MINI REVIEW article

Front. Phys., 27 October 2021

Sec. Interdisciplinary Physics

Volume 9 - 2021 | https://doi.org/10.3389/fphy.2021.772238

Harnessing Conductive Oxide Interfaces for Resistive Random-Access Memories

  • Andrew and Erna Viterbi Department of Electrical Engineering, Technion Israel Institute of Technology, Haifa, Israel

Article metrics

View details

7

Citations

4,5k

Views

1,1k

Downloads

Abstract

Two-dimensional electron gases (2DEGs) can be formed at some oxide interfaces, providing a fertile ground for creating extraordinary physical properties. These properties can be exploited in various novel electronic devices such as transistors, gas sensors, and spintronic devices. Recently several works have demonstrated the application of 2DEGs for resistive random-access memories (RRAMs). We briefly review the basics of oxide 2DEGs, emphasizing scalability and maturity and describing a recent trend of progression from epitaxial oxide interfaces (such as LaAlO3/SrTiO3) to simple and highly scalable amorphous-polycrystalline systems (e.g., Al2O3/TiO2). We critically describe and compare recent RRAM devices based on these systems and highlight the possible advantages and potential of 2DEGs systems for RRAM applications. We consider the immediate challenges to revolve around scaling from one device to large arrays, where further progress with series resistance reduction and fabrication techniques needs to be made. We conclude by laying out some of the opportunities presented by 2DEGs based RRAM, including increased tunability and design flexibility, which could, in turn, provide advantages for multi-level capabilities.

Introduction

Two-dimensional electron gases (2DEGs) can be formed at some oxides interfaces [1]. These oxide interfaces provided a fertile ground for the discovery and manipulation of extraordinary physics, such as superconductivity [25], magnetism [6, 7], magnetoelectric coupling [8, 9], Rashba spin-orbit coupling [10], persistent photoconductivity [11, 12], and integer/fractional quantum Hall effect [13, 14]. Over the last decade, leveraging these phenomena towards various devices, such as transistors [1519], diodes [20], gas sensors [21], spintronic devices [22, 23], and memory devices [2429], has drawn considerable attention. In addition to the exotic phenomena listed above, the emergence of a high sheet density of electrons (typically 1012∼1015 cm−2) between two insulators is already attractive for some devices, such as in the role of channels or back electrodes. We note that for the sake of convenience and simplicity, we very broadly use the term 2DEGs as a general name for conductive oxide interfaces, covering 2D, quasi-2D systems, and conducting interfaces where the dimensionality is not well-defined.

Oxide 2DEGs were first reported in epitaxial oxide interfaces, where a complex oxide such as LaAlO3 is grown, typically by pulsed laser deposition (PLD), on a single-crystal oxide substrate, typically SrTiO3 [1, 2] (Figure 1A). Therefore, forming such 2DEGs requires epitaxial oxide thin film deposition at high temperatures. Exploiting 2DEGs for novel electronic devices will significantly benefit from simplifying the materials and deposition methods, where low-temperature, scalable, and microelectronics-compatible approaches are of considerable advantage. Later work has demonstrated that 2DEGs can be formed at more simple interfaces, between amorphous and single-crystalline oxides [30, 31] with the benefit of room temperature preparation. Recently 2DEGs were shown to form even at amorphous/polycrystalline oxide interfaces [17, 21, 32, 33] (Figure 1C). Furthermore, the oxide deposition temperatures were reduced from 650-900°C to 25–300°C, and the deposition techniques have been extended from PLD to the more scalable atomic layer deposition (ALD), which is widely used by the microelectronics industry.

FIGURE 1

Among their various device prospects, recently, 2DEGs were utilized for resistive random-access memories (RRAMs) [2428]. RRAM devices [3436] are highly attractive for the next-generation memories [37, 38] and new computing paradigms [3946]. The potential of 2DEGs in this role has yet to be critically discussed. In this mini review, we briefly review the oxide material systems hosting 2DEGs, focus on their application in the RRAM devices, and finally discuss the challenges and opportunities for 2DEGs in RRAM applications.

Two-Dimensional Electron Gases Formed at Oxide Interfaces

The 2DEG formed in the oxide material system was first observed at the atomically sharp interface between epitaxial LaAlO3 and single-crystalline SrTiO3 substrates, each insulating on its own [1, 2] (Figure 1A). In parallel to significant research into the fundamentals of this rich 2D system [4749], 2DEGs were reported in dozens of other oxide combinations, such as GdTiO3/SrTiO3 [50] and NdTiO3/SrTiO3 [51].

The origin of the 2DEG formed at the LaAlO3/SrTiO3 interface was initially ascribed to polar discontinuity, commonly referred to as the “polar catastrophe”. The LaAlO3 film consisting of charge-alternating planes of LaO+ and AlO2 [52] is grown epitaxially on a TiO2-terminated SrTiO3 substrate. An electrostatic potential builds up in the LaAlO3 layer and increases with its thickness. As the thickness of the LaAlO3 film increases to four unit cells or higher, the voltage drop becomes sufficiently large for electrons to move from the surface of the LaAlO3 film to the LaAlO3/SrTiO3 interface, where they occupy delocalized Ti 3d states in SrTiO3 [5256].

Besides the polar catastrophe mechanism, the ionic aspect of the interface plays an important role in its electronic properties [57]. Interdiffusion and intermixing of atoms across the interface [58] and oxygen vacancies [5961] can account for the 2DEG formation via various ionic doping mechanisms. It is further argued that polar effects can drive such ionic mechanisms by making them more energetically favorable [62, 63]. These ionic features of the interface open opportunities to simplify the 2DEG material systems to non-polar, amorphous oxide materials. As such, the formation of 2DEG and their properties are strongly dependent on the material system, deposition method, and post-deposition processes.

The growth of epitaxial oxides requires slow and high-temperature (typically 650–900°C) processes using PLD or molecular-beam epitaxy (MBE). These features, and their low scalability (PLD), make the 2DEGs formed at epitaxial oxide interfaces incompatible with CMOS processes and large-scale fabrication. The use of amorphous oxide on single crystal oxide substrates [16, 24, 30, 31, 6468] (Figure 1B) lowered the oxide deposition temperatures to <300°C and expanded the deposition methods to ALD. The use of amorphous oxides deposited on polycrystalline oxide [17, 21, 25, 32, 33, 69], which we term “All-ALD 2DEGs”, provides a great advantage towards scalability and integration with existing and future technologies (Figure 1C). We note that significant progress has been demonstrated in MBE-based integration of epitaxial oxide 2DEGs systems with silicon [7072] and other semiconductors [73, 74]. Still, while potentially scalable [75], they remain slow, expensive, and high temperature (∼600°C) and thus fall far behind the non-epitaxial ALD approaches.

