ORIGINAL RESEARCH article
Front. Mater.
Sec. Structural Materials
This article is part of the Research TopicFunctional Materials for Sustainable Pavement Engineering: Multi-scale Design and Environmental IntegrationView all 9 articles
Effect of Fly Ash Content on the Leaching Resistance of Shotcrete
Provisionally accepted- 1Guangxi Guilu Expressway Co, Ltd., Nanning, China
- 2Guangxi University, Nanning, China
Select one of your emails
You have multiple emails registered with Frontiers:
Notify me on publication
Please enter your email address:
If you already have an account, please login
You don't have a Frontiers account ? You can register here
To investigate the influence of fly ash (FA) content on the leaching resistance of shotcrete, this study adopted FA replacement ratios as the main variables (0%, 15%, 20%, 25%). Shotcrete specimens were prepared using the wet-mix spraying method and subjected to accelerated leaching tests in a 6 mol/L ammonium chloride solution. Systematic analyses of compressive strength, porosity, leaching depth, and calcium ion leaching amount were conducted to examine the effect of FA content on the leaching resistance of shotcrete. Microstructural evolution was also analyzed using scanning electron microscopy (SEM). The results indicate that the incorporation of FA significantly enhances the leaching resistance of shotcrete. An appropriate amount of FA promotes the formation of additional C–S–H gel through pozzolanic reactions at later stages, improving concrete density and inhibiting calcium ion migration as well as the advancement of the leaching front. With a 20% FA content, shotcrete exhibited optimal leaching resistance: after 90 days of leaching, the compressive strength loss rate was 34.13%, porosity increased by only 3.09%, leaching depth reached 22.09 mm, and the total calcium ion leaching was 3.7 mol/L. The synergistic effect of the pozzolanic reaction and the micro-aggregate effect of FA optimizes the pore structure and reduces the content of soluble calcium phases, thereby enhancing the chemical erosion resistance of concrete. The results demonstrate that reactive components in FA can react with calcium hydroxide from cement hydration to form more stable calcium silicate hydrate, significantly delaying the leaching process of shotcrete. At a 20% replacement ratio, leaching damage is effectively suppressed while mechanical performance is maintained. This study provides theoretical and technical support for mix design and engineering application of shotcrete in erosive environments.
Keywords: Fly ash, Leaching depth, Leaching resistance, Mechanical Properties, Porosity, Shotcrete
Received: 26 Nov 2025; Accepted: 22 Jan 2026.
Copyright: © 2026 Zeng, Wu, Liang, Lan, Liang and Wu. This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) or licensor are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.
* Correspondence: Qingyu Wu
Disclaimer: All claims expressed in this article are solely those of the authors and do not necessarily represent those of their affiliated organizations, or those of the publisher, the editors and the reviewers. Any product that may be evaluated in this article or claim that may be made by its manufacturer is not guaranteed or endorsed by the publisher.
