer has long been one of the central subjects in inorganic chemistry (Mason and Norman, 1965…)”.
The authors apologize for these errors and state that this does not change the scientific conclusions of the article in any way. The original article has been updated.
References
1
JalilahA. J.AsanomaF.FujikiM. (2018). Unveiling controlled breaking of the mirror symmetry of Eu(Fod)3 with α-/β-pinene and BINAP by circularly polarised luminescence (CPL), CPL excitation, and 19F-/31P{1H}-NMR spectra and mulliken charges. Inorg. Chem. Front.5, 2718–2733. 10.1039/C8QI00509E
2
MasonS. F.NormanB. J. (1965). Outer-sphere co-ordination and optical activity in transition-metal complexes. Chem. Commun. 335–336. 10.1039/c19650000335
Summary
Keywords
non-covalent interaction, circularly polarized luminescence, circular dichroism, europium, terbium, cellulose, saccharide, terpene
Citation
Fujiki M, Wang L, Ogata N, Asanoma F, Okubo A, Okazaki S, Kamite H and Jalilah AJ (2020) Corrigendum: Chirogenesis and Pfeiffer Effect in Optically Inactive EuIII and TbIII Tris(β-diketonate) Upon Intermolecular Chirality Transfer From Poly- and Monosaccharide Alkyl Esters and α-Pinene: Emerging Circularly Polarized Luminescence (CPL) and Circular Dichroism (CD). Front. Chem. 8:598729. doi: 10.3389/fchem.2020.598729
Received
25 August 2020
Accepted
31 August 2020
Published
02 October 2020
Volume
8 - 2020
Edited and reviewed by
Keiji Hirose, Graduate School of Engineering Science, Osaka University, Japan
Updates
Copyright
© 2020 Fujiki, Wang, Ogata, Asanoma, Okubo, Okazaki, Kamite and Jalilah.
This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.
*Correspondence: Michiya Fujiki fujikim@ms.naist.jp; michiyafujiki@icloud.comAbd Jalil Jalilah jalilahjalil@unimap.edu.my
This article was submitted to Supramolecular Chemistry, a section of the journal Frontiers in Chemistry
†ORCID: Michiya Fujiki orcid.org/0000-0002-3139-9478
Laibing Wang orcid.org/0000-0002-3380-7826
Abd Jalil Jalilah orcid.org/0000-0003-1265-0919
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