This chronological trend of simplifying the materials and fabrication techniques has seen the transition from epitaxial interfaces (e.g., single crystalline LaAlO3/single crystalline SrTiO3, Figure 1A) to amorphous oxides on single-crystals (e.g., a-LaAlO3/single crystalline SrTiO3, Figure 1B), and recently to All-ALD 2DEGs with amorphous-polycrystalline systems (e.g., amorphous Al2O3/polycrystalline TiO2, Figure 1C). The third system allows deposition temperatures to decrease to <300°C, well below the requirements of CMOS backend processes. Such advances hold the significant promise of realizing the potential of 2DEGs into practical devices and maturing them from single device lab-scale demonstrators towards scalable and microelectronics-compatible technology. In this mini review, we focus on the application of 2DEGs in RRAM devices.

Resistive Random-Access Memory Devices

The RRAM device has a simple metal-insulator-metal (MIM) structure with a resistive switching layer(s) sandwiched between two electrodes. It stores information by using different resistance states. For binary information storage, “0” and “1” information can be stored within one device cell using high and low resistance states (HRS and LRS, respectively). For multi-level information storage, more than a single bit of information can be stored within a single device cell using multiple resistance states. For example, information of “00”, “01”, “10”, and “11” can be stored within one device cell using four different resistance states. Besides information storage, RRAM devices are also promising for new computing paradigms [3944], which are faster in speed and lower in energy consumption. The resistive switching processes can accompany typical physical/chemical effects such as electrochemical/thermochemical reactions or metal-insulator transitions [34, 36, 40]. In the conductive filament (CF)-type RRAM devices, the mechanism of the resistance switching is the formation and disruption of conductive filaments (nanometric in diameter) within the resistive switching layer (a few nanometers in thickness) under external electrical stimuli. RRAM devices have many attractive features, such as small device area (4 F2), fast switching speed (<1 ns) [76], high scalability [7779], 3D integration capability [80, 81], and low energy consumption for resistance switching (<10 pJ/bit) [82, 83]. Based on the type of the conductive filaments, the RRAM devices can be divided into two types, which are the valence change memory (VCM) [76] and the electrochemical metallization memory (ECM) [8486], which is also known as conductive-bridge RAM (CBRAM).

Two-Dimensional Electron Gases at Oxide Interfaces for Resistive Random-Access Memory Applications

Recently, 2DEGs have been leveraged for forming different types of RRAMs, by replacing one of the metal electrodes. This path can potentially increase design flexibility, enhance performance, and yield additional interesting properties.

In VCM devices, the 2DEG acts as an unconventional bottom electrode. In addition to the (electronic) conductivity of 2DEGs, their inherent ionic defects and instabilities can induce, interact with, and be utilized to control the resistive switching process. The oxide forming the 2DEG adjacent to the top electrode also acts as the resistive switching layer. The oxygen vacancies drift under the external electric field and create defect-induced gap states within the resistive switching layer during the resistive switching process. Whereas the electronic conduction property of 2DEGs performs as the function of a traditional metal bottom electrode. Several VCM RRAM devices have been recently reported, leveraging such 2DEG electrodes. These include Pt/LaAlO3/SrTiO3 [26], indium tin oxide (ITO)/LaAlO3/SrTiO3 [28], Pt/Ta2O5-y/Ta2O5-x/SrTiO3 [27], and Pt/Al2O3/SrTiO3 [24].

Wu et al. [26] were the first to use oxide 2DEGs in RRAM devices. Their device utilized the 2DEG formed at the epitaxial LaAlO3/SrTiO3 interface as the bottom electrode, the LaAlO3 layer as the resistive switching layer, and the Pt layer as the top electrode layer. The conduction mechanisms are Ohmic transport at the low resistance state (LRS) and tunneling at the high resistance state (HRS). The LaAlO3 layer was deposited on TiO2-terminated SrTiO3 (001) substrates using PLD at 800°C. The device switches based on the electric-field-induced drift of positively charged oxygen vacancies across the LaAlO3/SrTiO3 interface and the creation of defect-induced gap states within the ultrathin LaAlO3 layer. Wu et al. [28] further substituted the Pt top electrode with ITO and demonstrated an optically transparent RRAM device. After replacing the Pt with ITO, the resistance window remained at 100. In contrast, the overall resistance level increased by five orders of magnitude from HRS at 104 Ω and LRS at 102 Ω to HRS at 109 and LRS at 107 Ω. The Pt/LaAlO3/SrTiO3 and ITO/LaAlO3/SrTiO3 structured devices both showed 2000 cycle endurance and 12 h retention, comparable to those in the Pt/LaAlO3/Nb:SrTiO3 structured devices [87].

Joung et al. [27] reported amorphous TaOx/single crystal SrTiO3 based VCM. Ta2O5-y (TO2)/Ta2O5-x (TO1) bilayer of TaOx was deposited using PLD at 200°C under 70–100 mTorr oxygen (TO2) and at 700°C under 0.5 mTorr oxygen (TO1). The interface conductivity results from ionic defects formed during the high-temperature step and possibly kinetic damage from the PLD process. This use of amorphous layers constitutes progress toward simplifying the materials and deposition techniques. However, the PLD process’s high temperature and low scalability remain incompatible with practical applications. The devices showed 2000 cycles endurance and 105 s retention. The best endurance and retention of TaOx based RRAM devices are reported in Pt/Ta2O5-δ/TaO2-β/Pt structured devices [88] with 109 endurance cycles and 7.2 × 106 s retention.

Miron et al. [24] continued this trend of using amorphous layers for the 2DEG formation but focused on simple, low temperature, and scalable deposition. They reported amorphous Al2O3/single crystal SrTiO3 based VCM devices, where the Al2O3 layer was deposited using ALD, with a low deposition temperature of 300°C (Figure 2A). The devices showed a large OFF/ON resistance ratio of ∼106 and low operation currents down to 10−13 A (HRS, Figure 2B) with good cycle-to-cycle uniformity. The memory is based on the formation and rupture of oxygen vacancies filaments inside the Al2O3 layer. The oxygen vacancies driven from the interface into the insulating oxide under high electric fields are the key in enabling the resistive switching behavior. A key feature of this work is the application of low-defect Al2O3 [89], where the 2DEG serves as the bottom electrode and as the source of oxygen vacancies. The oxygen vacancies are injected by the electric field into the insulating Al2O3 to form the conductive filament. The practical consequence of this approach is the trigger of resistive switching behavior as compared to the Pt/Al2O3/Nb:SrTiO3 stuctured device [89] and a large OFF/ON resistance ratio afforded by using a good insulator of Al2O3 as the resistive switching layer and the 2DEG as the bottom electrode [24, 90, 91]. The key shortcoming here was the large set/reset voltages, on the order of ±7 V, another consequence of the insulating Al2O3. Further optimization of these devices, focusing on the insulator thickness, is expected to yield a better tradeoff between lowering the set/reset voltages while preserving the high OFF/ON resistance ratios.

