Editorial: High-T_c Superconductivity in Electron-Doped Iron Selenide and Related Compounds

Iron-selenide superconductors comprise a particularly interesting group of materials inside the family of iron-based superconductors. The simplest member of the group is bulk FeSe, which has a modest critical temperature of T_c = 9 K. Like iron-pnictide superconductors, bulk FeSe shows a structural transition at T_s = 90 K from a tetragonal to an orthorhombic phase driven by nematic ordering of the electronic degrees of freedom. Angle-resolved photoemission spectroscopy (ARPES), for example, reveals a small hole Fermi surface pocket at the center of the Brillouin zone and two electron Fermi surface pockets at the corner of the Brillouin zone, each with unequal d_xz/d_yz-orbital character. Unlike in iron-pnictide superconductors, however, no magnetic order coexists with the nematic order at temperatures below the structural transition. Inelastic neutron scattering (INS) spectroscopy finds a spin resonance inside the energy gap of the superconducting phase in bulk FeSe, however, at wavevectors corresponding to a stripe spin-density wave (SDW) [1]. It strongly suggests s⁺⁻ superconductivity across the hole and electron Fermi surface pockets driven by associated antiferromagnetic spin fluctuations. INS also finds spin fluctuations at the Néel wavevector (π, π) above the superconducting energy gap [2]. This suggests that superconductivity, nematic order, stripe-SDW order, and some type of Néel antiferromagnetic order compete at low temperature in bulk FeSe. One of the editors of the research topic has proposed that the latter is hidden Néel order [3, 4]. The superconducting critical temperature increases dramatically to 30–40 K and above upon doping iron selenide with electrons. The latter has been achieved in various ways; for example, by alkali-metal intercalation, by placing a monolayer of FeSe on a substrate, and by organic-molecule intercalation. ARPES finds that the hole bands at the center of the Brillouin zone lie buried below the Fermi level. INS finds a spin resonance inside the superconducting energy gap, but it lies midway between the SDW and Néel wavenumbers [5]. INS also finds peaks and rings of low-energy spin excitations above the energy gap around the Néel wavevector [6, 7]. ARPES and scanning tunneling microscopy (STM) find a non-zero superconducting energy gap. The situation with electron-doped FeSe is rather puzzling then, with high-T_c superconductivity existing over electron Fermi surface pockets alone! This is not expected in iron-selenide superconductors, where electron-electron repulsion is strong [8]. The latter requires that the sign of the pair wave function oscillates over the Brillouin zone [4].

It is our pleasure to introduce eight articles from the Research Topic that address many of the unsolved problems that have emerged in the field of iron-selenide superconductors, some of which we have listed above. The contributions to the Research Topic contain articles on both theory and experiment, with four papers reporting on original research, and with four review papers. Chen et al. review how nematicity in bulk iron selenide can be scrutinized by exploiting detwinning techniques [9], while Coldea reviews the series of nematic superconductors FeSe_1−xS_x [10]. Both articles tackle the interplay between nematicity and superconductivity that exists in bulk FeSe, with or without chemical substitutions. Yeh et al. show that insulating Fe₄Se₅ becomes a superconductor with T_c = 8 K after proper annealing [11]. They thereby argue that Fe₄Se₅ is the insulating parent compound for iron-selenide superconductors. It would clearly be useful to compare future studies of the low-energy spin excitations in Fe₄Se₅ with those of its electron-doped counterpart Rb₂Fe₄Se₅ [5, 6]. Finally, Dong et al. review a new soft-chemical technique to grow high-quality single crystals of organic-molecule intercalated FeSe [12]. Their samples have critical temperatures of T_c = 42 K, and they notably show record critical currents.

On the theory side, Yu et al. review 3d-orbital-selective physics in iron superconductors [13]. They point out how the d_xy orbital is the one most susceptible to Mott localization in iron-selenide superconductors [8]. They also emphasize how the relatively small energy splitting between the d_xz/d_yz orbitals that is seen by ARPES in the nematic phase of bulk FeSe, ΔE_Γ and ΔE_M < 50 meV, can be reconciled with the large orbitally-dependent wavefunction renormalizations seen by STM in the same phase, Z(d_yz)/Z(d_xz) = 4. Dzero and Khodas study the effect of point disorder on the stripe SDW state by exploiting a quasi-classical Green’s function technique [14]. They find that the tetragonally symmetric stripe SDW state is more robust with respect to disorder than the orthorhombically symmetric one. This result could have bearing on the absence of magnetic order in the nematic phase of bulk FeSe, for example. Last, Ptok et al. study a two-band model for iron superconductors that includes intra-band and inter-band coupling between Cooper pairs [15]. They notably find Cooper pair states in relative orbitals of mixed symmetry. Finally, Gupta et al. applied muon-spin rotation/relaxation (μSR) on the iron-pnictide superconductor NdFeAsO_0.65F_0.35, thereby obtaining London penetration lengths [16]. Interestingly, a two-band analysis of their data yields only weak inter-band coupling of the Cooper pairs.

The brief survey above of the author contributions to the Research Topic conveys the richness of the field of iron-selenide superconductivity and related materials. We believe that you will enjoy reading the Research Topic.

Statements

Summary

Keywords

iron chalcogenide, iron-based superconductor Fe(SeTe), iron selenide superconductors, high-temperature superconductors, antiferromagnetic ordering

Citation

Rodriguez JP, Inosov DS and Zhao J (2022) Editorial: High-T_c Superconductivity in Electron-Doped Iron Selenide and Related Compounds. Front. Phys. 10:885420. doi: 10.3389/fphy.2022.885420

Received

28 February 2022

Accepted

25 April 2022

Published

13 May 2022

Volume

10 - 2022

Edited and reviewed by

James Avery Sauls, Northwestern University, United States

Updates

Check for updates

Copyright

© 2022 Rodriguez, Inosov and Zhao.

This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.

*Correspondence: Jose P. Rodriguez, jrodrig@calstatela.edu

This article was submitted to Condensed Matter Physics, a section of the journal Frontiers in Physics

Disclaimer

All claims expressed in this article are solely those of the authors and do not necessarily represent those of their affiliated organizations, or those of the publisher, the editors and the reviewers. Any product that may be evaluated in this article or claim that may be made by its manufacturer is not guaranteed or endorsed by the publisher.