FIGURE 2

As discussed earlier, All-ALD 2DEGs provide the most practical and scalable approach for 2DEG formation. Kim et al. [25] reported the first RRAM application of such 2DEGs, the only reported 2DEG CBRAM device (Figures 2C,D). They demonstrated a Cu conductive filament device based on 2DEG formed between amorphous Al2O3 and polycrystalline anatase TiO2 (Figure 1C). Both materials were fabricated by ALD (250°C) and, most importantly, without a crystalline substrate. The devices showed good endurance of 107 cycles and a high OFF/ON resistance ratio of 106. Four different HRS levels are also achieved by adjusting the amplitude of the operation voltage pulses. The LRS kept constant, whereas the HRS increased as the device areas decreased. This resistance and device area dependency is beneficial for device area scaling. A higher OFF/ON resistance ratio and a lower current level can be achieved as the device area becomes smaller. The Cu conductive filament formed at LRS, observed by TEM, is about 20 nm in diameter. A device diameter of 20 nm is, in principle, the area scaling limit of such a device. This device also showed better endurance and retention behavior than Cu/Al2O3/Pt structured devices [93, 94]. We highlight again the significant progress made by circumventing a single crystalline substrate, which allows integrating these devices on many substrates, such as the backend of silicon chips, flexible electronics [21], and others.

In more conventional VCM-type RRAM devices, the resistive-switching material typically contains some initial number of defects rearranged during the first forming process. A difference of 2DEGs-based VCM RRAM is that one can start with a fairly insulating material and use the 2DEG as an extrinsic source of defects [24]. This provides 2DEGs-based VCM RRAM with significantly larger OFF/ON resistance ratios compared to more conventional approaches. The high OFF/ON resistance ratio offers potential for multi-level resistance operation. The broader ratio provides more room for improvement of this feature, as more distinct states can fit this wider resistivity range [94]. However, multi-level behavior has yet to be reported in 2DEGs based VCM devices due to the abruptness of their switching. Another consequence of the high OFF/ON resistance ratio is extremely low current at HRS, which benefits low-power operation. A comparison of 2DEG based RRAM devices, devices that show close similarity to the 2DEG based device structures, and some other RRAM devices are listed in Table 1.

TABLE 1

Device StructureDevice SizeForming (Yes/No, Vforming, Icc)Top electrodeResistive switching layerBottom electrodeSwitching polaritySET/RESET Voltage (DC)Max Iset/ICC (DC)Max Ireset (DC)SET/RESET Voltage (AC)SET/RESET Switching speed (AC)HRS/LRS (Ω)Resistance ratioEndurance (cycles)Retention (s)
Pt/LaAlO3/SrTiO3 [26]2.25 × 104 μm2Yes, -4 V, 30 mAPtLaAlO3LaAlO3/SrTiO3 2DEGbipolar−4 V/+4 V30 mA/No ICC30 mA−4 V/+4 V5 ns/100 μs104/1021022000>4.32 × 103 (@25°C)
−4 V/+9 V5 ns/1 μs
ITO/LaAlO3/SrTiO3 [28]9 × 104 μm2Yes, -3.3 V, 30 μAITOLaAlO3LaAlO3/SrTiO3 2DEGbipolar−1.5 V/+5 V30 μA/No ICC0.5 nA−5 V/+5 VNot given109/1071022000>4 × 104 (@25°C)
Pt/LaAlO3/Nb:SrTiO3 [87]106 to 104 μm2Yes, -13 V to -40 V (PO2 and tox dependent), ICC not givenPtLaAlO3Nb: SrTiO3bipolar−6 V/+6 V70 mA/no ICC10 mA−8 V/+8 VNot given106/1031032000>4.32 × 103 (@25°C)
ITO/LaAlO3/ITO [94]1.13 × 106 μm2 (⌀ = 1,200 μm)Yes, -1 V to -2.6 V (PO2 dependent), 10 mAITOLaAlO3ITObipolarNot given/+3 VNot given5–10 mANot givenNot given103/10210100Not given
Pt/Ta2O5-y/Ta2O5-x/STO [27]490.63 μm2 (⌀ = 25 μm)Not mentionedPtTa2O5-yTa2O5-x/STO 2DEGbipolar+4 V/−2.5 V2 μA/no ICC1 μANot givenNot given1012/1081042,900>105 (@25°C)
Pt/Ta2O5-δ/TaO2-β/Pt [88]0.25 μm2Not mentionedPtTa2O5-δ/TaO2-βPtbipolar−0.9 V/+2 V170 μA/170 μA170 μA2 V/−1.5 V10 ns103/102101091.08 × 107 (@150°C)
Pt/Al2O3/STO [24]2.7 × 104 to 1.5 × 105 μm2Yes, -6 V to −4 V, 0.1 mAPtAl2O3Al2O3/STO 2DEGbipolar−7 V/+7 V0.5 mA/not mentioned0.5 mANot givenNot given1010/104106100Not Given
Pt/Al2O3/Nb:SrTiO3 [89]No resistive switching behavior
Pt/Al2O3/TiN [90]2.5 × 10−3 μm2Yes, 7 V, <10 μA, no ICCPtAl2O3TiNBipolar+3 V/−2 V<300 μA/300 μA<1 mA8 V/−4 V10 ns/10 ns106/1031031,000Not given
Ni/Al2O3/Pt [90]104 μm2Yes, 5 V, 500 μANiAl2O3PtBipolar+1.2 V/−0.45 V to −0.6 V500 μA/500 μA<2 mA1.5 V/−0.4 V to −0.58 V5 ms/5 ms2.8 × 103 to 2.2 × 103/4706 to 4.7100103 s
Cu/Al2O3/TiO2 [25]0.02–340 μm2Yes, 1 to 5V, no Icc (self-compliance), Imax<0.1 mACuAl2O3Al2O3/TiO2 2DEGbipolar+3 V/−5 V<0.1 mA/no ICC (self-compliance)<0.1 mANot given500–800 ns1011/105106107106 (@85°C)
Cu/Al2O3/Pt [92]3.14 × 104 μm2 (⌀ = 200 μm)Yes, 8 V, 200 μACuAl2O3Ptbipolar0.3–1.2 V/-0.1 V to −0.7 V150 μA/150 μA<0.1 mANot givenNot given109/1031062000105
Cu/Ti/Al2O3/Pt [93]0.05 μm2 (via hole ⌀ = 0.25 μm)Yes, 1.1 V, 200 μACu/TiAl2O3Ptbipolar0.3–0.7 V/−0.1 V to −0.3 V200 μA/200 μA∼0.1 mANot givenNot given109/104105Not given104
Pt/WOx/W [96]2 × 10−3 μm2No, Forming freePtWOxWbipolar1 V/−1 V4 mA/no ICC<0.2 mA+1.25 V/-1 V5 μs/5 μs106/104102107Not Given
IrOx/Al2O3/TiOx/TiN [97]0.24 μm2Yes, 7.5–20 V, 100 μAIrOxAl2O3 (2–8 nm)/TiOxTiNbipolar3.5–5.4 V/−3 V100 μA/100 μA<15 μA+3 V−5.5 V/-3 V500 μs/10 ms4 × 106 to 107/0.4 × 106 to 1.2 × 10610.8 to 21.62105 to 106Not Given
TiN/Ti/TiO2-x/TiO2-y/Au [98]104 μm2No, Forming freeTiN/TiTiO2-x/TiO2-yAubipolar3 V/−3 V<0.1 mA/No ICC (self-compliance)<0.1 μA+8 V/−8 V10 ms/10 ms8 × 108 to 4 × 1010/6 × 105 to 5 × 1082 to 3.6 × 103Not GivenNot Given
Ru/TiO2−x/HfO2/Ru [99]104 μm2Yes, 4–4.5 V, 5 mARuTiO2−x/HfO2Rubipolar2 V/−1.5 V5 mA/5 mA<5 mANot givenNot given103/10210104105
Ni/GeO/SrTiO3/TaN [100]11304 μm2Not givenNiGeO/SrTiO3TaNbipolar−0.3 V to −1.2 V/0.13–0.3 V3.5 μA/No ICC (self-compliance)0.12 nA−1.5 V/0.5 V50 ns/50 ns1012/1061061064 × 105 (@85°C)

Comparison of device performances.

We consider the progress made with the All-ALD 2DEGs [25, 33] to be a defining point. The All-ALD 2DEGs have liberated 2DEGs from small and expensive single-crystal substrates and from costly high-temperature fabrication processes. 2DEGs are now being fabricated by ALD on many substrates while keeping a low thermal budget and using low-cost, highly scalable, mature, and microelectronics-compatible techniques. The use of anatase TiO2 provides another advantage of a potentially more conductive 2DEG compared to the LaAlO3/SrTiO3 interface at room temperature [64] and offers tunability of the conductivity [32, 33]. Higher conductivity of the 2DEG is desirable in RRAM applications because the resistance of the bottom electrode is in series with the resistive switching layer, making lower resistance beneficial for stabilizing the resistive switching behavior, and for reducing the operating power. These issues become more important when considering integrating devices into a crossbar structure.

Challenges

The 2DEGs based RRAM devices reported so far are all single device demonstrations. Integration of the 2DEGs based RRAM devices into a crossbar array or 3D vertical structures poses an open challenge, which requires several issues to be addressed. Due to their high series resistance, the relatively high sheet resistance of many 2DEGs (typically >104 Ω/□) makes it challenging to utilize 2DEGs as thin line bottom electrodes. Beyond increasing the operating voltage (and power), this series resistance of the bottom electrode could further cause a significant spatial distribution of operation voltages across a crossbar array. As such, it remains an important task to reduce the 2DEG resistivity and design new device structures for high-density RRAM integration. Another facet of these challenges is microfabrication: 2DEGs, particularly those driven by defects, can be challenging to pattern efficiently [101103]. Robust fabrication techniques need to be designed to produce the small features necessary for high-density RRAM arrays. In addition, further flexibility in the tuning of the 2DEG resistivity would provide an advantage for device and array optimization, which would further benefit from a deeper understanding of the 2DEGs-based RRAM switching mechanisms.

Opportunities

As discussed earlier, 2DEGs-based RRAMs can feature large, potentially tunable OFF/ON resistance ratios. These provide prospects of low power operation, allow additional “room” for efficient multi-level resistance states, and provide additional design flexibility and tunability compared to some of the current devices. The 2DEGs-based VCM devices so far all showed abrupt switching processes, resulting in binary resistance states. Further development of these devices into multi-level capabilities will provide considerable functionality benefits. Since 2DEGs are successfully applied as the channel of transistors [15, 16, 19, 32]. This opens routes for integrating both the memory and the peripheral circuits within the same material system and even within the same lithography process steps. This is also a very attractive feature for RRAM devices in crossbar arrays since the crossbar structured RRAM devices require selectors to select different rows and columns.

Statements

Author contributions

All authors discussed and designed the structure and scope of the mini-review, which was written by YL. All authors read and commented on the text.

Acknowledgments

YL and LK acknowledge the support of the Israeli Science Foundation (ISF Grant 375/17). YL acknowledges the support from a Technion Fellowship. The authors acknowledge discussions with Wei Wang and his inputs to the manuscript.

Conflict of interest

The authors declare that the research was conducted in the absence of any commercial or financial relationships that could be construed as a potential conflict of interest.

Publisher’s note

All claims expressed in this article are solely those of the authors and do not necessarily represent those of their affiliated organizations, or those of the publisher, the editors, and the reviewers. Any product that may be evaluated in this article, or claim that may be made by its manufacturer, is not guaranteed or endorsed by the publisher.

References

  • 1.

    OhtomoAHwangHY. A High-Mobility Electron Gas at the LaAlO3/SrTiO3 Heterointerface. Nature (2004) 427:4236. 10.1038/nature02308

  • 2.

    ReyrenNThielSCavigliaADKourkoutisLFHammerlGRichterCet alSuperconducting Interfaces between Insulating Oxides. Science (2007) 317:11969. 10.1126/science.1146006

  • 3.

    GariglioSReyrenNCavigliaADTrisconeJ-M. Superconductivity at the LaAlO3/SrTiO3 interface. J Phys Condens Matter (2009) 21:1642132. 10.1088/0953-8984/21/16/164213

  • 4.

    HanY-LShenS-CYouJLiH-OLuoZ-ZLiC-Jet alTwo-dimensional Superconductivity at (110) LaAlO3/SrTiO3 Interfaces. Appl Phys Lett (2014) 105:1926038. 10.1063/1.4901940

  • 5.

    MonteiroAMRVLGroenendijkDJGroenIDe BruijckereJGaudenziRVan Der ZantHSJet alTwo-dimensional Superconductivity at the (111) LaAlO3/SrTiO3 Interface. Phys Rev B (2017) 96:14. 10.1103/PhysRevB.96.020504

  • 6.

    BrinkmanAHuijbenMVan ZalkMHuijbenJZeitlerUMaanJCet alMagnetic Effects at the Interface between Non-magnetic Oxides. Nat Mater (2007) 6:4936. 10.1038/nmat1931

  • 7.

    BertJAKaliskyBBellCKimMHikitaYHwangHYet alDirect Imaging of the Coexistence of Ferromagnetism and Superconductivity at the LaAlO3/SrTiO3 Interface. Nat Phys (2011) 7:76771. 10.1038/nphys2079

  • 8.

    WeiL-y.LianCMengS. Prediction of Two-Dimensional Electron Gas Mediated Magnetoelectric Coupling at Ferroelectric PbTiO3/SrTiO3 Heterostructures. Phys Rev B (2017) 95:38. 10.1103/PhysRevB.95.184102

  • 9.

    SunWWangWChenDChengZJiaTWangY. Giant Magnetoelectric Coupling and Two-Dimensional Electron Gas Regulated by Polarization in BiFeO3/LaFeO3 Heterostructures. J Phys Chem C (2019) 123:163939. 10.1021/acs.jpcc.9b04499

  • 10.

    LiangHChengLWeiLLuoZYuGZengCet alNonmonotonically Tunable Rashba Spin-Orbit Coupling by Multiple-Band Filling Control in SrTiO3-Based Interfaciald-Electron Gases. Phys Rev B (2015) 92:17. 10.1103/PhysRevB.92.075309

  • 11.

    TebanoAFabbriEPergolesiDBalestrinoGTraversaE. Room-Temperature Giant Persistent Photoconductivity in SrTiO3/LaAlO3 Heterostructures. ACS Nano (2012) 6:127883. 10.1021/nn203991q

  • 12.

    TarunMCSelimFAMcCluskeyMD. Persistent Photoconductivity in Strontium Titanate. Phys Rev Lett (2013) 111:15. 10.1103/PhysRevLett.111.187403

  • 13.

    TsukazakiAOhtomoAKitaTOhnoYOhnoHKawasakiM. Quantum Hall Effect in Polar Oxide Heterostructures. Science (2007) 315:138891. 10.1126/science.1137430

  • 14.

    TsukazakiAAkasakaSNakaharaKOhnoYOhnoHMaryenkoDet alObservation of the Fractional Quantum Hall Effect in an Oxide. Nat Mater (2010) 9:88993. 10.1038/nmat2874

  • 15.

    KornblumL. Conductive Oxide Interfaces for Field Effect Devices. Adv Mater Inter (2019) 6:1900480. 10.1002/admi.201900480

  • 16.

    MoonTLeeHJHyunSDKimBSKimHHHwangCS. Origin of the Threshold Voltage Shift in a Transistor with a 2D Electron Gas Channel at the Al2O3/SrTiO3 Interface. Adv Electron Mater (2020) 6:19012868. 10.1002/aelm.201901286

  • 17.

    LeeHJMoonTHyunSDKangSHwangCS. Characterization of a 2D Electron Gas at the Interface of Atomic‐Layer Deposited Al2O3/ZnO Thin Films for a Field‐Effect Transistor. Adv Electron Mater (2021) 7:20008768. 10.1002/aelm.202000876

  • 18.

    JanyRRichterCWoltmannCPfanzeltGFörgBRommelMet alMonolithically Integrated Circuits from Functional Oxides. Adv Mater Inter (2014) 1:1300031. 10.1002/admi.201300031

  • 19.

    FörgBRichterCMannhartJ. Field-effect Devices Utilizing LaAlO3-SrTiO3 Interfaces. Appl Phys Lett (2012) 100:053506. 10.1063/1.3682102

  • 20.

    MoonTJungHJKimYJParkMHKimHJKimKDet alResearch Update: Diode Performance of the Pt/Al2O3/two-Dimensional Electron gas/SrTiO3 Structure and its Time-dependent Resistance Evolution. APL Mater (2017) 5:042301. 10.1063/1.4967280

  • 21.

    KimSMKimHJJungHJParkJYSeokTJChoaYHet alHigh‐Performance, Transparent Thin Film Hydrogen Gas Sensor Using 2D Electron Gas at Interface of Oxide Thin Film Heterostructure Grown by Atomic Layer Deposition. Adv Funct Mater (2019) 29:1807760. 10.1002/adfm.201807760

  • 22.

    NoëlPTrierFVicente ArcheLMBréhinJVazDCGarciaVet alNon-volatile Electric Control of Spin-Charge Conversion in a SrTiO3 Rashba System. Nature (2020) 580:4836. 10.1038/s41586-020-2197-9

  • 23.

    VarignonJVilaLBarthélémyABibesM. A New Spin for Oxide Interfaces. Nat Phys (2018) 14:3225. 10.1038/s41567-018-0112-1

  • 24.

    MironDCohen-AzarzarDHofferBBaskinMKvatinskySYalonEet alOxide 2D Electron Gases as a Reservoir of Defects for Resistive Switching. Appl Phys Lett (2020) 116:223503. 10.1063/5.0003590

  • 25.

    KimSMKimHJJungHJKimSHParkJ-YSeokTJet alHighly Uniform Resistive Switching Performances Using Two-Dimensional Electron Gas at a Thin-Film Heterostructure for Conductive Bridge Random Access Memory. ACS Appl Mater Inter (2019) 11:3002836. 10.1021/acsami.9b08941

  • 26.

    WuSLuoXTurnerSPengHLinWDingJet alNonvolatile Resistive Switching in Pt/LaAlO3/SrTiO3 Heterostructures. Phys Rev X (2013) 3:041027. 10.1103/PhysRevX.3.041027

  • 27.

    JoungJGKimS-IMoonSYKimD-HGwonHJHongS-Het alNonvolatile Resistance Switching on Two-Dimensional Electron Gas. ACS Appl Mater Inter (2014) 6:1778591. 10.1021/am504354c

  • 28.

    WuSRenLQingJYuFYangKYangMet alBipolar Resistance Switching in Transparent ITO/LaAlO3/SrTiO3 Memristors. ACS Appl Mater Inter (2014) 6:85759. 10.1021/am501387w

  • 29.

    GaoZHuangXLiPWangLWeiLZhangWet alReversible Resistance Switching of 2D Electron Gas at LaAlO3/SrTiO3 Heterointerface. Adv Mater Inter (2018) 5:17015658. 10.1002/admi.201701565

  • 30.

    ChenYPrydsNKleibeukerJEKosterGSunJStamateEet alMetallic and Insulating Interfaces of Amorphous SrTiO3-Based Oxide Heterostructures. Nano Lett (2011) 11:37748. 10.1021/nl201821j

  • 31.

    MoonSYMoonCWChangHJKimTKangC-YChoiH-Jet alThermal Stability of 2DEG at Amorphous LaAlO3/crystalline SrTiO3 Heterointerfaces. Nano Convergence (2016) 3:16. 10.1186/s40580-016-0067-9

  • 32.

    SeokTJLiuYJungHJKimSBKimDHKimSMet alField-Effect Device Using Quasi-Two-Dimensional Electron Gas in Mass-Producible Atomic-Layer-Deposited Al2O3/TiO2 Ultrathin (<10 Nm) Film Heterostructures. ACS Nano (2018) 12:104039. 10.1021/acsnano.8b05891

  • 33.

    SeokTJLiuYChoiJHKimHJKimDHKimSMet alIn Situ Observation of Two-Dimensional Electron Gas Creation at the Interface of an Atomic Layer-Deposited Al2O3/TiO2 Thin-Film Heterostructure. Chem Mater (2020) 32:76629. 10.1021/acs.chemmater.0c01572

  • 34.

    WaserRDittmannRStaikovGSzotKStaikovCSzotK. Redox-Based Resistive Switching Memories - Nanoionic Mechanisms, Prospects, and Challenges. Adv Mater (2009) 21:263263. 10.1002/adma.200900375

  • 35.

    YangJJStrukovDBStewartDR. Memristive Devices for Computing. Nat Nanotech (2013) 8:1324. 10.1038/nnano.2012.240

  • 36.

    WongH-SPLeeH-YYuSChenY-SWuYChenP-Set alMetal-oxide RRAM. Proc IEEE (2012) 100:195170. 10.1109/JPROC.2012.2190369

  • 37.

    LeeSRKimY-BChangMKimKMLeeCBHurJHParkG-SLeeDLeeM-JKimCJet alMulti-level Switching of Triple-Layered TaOx RRAM with Excellent Reliability for Storage Class Memory In: Symposium on VLSI Technology (VLSIT). Honolulu, HI, USA: IEEE (2012) p. 712. 10.1109/VLSIT.2012.6242466

  • 38.

    HsuC-WWangI-TLoC-LChiangMJangWLinC-HHouT-H. Self-Rectifying Bipolar TaOx/TiO2 RRAM with Superior Endurance over 1012 Cycles for 3D High-Density Storage-Class Memory In: Symposium on VLSI Circuits (VLSI). Kyoto, Japan: IEEE (2013). p. T166T167.

  • 39.

    XiaQYangJJ. Memristive Crossbar Arrays for Brain-Inspired Computing. Nat Mater (2019) 18:30923. 10.1038/s41563-019-0291-x

  • 40.

    DittmannRStrachanJP. Redox-based Memristive Devices for New Computing Paradigm. APL Mater (2019) 7:110903. 10.1063/1.5129101

  • 41.

    SunZPedrettiGAmbrosiEBricalliAWangWIelminiD. Solving Matrix Equations in One Step with Cross-point Resistive Arrays. Proc Natl Acad Sci USA (2019) 116:41238. 10.1073/pnas.1815682116

  • 42.

    WangWSongWYaoPLiYVan NostrandJQiuQet alIntegration and Co-design of Memristive Devices and Algorithms for Artificial Intelligence. iScience (2020) 23:101809. 10.1016/j.isci.2020.101809

  • 43.

    IelminiDAmbrogioS. Emerging Neuromorphic Devices. Nanotechnology (2020) 31:092001. 10.1088/1361-6528/ab554b

  • 44.

    ZidanMAStrachanJPLuWD. The Future of Electronics Based on Memristive Systems. Nat Electron (2018) 1:229. 10.1038/s41928-017-0006-8

  • 45.

    KvatinskySBelousovDLimanSSatatGWaldNFriedmanEGet alMAGIC-Memristor-Aided Logic. IEEE Trans Circuits Syst (2014) 61:8959. 10.1109/TCSII.2014.2357292

  • 46.

    ChristensenDVDittmannRLinares-BarrancoBSebastianAGalloMLRedaelliAet alRoadmap on Neuromorphic Computing and Engineering, arXiv Prepr (2021).

  • 47.

    PaiY-YTylan-TylerAIrvinPLevyJ. Physics of SrTiO3-Based Heterostructures and Nanostructures: a Review. Rep Prog Phys (2018) 81:036503. 10.1088/1361-6633/aa892d

  • 48.

    LiuZAnnadiAAriando. Two-Dimensional Electron Gas at LaAlO3/SrTiO3 Interfaces. In: YiJLiS, editors. Functional Materials and Electronics. Apple Academic Press (2018) p. 3595. 10.1201/9781315167367

  • 49.

    PrydsNEspositoV. When Two Become One: An Insight into 2D Conductive Oxide Interfaces. J Electroceram (2017) 38:123. 10.1007/s10832-016-0051-0

  • 50.

    MoetakefPCainTAOuelletteDGZhangJYKlenovDOJanottiAet alElectrostatic Carrier Doping of GdTiO3/SrTiO3 Interfaces. Appl Phys Lett (2011) 99:232116. 10.1063/1.3669402

  • 51.

    XuPAyinoYChengCPribiagVSComesRBSushkoPVet alPredictive Control over Charge Density in the Two-Dimensional Electron Gas at the Polar-Nonpolar NdTiO3/SrTiO3 Interface. Phys Rev Lett (2016) 117:106083. 10.1103/PhysRevLett.117.106803

  • 52.

    NakagawaNHwangHYMullerDA. Why Some Interfaces Cannot Be Sharp. Nat Mater (2006) 5:2049. 10.1038/nmat1569

  • 53.

    MannhartJSchlomDG. Oxide Interfaces-An Opportunity for Electronics. Science (2010) 327:160711. 10.1126/science.1181862

  • 54.

    SchlomDGMannhartJ. Interface Takes Charge over Si. Nat Mater (2011) 10:1689. 10.1038/nmat2965

  • 55.

    NazirSYangK. First-Principles Characterization of the Critical Thickness for Forming Metallic States in Strained LaAlO3/SrTiO3(001) Heterostructure. ACS Appl Mater Inter (2014) 6:223518. 10.1021/am506336w

  • 56.

    MannhartJBlankDHAHwangHYMillisAJTrisconeJ-M. Two-Dimensional Electron Gases at Oxide Interfaces. MRS Bull (2008) 33:102734. 10.1557/mrs2008.222

  • 57.

    RoseMASmidBVorokhtaMSlipukhinaIAndraMBluhmHet alIdentifying Ionic and Electronic Charge Transfer at Oxide Heterointerfaces. Adv Mater Interfaces (2020) 33:2004132. 10.1002/adma.202004132

  • 58.

    WillmottPRPauliSAHergerRSchlepützCMMartocciaDPattersonBDet alStructural Basis for the Conducting Interface between LaAlO3 and SrTiO3. Phys Rev Lett (2007) 99:14. 10.1103/PhysRevLett.99.155502

  • 59.

    ShenJLeeHValentíRJeschkeHO. Ab Initiostudy of the Two-Dimensional Metallic State at the Surface of SrTiO3: Importance of Oxygen Vacancies. Phys Rev B (2012) 86:195119. 10.1103/PhysRevB.86.195119

  • 60.

    LiuZQSunLHuangZLiCJZengSWHanKet alDominant Role of Oxygen Vacancies in Electrical Properties of Unannealed LaAlO3/SrTiO3 Interfaces. J Appl Phys (2014) 115:054303. 10.1063/1.4863800

  • 61.

    LiuZQLiCJWMHuangXHHuangZZengSWet alOrigin of the Two-Dimensional Electron Gas at LaAlO3/SrTiO3 Interfaces: The Role of Oxygen Vacancies and Electronic Reconstruction. Phys Rev X (2013) 3:021010. 10.1103/PhysRevX.3.021010

  • 62.

    LiYWeiXYuJ. Inevitable High Density of Oxygen Vacancies at the Surface of Polar-Nonpolar Perovskite Heterostructures LaAlO3/SrTiO3. J Appl Phys (2020) 127:205302. 10.1063/1.5128080

  • 63.

    YuLZungerA. A Polarity-Induced Defect Mechanism for Conductivity and Magnetism at Polar-Nonpolar Oxide Interfaces. Nat Commun (2014) 5:19. 10.1038/ncomms6118

  • 64.

    ZhangYGanYNiuWNorrmanKYanXChristensenDVet alTuning the Two-Dimensional Electron Gas at Oxide Interfaces with Ti-O Configurations: Evidence from X-ray Photoelectron Spectroscopy. ACS Appl Mater Inter (2018) 10:14349. 10.1021/acsami.7b16510

  • 65.

    MauroCBaroneCDi GennaroESambriAGuarinoAGranozioFMet alPhotoconductivity in 2D Electron Gases at the Amorphous-LGO/STO Oxide Interface: a Dynamical Analysis. Eur Phys J Spec Top (2019) 228:67581. 10.1140/epjst/e2019-800168-y

  • 66.

    ShibuyaKOhnishiTLippmaaMOshimaM. Metallic Conductivity at the CaHfO3∕SrTiO3 Interface. Appl Phys Lett (2007) 91:2321068. 10.1063/1.2816907

  • 67.

    LeeSWLiuYHeoJGordonRG. Creation and Control of Two-Dimensional Electron Gas Using Al-Based Amorphous Oxides/SrTiO3 Heterostructures Grown by Atomic Layer Deposition. Nano Lett (2012) 12:477583. 10.1021/nl302214x

  • 68.

    LeeSWHeoJGordonRG. Origin of the Self-Limited Electron Densities at Al2O3/SrTiO3 Heterostructures Grown by Atomic Layer Deposition - Oxygen Diffusion Model. Nanoscale (2013) 5:89404. 10.1039/c3nr03082b

  • 69.

    LeeHJMoonTAnCHHwangCS. 2D Electron Gas at the Interface of Atomic-Layer-Deposited Al2O3/TiO2 on SrTiO3 Single Crystal Substrate. Adv Electron Mater (2019) 5:1800527. 10.1002/aelm.201800527

  • 70.

    KumahDPNgaiJHKornblumL. Epitaxial Oxides on Semiconductors: From Fundamentals to New Devices. Adv Funct Mater (2020) 30:1901597. 10.1002/adfm.201901597

  • 71.

    KornblumLJinENShoronOBoucheritMRajanSAhnCHet alElectronic Transport of Titanate Heterostructures and Their Potential as Channels on (001) Si. J Appl Phys (2015) 118:105301. 10.1063/1.4930140

  • 72.

    ParkJWBogorinDFCenCFelkerDAZhangYNelsonCTet alCreation of a Two-Dimensional Electron Gas at an Oxide Interface on Silicon. Nat Commun (2010) 1:17. 10.1038/ncomms1096

  • 73.

    EdmondsonBILiuSLuSWuHPosadasASmithDJet alEffect of SrTiO3 Oxygen Vacancies on the Conductivity of LaTiO3/SrTiO3 Heterostructures. J Appl Phys (2018) 124:185303. 10.1063/1.5046081

  • 74.

    KornblumLFaucherJMorales-AcostaMDLeeMLAhnCHWalkerFJ. Oxide Heterostructures for High Density 2D Electron Gases on GaAs. J Appl Phys (2018) 123:025302. 10.1063/1.5004576

  • 75.

    ZhangLEngel-HerbertR. Growth of SrTiO3on Si(001) by Hybrid Molecular Beam Epitaxy. Phys Status Solidi RRL (2014) 8:91723. 10.1002/pssr.201409383

  • 76.

    ChenJ-YHuangC-WChiuC-HHuangY-TWuW-W. Switching Kinetic of VCM-Based Memristor: Evolution and Positioning of Nanofilament. Adv Mater (2015) 27:502833. 10.1002/adma.201502758

  • 77.

    PiSLiCJiangHXiaWXinHYangJJet alMemristor Crossbar Arrays with 6-nm Half-Pitch and 2-nm Critical Dimension. Nat Nanotech (2018) 14:359. 10.1038/s41565-018-0302-0

  • 78.

    MaXWuHWuDQianH. A 16 Mb RRAM Test Chip Based on Analog Power System with Tunable Write Pulses In: 15th Non-Volatile Memory Technology Symposium (NVMTS). Piscataway, NJ: IEEE (2015) p. 13. 10.1109/NVMTS.2015.7457478

  • 79.

    YuSLiZChenP-YWuHGaoBWangDWuWQianH. Binary Neural Network with 16 Mb RRAM Macro Chip for Classification and Online Training In: IEEE International Electron Devices Meeting (IEDM), Piscataway, NJ: IEEE (2016) 162. 10.1109/IEDM.2016.7838429

  • 80.

    HsuCWanCWangIChenMLoCLeeYet al3D Vertical TaOx/TiO2 RRAM with over 103 Self-Rectifying Ratio and Sub-μa Operating Current. IEDM Tech Dig - Int Electron Devices Meet (2013) 2:2647. 10.1109/IEDM.2013.6724601

  • 81.

    HsiehM-CLiaoY-CChinY-WLienC-HChangT-SChihY-Det alUltra High Density 3D via RRAM in Pure 28nm CMOS Process. Tech Dig - Int Electron Devices Meet IEDM (2013) 1:2603. 10.1109/IEDM.2013.6724600

  • 82.

    YuSGaoBFangZYuHKangJWongH-SP. A Neuromorphic Visual System Using RRAM Synaptic Devices with Sub-pJ Energy and Tolerance to Variability: Experimental Characterization and Large-Scale Modeling In: International electron devices meeting (IEMD). Piscataway, NJ: IEEE (2012) p. 104. 10.1109/LED.2012.221085610.1109/iedm.2012.6479018

  • 83.

    TorrezanACStrachanJPMedeiros-RibeiroGWilliamsRS. Sub-nanosecond Switching of a Tantalum Oxide Memristor. Nanotechnology (2011) 22:485203. 10.1088/0957-4484/22/48/485203

  • 84.

    ValovIWaserRJamesonJRKozickiMN. Electrochemical Metallization Memories-Fundamentals, Applications, Prospects. Nanotechnology (2011) 22:289502. 10.1088/0957-4484/22/28/289502

  • 85.

    YangYLuWD. Progress in the Characterizations and Understanding of Conducting Filaments in Resistive Switching Devices. IEEE Trans Nanotechnology (2016) 15:46572. 10.1109/TNANO.2016.2544782

  • 86.

    YangYGaoPGabaSChangTPanXLuW. Observation of Conducting Filament Growth in Nanoscale Resistive Memories. Nat Commun (2012) 3:7328. 10.1038/ncomms1737

  • 87.

    WuSXPengHYWuT. Concurrent Nonvolatile Resistance and Capacitance Switching in LaAlO3. Appl Phys Lett (2011) 98:093503. 10.1063/1.3560257

  • 88.

    WeiZKanzawaYAritaKKatohYKawaiKMuraokaSet alHighly Reliable TaOx ReRAM and Direct Evidence of Redox Reaction Mechanism. IEEE Int Electron Devices Meet (2008) 14. 10.1109/IEDM.2008.4796676

  • 89.

    MironDKrylovIBaskinMYalonEKornblumL. Understanding Leakage Currents through Al2O3 on SrTiO3. J Appl Phys (2019) 126:185301. 10.1063/1.5119703

  • 90.

    WuYYuSLeeBWongP. Low-power TiN/Al2O3/Pt Resistive Switching Device with Sub-20 μA Switching Current and Gradual Resistance Modulation. J Appl Phys (2011) 110:094104. 10.1063/1.3657938

  • 91.

    SarkarBLeeBMisraV. Understanding the Gradual Reset in Pt/Al2O3/Ni RRAM for Synaptic Applications. Semicond Sci Technol (2015) 30:105014. 10.1088/0268-1242/30/10/105014

  • 92.

    SuCShanLYangDZhaoYFuYLiuJet alMicroelectronic Engineering Effects of Heavy Ion Irradiation on Cu/Al2O3/Pt CBRAM Devices. Microelectron Eng (2021) 247:111600. 10.1016/j.mee.2021.111600

  • 93.

    AttarimashalkoubehBPrakashALeeSSongJWooJMishaSHet alEffects of Ti Buffer Layer on Retention and Electrical Characteristics of Cu-Based Conductive-Bridge Random Access Memory (CBRAM). ECS Solid State Lett (2014) 3:P120P122. 10.1149/2.0031410ssl

  • 94.

    WuYYuSWongHSPChenYSLeeHYWangSMGuPYChenFTsaiMJ. AlOx-based Resistive Switching Device with Gradual Resistance Modulation for Neuromorphic Device Application. 2012 4th IEEE International Memory Workshop, Milan, Italy: IEEE (2012) p. 14. 10.1109/IMW.2012.6213663

  • 95.

    LiuKTzengWChangKHuangJLeeYYehPet alInvestigation of the Effect of Different Oxygen Partial Pressure to LaAlO3 Thin Film Properties and Resistive Switching Characteristics. Thin Solid Films (2011) 520:124650. 10.1016/j.tsf.2011.04.205

  • 96.

    KimSBijuKPJoMJungSParkJLeeJet alEffect of Scaling WOx-Based RRAMs on Their Resistive Switching Characteristics. IEEE Electron Device Lett (2011) 32:6713. 10.1109/LED.2011.2114320

  • 97.

    WritamBXiaoxinXHangbingLQiLShibingLMingL. Variability Improvement of TiOx/Al2O3 Bilayer Nonvolatile Resistive Switching Devices by Interfacial Band Engineering with an Ultrathin Al2O3 Dielectric Material. ACS OMEGA (2017) 2:688895. 10.1021/acsomega.7b01211

  • 98.

    BousoulasPAsenovPKarageorgiouISakellaropoulosDStathopoulosSTsoukalasD. Engineering Amorphous-Crystalline Interfaces in TiO2-x/TiO2-Y-Based Bilayer Structures for Enhanced Resistive Switching and Synaptic Properties. J Appl Phys (2019) 120:154501. 10.1063/1.4964872

  • 99.

    BrandenLYiboLRashmiJ. Switching Characteristics of Ru/HfO2/TiO2-x/Ru RRAM Devices for Digital and Analog Nonvolatile Memory Applications. IEEE Electron Device Lett (2012) 33:7068. 10.1109/LED.2012.2188775

  • 100.

    ChengCHAlbertCYehFS. Novel Ultra-low Power RRAM with Good Endurance and Retention. Dig Tech Pap - Symp VLSI Technol (2010) 856. 10.1109/VLSIT.2010.5556180

  • 101.

    SchneiderCWThielSHammerlGRichterCMannhartJ. Microlithography of Electron Gases Formed at Interfaces in Oxide Heterostructures. Appl Phys Lett (2006) 89:122101. 10.1063/1.2354422

  • 102.

    BanerjeeNHuijbenMKosterGRijndersG. Direct Patterning of Functional Interfaces in Oxide Heterostructures. Appl Phys Lett (2012) 100:041601. 10.1063/1.3679379

  • 103.

    AndersVBMerlin vonSRicciERasmus TindalDYuZYulinGet alNanoscale Patterning of Electronic Devices at the Amorphous LaAlO3/SrTiO3 Oxide Interface Using an Electron Sensitive Polymer Mask. Appl Phys Lett (2018) 112:171606. 10.1063/1.5026362

Summary

Keywords

oxide interfaces, resistive random-access memories, device physics, oxide electronics, oxide electronic devices

Citation

Li Y, Kvatinsky S and Kornblum L (2021) Harnessing Conductive Oxide Interfaces for Resistive Random-Access Memories. Front. Phys. 9:772238. doi: 10.3389/fphy.2021.772238

Received

07 September 2021

Accepted

11 October 2021

Published

27 October 2021

Volume

9 - 2021

Edited by

Ayan Roy Chaudhuri, Indian Institute of Technology Kharagpur, India

Reviewed by

Writam Banerjee, Pohang University of Science and Technology, South Korea

Nagarajan Raghavan, Singapore University of Technology and Design, Singapore

Amit Prakash, Crossbar inc., United States

Updates

Copyright

*Correspondence: Yang Li, ; Lior Kornblum,

This article was submitted to Interdisciplinary Physics, a section of the journal Frontiers in Physics

Disclaimer

All claims expressed in this article are solely those of the authors and do not necessarily represent those of their affiliated organizations, or those of the publisher, the editors and the reviewers. Any product that may be evaluated in this article or claim that may be made by its manufacturer is not guaranteed or endorsed by the publisher.

Outline

Figures

Cite article

Copy to clipboard


Export citation file


Share article

Article metrics